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At least 685 records · Page 38

Development and Implementation of Environmentally Compatible Solid Film Lubricants

Multi-body launch vehicles require the use of Solid Film Lubricants (SFLs) to allow for unrestricted relative motion between structural assemblies and components during lift off and ascent into orbit. The Space Shuttle Solid Rocket Booster (SRB), uses a dual coat, ceramic-bonded high temperature SFL in several locations such as restraint hardware between the SRB aft skirt and the Mobile Launch Platform (MLP), the aft SRB/External Tank (ET) attach struts, and the forward skirt SRB/ET attach ball assembly. The proposed National Launch System (NLS) may require similar applications of SFLs for attachment and restraint hardware. A family of environmentally compatible nonlead/antimony bearing alternative SFLs have been developed including a compatible repair material. In addition, commercial applications for SFLs on transportation equipment, all types of lubricated fasteners, and energy related equipment allow for wide usage of these new lubricants. The new SFLs named BOOSTERLUBE is a family of single layer thin film (0.001 inch maximum) coatings that are a unique mixture of non-hazardous pigments in a compatible resin system that allows for low temperature curing (450 F). Significant savings in energy and processing time as well as elimination of hazardous material usage and disposal would result from the non-toxic onestep SFL application. Compatible air-dry field repair lubricants will help eliminate disassembly of launch vehicle restraint hardware during critical time sensitive assembly operations.

Novak, Howard L.↗

Understanding the Environmental and Climate Impacts of Biomass Burning in Northern Sub-Saharan Africa

The northern sub-Saharan African (NSSA) region, bounded on the north and south by the Sahara and the Equator, respectively, and stretching from the West to the East African coastlines, has one of the highest biomass-burning rates per unit land area among all regions of the world. Because of the high concentration and frequency of fires in this region, with the associated abundance of heat release and gaseous and particulate smoke emissions, biomass-burning activity is believed to be one of the drivers of the regional carbon and energy cycles, with serious implications for the water cycle. A new interdisciplinary research effort sponsored by NASA is presently being focused on the NSSA region, to better understand the possible connection between the intense biomass burning observed from satellite year after year across the region and the rapid depletion of the regional water resources, as exemplified by the dramatic drying of Lake Chad. A combination of remote sensing and modeling approaches is being utilized in investigating multiple regional surface, atmospheric, and water-cycle processes, and inferring possible links between them. In this presentation, we will discuss preliminary results as well as the path toward improved understanding'of the interrelationships and feedbacks between the biomass burning and the environmental change dynamics in the NSSA region.

Ichoku, Charles↗

Interactions and Feedbacks Between Biomass Burning and Water Cycle Dynamics Across the Northern Sub-Saharan African Region

The northern sub-Saharan African (NSSA) region, bounded on the north and south by the Sahara and the Equator, respectively, and stretching from the West to the East African coastlines, has one of the highest biomass-burning rates per unit land area among all regions of the world. Because of the high concentration and frequency of fires in this region, with the associated abundance of heat release and gaseous and particulate smoke emissions, biomass-burning activity is believed to be one of the drivers of the regional carbon and energy cycles, with serious implications for the water cycle. A new interdisciplinary research effort sponsored by NASA is presently being focused on the NSSA region, to better understand the possible connection between the intense biomass burning observed from satellite year after year across the region and the rapid depletion of the regional water resources, as exemplified by the dramatic drying of Lake Chad. A combination of remote sensing and modeling approaches is being utilized in investigating multiple regional surface, atmospheric, and water-cycle processes, and inferring possible links between them. In this presentation, we will discuss preliminary results as well as the path toward improved understanding of the interrelationships and feedbacks between the biomass burning and the environmental change dynamics in the NSSA region.

Ichoku, Charles↗

Spaceborne Applications of P-Band Imaging Radars for Measuring Forest Biomass

In three test sites of boreal and temperate forests, P-band polarimetric radar data estimate total above-ground dry woody biomass with 10 to 30 of the actual biomass values, depending on the complexity of the forest. A description and examples of the process are provided. The worldwide need for large scale, updated biomass estimates, achieved with a uniformly applied method, justifies a more in-depth exploration of long wavelength imaging radar applications for tropical forest inventories.

Oren, Ram↗

Scaleup and Site-Specific Engineering Design for Global Thermostat Direct Air Capture Technology

The overall goal of the project is completion of an initial design of a commercial-scale, Carbon Capture, Utilization, and Storage Direct Air Capture (CCUS-DAC) plant design at three different sites that captures a net of at least 100,000 tonnes per year (TPY) carbon dioxide (CO 2 ) from the atmosphere and considers compression and conditioning of the captured CO 2 for purpose of pipeline transportation to different geological formation sites for deep well injection and underground storage. In addition to the leading system consisting of a scaled-up Global Thermostat DAC unit, overall plant design includes a combined Heat and Power (CHP) unit integrated with a conventional liquid amine-based carbon capture system (90% capture) and compression facilities. These are considered balance of plant (BOP) systems and are required to provide low carbon-intensity steam and power to the DAC process. A second approach involving provision of DAC units modified to directly capture emissions from the CHP unit was initially assessed as an alternative and it was determined to be less mature than considered approach and not included in the scaled-up plant design efforts. Three geographically diverse continental United States locations were selected to better understand the effect of local/regional ambient conditions on scaled-up DAC system performance and project costs: Bucks, Alabama (hot wet climate), Odessa, Texas (dry hot climate), and Goose Creek, Illinois (mid continental climate). The team focused on initial engineering design activities, including the development of project design criteria, initiation of site-specific studies and investigations, completion of DAC system process and equipment design, and definition of balance of plant (BOP) engineering. The purpose of the activities were to develop Technoeconomic Analysis (TEA), Life-Cycle Analysis (LCA), and Environmental, Health, and Safety (EH&S) analysis, and Business Case Analysis (BCA) to validate that the project engineering and scale-up plans of the DAC systems, at each of the three distinct case studies considered, are technically, economically, and environmentally feasible for commercial-scale operation.

20 FOSSIL-FUELED POWER PLANTS↗

Winter wheat: A model for the simulation of growth and yield in winter wheat

The basic ideas and constructs for a general physical/physiological process level winter wheat simulation model are documented. It is a materials balance model which calculates daily increments of photosynthate production and respiratory losses in the crop canopy. The partitioning of the resulting dry matter to the active growing tissues in the plant each day, transpiration and the uptake of nitrogen from the soil profile are simulated. It incorporates the RHIZOS model which simulates, in two dimensions, the movement of water, roots, and soluble nutrients through the soil profile. It records the time of initiation of each of the plant organs. These phenological events are calculated from temperature functions with delays resulting from physiological stress. Stress is defined mathematically as an imbalance in the metabolite supply; demand ratio. Physiological stress is also the basis for the calculation of rates of tiller and floret abortion. Thus, tillering and head differentiation are modeled as the resulants of the two processes, morphogenesis and abortion, which may be occurring simulaneously.

Baker, D. N.↗

Improved Soil Moisture Estimation and Detection of Irrigation Signal By Incorporating SMAP Soil Moisture Into the Indian Land Data Assimilation System (ILDAS)

Land surface models have facilitated the estimation of soil moisture over a range of spatiotemporal scales. However, limitations in model parameterization and under-representation of anthropogenic processes restrict their ability to estimate local-scale soil moisture variability, especially over irrigated areas. Assimilation of satellite-based soil moisture retrievals into land surface models can be a viable approach to overcome these constraints, specially over highly irrigated countries such as India, where such applications are rare. Additionally, large-scale validation of modeled soil moisture has been limited over India till now due to lack of a representative station network. By assimilating Soil Moisture Active Passive (SMAP)-based estimates into the state-of-the-art Indian Land Data Assimilation System (ILDAS) and combining with a new soil moisture station network of more than 200 stations, this study demonstrates improved soil moisture estimations and capture of irrigation signals over the region. The Noah-MP land surface model is forced by multiple local and global meteorological datasets and Ensemble Kalman Filter (EnKF) is used for assimilation of soil moisture. Comparison of open-loop and data assimilated soil moisture against station soil moisture data shows relative spatial mean improvement of 0.0178 in correlation and 0.0029 m3/m3 in RMSE. Further statistical comparison with in-situ data has also shown better results over most of the stations, as evident from improved correlations and reduced unbiased RMSE after assimilation. Finally, the climatology of soil moisture over the different irrigation fractions reveals that data assimilated outputs over irrigated grid cells tend to have higher soil moisture during dry winter season, demonstrating the ability to capture irrigation signals. These findings quantify the value of data assimilation in improving soil moisture estimates and the ability to capture unmodeled processes such as irrigation, which lays the science groundwork for upcoming space missions such as NASA ISRO Synthetic Aperture Radar (NISAR).

Soil Moisture↗

Wetting and drying trends in the land–atmosphere reservoir of large basins around the world

Abstract. Global change is altering hydrologic regimes worldwide, including large basins that play a central role in the sustainability of human societies and ecosystems. The basin water budget is a fundamental framework for understanding these basins' sensitivity and future dynamics under changing forcings. In this budget, studies often treat atmospheric processes as external to the basin and assume that atmosphere-related water storage changes are negligible in the long term. These assumptions are potentially misleading in large basins with strong land–atmosphere feedbacks, including terrestrial moisture recycling, which is critical for global water distribution. Here, we introduce the land–atmosphere reservoir (LAR) concept, which includes atmospheric processes as a critical component of the basin water budget and use it to study long-term changes in the water storage of some of the world's largest basins. Our results show significant LAR water storage trends over the last 4 decades, with a marked latitudinal contrast: while low-latitude basins have accumulated water, high-latitude basins have been drying. If they continue, these trends will disrupt the discharge regime and compromise the sustainability of these basins, resulting in widespread impacts.

54 ENVIRONMENTAL SCIENCES↗

Hydrometeor Transport and the Stratiform Water Budget in Amazonian Mesoscale Convective Systems

A significant portion of precipitation falls within the stratiform regions of mesoscale convective systems (MCSs). These regions are formed from convective clouds that have either weakened and formed a horizontally stratified structure or have advected hydrometeors to form a trailing-stratiform region, with further precipitation growth promoted by in situ dynamical and microphysical processes. Green Ocean Amazon 2014/5 (GoAmazon2014/5) field campaign observations are used to quantify the stratiform water budget of six MCSs (three each from the wet and dry seasons) utilizing the framework from Leary and Houze, with an emphasis on the transfer of hydrometeors (C A ) from the convective to the stratiform regions. The storms were predominantly leading-line/trailing-stratiform MCSs, but two had embedded convection in the stratiform region, which can complicate water budget calculations. A pulse-like pattern with a mean interval of 21 min occurs in C A during each storm resulting from a lag between the initial convective updrafts and the subsequent hydrometeor transport and sedimentation in the stratiform region. Here, the peaks in C A were followed by peaks in hydrometeor growth associated with the mesoscale updraft (C mu ) in the stratiform region. Averaged over the six storms, the positive contributions of C A and C mu to the stratiform water budget were roughly equal, although storm-to-storm variations existed. Negative contributions from evaporation below cloud base in the mesoscale downdraft and detrainment from the stratiform region into the nonprecipitating anvil cloud and environment accounted for 53% and 21% of the sum of C A and C mu , respectively, resulting in a mean stratiform region precipitation efficiency of 26%.

54 ENVIRONMENTAL SCIENCES↗

Microwave Absorbing Perovskite Catalysts for Efficient Electrification of Syngas Production from CO2 and Methane

Microwave absorbing catalysts have the potential to make thermal reactions such as methane reforming (CH4 + CO2 + H2O → H2 + CO) into carbon negative processes when coupled with decarbonized electricity. Due to microwaves directly heating the catalyst rather than heating the reactor and gases, even high temperature reactions such as dry reforming methane (DRM, CH4 + CO2 → H2 + CO) can be achieved rapidly, efficiently, and on-demand, ideal for coupling with intermittent renewable electricity. However, microwave catalysts present unique design challenges due to the same material needing to both efficiently absorb microwaves in oxidative and reductive reaction conditions and be an efficient and stable catalyst in inherently non-isothermal reactors. We screened from over 28 catalysts in the La0.8Sr0.2(Co-Ni-Mn)O3 perovskite solid-solution family to determine promising microwave reforming catalysts and identify design principles for effective materials. The best performing catalyst candidate was able to produce syngas ratios (H2:CO) from 1-3, and scale up testing showed CO and H2 production efficiencies rivaling conventional carbon intensive steam reforming efficiencies at the liters per minute level of production.

Marin, Christopher↗

Domestic applications for aerospace waste and water management technologies

Some of the aerospace developments in solid waste disposal and water purification, which are applicable to specific domestic problems are explored. Also provided is an overview of the management techniques used in defining the need, in utilizing the available tools, and in synthesizing a solution. Specifically, several water recovery processes will be compared for domestic applicability. Examples are filtration, distillation, catalytic oxidation, reverse osmosis, and electrodialysis. Solid disposal methods will be discussed, including chemical treatment, drying, incineration, and wet oxidation. The latest developments in reducing household water requirements and some concepts for reusing water will be outlined.

Disanto, F.↗

Space Food

In planning for the long duration Apollo missions, NASA conducted extensive research into space food. One of the techniques developed was freeze drying. Action Products commercialized this technique, concentrating on snack food including the first freeze-dried ice cream. The foods are cooked, quickly frozen and then slowly heated in a vacuum chamber to remove the ice crystals formed by the freezing process. The final product retains 98 percent of its nutrition and weighs only 20 percent of its original weight. Action snacks are sold at museums, NASA facilities and are exported to a number of foreign countries. Sales run to several million dollars annually.

Source record↗

Optical-Quality Thin Polymer Membranes

A method of fabricating both curved and flat thin polymer membranes of optical quality has been developed. The method was originally intended to enable the fabrication of lightweight membrane imaging and interferometric optics, possibly with apertures multiple meters wide, for use in scientific instruments that would operate in outer space. The method may also be applicable to the fabrication of lightweight membrane optics for terrestrial use. The method involves flow-casting of a soluble polymer with mechanical and environmental controls that provide nearly ideal conditions for the formation of a membrane. The preferred environmental conditions and other details of the process depend on the choice of polymer and substrate material and on the shape and size of the membrane to be cast. Once the polymer has dried to a membrane, it is cured with convective heating, then released. Membranes with root-mean-square surface roughnesses of less than 10.5 can be produced routinely by this method. Variations in the thicknesses of the membranes have ranged from 1/3 wavelength down to as little as 1/20 wavelength (at a wavelength of 633 nm). Membranes fabricated thus far have had diameters up to 0.5 m, and there appears to be no major obstacle to scaling up to multiple-meter diameters.

Moore, James↗

An Automated Detection Methodology for Dry Well-Mixed Layers

The intense surface heating over arid land surfaces produces dry well-mixed layers (WML) via dry convection. These layers are characterized by nearly constant potential temperature and low, nearly constant water vapor mixing ratio. To further the study of dry WMLs, we created a detection methodology and supporting software to automate the identification and characterization of dry WMLs from multiple data sources including rawinsondes, remote sensing platforms, and model products. The software is a modular code written in Python, an open source language. Radiosondes from a network of synoptic stations in North Africa were used to develop and test the WML detection process. The detection involves an iterative decision tree that ingests a vertical profile from an input data file, performs a quality check for sufficient data density, and then searches upward through the column for successive points where the simultaneous changes in water vapor mixing ratio and potential temperature are less than the specified maxima. If points in the vertical profile meet the dry WML identification criteria, statistics are generated detailing the characteristics of each layer in the profile. At the end of the vertical profile analysis, there is an option to plot analyzed profiles in a variety of file formats. Initial results show that the detection methodology can be successfully applied across a wide variety of input data and North African environments and for all seasons. It is sensitive enough to identify dry WMLs from other types of isentropic phenomena such as subsidence layers and distinguish the current day’s dry WML from previous days.

Stephen D. Nicholls↗

High performance heat exchangers for next generation hybrid cooler (CRADA NFE-19-07891 Final Report)

The evaporative cooling process has been successfully deployed in multiple energy conversion processes such as power generation, process cooling, heating, ventilation & cooling (HVAC), and commercial and industrial refrigeration. The heat exchanger is a very common yet extremely critical component of such systems. The device is important since the performance of the overall cooling system heavily relies on the thermal-hydraulic efficiency of the heat exchanger. The possible wet operation as evaporative cooling heat exchanger complicates the issue. Indeed, based on the hybrid nature of operation (fully dry, partially wet, fully wet) the efficiency can vary significantly and can cause performance variation for the whole system. Understanding the importance of the issue, Oak Ridge National Laboratory (Contractor) and Baltimore Aircoil Company (Participant) propose an activity focused on the analysis of the existing heat exchanger technology used in air and evaporative cooling processes and design, development and demonstration of a novel heat exchanger design based on porous materials. The potential candidates include metallic wire meshes and metal foams carefully designed for the proposed application. Prior research has indicated that these materials have great potential for deployment in thermal systems, particularly heat sinks and heat exchangers. It is expected that the successful completion of the project will lead to novel heat exchanger technology for hybrid systems (capable of dry and wet operation) by exploring newly emerging materials and their potential for heat transfer application. The overall goal is to develop a next generation heat exchanger technology which can be deployed in evaporative cooling systems. The impact of the such development is significant since, it will not only make the overall system highly efficient but will also, reduce the total refrigerant charge in the heat exchanger, a critical aspect for the deployment of refrigerants with lower Global Warming Potential (GWP).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Production of Ultrafine, High-purity Ceramic Powders Using the US Bureau of Mines Developed Turbomill

Turbomilling, an innovative grinding technology developed by the U.S. Bureau of Mines in the early 1960's for delaminating filler-grade kaolinitic clays, has been expanded into the areas of particle size reduction, material mixing, and process reaction kinetics. The turbomill, originally called an attrition grinder, has been used for particle size reduction of many minerals, including natural and synthetic mica, pyrophyllite, talc, and marble. In recent years, an all-polymer version of the turbomill has been used to produce ultrafine, high-purity, advanced ceramic powders such as SiC, Si3N4, TiB2, and ZrO2. In addition to particle size reduction, the turbomill has been used to produce intimate mixtures of high surface area powders and whiskers. Raw materials, TiN, AlN, and Al2O3, used to produce a titanium nitride/aluminum oxynitride (TiN/AlON) composite, were mixed in the turbomill, resulting in strength increases over samples prepared by dry ball milling. Using the turbomill as a leach vessel, it was found that 90.4 pct of the copper was extracted from the chalcopyrite during a 4-hour leach test in ferric sulfate versus conventional processing which involves either roasting of the ore for Cu recovery or leaching of the ore for several days.

Hoyer, Jesse L.↗

Precision metering of microliter volumes of biological fluids in micro-gravity

Concepts were demonstrated and investigated for transferring accurately known and reproducible microliter volumes of biological fluids from sample container onto dry chemistry slides in microgravity environment. Specific liquid transfer tip designs were compared. Information was obtained for design of a liquid sample handling system to enable clinical chemical analysis in microgravity. Disposable pipet tips and pipet devices that were designed to transfer microliter volumes of biological fluid from a (test tube) sample container in 1-G environment were used during microgravity periods of parabolic trajectories of the KC-135 aircraft. The transfer process was recorded using charge coupled device camera and video cassette equipment. Metering behavior of water, a synthetic aqueous protein solution, and anticoagulated human blood was compared. Transfer of these liquids to 2 substrate materials representative of rapidly wettable and slowly wettable dry chemistry slide surface was compared.

Columbus, Richard L.↗

Automated Fiber Placement of Composite Wind Tunnel Blades: Process Planning and Manufacturing

The ability to accurately manufacture large complex shapes in a consistent and repeatable manner has led to Automated Fiber Placement (AFP) being the predominant mode of manufacturing for large composite aerospace structures today. Currently, AFP is being considered for medium- and small-scale parts. Composite wind tunnel blades have traditionally been fabricated by hand layup for pre-impregnated or dry fabrics with resin infusion. Though well proven, the traditional fabrication method is laborious and tedious, and hence expensive. The project described in this paper used the Integral Structural Assembly of Advanced Composites (ISAAC) facility at the NASA Langley Research Center to build a manufacturing demonstration unit (MDU) with a shape representative of a wind tunnel blade. This MDU is used to discuss tooling, process planning, and fabrication. Additionally, details of the generic manufacturing workflow are presented.

Harik, Ramy↗