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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Micro-Scale Regenerative Heat Exchanger

A micro-scale regenerative heat exchanger has been designed, optimized and fabricated for use in a micro-Stirling device. Novel design and fabrication techniques enabled the minimization of axial heat conduction losses and pressure drop, while maximizing thermal regenerative performance. The fabricated prototype is comprised of ten separate assembled layers of alternating metal-dielectric composite. Each layer is offset to minimize conduction losses and maximize heat transfer by boundary layer disruption. A grating pattern of 100 micron square non-contiguous flow passages were formed with a nominal 20 micron wall thickness, and an overall assembled ten-layer thickness of 900 microns. Application of the micro heat exchanger is envisioned in the areas of micro-refrigerators/coolers, micropower devices, and micro-fluidic devices.

Moran, Matthew E.↗

The Convolutional Multiple Whole Profile (CMWP) Fitting Method, a Global Optimization Procedure for Microstructure Determination

The analysis of line broadening in X-ray and neutron diffraction patterns using profile functions constructed on the basis of well-established physical principles and TEM observations of lattice defects has proven to be a powerful tool for characterizing microstructures in crystalline materials. These principles are applied in the convolutional multiple-whole-profile (CMWP) procedure to determine dislocation densities, crystallite size, stacking fault and twin boundary densities, and intergranular strains. The different lattice defect contributions to line broadening are separated by considering the hkl dependence of strain anisotropy, planar defect broadening and peak shifts, and the defect dependent profile shapes. The Levenberg–Marquardt (LM) peak fitting procedure can be used successfully to determine crystal defect types and densities as long as the diffraction patterns are relatively simple. However, in more complicated cases like hexagonal materials or multiple-phase patterns, using the LM procedure alone may cause uncertainties. Here, we extended the CMWP procedure by including a Monte Carlo statistical method where the LM and a Monte Carlo algorithm were combined in an alternating manner. The updated CMWP procedure eliminated uncertainties and provided global optimized parameters of the microstructure in good correlation with electron microscopy methods.

36 MATERIALS SCIENCE↗

Reversibility, pattern formation, and edge transport in active chiral and passive disk mixtures

In this study, we numerically examine mixtures of circularly moving and passive disks as a function of density and active orbit radius. For low or intermediate densities and/or small orbit radii, the system can organize into a reversible partially phase separated labyrinth state in which there are no collisions between disks, with the degree of phase separation increasing as the orbit radius increases. As a function of orbit radius, we find a divergence in the number of cycles required to reach a collision-free steady state at a critical radius, while above this radius, the system remains in a fluctuating liquid state. For high densities, the system can organize into a fully phase separated state that is mostly reversible, but collisions at the boundaries between the phases lead to a net transport of disks along the boundary edges in a direction determined by the chirality of the active disk orbits. We map the dynamic phases as a function of density and orbit radii and discuss the results in terms of the reversible-irreversible transition found in other periodically driven non-thermal systems. Finally, we also consider mixtures of circularly driven disks and ac driven disks where the ac drive is either in or out of phase with the circular motion and find a rich variety of pattern forming and reentrant disordered phases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Wind Tunnel Test of a Risk-Reduction Wing/Fuselage Model to Examine Juncture-Flow Phenomena

A wing/fuselage wind-tunnel model was tested in the Langley 14- by 22-foot Subsonic Wind Tunnel in preparation for a highly-instrumented Juncture Flow Experiment to be conducted in the same facility. This test, which was sponsored by the NASA Transformational Tool and Technologies Project, is part of a comprehensive set of experimental and computational research activities to develop revolutionary, physics-based aeronautics analysis and design capability. The objectives of this particular test were to examine the surface and off-body flow on a generic wing/body combination to: 1) choose a final wing for a future, highly instrumented model, 2) use the results to facilitate unsteady pressure sensor placement on the model, 3) determine the area to be surveyed with an embedded laser-doppler velocimetry (LDV) system, 4) investigate the primary juncture corner- flow separation region using particle image velocimetry (PIV) to see if the particle seeding is adequately entrained and to examine the structure in the separated region, and 5) to determine the similarity of observed flow features with those predicted by computational fluid dynamics (CFD). This report documents the results of the above experiment that specifically address the first three goals. Multiple wing configurations were tested at a chord Reynolds number of 2.4 million. Flow patterns on the surface of the wings and in the region of the wing/fuselage juncture were examined using oil- flow visualization and infrared thermography. A limited number of unsteady pressure sensors on the fuselage around the wing leading and trailing edges were used to identify any dynamic effects of the horseshoe vortex on the flow field. The area of separated flow in the wing/fuselage juncture near the wing trailing edge was observed for all wing configurations at various angles of attack. All of the test objectives were met. The staff of the 14- by 22-foot Subsonic Wind Tunnel provided outstanding support and delivered exceptional value to the experiment, which exceeded expectations. The results of this test will directly inform the planning for the first of a series of instrumented-model tests at the same Reynolds number. These tests will be performed on a slightly larger-scale model with the selected wing, and will include off-body measurements with LDV and PIV, steady and unsteady pressure measurements, and the flow-visualization techniques that are discussed in this report.

Kegerise, Michael A.↗

Separating the Influences of Low-Latitude Warming and Sea Ice Loss on Northern Hemisphere Climate Change

Abstract Analyzing a multimodel ensemble of coupled climate model simulations forced with Arctic sea ice loss using a two-parameter pattern-scaling technique to remove the cross-coupling between low- and high-latitude responses, the sensitivity to high-latitude sea ice loss is isolated and contrasted to the sensitivity to low-latitude warming. Despite some differences in experimental design, the Northern Hemisphere near-surface atmospheric sensitivity to sea ice loss is found to be robust across models in the cold season; however, a larger intermodel spread is found at the surface in boreal summer, and in the free tropospheric circulation. In contrast, the sensitivity to low-latitude warming is most robust in the free troposphere and in the warm season, with more intermodel spread in the surface ocean and surface heat flux over the Northern Hemisphere. The robust signals associated with sea ice loss include upward turbulent and longwave heat fluxes where sea ice is lost, warming and freshening of the Arctic Ocean, warming of the eastern North Pacific Ocean relative to the western North Pacific with upward turbulent heat fluxes in the Kuroshio Extension, and salinification of the shallow shelf seas of the Arctic Ocean alongside freshening in the subpolar North Atlantic Ocean. In contrast, the robust signals associated with low-latitude warming include intensified ocean warming and upward latent heat fluxes near the western boundary currents, freshening of the Pacific Ocean, salinification of the North Atlantic, and downward sensible and longwave fluxes over the ocean.

54 ENVIRONMENTAL SCIENCES↗

First Ever Polymer Flood Field Pilot To Enhance The Recovery Of Heavy Oils On Alaska’s North Slope - Pushing Ahead One Year Later

In June 2018 the team embarked on an ambitious project to address the slow development pace of Alaska’s 20+ billion barrels heavy oil resource via the first ever polymer flood pilot. Following the successful commencement of the pilot in August 2018, the field demonstration, supporting laboratory experiments and numerical simulation have steadily progressed. A significant amount of valuable data and lessons learned have been collected, and are reported in this paper. The ongoing pilot and the research activities is making headway toward the primary objective of validating the use of polymer flooding for extracting heavy oil in Alaska’s challenging environment. The pilot is conducted in two pre-existing pairs of horizontal injectors and producers in an isolated fault block of the Schrader Bluff heavy oil reservoir at the Milne Point Field. A customized polymer blending and pumping unit injects HPAM polymer at a concentration of 1,750 ppm to achieve a target viscosity of 45 cP. Supporting coreflood laboratory experiments have focused on quantification of polymer retention in the rock, and effect of injection water salinity, polymer, and their combinations on oil recovery. The injection and production response of the pilot flood pattern is utilized to develop a history matched reservoir simulation model for forecasting oil recovery beyond the pilot. Finally, specially designed laboratory experiments address anticipated operating concerns regarding post-polymer breakthrough such as oil-water separation efficiency and polymer induced fouling of heater tubes. Polymer has been injected continuously since startup except for two short equipment modification shutdowns, and more recently a prolonged disruption due to polymer hydration issues at the J-pad field site. Cumulatively, over 600,000 lbs. of polymer has been injected, corresponding to ~7%PV. The two producers show significant decrease in the water cut, gradually increasing oil rate, and no polymer breakthrough. Two main observations from the coreflood are a significant uncertainty in polymer retention values, and positive oil recovery response to low salinity water (2,600 mg/liter TDS). The heterogeneity in the flood pattern presents some challenges in obtaining a robust history matched simulation model. Experimental results on produced fluids treatment indicate the formation of a dense polymer deposit, at certain conditions, on heating tubes that can negatively impact the heat transfer efficiency. The scientific knowledge, including the lessons learned during unanticipated shutdowns, quality control, logistics and field data that is being acquired from this effort has referential value for other planned EOR projects. Finally, by all indications, the polymer field pilot is steadily progressing toward achieving the ultimate goal of unlocking the massive heavy oil resources on Alaska North Slope (ANS).

Dandekar, Abhijit↗

Pattern formation and flocking for particles near the jamming transition on resource gradient substrates

Here, we numerically examine a bidisperse system of active and passive particles coupled to a resource substrate. The active particles deplete the resource at a fixed rate and move toward regions with higher resources, while all of the particles interact sterically with each other. We show that at high densities, this system exhibits a rich variety of pattern-forming phases along with directed motion or flocking as a function of the relative rates of resource absorption and consumption as well as the active to passive particle ratio. These include partial phase separation into rivers of active particles flowing through passive clusters, strongly phase separated states where the active particles induce crystallization of the passive particles, mixed jammed states, and fluctuating mixed fluid phases. For higher resource recovery rates, we demonstrate that the active particles can undergo motility-induced phase separation, while at high densities, there can be a coherent flock containing only active particles or a solid mixture of active and passive particles. The directed flocking motion typically shows a transient in which the flow switches among different directions before settling into one direction, and there is a critical density below which flocking does not occur. We map out the different phases as function of system density, resource absorption and recovery rates, and the ratio of active to passive particles.

97 MATHEMATICS AND COMPUTING↗

Cohesive finite element modeling of the delamination of HTPB binder and HMX crystals under tensile loading

Accurately modeling the mechanical behavior of the polymer binders and the degradation of interfaces between binder and crystal is important to science-based understanding of the macro-scale response of polymer bonded explosives. The paper presents a description of relatively a simple bi-crystal HMX-HTPB specimen and associated tensile loading experiment including computed tomography imaging, the pertinent constitutive theory, and details of numerical simulations used to infer the behavior of the material during the delamination process. Within this work, mechanical testing and direct numerical simulation of this relatively simple bi-crystal system enabled reasonable isolation of binder-crystal interface delamination, in which the effects of the complicated thermomechanical response of explosive crystals were minimized. Cohesive finite element modeling of the degradation and delamination of the interface between a modified HTPB binder and HMX crystals was used to reproduce observed results from tensile loading experiments on bi-crystal specimens. Several comparisons are made with experimental measurements in order to identify appropriate constitutive behavior of the binder and appropriate parameters for the cohesive traction-separation behavior of the crystal-binder interface. This research demonstrates the utility of directly modeling the delamination between binder and crystal within crystal-binder-crystal tensile specimen towards characterizing the behavior of these interfaces in a manner amenable to larger scale simulation of polycrystalline PBX materials. One critical aspect of this approach is micro computed tomography imaging conducted during the experiments, which enabled comparison of delamination patterns between the direct numerical simulation and actual specimen. In addition to optimizing the cohesive interface parameters, one important finding from this investigation is that understanding and representing the strain-hardening plasticity of HTPB binder is important within the context of using a cohesive traction-separation model for the delamination of a crystal-binder system.

42 ENGINEERING↗

Mechanism of zeolite X crystallization from diatomite

Highlights: • The intermediate species of zeolite X appears on the surface of solid particles. • The β cages build up the intermediate species, which was consist of four-membered rings (4R) and six-membered rings (6R). • The double six-membered ring (D6R) played a critical role for the crystallization process. • The β cages interconnect via double six-membered rings to form the framework of zeolite X. - Abstract: Here we systemically investigated the crystallization process of zeolite X using diatomite, a natural cost-effective silica precursor by the hydrothermal method. To decipher the mechanism, solids were separated from the mixtures at various stages of crystallization and were characterized by XRD, SEM, solid state NMR, FT-IR, UV-Raman and XRF. The XRD patterns revealed that the crystallization started between 3 and 3.5 h and ended by 5 h. The SEM images showed that the intermediate species of zeolite X appear on the surface of particles. The FT-IR and UV-Raman spectra suggested the presence of double six-membered rings (D6R) in the framework of zeolite X and they played a critical role in the crystallization process. Furthermore, the UV-Raman spectra indicated that the secondary building units of β cages formed the intermediate species and they were interconnected via double six-membered rings to form the framework of zeolite X.

36 MATERIALS SCIENCE↗

Improving CLM5.0 Biomass and Carbon Exchange Across the Western United States Using a Data Assimilation System

The Western United States is dominated by natural lands that play a critical role for carbon balance, water quality, and timber reserves. This region is also particularly vulnerable to forest mortality from drought, insect attack, and wildfires, thus requiring constant monitoring to assess ecosystem health. Carbon monitoring techniques are challenged by the complex mountainous terrain, thus there is an opportunity for data assimilation systems that combine land surface models and satellite-derived observations to provide improved carbon monitoring. Here, we use the Data Assimilation Research Testbed to adjust the Community Land Model (CLM5.0) with remotely sensed observations of leaf area and above-ground biomass. The adjusted simulation significantly reduced the above-ground biomass and leaf area, leading to a reduction in both photosynthesis and respiration fluxes. The reduction in the carbon fluxes mostly offset, thus both the adjusted and free simulation projected a weak carbon sink to the land. This result differed from a separate observation-constrained model (FLUXCOM) that projected strong carbon uptake to the land. Simulation diagnostics suggested water limitation had an important influence upon the magnitude and spatial pattern of carbon uptake through photosynthesis. We recommend that additional observations important for water cycling (e.g., snow water equivalent, land surface temperature) be included to improve the veracity of the spatial pattern in carbon uptake. Furthermore, the assimilation system should be enhanced to maximize the number of the simulated state variables that are adjusted, especially those related to the recommended observed quantities including water cycling and soil carbon.

54 ENVIRONMENTAL SCIENCES↗

Siderophore profiling of co-habitating soil bacteria by ultra-high resolution mass spectrometry

The chemical structure of organic molecules profoundly impacts their interactions with metal ions and mineral phases in soils. Understanding the sources and cycling of metal-chelating compounds is therefore essential for predicting the bioavailability and transport of metals throughout terrestrial environments. We investigate the molecular speciation of organic molecules that solubilize trace metals in calcareous soils from Eastern Washington. Ultra-high performance Fourier transform ion cyclotron resonance mass spectrometry at 21 Tesla enabled fast and confident detection and identification of metal chelators that are produced by microbes that inhabit these soils based on screening for features that match diagnostic metal isotope patterns. We compared two approaches, one based on direct infusion using the incorporation of a rare isotope to validate true iron-binding features, and another based on separation with liquid chromatography and detection of isotopologues with coherent elution profiles. While the isotopic exchange method requires significantly shorter analysis time, nearly twice as many features were observed with liquid chromatography mass spectrometry (LCMS), mostly due to the reduction in ion suppression where major features limit the sensitivity of minor features. In addition, LCMS enabled the collection of higher quality fragmentation spectra and facilitated feature identification. Siderophores belonging to four major classes were identified, including ferrioxamines, pseudobactins, enterobactins, and arthrobactins. Each of these siderophores likely derives from a unique member of the microbial community, and each possesses different chemical characteristics and uptake pathways, likely contributing to fierce competition for iron within these soils. Our results provide insight into the metabolic pathways by which microbes that co-inhabit calcareous soils compete for this essential micronutrient.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

From quantitative trait loci towards mechanisms: Linkage Integration Hypothesis Testing (LIgHT) sheds light on the mechanisms of genetically modulated stress tolerance

The goal of this work is to assess the mechanistic bases of natural genetic variations in plant responses of photosynthesis to stress. To achieve this goal, we devised the Linkage Integration Hypothesis Testing (LIgHT) approach, comparing chromosomal locations of quantitative trait loci (QTLs) for multiple phenotypes to distinguish between hypothetical mechanisms. As a use case, we explored genetic variations in photosynthesis-related processes under chilling stress in recombinant inbred lines of cowpea ( Vigna unguiculata L. Walp.). We focused on photosynthesis-related parameters measurable in high throughput and indicative of proposed chilling responses, including the states of PSI and PSII, photoprotective non-photochemical quenching, PSII photodamage, and nyctinastic leaf movements (NLMs). The patterns of QTL linkages indicated that chilling stress tolerance is genetically controlled by avoiding PSII photodamage rather than PSI damage or NLMs. This model was validated in a separate experiment measuring the rates of PSII photodamage and repair. Additional linkages suggest that chilling-induced damage to PSII is controlled by the thylakoid proton motive force and redox state of PSII. This regulation appears to be modulated by thylakoid fatty acid composition, previously associated with the same genetic loci and now supported by broader mechanistic evidence. We propose that the LIgHT approach can be broadly applied to test mechanisms underlying genetic variations.

MultispeQ↗

β -delayed neutron spectroscopy of Co 70 , 72 ground-state and isomeric-state decays

Here, the β-decaying states of 70,72 Co were studied at the National Superconducting Cyclotron Laboratory using the VANDLE neutron time-of-flight array. The (6 - ,7 - )⁢β-decaying state in 70 Co is near-spherical with a lifetime of 113 ± 7 ms, and the low-spin (1 + ,2 + )⁢β-decaying state is postulated to be the prolate deformed ground state with a lifetime of 508 ± 7 ms. Both decay predominantly to the bound states of 70 Ni. For the first time neutron-emissions from neutron unbound states from both the (6 - ,7 - ) and (1 + ,2 + )⁢β decays were measured. Even with the low statistics data, we were able to disentangle the neutron emission from both decays, which enabled a determination of β-decay strength above the neutron separation energy of 70 Ni. Neutron emission probabilities were measured to be 7.1 ± 1.5% and 9.4 ± 1.7%, respectively, for the (6 - ,7 - ) and (1 + ,2 + ) decays. The decay pattern of the 70 Co is driven by neutron f 5/2 to proton f 7/2 Gamow-Teller transformation. The observed population of neutron unbound states is attributed to the conversion of p 1/2 and p 3/2 neutrons to p 3/2 and p 1/2 protons excited across the Z = 28 closed shell.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Quantifying the Impact of Advanced Web Platforms on High Performance Computing Usage

The deployment of Science Gateways for High Performance Computing (HPC) systems can alter long-accepted usage patterns on supercomputing systems in positive ways as an ever-increasing number of users migrate their workflows to HPC systems. Idaho National Laboratory (INL) has deployed two separate advanced web platforms, Open OnDemand and NICE DCV, for integration with HPC resources to improve web accessibility for HPC users. Researchers conducted a multi-year study on how HPC usage pat- terns changed in the presence of these platforms. This work reports the results of that study and quantifies the observed impacts, including adoption by visualization and Jupyter Notebook/Lab users, decreased job submission friction, rapid uptake of HPC by Windows users, and increased overall system utilization. The most significant impacts were observed from the deployment of Open OnDemand, and this work also identifies some best practices for Open OnDemand deployment for HPC datacenters.

97 MATHEMATICS AND COMPUTING↗

Evidence for amino-acids of extraterrestrial origin in the Orgueil meteorite.

The problems of separation of contaminant from indigenous amino-acids in meteorites can be largely overcome by applying gas chromatographic techniques for the separation of D,L enantiomers of amino-acids as their diastereomeric derivatives and the identification of these compounds by gas chromatographic retention times and mass spectral fragmentation patterns. Two samples of Orgueil meteorite were examined. The results show that there are amino-acids indigenous to the Orgueil meteorite in addition to those present as contaminants.

Lawless, J. G.↗

On the occurrence of sympathetic flares

Random-coincidence formulas are applied to the data used in previous studies of alleged sympathetic flares to determine whether statistical evidence on the occurrence of such flares can be found for specific physically connected pairs of active regions. Only those active regions that are interconnected by magnetic loops in soft X-rays on Skylab photographs are considered to be physically connected. All pairs of flaring active regions (both interconnected and otherwise) observed on the sun during the Skylab flight are also evaluated. The only positive result is obtained with statistical confidence of 3.4 sigmas for pairs of active regions separated by no more than 30 deg. The occurrence of short time intervals between flares is shown to be increased for such active-region pairs, but the pattern of time intervals is found not to correspond with any propagation mode of a triggering agent in the solar atmosphere. It is suggested that some subphotospheric synchronization of activity in nearby plages and sunspot groups could increase the number of short time intervals between flares at different locations without any actual influence of one 'sympathetic' flare upon another, leading to the concept of 'sympathetic active regions' instead of 'sympathetic flares'.

Fritzova-Svestkova, L.↗

Design and test of a four channel motor for electromechanical flight control actuation

To provide a suitable electromagnetic torque summing approach to flight control system redundancy, a four channel motor capable of sustaining full performance after any two credible failures was designed, fabricated, and tested. The design consists of a single samarium cobalt permanent magnet rotor with four separate three phase windings arrayed in individual stator quadrants around the periphery. Trade studies established the sensitivities of weight and performance to such parameters as design speed, winding pattern, number of poles, magnet configuration, and strength. The motor electromagnetically sums the torque of the individual channels on a single rotor and eliminate complex mechanical gearing arrangements.

Source record↗

Jet vortex generators for turbulent flow separation control

A parametric study was performed with jet vortex generators to determine their effectiveness in controlling flow separation associated with low speed turbulent flow over a two dimensional rearward-facing ramp. Results indicate that flow separation control can be accomplished with the level of control achieved being a function of jet speed, jet orientation (with respect to the free stream direction), and orifice pattern (double row of jets vs. single row). Compared to slot blowing, jet vortex generators can provide an equivalent level of flow control over a larger spanwise region (for constant jet flow area and speed).

Selby, Gregory↗