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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

The CO2-Broadened H2O Continuum in the 100-1500 cm(sup -1) Region: Measurements, Predictions and Empirical Model

Transmission spectra of H2O+CO2 mixtures have been recorded, at 296, 325 and 366 K, for various pressures and mixture compositions using two experimental setups. Their analysis enables to retrieve values of the “continuum” absorption by the CO2-broadened H2O line wings between 100 and 1500 cm(exp -1). The results are in good agreement with those, around 1300 cm(exp -1), of the single previous experimental study available. Comparisons are also made with direct predictions based on line-shape correction factors X calculated, almost thirty years ago, using a quasistatic approach and an input H2O-CO2 intermolecular potential. They show that this model quite nicely predicts, with slightly overestimated values, the continuum over a spectral range where it varies by more than three orders of magnitude. An empirical correction is proposed, based on the experimental data, which should be useful for radiative transfer and climate studies in CO2 rich planetary atmospheres.

CO2↗

Experimental Reexamination of Transverse Tensile Strength for IM7/8552 Tape-Laminate Composites

Due to the observed dependence of transverse-tensile strength, YT, on test geometry and specimen size, there is no consensus regarding a test method that can uniquely measure YT. This study reexamines characterization of YT by comparing results from established flexure tests with results from a new tensile test that exhibits consistent failure in the gage region. Additionally, the effects of surface preparation and direction of transverse fracture are investigated. Results show that YT is inversely proportional to specimen volume and surface roughness, and is insensitive to direction of transverse fracture. The relationship between specimen volume and YT is adequately captured by Weibull strength-scaling theory, except at the tails of the YT distributions. However, specimens exhibited microcracking prior to failure, which violates the “weak-link” assumptions of the Weibull theory. These findings highlight the challenges of using deterministic YT values in progressive damage analysis.

Arndt, Caitlin M.↗

Hawaii Water Resources: Monitoring the Impact of Land-Based Sources of Pollution on Water Quality Along the Coast of West Maui, Hawai'i, to Assess Coral Reef Condition

West Maui is at risk of losing ecosystem services provided by coral reefs due to land-based sources of pollution (LBSP). In 2011, the US Coral Reef Task Force (USCRTF) identified the West Maui watershed as a priority watershed (along with its sub-watersheds of Wahikuli, Honokōwai, Kahana, Honokahua, and Honolua) after decades of coral decline, giving rise to the multi-agency West Maui Ridge to Reef (R2R) Initiative. The DEVELOP Hawai’i Water Resources team partnered with the R2R Initiative and the Hawai’i Department of Land and Natural Resources Division of Aquatic Resources (DLNR-DAR) to address the need for better watershed management practices. The team provided the partners with a Google Earth Engine tool that displays land use and land cover changes (LULCC) in the five watersheds and detects near-shore turbidity, chlorophyll-a (chl-a), and sea surface temperature using Landsat 4 Thematic Mapper (TM), Landsat 5 TM, Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), Terra Moderate Resolution Imaging Spectroradiometer (MODIS), and Aqua MODIS. Team members used ancillary data provided by the R2R Initiative and the USGS Pacific Coastal and Marine Science Center (PCMSC) to validate satellite parameter values. The land cover analysis captured a general trend of increasing impervious cover and decreasing vegetated cover from 1989 to 2019; however, the extent of this change varied between each watershed. This analysis, coupled with the tool, can help project partners continually monitor terrestrial and marine patterns associated with coral decline.

Water Resources↗

Electric Propulsion for the Psyche Mission: Development Activities and Status

NASA’s Psyche mission will launch in 2022 and begin a 3.6-year cruise to the metallic asteroid Psyche, where it will examine this unique body. The baseline spacecraft design is a hybrid of JPL’s deep-space heritage subsystems with commercial partner Maxar’s electric propulsion, power, and structure subsystems. All primary propulsion will be done with SPT-140 thrusters, which will be the first use of Hall thrusters for a NASA mission. The electric propulsion subsystem and its implementation for the Psyche mission are described here. Major testing activities have included the successful completion of subsystem integrated testing with the design modifications required for Psyche, and a series of low-power thrust repeatability tests that were performed in support of navigation analyses. Thruster performance models have been further validated with new SPT-140 flight data, and new analyses of thruster swirl torque have been performed that result in much higher values than previously estimated. Analysis of recent Maxar flight data has also provided a new understanding of in-flight propellant usage uncertainties. Subsystem integration and test activities are now underway and the status and plans are discussed.

Johnson, Ian↗

Testing the Gravitational Redshift With an Inner Solar System Probe: the Veritas Case

The NASA Discovery-class mission VERITAS, selected in June 2021, will be launched towards Venus after 2027. In addition to the science instrumentation that will build global foundational geophysical datasets, VERITAS proposed to conduct a technology demonstration for the Deep Space Atomic Clock (DSAC-2). A first DSAC successfully operated in low-Earth orbit for more than two years, demonstrated the trapped ion atomic clock technology, and established a new level of performance for clocks in space. DSAC-2 would have further improvements in size, power, and performance. It would host a 1× 10 -13 grade USO to produce a frequency output with short-term stability of less than 2× 10 -13 /√ τ (where τ is the averaging time).However, due to funding shortfalls, DSAC-2, had to be canceled. The initially foreseen presence of an atomic clock on board the probe, however, raised the question whether this kind of instrumentation could be useful not only for navigation and time transfer but also for fundamental physics tests. In this work, we consider the DSAC-2 atomic clock and VERITAS mission as a specific example to measure possible discrepancies in the redshift predicted by General Relativity by using an atomic clock onboard an interplanetary spacecraft. In particular we investigate the possibility of measuring possible violations of the Local Lorentz Invariance and Local Position Invariance principles. We perform accurate simulations of the experiment during the VERITAS cruise phase. We consider different parametrizations of the possible violations of the General Relativity, different operational conditions, and several different assumptions on the expected measurement performance. We show that DSAC-2 onboard VERITAS would provide new and improved constraints with respect to the current knowledge. Our analysis shows the scientific value of atomic clocks like DSAC-2 hosted onboard interplanetary spacecraft.

Fabrizio De Marchi↗

Boninites as Mercury Lava Analogues: Geochemical and Spectral Measurements from Pillow Lavas on Cyprus Island

In the absence of Mercurian rocks or meteorites in our collections, komatiites and boninites are often proposed as the best analog rocks to Mercury lavas. However, despite previous work on the possible analogy between komatiites and Mercury rocks, similar work has not been done for boninites. In this work, we investigate the whole-rock geochemistry and visible/near-infrared (VNIR) spectroscopy of boninitic material collected at three specific areas of the Troodos Massif (Cyprus island). The objective is to evaluate if collected boninites, these along with other boninites present in the literature, can be analogous to Mercury geochemical terranes. On average, we find an unusually high MgO/SiO 2 ratio (0.68) for the boninites from the Troodos Massif compared with previous boninite analysis. This MgO/SiO 2 value is most closely related to the high-Mg regions of Mercury, while the average Al 2 O 3 /SiO 2 ratio (0.25) is consistent with the Mercurian intermediate terrain and to the Mercury’s largest pyroclastic deposit. In addition, further affinity to the high-Mg regions and the intermediate terrains of Mercury are shown in regard to Si vs. Mg, Si vs. Ca, and Si vs. Fe content for one sample in particular. We then conduct magmatic modeling on this specific sample to provide a possible parental melt composition for analogue Mercurian magmas. In conclusion, we suggest these specific locations on the Troodos Massif in Cyprus as good geochemical analogue sites for the high-Mg regions of Mercury and explain how boninites could be important benchmark samples for the chemical and spectral data expected from the BepiColombo mission.

Boninites↗

Developing Satellite-Assisted Particulate Matter (SAPM) Estimates over India for the MIRA Working Group

The Models, In Situ, and Remote Sensing of Aerosols (MIRA) Working Group is an international collective that encourages collaboration among researchers from these three atmospheric aerosol communities. MIRA currently comprises five interdisciplinary and independently funded Topic Groups, each with specific goals, and involves requests for additional scientific datasets. The Satellite-Assisted Particulate Matter (SAPM) Topic Group, as part of MIRA, focuses on studying particulate matter smaller than 2.5 microns in diameter (PM2.5) due to its significant contribution to air pollution and its harmful effects on human health. While the annual mean PM2.5 levels are typically low (~5-15 μg/m³) across most of the contiguous United States (CONUS), other countries experience much higher concentrations (e.g., India). SAPM aims to compare different methods and techniques for obtaining surface PM2.5 proxies using spaceborne passive and active remote sensors, aerosol models, and in situ measurements. Ultimately, SAPM aims to provide more extensive coverage of PM2.5 concentrations than what is currently available from in situ ground stations, which are limited in some parts of the CONUS and large regions worldwide. Current SAPM members are exploring PM2.5 estimation techniques using active sensors. This presentation offers an overview of these techniques and highlights the strengths and limitations of each approach. These techniques include 1) spaceborne lidar (CALIOP: Cloud-Aerosol Lidar with Orthogonal Polarization) alone, and 2) a combination of spaceborne lidar (CATS: Cloud Aerosol Transport System) and a global aerosol transport model (GEOS: Goddard Earth Observing System). Additionally, we present a case study featuring our SAPM research in India, a country with high levels of PM2.5 concentrations (i.e., state-level annual means of ~100-200 μg/m³). Consistent spatial patterns in PM2.5 over India are found from the in situ data, CALIOP-based, and CATS/model-based methods, with the highest concentrations found in northern India near New Delhi. The gridded PM2.5 analysis yields high R values between in situ and CATS/model (~0.7) and between in situ and CALIOP nighttime (~0.9), as well as good agreement between CATS/model and CALIOP nighttime PM2.5 estimates (R = ~0.8 and slope = ~0.9). For current and future efforts, the SAPM Topic Group is actively seeking new collaborators, especially those working with in situ aerosol measurements, and is interested in acquiring additional aerosol datasets to improve and validate the PM2.5 proxies.

Travis D Toth↗

Fabrication and Characterization of A Lunar Simulant-Based Sintered Construction Material

In-situ resource utilization (ISRU) is critical to enable future efforts to have a long-term human presence on the Moon as well as Mars. ISRU technologies are being developed for radiation protection, dust mitigation, thermal insulation, and other applications. One such ISRU technology for creating construction materials out of lunar and Martian regolith is sintering, which is a thermal-based construction process that bonds finely grained material together at temperatures below the melting point. However, the conditions employed during the sintering, such as temperature, atmospheric composition, duration of the process, and pressure, can have a significant impact on the quality and strength of the resulting materials. In parallel, the development of methods for characterizing the quality, porosity, density, and other properties of these materials is critical. X-ray computed tomography (X-ray CT) can image large changes in density within a material, such as the presence of pores throughout an otherwise uniform medium, with relatively high spatial resolution. Similarly, Terahertz time-domain spectroscopic (THz-TDS) imaging is sensitive to density variations within samples, but is restricted to non-conducting materials. Specifically, previous work has shown that the refractive index (n eff ) values obtained through the analysis of THz-TDS images increases with increasing density within plastic samples. Even further, this work showed that it is possible to create a calibration curve for a given material from samples of different, but known density, which can enable one to directly convert n eff to density for samples having the same composition, but unknown density. Here, we report on the fabrication of a lunar simulant-based sintered construction material using vacuum hot pressed (VHP) sintering, then show X-ray CT and THz-TDS imaging results of the sample, which show spatial variations in the material. This has important implications for efforts to improve these types of lunar construction material processes and verify the quality of these materials in terms of consolidation. To the best of our knowledge, there is no previous work utilizing VHP sintering to make lunar simulant-based construction materials or exploring the feasibility of THz imaging to spatially map the density variation through a lunar simulant-based construction material.

Terahertz time-domain spectroscopic imaging↗

Learning Deep Neural Network Representations for Koopman Operators of Nonlinear Dynamical Systems

The Koopman operator has recently garnered much attention for its value in dynamical systems analysis and data-driven model discovery. However, its application has been hindered by the computational complexity of extended dynamic mode decomposition; this requires a combinatorially large basis set to adequately describe many nonlinear systems of interest, e.g. cyber-physical infrastructure systems, biological networks, social systems, and fluid dynamics. Often the dictionaries generated for these problems are manually curated, requiring domain-specific knowledge and painstaking tuning. In this paper we introduce a deep learning framework for learning Koopman operators of nonlinear dynamical systems. We show that this novel method automatically selects efficient deep dictionaries, outperforming state-of-the-art methods. We benchmark this method on partially observed nonlinear systems, including the glycolytic oscillator and show it is able to predict quantitatively 100 steps into the future, using only a single timepoint, and qualitative oscillatory behavior 400 steps into the future.

koopman operators, machine learning, deep learning↗

Atomic Layer Deposition (ALD) to Extend Catalyst Lifetime for Biobased Adipic Acid Production

Robust heterogeneous catalysts are essential for enabling biomass conversion; however, harsh reaction environments introduce durability challenges for many conventional catalyst materials [1]. The hydrogenation of biobased muconic acid to adipic acid is one such emerging chemistry that faces PGM catalyst stability challenges [2]. Muconic acid is a heavily-investigated biobased platform chemical that can be converted into an array of large-market commodity chemicals [2]. PGM catalysts are exceptionally effective for muconic acid hydrogenation to adipic acid, with Pd the most active to date. [2] However, Pd leaches in an acidic environment and this chemistry has a high propensity for fouling. Atomic layer deposition (ALD) is one such material design strategy that has emerged to stabilize supported metal catalysts [3]. ALD coatings are theorized to stabilize supported metal active sites by i) covering high-energy facets most susceptible to degradation, ii) disrupting the physical mobility of active sites, and iii) reinforcing the structure of the underlying catalyst support [3]. However, ALD coatings for catalyst durability with carboxylic acids remains an underdeveloped area of research and literature reports have yet to consider the techno-economic tradeoffs between the ALD manufacturing cost and catalyst lifetime productivity. This study examines low-cycle Al2O3 ALD coatings to stabilize Pd/TiO2 against deactivation during muconic acid hydrogenation. The unique harshness of muconic acid for Pd leaching was evaluated by both experiment and computation. Based on batch reactor screening results, uncoated and ALD coated catalysts were evaluated in a continuous flow reactor for their productivity, stability, and post-reaction regenerability at 700 degrees C. Characterization was performed to assess the impact of ALD coatings on catalyst morphology, as well as following regeneration. Finally, techno-economic analysis models evaluated the value proposition for ALD-coated catalysts within an nth-generation adipic acid biorefinery.

09 BIOMASS FUELS↗

Heavy metals and trace elements in the groundwater in El Paso, Texas

The chemical elements studied here (Al, As, Ba, Cd, Cr, Cu, Fe, Pb, Mn, Hg, Ni, Se, Ag, Zn, Li, B) include toxic heavy metals and non-toxic elements which have occurred at high levels in El Paso, TX groundwater (Fe, Cu, Mn, As, Pb; up to 24,000, 17,000, 3200, 95, and 1000 ppb respectively). The objective of this study is to investigate the origins of these heavy metals in the groundwater. Previous works found some of these metals in the rocks of the mountains that recharge the watershed, and sufficient evidence for natural origins of arsenic in the groundwater. Statistical analyses in this report are consistent with natural origin also for the heavy metals studied but cannot dismiss human activity as a contributing factor. Interesting correlations with R-value>0.60, p-value<0.01 warrant further analysis.

Marquez B, Elia↗

A comparison of airborne wake vortex detection measurements with values predicted from potential theory

An analysis of flight measurements made near a wake vortex was conducted to explore the feasibility of providing a pilot with useful wake avoidance information. The measurements were made with relatively low cost flow and motion sensors on a light airplane flying near the wake vortex of a turboprop airplane weighing approximately 90000 lbs. Algorithms were developed which removed the response of the airplane to control inputs from the total airplane response and produced parameters which were due solely to the flow field of the vortex. These parameters were compared with values predicted by potential theory. The results indicated that the presence of the vortex could be detected by a combination of parameters derived from the simple sensors. However, the location and strength of the vortex cannot be determined without additional and more accurate sensors.

Stewart, Eric C.↗

Comparing the OpenSolar Remote Shading Analysis Tool to On-Site Shading Measurements

OpenSolar is a free of charge application built for solar installers that creates a fully articulated 3D model of the site and performs remote shading analysis, in order to produce highly accurate designs and interactive, customizable proposals. Under the National Renewable Energy Laboratory (NREL) Commercialization Assistance Program (NCAP), NREL independently verified the accuracy of OpenSolar's remote analysis of solar access percentage values (SAVs) on an annual basis for locations in Los Angeles, CA, and Denver, CO. In aggregate, the results of the analysis show that Open Solar-calculated annual SAV measurements were statistically equivalent within ±2.63 SAVs for Los Angeles locations and ±2.69 SAVs for Denver locations compared to those of on-site measurements made with SunEye devices.

MATHEMATICS AND COMPUTING,SOLAR ENERGY↗

Efficiency and Output Power Sensitivity to Control Parameter Variations in an LCC-Series Wireless Power Transfer System

In wireless power transfer (WPT) systems, output power (Pout) can be controlled through input parameters such as, input voltage (Vin) , duty cycle (d) , and switching frequency (fsw) . The impact of these control parameters on the overall system efficiency has not been explored in previous studies. This paper focuses on the efficiency (η) and Pout sensitivity to these control parameter variations in an LCC-Series tuned WPT system. There are multiple combinations of Vin, d , and fsw that can achieve a specified target Pout . However, it is important to determine the optimal combination of these control variables that will yield the maximum η for a target Pout . A MATLAB/Simulink model is built to calculate and measure η and Pout . In order to achieve this result, several simulations are run where Vin,d , and fsw are swept across a wide range to cover all possible combinations. MATLAB's Sensitivity Analysis toolbox is used to evaluate how the parameters influence the model's output. Finally, an experimental prototype is implemented. The optimal values acquired using the sensitivity analysis is then plugged into the hardware prototype and compared with the simulation. The results obtained confirm the validity of the proposed method.

Harave, Sudarshan↗

Evaluation and Validation of the Messinger Freezing Fraction

One of the most important non-dimensional parameters used in ice-accretion modeling and scaling studies is the freezing fraction defined by the heat-balance analysis of Messinger. For fifty years this parameter has been used to indicate how rapidly freezing takes place when super-cooled water strikes a solid body. The value ranges from 0 (no freezing) to 1 (water freezes immediately on impact), and the magnitude has been shown to play a major role in determining the physical appearance of the accreted ice. Because of its importance to ice shape, this parameter and the physics underlying the expressions used to calculate it have been questioned from time to time. Until now, there has been no strong evidence either validating or casting doubt on the current expressions. This paper presents experimental measurements of the leading-edge thickness of a number of ice shapes for a variety of test conditions with nominal freezing fractions from 0.3 to 1.0. From these thickness measurements, experimental freezing fractions were calculated and compared with values found from the Messinger analysis as applied by Ruff. Within the experimental uncertainty of measuring the leading-edge thickness, agreement of the experimental and analytical freezing fraction was very good. It is also shown that values of analytical freezing fraction were entirely consistent with observed ice shapes at and near rime conditions: At an analytical freezing fraction of unity, experimental ice shapes displayed the classic rime shape, while for conditions producing analytical freezing fractions slightly lower than unity, glaze features started to appear.

Anderson, David N.↗

Single Degree-of-Freedom Modeling of SLS Liquid Hydrogen Pre-Valve Flow Guide to Enable Rapid Transient Analysis

A unique single degree-of-freedom approximation technique has been developed to enable rapid application of a temporally-defined multi-spectral semi-narrow-band loading for generation of realistic stress/cycle values compared to a resonant analysis. The technique uses the harmonic analysis at resonance of a high-fidelity finite element model to produce a transfer function, which is then used to calibrate the response of the SDOF model. A standard numerical ordinary differential equation solver is then used to obtain the temporal response, and its histogram is used in a fatigue/fracture model. This technique is related to other SDOF methods used widely in industry, such as Miles' Equation and the Shock Response Spectra, but it is unique in that it produces a realistic time history of the response. The most obvious error in the process, which is the effect of closely-spaced modes, was also assessed using the parallel application of several SDOF models, and the error is shown to be small. The application of this unique and tractable reduced-order methodology has enabled the SLS program to avoid substantial cost and schedule penalties if a redesign or change of material were required. It has also enabled quick analysis of a number of other structures undergoing the same or similar excitation fields, and quick assessment when the excitation and structural configuration has been altered due to design changes in the system.

Brown, Andrew M.↗

Sasaki's variational optimization analysis of temperature and moisture advection in a severe storm environment

Temperature and moisture advection patterns of dry air intrusion were analyzed by a variational optimization method to relate mesoscale advection to a severe thunderstorm environment. The analysis results presented here were obtained from a case study, May 26, 1973, when a tornado squall line developed in Oklahoma in conjunction with a clearly delineated dry air intrusion. Observations from the synoptic upper air network were used for inputs of horizontal wind components, potential temperature, and mixing ratio at each 50 mb increment from 950 to 100 mb. An objective analysis was performed to assign values of the variables to grid points of a 15 x 14 horizontal grid with approximate 125 km grid spacing at each pressure level. After the analysis the data fields were smoothed using a variational formalism.

Mcfarland, M. J.↗