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NASA NTRS2009

Space Environmental Effects on Materials and Processes

The Materials and Processes (M&P) Branch of the Structural Engineering Division at Johnson Space Center (JSC) seeks to uphold the production of dependable space hardware through materials research, which fits into NASA's purpose of advancing human exploration, use, and development of space. The Space Environmental Effects projects fully support these Agency goals. Two tasks were assigned to support M&P. Both assignments were to further the research of material behavior outside of Earth's atmosphere in order to determine which materials are most durable and safe to use in space for mitigating risks. One project, the Materials on International Space Station Experiments (MISSE) task, was to compile data from International Space Station (ISS) experiments to pinpoint beneficial space hardware. The other project was researching the effects on composite materials of exposure to high doses of radiation for a Lunar habitat project.

Sabbann, Leslie M.↗

NASA NTRS2016

Hemispherically Asymmetric Volcanic Forcing of Tropical Hydroclimate During the Last Millennium

Volcanic aerosols exert the most important natural radiative forcing of the last millennium. State-of-the-art paleoclimate simulations of this interval are typically forced with diverse spatial patterns of volcanic forcing, leading to different responses in tropical hydroclimate. Recently, theoretical considerations relating the intertropical convergence zone (ITCZ) position to the demands of global energy balance have emerged in the literature, allowing for a connection to be made between the paleoclimate simulations and recent developments in the understanding of ITCZ dynamics. These energetic considerations aid in explaining the well-known historical, paleoclimatic, and modeling evidence that the ITCZ migrates away from the hemisphere that is energetically deficient in response to asymmetric forcing. Here we use two separate general circulation model (GCM) suites of experiments for the last millennium to relate the ITCZ position to asymmetries in prescribed volcanic sulfate aerosols in the stratosphere and related asymmetric radiative forcing. We discuss the ITCZ shift in the context of atmospheric energetics and discuss the ramifications of transient ITCZ migrations for other sensitive indicators of changes in the tropical hydrologic cycle, including global streamflow. For the first time, we also offer insight into the large-scale fingerprint of water isotopologues in precipitation (delta sup 18 Op) in response to asymmetries in radiative forcing. The ITCZ shifts away from the hemisphere with greater volcanic forcing. Since the isotopic composition of precipitation in the ITCZ is relatively depleted compared to areas outside this zone, this meridional precipitation migration results in a large-scale enrichment (depletion) in the isotopic composition of tropical precipitation in regions the ITCZ moves away from (toward). Our results highlight the need for careful consideration of the spatial structure of volcanic forcing for interpreting volcanic signals in proxy records and therefore in evaluating the skill of Common Era climate model output.

Radiative forcing↗

NASA NTRS1974

Radiation damage and structure recorded at high resolution in grains from fine fractions of Luna 16 surface material

Samples returned to earth by Luna 16, were studied with a high voltage electron microscope for ultramicroscopic features. The following amazing features were noted in particles of surface material returned in all the lunar trips: A very high density of tracks of nuclear particles, ultrathin amorphous shells, highly rounded forms, and amazingly good ordering of crystal lattice. These features were used along with calibration experiments in solving the following problems: (1) determining the energy spectrum and chemical abundances of the very heavy nuclei in the solar wind and in the solar cosmic rays; (2) studying the past activity of the sun; (3) obtaining data on lunar dynamic processes affecting dust particles; (4) analyzing composite effects caused by penetration of solar wind into the lunar surface material; and (5) establishing the existence of the ancient lunar atmosphere and magnetic field.

Durrieu, L.↗

NASA NTRS1981

Atmospheric structure of the outer planets from thermal emission data

Methods for determining atmospheric structure exploit the opacities provided by the collision induced H2 dipole and the nu4 fundamental of CH4. In addition to earth-based observations, useful measurements of thermal emission from Jupiter and Saturn have been or soon will be made by several spacecraft, with results cross-checked with independent radio occultaion results. For Uranus and Neptune, only a limited set of whole-disk earth-based data exists. All the outer planets show evidence for stratospheric temperature inversions; temperature minima range from about 105 K for Jupiter and 87 K for Saturn, to roughly 55 K for Uranus and Neptune. Remaining problems may be resolved by better quantitative understanding of gas and aerosol absorption and scattering properties, chemical composition, and non-LTE source functions. Ultimately, temperature structure results must be supplemented by quantitative energy equilibrium models which will allow some meaning to be given to the relationships between such characteristics as temperature, clouds, incident solar and planetary radiation, and chemical composition.

Orton, G. S.↗

NASA NTRS2008

The GEOS Chemistry Climate Model: Implications of Climate Feedbacks on Ozone Depletion and Recovery

The Goddard Earth Observing System Chemistry Climate Model (GEOS CCM) has been developed by combining the atmospheric chemistry and transport modules developed over the years at Goddard and the GEOS general circulation model, also developed at Goddard. The first version of the model was used in the CCMVal intercomparison exercises that contributed to the 2006 WMO/UNEP Ozone Assessment. The second version incorporates the updated version of the GCM (GEOS 5) and will be used for the next round of CCMVal evaluations and the 2010 Ozone Assessment. The third version, now under development, incorporates the combined stratosphere and troposphere chemistry package developed under the Global Modeling Initiative (GMI). We will show comparison to past observations that indicate that we represent the ozone trends over the past 30 years. We will also show the basic temperature, composition, and dynamical structure of the simulations. We will further show projections into the future. We will show results from an ensemble of transient and time-slice simulations, including simulations with fixed 1960 chlorine, simulations with a best guess scenario (Al), and simulations with extremely high chlorine loadings. We will discuss planned extensions of the model to include emission-based boundary conditions for both anthropogenic and biogenic compounds.

Stolarski, Richard S.↗

NASA NTRS2002

Ground and Flight Test Structural Excitation Using Piezoelectric Actuators

A flight flutter experiment at the National Aeronautics and Space Administration (NASA) Dryden Flight Research Center, Edwards, California, used an 18-inch half-span composite model called the Aerostructures Test Wing (ATW). The ATW was mounted on a centerline flight test fixture on the NASA F-15B and used distributed piezoelectric strain actuators for in-flight structural excitation. The main focus of this paper is to investigate the performance of the piezoelectric actuators and test their ability to excite the first-bending and first-torsion modes of the ATW on the ground and in-flight. On the ground, wing response resulting from piezoelectric and impact excitation was recorded and compared. The comparison shows less than a 1-percent difference in modal frequency and a 3-percent increase in damping. A comparison of in-flight response resulting from piezoelectric excitation and atmospheric turbulence shows that the piezoelectric excitation consistently created an increased response in the wing throughout the flight envelope tested. The data also showed that to obtain a good correlation between the piezoelectric input and the wing accelerometer response, the input had to be nearly 3.5 times greater than the turbulence excitation on the wing.

Voracek, David F.↗

NASA NTRS1981

Photochemical processes induced by a major warming of the upper atmosphere - Variations in mesospheric trace constituents

The temperature rise and enhanced winds during an upper atmospheric warming cause substantial changes in the high level ozone profile of the sunlit winter hemisphere. Calculations based on a photochemical model, using temperatures measured at Fort Churchill during a major warming, predict a factor of 2 variation in the ozone number density near 60 km over a time period of approximately 3 weeks. This temporal variability at a fixed location results from the planetary wave structure of the temperature field and reflects a similar longitudinal behavior at a given time. The ozone number density at fixed altitude is a maximum when the temperature is greatest at and below this level. This is due primarily to thermal expansion of the atmosphere which results in a large increase in pressure at constant altitude. However, chemical activity during a warming decreases the mesospheric ozone mixing ratio at fixed pressure. The ozone mixing ratio at constant pressure during the peak of the event studied is near 75% of its unperturbed value. The predicted variability of ozone in longitude and time demonstrates the need for hemispheric scale information on trace gas abundances, temperature, and winds in order to delineate adequately the response of upper atmospheric composition to a major perturbation.

Frederick, J. E.↗

NASA NTRS2011

NASA Tech Briefs, June 2011

Topics covered include: Wind and Temperature Spectrometry of the Upper Atmosphere in Low-Earth Orbit; Health Monitor for Multitasking, Safety-Critical, Real-Time Software; Stereo Imaging Miniature Endoscope; Early Oscillation Detection Technique for Hybrid DC/DC Converters; Parallel Wavefront Analysis for a 4D Interferometer; Schottky Heterodyne Receivers With Full Waveguide Bandwidth; Carbon Nanofiber-Based, High-Frequency, High-Q, Miniaturized Mechanical Resonators; Ultracapacitor-Based Uninterrupted Power Supply System; Coaxial Cables for Martian Extreme Temperature Environments; Using Spare Logic Resources To Create Dynamic Test Points; Autonomous Coordination of Science Observations Using Multiple Spacecraft; Autonomous Phase Retrieval Calibration; EOS MLS Level 1B Data Processing Software, Version 3; Cassini Tour Atlas Automated Generation; Software Development Standard Processes (SDSP); Graphite Composite Panel Polishing Fixture; Material Gradients in Oxygen System Components Improve Safety; Ridge Waveguide Structures in Magnesium-Doped Lithium Niobate; Modifying Matrix Materials to Increase Wetting and Adhesion; Lightweight Magnetic Cooler With a Reversible Circulator; The Invasive Species Forecasting System; Method for Cleanly and Precisely Breaking Off a Rock Core Using a Radial Compressive Force; Praying Mantis Bending Core Breakoff and Retention Mechanism; Scoring Dawg Core Breakoff and Retention Mechanism; Rolling-Tooth Core Breakoff and Retention Mechanism; Vibration Isolation and Stabilization System for Spacecraft Exercise Treadmill Devices; Microgravity-Enhanced Stem Cell Selection; Diagnosis and Treatment of Neurological Disorders by Millimeter-Wave Stimulation; Passive Vaporizing Heat Sink; Remote Sensing and Quantization of Analog Sensors; Phase Retrieval for Radio Telescope and Antenna Control; Helium-Cooled Black Shroud for Subscale Cryogenic Testing; Receive Mode Analysis and Design of Microstrip Reflectarrays; and Chance-Constrained Guidance With Non-Convex Constraints.

Source record↗

NASA NTRS2013

Differential Muon Tomography to Continuously Monitor Changes in the Composition of Subsurface Fluids

Muon tomography has been used to seek hidden chambers in Egyptian pyramids and image subsurface features in volcanoes. It seemed likely that it could be used to image injected, supercritical carbon dioxide as it is emplaced in porous geological structures being used for carbon sequestration, and also to check on subsequent leakage. It should work equally well in any other application where there are two fluids of different densities, such as water and oil, or carbon dioxide and heavy oil in oil reservoirs. Continuous monitoring of movement of oil and/or flood fluid during enhanced oil recovery activities for managing injection is important for economic reasons. Checking on leakage for geological carbon storage is essential both for safety and for economic purposes. Current technology (for example, repeat 3D seismic surveys) is expensive and episodic. Muons are generated by high- energy cosmic rays resulting from supernova explosions, and interact with gas molecules in the atmosphere. This innovation has produced a theoretical model of muon attenuation in the thickness of rock above and within a typical sandstone reservoir at a depth of between 1.00 and 1.25 km. Because this first simulation was focused on carbon sequestration, the innovators chose depths sufficient for the pressure there to ensure that the carbon dioxide would be supercritical. This innovation demonstrates for the first time the feasibility of using the natural cosmic-ray muon flux to generate continuous tomographic images of carbon dioxide in a storage site. The muon flux is attenuated to an extent dependent on, amongst other things, the density of the materials through which it passes. The density of supercritical carbon dioxide is only three quarters that of the brine in the reservoir that it displaces. The first realistic simulations indicate that changes as small as 0.4% in the storage site bulk density could be detected (equivalent to 7% of the porosity, in this specific case). The initial muon flux is effectively constant at the surface of the Earth. Sensitivity of the method would be decreased with increasing depth. However, sensitivity can be improved by emplacing a greater array of particle detectors at the base of the reservoir.

Coleman, Max↗

NASA NTRS2019

Aerosol Radiative Effects over Ascension Island Using LASIC Observations and MERRA-2

Marine boundary layer clouds, including the transition from stratocumulus to cumulus, are poorly represented in numerical weather prediction and general circulation models. In many cases, the complex physical relationships between marine boundary cloud morphology and the environmental conditions in which the clouds exist are not well understood. Such uncertainties arise in the presence of biomass burning carbonaceous aerosol, as is the case over the southeast Atlantic Ocean. It is likely that the absorbing and heating properties of these aerosols influence the microphysical composition and macrophysical arrangement of marine stratocumulus and trade cumulus in this region; however, this has yet to be quantified. The deployment of the Atmospheric Radiation Measurement Mobile Facility #1 (AMF1) in support of LASIC (Layered Atlantic Smoke Interactions with Clouds) provided a unique opportunity to collect observations of cloud and aerosol properties during two consecutive biomass burning seasons during July through October of 2016 and 2017 over Ascension Island (7.96 S, 14.35 W). Thermodynamic profiles will be analyzed through the unique combination of sounding data from radiosonde launches and microwave profiling radiometers, giving observations of additional quantities important for cloud development such as CAPE and CIN at a fine temporal resolution. The thermodynamic profiles will be presented in conjunction with detailed observations of the cloud structure over the site from a K-band cloud radar, micropulse lidar, and laser ceilometer. Finally, the observed thermodynamic and cloud profiles will be used as input forcing, alongside aerosols from the Modern Era Retrospective analysis for Research and Applications, version 2 (MERRA-2), for the Rapid Radiative Transfer Model (RRTM) to gain information regarding the radiative heating profiles. Idealized experiments using RRTM with and without aerosols will be used to quantify the impact of biomass burning carbonaceous aerosol plumes as they pass over the site.

Collow, Allie↗

NASA NTRS2019

Thermodynamic, Cloud, and Radiative Heating Profiles over Ascension Island During the 2016 and 2017 Biomass Burning Seasons

Collow, Allison B.↗

NASA NTRS1987

Orbital atmospheric physics and dynamics

There are two ways of modeling the upper atmosphere. One is the empirical model that makes use of experimental data on means and excursions from the mean and fits the data in a self-consistent manner. The other approach is to deal directly with the physical processes. This is difficult since what is happening is extremely complex. Data measured using an interferometer to give Doppler shifts of airglow lines showed 300 to 800 m/sec winds with a complex structure in the upper region of the thermosphere at high latitudes. Ionospheric electric fields, strongly influenced by interaction with the solar wind, drive the ionized component and large neutral winds result due to momentum transfer between the charged particles and the neutrals. Frictional heating results from movement of ions through the neutrals, which also influences the compositional structure. These are examples of the complex interactions involved. The NCAR General Circulation Model (tropospheric) was adapted for use at thermospheric altitudes: the Thermospheric General Circulation Model (TGCM). The model makes use partly of primitive equations and partly of empirical data for some quantities such as electron density, magnetic field, and ion drift.

Roble, Raymond↗

NASA NTRS1990

Additives to reduce susceptibility of thermosets and thermoplastics to erosion from atomic oxygen

Polymeric materials have many attractive features such as light weight, high strength, and broad applicability in the form of films, fibers, and molded objects. In low earth orbit (LEO), these materials, when exposed on the exterior of the spacecraft, have the serious disadvantage of being susceptible to erosion by atomic oxygen (AO). AO is the most common chemical species at LEO altitudes. AO can be an extremely efficient oxidizing agent as was apparent from the extensive erosion of organic films exposed in STS missions. The mechanism for erosion involves the reaction of oxygen atoms at the surface of the substrate to form small molecular species. The susceptibility of polymeric materials varies with their chemical composition. Films with silicon atoms incorporated in the molecular structures have large coefficients of thermal expansion. This limits their utility. In an alternative approach additives were sought that mix physically and form a protective oxide layer when the film is exposed to AO. A large number of organic compounds containing silicon, germanium, or tin atoms were screened. Most were found to have very limited solubility in the polyetherimide (Ultem) films that were being protected from AO. However, one, bis(triphenyl tin) oxide, (BTO), is miscible in Ultem up to about 25 percent. Films of Ultem polyimide containing up to 25 wt percent BTO were prepared by evaporation of solvent from a solution of Ultem and BTO. The effects of AO on these films were simulated in the oxygen atmosphere of a radio frequency glow-discharge chamber. In the second part of this study, atoms were incorporated in epoxy resins. Experiments are in progress to measure the resistance of films of the cured epoxy to AO in the discharge chamber.

Orwoll, Robert A.↗

NASA NTRS2001

Remote Sensing of Wind Fields and Aerosol Distribution with Airborne Scanning Doppler Lidar

The coherent Doppler laser radar (lidar), when operated from an airborne platform, is a unique tool for the study of atmospheric and surface processes and features. This is especially true for scientific objectives requiring measurements in optically-clear air, where other remote sensing technologies such as Doppler radar are typically at a disadvantage. The atmospheric lidar remote sensing groups of several US institutions, led by Marshall Space Flight Center, have developed an airborne coherent Doppler lidar capable of mapping the wind field and aerosol structure in three dimensions. The instrument consists of an eye-safe approx. 1 Joule/pulse lidar transceiver, telescope, scanner, inertial measurement unit, and flight computer system to orchestrate all subsystem functions and tasks. The scanner is capable of directing the expanded lidar beam in a variety of ways, in order to extract vertically-resolved wind fields. Horizontal resolution is approx. 1 km; vertical resolution is even finer. Winds are obtained by measuring backscattered, Doppler-shifted laser radiation from naturally-occurring aerosol particles (of order 1 micron diameter). Measurement coverage depends on aerosol spatial distribution and composition. Velocity accuracy has been verified to be approx. 1 meter per second. A variety of applications have been demonstrated during the three flight campaigns conducted during 1995-1998. Examples will be shown during the presentation. In 1995, boundary layer winds over the ocean were mapped with unprecedented resolution. In 1996, unique measurements were made of. flow over the complex terrain of the Aleutian Islands; interaction of the marine boundary layer jet with the California coastal mountain range; a weak dry line in Texas - New Mexico; the angular dependence of sea surface scattering; and in-flight radiometric calibration using the surface of White Sands National Monument. In 1998, the first measurements of eyewall and boundary layer winds within a hurricane were made with the airborne Doppler lidar. Potential applications and plans for improvement will also be described.

Rothermel, Jeffry↗

NASA NTRS2011

Thermal Stability of a 4 Meter Primary Reflector for the Scanning Microwave Limb Sounder

The Scanning Microwave Limb Sounder (SMLS) is a space-borne heterodyne radiometer which will measure pressure, temperature and atmospheric constituents from thermal emission in [180,680] GHz. SMLS, planned for the NRC Decadal Survey's Global Atmospheric Composition Mission, uses a novel toric Cassegrain antenna to perform both elevation and azimuth scanning. This provides better horizontal and temporal resolution and coverage than were possible with elevation-only scanning in the two previous MLS satellite instruments. SMLS is diffraction-limited in the vertical plane but highly astigmatic in the horizontal (beam aspect ratio approx. 1:20). Nadir symmetry ensures that beam shape is nearly invariant over plus or minus 65 deg azimuth. A low-noise receiver FOV is swept over the reflector system by a small azimuth-scanning mirror. We describe the fabrication and thermal-stability test of a composite demonstration primary reflector, having full 4m height and 1/3 the width planned for flight. Using finite-element models of reflectors and structure, we evaluate thermal deformations and optical performance for 4 orbital environments and isothermal soak. We compare deformations with photogrammetric measurements made during soak tests in a chamber. The test temperature range exceeds predicted orbital ranges by large factors, implying in-orbit thermal stability of 0.21 micron rms (root mean square)/C, which meets SMLS requirements.

thermal distortion↗

NASA NTRS1979

HCMM: Soil moisture in relation to geologic structure and lithology, northern California

The author has identified the following significant results. First-look qualitative geologic evaluation of day- and night-IR images discloses several en echelon linear features extending throughout the central part of the northern coast range in California, across the Mendocino triple junction and into southern Oregon. Preliminary examination of these features with respect to topographic expression, vegetation, sun angle and azimuth, and atmospheric conditions suggests that they may be related to the intracontinental plate boundary (Lake Mountain Fault zone of Herd) of the Humbolt Plate. The linear features, which cut across several climatic zones and differently vegetated regions are not confined to topographic valleys, but cross the ridges and valleys at varying angles. Lithology within the Great Valley Sequence can be detected on a few of the images; however, preliminary evaluation suggests that the thermal banding observed may be a function of sun azimuth or late-day sun angle. Soil moisture, related to lithologic composition cannot be ruled out at this time.

Rich, E. I.↗

NASA NTRS2005

Improvement of Raman lidar algorithm for quantifying aerosol extinction

Aerosols are particles of different composition and origin and influence the formation of clouds which are important in atmospheric radiative balance. At the present there is high uncertainty on the effect of aerosols on climate and this is mainly due to the fact that aerosol presence in the atmosphere can be highly variable in space and time. Monitoring of the aerosols in the atmosphere is necessary to better understanding many of these uncertainties. A lidar (an instrument that uses light to detect the extent of atmospheric aerosol loading) can be particularly useful to monitor aerosols in the atmosphere since it is capable to record the scattered intensity as a function of altitude from molecules and aerosols. One lidar method (the Raman lidar) makes use of the different wavelength changes that occur when light interacts with the varying chemistry and structure of atmospheric aerosols. One quantity that is indicative of aerosol presence is the aerosol extinction which quantifies the amount of attenuation (removal of photons), due to scattering, that light undergoes when propagating in the atmosphere. It can be directly measured with a Raman lidar using the wavelength dependence of the received signal. In order to calculate aerosol extinction from Raman scattering data it is necessary to evaluate the rate of change (derivative) of a Raman signal with respect to altitude. Since derivatives are defined for continuous functions, they cannot be performed directly on the experimental data which are not continuous. The most popular technique to find the functional behavior of experimental data is the least-square fit. This procedure allows finding a polynomial function which better approximate the experimental data. The typical approach in the lidar community is to make an a priori assumption about the functional behavior of the data in order to calculate the derivative. It has been shown in previous work that the use of the chi-square technique to determine the most likely functional behavior of the data prior to actually calculating the derivative eliminates the need for making a priori assumptions. We note that the a priori choice of a model itself can lead to larger uncertainties as compared to the method that is validated here. In this manuscript, the chi-square technique that determines the most likely functional behavior is validated through numerical simulation and by application to a large body of Raman lidar measurements. In general, we show that the chi-square approach to evaluate aerosol extinction yields lower extinction uncertainty than the traditional technique. We also use the technique to study the feasibility of developing a general characterization of the extinction uncertainty that could permit the uncertainty in Raman lidar aerosol extinction measurements to be estimated accurately without the use of the chi-square technique.

Russo, Felicita↗

NASA NTRS1993

Near-surface temperature gradients and their effects on thermal-infrared emission spectra of particulate planetary surfaces

The infrared energy emitted from a planetary surface is generated within a finite depth determined by the material's absorption skin depth. This parameter varies significantly with wavelength in the infrared but has an average value of around 50 microns for most geologic materials. In solid rock, heat transfer is efficient enough so that this 50 micron zone of the near surface from which the radiation emanates will be more or less isothermal. In particulate materials, however, heat transfer is more complicated and occurs via a combination of mechanisms, including solid conduction within grains and across grain contacts, conduction through the interstitial gas, and thermal radiation within individual particles and across the void spaces in between grains. On planets with substantial atmospheres, the gas component dominates the heat transfer and tends to mitigate near-surface thermal gradients. However, on airless bodies, the gas component is absent and heat transfer occurs via solid conductions and radiation. If the particles are small relative to the average absorption skin depth, then the top 50-100 microns or so of the surface will be cooled by radiation to space allowing the creation of significant near-surface thermal gradients. In those regions of the spectrum where the absorption coefficient is low, the emission will come from the deeper, warmer parts of the medium, whereas in regions of high absorption, the emission will emanate from shallower, cooler parts of the medium. The resulting emission spectrum will show non-compositional features as a result of the thermal structure in the material. We have modeled the heat transfer in a particulate medium in order to determine the magnitude of near-surface thermal gradients for surfaces on airless bodies and on Mars. We use the calculated thermal structure to determine the effects it has on the infrared emission spectrum of the surface.

Henderson, B. G.↗