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At least 703 records · Page 39

Effect of Heat on Space-Time Correlations in Jets

Measurements of space-time correlations of velocity, acquired in jets from acoustic Mach number 0.5 to 1.5 and static temperature ratios up to 2.7 are presented and analyzed. Previous reports of these experiments concentrated on the experimental technique and on validating the data. In the present paper the dataset is analyzed to address the question of how space-time correlations of velocity are different in cold and hot jets. The analysis shows that turbulent kinetic energy intensities, lengthscales, and timescales are impacted by the addition of heat, but by relatively small amounts. This contradicts the models and assumptions of recent aeroacoustic theory trying to predict the noise of hot jets. Once the change in jet potential core length has been factored out, most one- and two-point statistics collapse for all hot and cold jets.

Bridges, James↗

Organic Combustion in the Presence of Ca-Carbonate and Mg-Perchlorate: A Possible Source for the Low Temperature CO2 Release Seen in Mars Phoenix Thermal and Evolved Gas Analyzer Data

Two of the most important discoveries of the Phoenix Lander were the detection of approx.0.6% perchlorate [1] and 3-5% carbonate [2] in landing site soils. The Thermal and Evolved Gas Analyzer (TEGA) instrument on the Phoenix lander could heat samples up to approx.1000 C and monitor evolved gases with a mass spectrometer. TEGA detected a low (approx.350 C) and high (approx.750 C) temperature CO2 release. The high temp release was attributed to the thermal decomposition of Ca-carbonate (calcite). The low temperature CO2 release could be due to desorption of CO2, decomposition of a different carbonate mineral, or the combustion of organic material. A new hypothesis has also been proposed that the low temperature CO2 release could be due to the early breakdown of calcite in the presence of the decomposition products of certain perchlorate salts [3]. We have investigated whether or not this new hypothesis is also compatible with organic combustion. Magnesium perchlorate is stable as Mg(ClO4)2-6H2O on the martian surface [4]. During thermal decomposition, this perchlorate salt releases H2O, Cl2, and O2 gases. The Cl2 can react with water to form HCl which then reacts with calcite, releasing CO2 below the standard thermal decomposition temperature of calcite. However, when using concentrations of perchlorate and calcite similar to what was detected by Phoenix, the ratio of high:low temperature CO2 evolved is much larger in the lab, indicating that although this process might contribute to the low temp CO2 release, it cannot account for all of it. While H2O and Cl2 cause calcite decomposition, the O2 evolved during perchlorate decomposition can lead to the combustion of any reduced carbon present in the sample [5]. We investigate the possible contribution of organic molecules to the low temperature CO2 release seen on Mars.

Archer, Douglas↗

Processing and Properties of Vacuum Assisted Resin Transfer Molded Phenylethynyl Terminated Imide Composites

Polyimide composites are very attractive for applications that require a high strength to weight ratio and thermal stability. Recent work at NASA Langley Research Center (LaRC) has concentrated on developing new polyimide resin systems that can be processed without the use of an autoclave for advanced aerospace applications. Due to their low melt viscosities and long melt stability, certain phenylethynyl terminated imides (PETI) can be processed into composites using high temperature vacuum assisted resin transfer molding (HT-VARTM). VARTM has shown the potential to reduce the manufacturing cost of composite structures. In the current study, two PETI resins, LARC(Trademark) PETI-330 and LARC(Trademark) PETI-9, were infused into carbon fiber preforms at 260 C and cured at temperatures up to 371 C. Photomicrographs of polished cross sections were taken and void contents, determined by acid digestion, were below 4.5%. Mechanical properties including short block compression (SBC), compression after impact (CAI), and open hole compression (OHC) were determined at room temperature, 177 C, and 288 C. Both PETI-9 and PETI-330 composites demonstrated very good retention of mechanical properties at elevated temperatures. SBC and OHC properties after aging for 1000 hours at temperatures up to 288 C were also determined.

Cano, Roberto J.↗

Modeling X-Ray Binary Evolution in Normal Galaxies: Insights from SINGS

We present the largest-scale comparison to date between observed extragalactic X-ray binary (XRB) populations and theoretical models of their production. We construct observational X-ray luminosity functions (oXLFs) using Chandra observations of 12 late-type galaxies from the Spitzer Infrared Nearby Galaxy Survey (SINGS). For each galaxy, we obtain theoretical XLFs (tXLFs) by combining XRB synthetic models, constructed with the population synthesis code StarTrack, with observational star formation histories (SFHs). We identify highest-likelihood models both for individual galaxies and globally, averaged over the full galaxy sample. Individual tXLFs successfully reproduce about half of oXLFs, but for some galaxies we are unable to find underlying source populations, indicating that galaxy SFHs and metallicities are not well matched and/or XRB modeling requires calibration on larger observational samples. Given these limitations, we find that best models are consistent with a product of common envelope ejection efficiency and central donor concentration approx.. = 0.1, and a 50% uniform - 50% "twins" initial mass-ratio distribution. We present and discuss constituent subpopulations of tXLFs according to donor, accretor and stellar population characteristics. The galaxy-wide X-ray luminosity due to low-mass and high-mass XRBs, estimated via our best global model tXLF, follows the general trend expected from the L(sub X) - star formation rate and L(sub X) - stellar mass relations of Lehmer et al. Our best models are also in agreement with modeling of the evolution both of XRBs over cosmic time and of the galaxy X-ray luminosity with redshift.

Normal Galaxies↗

Secondary Inorganic Aerosol Chemistry and Its Impact on Atmospheric Visibility Over an Ammonia-Rich Urban Area in Central Taiwan

This study investigated the hourly inorganic aerosol chemistry and its impact on atmospheric visibility over an urban area in Central Taiwan, by relying on measurements of aerosol light extinction, inorganic gases, and PM 2.5 water-soluble ions (WSIs), and simulations from a thermodynamic equilibrium model. On average, the sulfate (SO 4 2− ), nitrate (NO 3 − ), and ammonium (NH 4 + ) components (SNA) contributed ∼90% of WSI concentrations, which in turn made up about 50% of the PM 2.5 mass. During the entire observation period, PM 2.5 and SNA concentrations, aerosol pH, aerosol liquid water content (ALWC), and sulfur and nitrogen conversion ratios all increased with decreasing visibility. In particular, the NO 3 − contribution to PM 2.5 increased, whereas the SO 4 2− contribution decreased, with decreasing visibility. The diurnal variations of the above parameters indicate that the interaction and likely mutual promotion between NO 3 − and ALWC enhanced the hygroscopicity and aqueous-phase reactions conducive for NO 3 − formation, thus led to severely impaired visibility. The high relative humidity (RH) at the study area (average 70.7%) was a necessary but not sole factor leading to enhanced NO 3 − formation, which was more directly associated with elevated ALWC and aerosol pH. Simulations from the thermodynamic model depict that the inorganic aerosol system in the study area was characterized by fully neutralized SO 4 2− (i.e. a saturated factor in visibility reduction) and excess NH 4 + amidst a NH 3 -rich environment. As a result, PM 2.5 composition was most sensitive to gas-phase HNO 3 , and hence NOx, and relatively insensitive to NH 3 . Consequently, a reduction of NOx would result in instantaneous cuts of NO 3 − , PM 2.5 , and ALWC, and hence improved visibility. On the other hand, a substantial amount of NH 3 reduction (>70%) would be required to lower the aerosol pH, driving more than 50% of the particulate phase NO 3 − to the gas phase, thereby making NH 3 a limiting factor in shifting PM 2.5 composition.

aerosol chemistry↗

Background and Lunar Neutron Populations Detected by LEND and Average Concentration of Near-Surface Hydrogen near the Moon's Poles

Neutron flux measurements by the Lunar Exploration Neutron Detector (LEND) on the Lunar Reconnaissance Orbiter (LRO) enable quantifying hydrogen-bearing volatiles in the lunar surface from orbit. Accurately determining hydrogen abundance requires discriminating between the instrument background detection rate and the population of lunar-sourced neutrons that are sensitive to surficial hydrogen. We have investigated the detection rate for lunar and non-lunar (spacecraft-sourced) neutrons in LEND by modeling maps of measured count rate in three LEND detector systems using linear combinations of maps compiled from LEND detectors and from the Lunar Prospector Neutron Spectrometer. We find that 30% of the global-average 24.926 +/- 0.020 neutron counts per second (cps) detected by the LEND STN3 thermal-energy neutron sensor are lunar-sourced neutrons in the thermal energy range (E < 0.4 eV), 65% are lunar-sourced neutrons in the epithermal and fast energy range (E > 0.4 eV), and 5% are from spacecraft-sourced background signal. In the SETN epithermal neutron detector, 90% of the 10.622 +/- 0.002 neutron detections per second are consistent with a lunar source of epithermal and fast neutrons combined (E > 0.4 eV), with 3% due to lunar-sourced thermal neutron leakage into the detector (E < 0.4 eV), and background signal accounting for 7% of total detections. Background signal due to spacecraft-derived neutrons is substantial in the CSETN collimated detector system, accounting for 57% of the global average detection rate of 5.082 +/- 0.001 cps, greater than the 48% estimated from cruise-phase data. Lunar-sourced epithermal and fast neutrons account for 43% of detected neutrons, including neutrons in collimation as well as neutrons that penetrate the collimator wall to reach the detector. We estimate a lower limit of 17% of lunar-sourced neutrons detected by CSETN are epithermal neutrons in collimation (0.37 cps), with an upper limit estimate of 54 +/- 11% of lunar-sourced neutrons received in collimation, or 1.2 +/- 0.2 cps global average. The pole-to-equator contrast ratio in epithermal and high-energy epithermal neutron flux indicates that the average concentration of hydrogen in the polar regolith above 80deg north or south latitude is ∼105 ppmw (parts per million by weight), or 0.095 +/- 0.01 wt% water-equivalent hydrogen. Above 88deg north or south, the concentration increases to ∼140 ppmw, or 0.13 +/- 0.02 wt% water-equivalent hydrogen. The similar pattern of neutron flux suppression at both poles suggests that hydrogen concentration generally increases nearer the pole and is not closely associated with a specific feature such as Shackleton Crater at the lunar south pole that has no northern counterpart. Epithermal neutron flux decreases with increasing latitude outside the polar regions, consistent with surface hydration that increases with latitude if that hydration extends to ∼13-40 cm into the surface.

T A Livengood↗

Quality indicators for trace gas concentrations determined from earthlimb emission spectra

Different techniques which can be used to indicate the quality of the mixing ratios retrieved from spectral radiance measurements made by the CLAES instrument for 11 different atmospheric gases are discussed. A key to retrieval from noisy data is the Singular Value Decomposition (SVD), which is described. The use of the SVD with simulated data and radiance measurements from a balloon floating at 30 km is discussed.

Uplinger, W. G.↗

Search for infrared absorption lines of atmospheric chlorine monoxide (ClO)

A search for features of the ClO (1-0) vibration-rotation band has been conducted based on a 5000 signal-to-rms noise ratio IR spectrum derived by coadding 39 high-quality 0.0053/cm resolution solar spectra recorded with the McMath Fourier transform spectrometer on Kitt Peak. Evidence for absorption has been found at the locations of several of the stronger ClO P-branch lines with minimal interference. Detailed results are presented for the P(8.5) and P(7.5) 2Pi3/2-2Pi3/2 lines of Cl-35O at 833.2974 and 834.6249/cm, respectively. If ClO is present in the stratosphere at the concentrations indicated by other methods, our analysis indicates that modest improvements in signal-to-noise ratio and spectral resolution would permit a definitive detection of ClO in IR ground-based spectra.

Rinsland, Curtis P.↗

The spectrum of the planetary nebula IC 418

A detailed high-spectral-resolution study of the spectrum of IC 418 is made for the region 3650 to 10050 A, using the Hamilton echelle spectrograph of Lick Observatory, and of the UV spectral region with archival International Ultraviolet Explorer (IUE) data. From high-resolution images in both the near- and mid-infrared, Hora et al. (1993) showed that IC 418 probably has a compact shell interior to the detached, well-known, main shell emission. If one assumes a black body or Hubeny (or standard LTE) model atmosphere energy distribution, it does not appear possible to construct a fully satisfactory nebula model that will simultaneously represent the H-beta flux, the (O III) 5007/H-beta ratio, and the scale of this planetary nebula (PN). Fortunately, IUE and IR data supply information on ions in addition to those optically observed so that the chemical composition can be reasonably well established by summing over concentrations of observed ions. In spite of the fact that IC 418 is carbon rich in sense of having a C/O ratio exceeding the solar value, it is a 'metal-poor' object. Possibly it resembles IC 4997 but in a more advanced evolutionary phase. The central star is variable and has a strong wind.

Hyung, Siek↗

The distribution of middle tropospheric carbon monoxide during early October 1984

The distribution of middle tropospheric carbon monoxide measure by the Measurement of Air Pollution from Satellites (MAPS) instrument carried aboard the space shuttle is reported. The data represent average mixing ratios in the middle troposphere and are presented in the form of maps that show the carbon monoxide mixing ratios averaged for 6 days of the mission. Comparisons with concurrent, direct measurements taken aboard aircraft show that the inferred concentrations are systematically low by from 20 to 40 percent depending upon which direct measurement calibration standard is used. The data show that there are very large CO sources resulting from biomass burning over South America and southern Africa. Measured mixing ratios were high over northeast Asia and were highly variable over Europe.

Reichle, Henry G., Jr.↗

Globular cluster winds with central accretion by a massive compact object or subcluster

Steady-state isothermal wind flows are computed with accretion by a central mass concentration in spherically symmetric systems of gas-losing stars. Solutions are uniquely determined by two dimensionless parameters lambda and m, where lambda is approximately equal to the square of the ratio of the central escape velocity to the sound speed and m is approximately equal to the ratio of the central point mass to the cluster core mass. The models are applied to globular clusters for two types of central mass concentration - a single massive black hole and a subcluster of massive stars. A hard (greater than a keV) X-ray source due to a central black hole fed by clusterwide inflow does not provide a consistent model for globular cluster X-ray sources. However, in the case of hot (T being greater than or approximately equal to 2 x 10 to the 5th K) winds, gas trapping by a central subcluster of neutron stars or of binaries containing white dwarfs could explain recent UV and H-alpha observations. Similar applications to elliptical galaxies are discussed.

Durisen, R. H.↗

Anomalous Iridium Enrichment at the Triassic-Jurassic Boundary, Blomidon Formation, Fundy Basin, Canada

We present new analyses that confirm Ir enrichment (up to 0.31 ng/g) in close proximity to the palynological Triassic-Jurassic boundary in strata near the top of the Blomidon Formation at Partridge Island, Nova Scotia. High Ir concentrations have been found in at least two samples within the uppermost 70 cm of the formation. Ratios of other PGEs and Au to Ir are generally higher by an order of magnitude than in ordinary chondrites. No impact-related materials have been identified at #is horizon in the Blomidon Formation, therefore we cannot confirm an extraterrestrial source for the anomalous Ir levels. We consider, however, the possibility that regional basaltic volcanism is a potential source for the Ir in these sediments. The elevated Ir concentrations are found in reduced, grey colored mudstones, so redox concentration is a possible explanation for the distribution of Ir in these strata.

Kyte, Frank T.↗

Early alterations in soleus GLUT-4, glucose transport, and glycogen in voluntary running rats

Voluntary wheel running (WR) by juvenile female rats was used as a noninterventional model of soleus muscle functional overload to study the regulation of insulin-stimulated glucose transport activity by the glucose transporter (GLUT-4 isoform) protein level and glycogen concentration. Soleus total protein content was significantly greater (+18%;P greater than 0.05) than in age-matched controls after 1 wk of WR, and this hypertrophic response continued in weeks 2-4 (+24-32%). GLUT-4 protein was 39% greater than in controls in 1-wk WR soleus, and this adaptation was accompanied by a similar increase in in vitro insulin-stimulated glucose transport activity(+29%). After 2 and 4 wk of WR, however, insulin-stimulated glucose transport activity had returned to control levels, despite a continued elevation (+25-28%) of GLUT-4 protein. At these two time points, glycogen concentration was significantly enhanced in WR soleus (+21-42%), which coincided with significant reductions in glycogen synthase activity ratios (-23 to-41%). These results indicate that, in this model of soleus muscle functional overload, the GLUT-4 protein level may initially regulate insulin-stimulated glucose transport activity in the absence of changes in other modifying factors. However,this regulation of glucose transport activity by GLUT-4 protein may be subsequently overridden by elevated glycogen concentration.

Henriksen, Erik J.↗

Investigating Sources of Ozone over California Using AJAX Airborne Measurements and Models: Assessing the Contribution from Long Range Transport

High ozone (O3) concentrations at low altitudes (1.5e4 km) were detected from airborne Alpha Jet Atmospheric eXperiment (AJAX) measurements on 30 May 2012 off the coast of California (CA). We investigate the causes of those elevated O3 concentrations using airborne measurements and various models. GEOS-Chem simulation shows that the contribution from local sources is likely small. A back trajectory model was used to determine the air mass origins and how much they contributed to the O3 over CA. Low-level potential vorticity (PV) from Modern Era Retrospective analysis for Research and Applications 2 (MERRA-2) reanalysis data appears to be a result of the diabatic heating and mixing of airs in the lower altitudes, rather than be a result of direct transport from stratospheric intrusion. The Q diagnostic, which is a measure of the mixing of the air masses, indicates that there is sufficient mixing along the trajectory to indicate that O3 from the different origins is mixed and transported to the western U.S.The back-trajectory model simulation demonstrates the air masses of interest came mostly from the mid troposphere (MT, 76), but the contribution of the lower troposphere (LT, 19) is also significant compared to those from the upper troposphere/lower stratosphere (UTLS, 5). Air coming from the LT appears to be mostly originating over Asia. The possible surface impact of the high O3 transported aloft on the surface O3 concentration through vertical and horizontal transport within a few days is substantiated by the influence maps determined from the Weather Research and Forecasting Stochastic Time Inverted Lagrangian Transport (WRF-STILT) model and the observed increases in surface ozone mixing ratios. Contrasting this complex case with a stratospheric-dominant event emphasizes the contribution of each source to the high O3 concentration in the lower altitudes over CA. Integrated analyses using models, reanalysis, and diagnostic tools, allows high ozone values detected by in-situ measurements to be attributed to multiple source processes.

Ryoo, Ju-Mee↗

U, Th, Pb and REE abundances and Pb 207/Pb 206 ages of individual minerals in returned lunar material by ion microprobe mass analysis.

Results of ion microprobe analyses of Apollo 11, 12 and 14 material, showing that U, Th, Pb and REE are concentrated in accessory minerals such as apatite, whitlockite, zircon, baddeleyite, zirkelite, and tranquillityite. Th/U ratios are found to vary by over a factor of 40 in these minerals. K, Ba, Rb and Sr have been localized in a K rich, U and Th poor glass phase that is commonly associated with the U and Th bearing accessory minerals. Li is observed to be fairly evenly distributed between the various accessory phases. The phosphates have been found to have REE abundance patterns (normalized to the chondrite abundances) that are fairly flat, while the Zr bearing minerals have patterns that rise steeply, by factors of ten or more, from La to Gd. All the accessory minerals have large negative Eu anomalies. Radiometric age dates (Pb 207/Pb 206) of the individual U and Th bearing minerals compare favorably with the Pb 207/Pb 206 age of the bulk rocks.

Andersen, C. A.↗

Adhesion and friction of iron-base binary alloys in contact with silicon carbide in vacuum

Single pass sliding friction experiments were conducted with various iron base binary alloys (alloying elements were Ti, Cr, Mn, Ni, Rh, and W) in contact with a single crystal silicon carbide /0001/ surface in vacuum. Results indicate that atomic size and concentration of alloying elements play an important role in controlling adhesion and friction properties of iron base binary alloys. The coefficient of friction generally increases with an increase in solute concentration. The coefficient of friction increases linearly as the solute to iron atomic radius ratio increases or decreases from unity. The chemical activity of the alloying elements was also an important parameter in controlling adhesion and friction of alloys, as these latter properties are highly dependent upon the d bond character of the elements.

Miyoshi, K.↗

Characterization of tropospheric desert aerosols at solar wavelengths by multispectral radiometry from Landsat

Characteristics of tropospheric desert aerosols are derived by comparing nadir spectral reflectivities computed from the radiative transfer models with reflectivities measured from Landsat. Over the ocean, reflectivities are compared, but over land the comparison is carried out by determining the ratios of the nadir reflectivity of the surface-atmosphere system over heavy aerosol concentration to the reflectivity of the underlying surface. This remote sensing technique is found to be a sensitive approach for measuring n sub 2, the imaginary part of the refractive index. The desert aerosols under study, in the Iran and Pakistan area, are essentially pure scatterers, inasmuch as an n sub 2 value of 0.001 + or - 0.001 was determined for each of the four Landsat spectral bands, that is, for a spectral interval from 0.5 to 1.1 microns.

Otterman, J.↗

Surface temperatures and glassy state investigations in tribology, part 5

Preliminary measurements of high shear rate viscosity at near atmospheric but variable pressure suggest the importance of low normal stress and cavitation or fluid fracture in the type of stress field existing in elastohydrodynam ic inlets and classical hydrodynamic configurations. An experimental basis is given for three regimes of traction in concentrated contacts: a thin film regime characterized by high traction and determined by lambda ratio, a thick film regime characterized by low traction and determined by the speed parameter, and the elastohydrodynamic regime for which traction is controlled by limiting shear stress. Traction measurements were performed with various liquids, two solid lubricants, and a grease. Film thickness and traction measurements of polymer blends and base oils are compared.

Bair, S.↗