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At least 703 records · Page 39

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NASA NTRS2010

Extinction-to-Backscatter Ratios of Saharan Dust Layers Derived from In-Situ Measurements and CALIPSO Overflights During NAMMA

We determine the aerosol extinction-to-backscatter (Sa) ratios of dust using airborne in-situ measurements of microphysical properties, and CALIPSO observations during the NASA African Monsoon Multidisciplinary Analyses (NAMMA). The NAMMA field experiment was conducted from Sal, Cape Verde during Aug-Sept 2006. Using CALIPSO measurements of the attenuated backscatter of lofted Saharan dust layers, we apply the transmittance technique to estimate dust Sa ratios at 532 nm and a 2-color method to determine the corresponding 1064 nm Sa. Using this method, we found dust Sa ratios of 39.8 plus or minus 1.4 sr and 51.8 plus or minus 3.6 sr at 532 nm and 1064 nm, respectively. Secondly, Sa ratios at both wavelengths is independently calculated using size distributions measured aboard the NASA DC-8 and estimates of Saharan dust complex refractive indices applied in a T-Matrix scheme. We found Sa ratios of 39.1 plus or minus 3.5 sr and 50.0 plus or minus 4 sr at 532 nm and 1064 nm, respectively, using the T-Matrix calculations applied to measured size spectra. Finally, in situ measurements of the total scattering (550 nm) and absorption coefficients (532 nm) are used to generate an extinction profile that is used to constrain the CALIPSO 532 nm extinction profile.

Omar, Ali H.↗

NASA NTRS2010

Extinction-to-Backscatter Ratios of Saharan Dust Layers Derived from In-Situ Measurements and CALIPSO Overflights During NAMMA

We determine the extinction-to-backscatter (Sa) ratios of dust using (1) airborne in-situ measurements of microphysical properties, (2) modeling studies, and (3) the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) observations recorded during the NASA African Monsoon Multidisciplinary Analyses (NAMMA) field experiment conducted from Sal, Cape Verde during Aug-Sept 2006. Using CALIPSO measurements of the attenuated backscatter of lofted Saharan dust layers, we apply the transmittance technique to estimate dust Sa ratios at 532 nm and a 2-color method to determine the corresponding 1064 nm Sa. This method yielded dust Sa ratios of 39.8 plus or minus 1.4 sr and 51.8 plus or minus 3.6 sr at 532 nm and 1064 nm, respectively. Secondly, Sa at both wavelengths is independently calculated using size distributions measured aboard the NASA DC-8 and estimates of Saharan dust complex refractive indices applied in a T-Matrix scheme. We found Sa ratios of 39.1 plus or minus 3.5 sr and 50.0 plus or minus 4 sr at 532 nm and 1064 nm, respectively, using the T-Matrix calculations applied to measured size spectra. Finally, in situ measurements of the total scattering (550 nm) and absorption coefficients (532 nm) are used to generate an extinction profile that is used to constrain the CALIPSO 532 nm extinction profile and thus generate a stratified 532 nm Sa. This method yielded an Sa ratio at 532 nm of 35.7 sr in the dust layer and 25 sr in the marine boundary layer consistent with a predominantly seasalt aerosol near the ocean surface. Combinatorial simulations using noisy size spectra and refractive indices were used to estimate the mean and uncertainty (one standard deviation) of these Sa ratios. These simulations produced a mean (plus or minus uncertainty) of 39.4 (plus or minus 5.9) sr and 56.5 (plus or minus 16.5) sr at 532 nm and 1064 nm, respectively, corresponding to percent uncertainties of 15% and 29%. These results will provide a measurements-based estimate of the dust Sa for use in backscatter lidar inversion algorithms such as CALIOP.

Omar, Ali H.↗

NASA NTRS2011

A Study on Various Meteoroid Disintegration Mechanisms as Observed from the Resolute Bay Incoherent Scatter Radar (RISR)

There has been much interest in the meteor physics community recently regarding the form that meteoroid mass flux arrives in the upper atmosphere. Of particular interest are the relative roles of simple ablation, differential ablation, and fragmentation in the meteoroid mass flux observed by the Incoherent Scatter Radars (ISR). We present here the first-ever statistical study showing the relative contribution of the above-mentioned three mechanisms. These are also one of the first meteor results from the newly-operational Resolute Bay ISR. These initial results emphasize that meteoroid disintegration into the upper atmosphere is a complex process in which all the three above-mentioned mechanisms play an important role though fragmentation seems to be the dominant mechanism. These results prove vital in studying how meteoroid mass is deposited in the upper atmosphere which has important implications to the aeronomy of the region and will also contribute in improving current meteoroid disintegration/ablation models.

Malhotra, A.↗

NASA NTRS2010

Simplified Vicarious Radiometric Calibration

A measurement-based radiance estimation approach for vicarious radiometric calibration of spaceborne multispectral remote sensing systems has been developed. This simplified process eliminates the use of radiative transfer codes and reduces the number of atmospheric assumptions required to perform sensor calibrations. Like prior approaches, the simplified method involves the collection of ground truth data coincident with the overpass of the remote sensing system being calibrated, but this approach differs from the prior techniques in both the nature of the data collected and the manner in which the data are processed. In traditional vicarious radiometric calibration, ground truth data are gathered using ground-viewing spectroradiometers and one or more sun photometer( s), among other instruments, located at a ground target area. The measured data from the ground-based instruments are used in radiative transfer models to estimate the top-of-atmosphere (TOA) target radiances at the time of satellite overpass. These TOA radiances are compared with the satellite sensor readings to radiometrically calibrate the sensor. Traditional vicarious radiometric calibration methods require that an atmospheric model be defined such that the ground-based observations of solar transmission and diffuse-to-global ratios are in close agreement with the radiative transfer code estimation of these parameters. This process is labor-intensive and complex, and can be prone to errors. The errors can be compounded because of approximations in the model and inaccurate assumptions about the radiative coupling between the atmosphere and the terrain. The errors can increase the uncertainty of the TOA radiance estimates used to perform the radiometric calibration. In comparison, the simplified approach does not use atmospheric radiative transfer models and involves fewer assumptions concerning the radiative transfer properties of the atmosphere. This new technique uses two neighboring uniform ground target areas having different reflectance values. The target areas can be natural or artificial and must be large enough to minimize adjacent-pixel contamination effects. The radiative coupling between the atmosphere and the terrain needs to be approximately the same for the two targets. This condition can be met for relatively uniform backgrounds when the distance between the targets is within a few hundred meters. For each target area, the radiance leaving the ground in the direction of the satellite is measured with a radiometrically calibrated spectroradiometer. Using the radiance measurements from the two targets, atmospheric adjacency and atmospheric scattering effects can be subtracted, thereby eliminating many assumptions about the atmosphere and the radiative interaction between the atmosphere and the terrain. In addition, the radiometrically calibrated spectroradiometer can be used with a known reflectance target to estimate atmospheric transmission and diffuse- to-global ratios without the need for ancillary sun photometers. Several comparisons between the simplified method and traditional techniques were found to agree within a few percent. Hence, the simplified method reduces the overall complexity of performing vicarious calibrations and can serve as a method for validating traditional radiative transfer models

Stanley, Thomas↗

DOE OSTI2025

Sustainable Shape Memory Elastomers with Reduced Melt Viscosity and Enhanced Stiffness

Melt reactive processing of lignin with nitrile rubber is a promising approach to synthesizing shape memory materials. The strong intramolecular interactions in lignin macromolecular structures, caused by π–π stacking in aromatic rings and hydrogen bonding, often result in large phase separation or low miscibility with rubbers. In this study, we investigated the chemical and molecular characteristics, as well as the stiffness and complex viscosity, of modified kraft lignin melt-reacted with an acrylonitrile/butadiene copolymer containing 41% acrylonitrile (NBR41). To enhance the macromolecular compatibility of kraft lignin with NBR41, kraft lignin was cross-linked with poly(propylene glycol) diglycidyl ether (PPDE) and trimethylolpropane triglycidyl ether (TTE), both rich in epoxy reactive groups capable of forming chemical bonds with hydroxyl and carboxyl groups. Here, our findings demonstrate that the modification of kraft lignin with PPDE and TTE resulted in significantly increased stiffness of the composites. The elastic modulus of NBR41-Kraft lignin-PPDE and NBR41-Kraft lignin-TTE increased by 82 and 162%, respectively. Both the yield strength and Young’s modulus of these two samples showed dramatic improvements. Specifically, the yield strength and Young’s modulus of NBR41-Kraft lignin-TTE increased nearly 4 and 3-fold, respectively, compared to the control sample. Interestingly, despite significant improvements in mechanical properties, the viscosity of NBR41-Kraft lignin-PPDE was substantially lower than that of the control sample. At 210 °C and an angular frequency of 1 rad/s, the complex viscosity of NBR41-Kraft lignin was approximately 100.25 ± 4.77 kPa·s, while that of NBR41-Kraft lignin-PPDE was significantly lower at 56 ± 0.93 kPa·s. These findings were validated through Fourier transform infrared spectroscopy, scanning electron microscopy, dynamic mechanical analysis, thermal characterization, rheological tests, and quasi-elastic neutron scattering techniques.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Charge state-dependent ion condensation near conjugated polymer backbones

Despite the technological appeal of polymeric organic mixed ionic/electronic conductors (OMIECs) for diverse applications, a deep understanding of the fundamentals of mixed charge transport in these materials, especially regarding the complex interplay between polymer, ion and solvent structure in determining transport, is lacking. Herein, extensive molecular dynamics (MD) simulations of a model OMIEC representing various electrochemically gated states are reported that reveal charge state-dependent counterion condensation. X-ray diffraction simulations based on the MD data predict a measurable change in the scattering intensity at the counterion absorption edge, indicative of counterion repositioning with charging. We leverage an operando resonant X-ray scattering technique to experimentally corroborate the simulated scattering and report excellent agreement between predicted and experimental data, confirming that counterions preferentially reside in the lamellar mid-plane of crystallites at low doping, and near the polymer backbone at higher doping. Driving forces for ion type-dependent spatial repositioning and implications thereof are discussed.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Deep Learning Methods for Symbolic Calculations in HEP

This project develops machine learning methods to accelerate symbolic calculations in high-energy physics. Using sequence-to-sequence transformer models, we construct frameworks to predict squared amplitudes and related quantities for Standard Model processes, including quantum electrodynamics, quantum chromodynamics, and electroweak interactions. The results demonstrate that deep learning can successfully learn complex symbolic relationships and provide a scalable approach to symbolic computation with potential applications in precision calculations and collider phenomenology.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1986

Multispecies CARS measurements in turbulent combustion

A coherent anti-Stokes Raman scattering (CARS) instrument was upgraded to more accurately measure the number density of oxygen molecules. This instrument is designed to simultaneously measure nitrogen number density, oxygen number density, and the ro-vibrational temperature of nitrogen. The CARS is a nonintrusive diagnostic technique which utilizes a pulsed Nd:YAG laser, broadband dye lasers, a complex optical system, and an intensified photodiode array detector to sample hostile combustion environments. Measurements were made in a flame produced by a coaxial subsonic diffusion hydrogen-air burner. These data were used as a data base for comparison with the results of two separate computational fluid dynamics calculations. Complications which had arisen in previous studies with regard to interpretation of the oxygen data were eliminated.

Antcliff, Richard R.↗

NASA NTRS1993

A doubly periodic moment method solution for the analysis and design of an absorber covered wall

The periodic moment method (PMM) solution for scattering from a doubly periodic array of lossy dielectric bodies is developed in this paper. The purpose of this study is to design electromagnetic wedge and pyramidal absorber for low reflectivity so that one can improve the performance of anechoic chamber measurements. The spectral-domain formulation and the moment method volume polarization current approach are applied to obtain the expressions used to determine the scattering from a doubly periodic array of lossy dielectric bodies. Through these studies, some wedge and pyramidal absorber configurations have been designed, fabricated, and then tested in the OSU/ESL compact range measurement facility. In this paper, wedge absorber, commercial pyramidal absorber, and some low-frequency pyramidal absorber designs are presented. By considering the complexity of dealing with real-world material structures, good agreement between calculations and measurements has been obtained.

Yang, Chang-Fa↗

NASA NTRS2014

The Variable Hard X-Ray Emission of NGC4945 as Observed by NuSTAR

We present a broadband (approx. 0.5 - 79 keV) spectral and temporal analysis of multiple NuSTAR observations combined with archival Suzaku and Chandra data of NGC4945, the brightest extragalactic source at 100 keV. We observe hard X-ray (> 10 keV) flux and spectral variability, with flux variations of a factor 2 on timescales of 20 ksec. A variable primary continuum dominates the high energy spectrum (> 10 keV) in all the states, while the reflected/scattered flux which dominates at E< 10 keV stays approximately constant. From modelling the complex reflection/transmission spectrum we derive a Compton depth along the line of sight of Thomson approx.2.9, and a global covering factor for the circumnuclear gas of approx. 0.15. This agrees with the constraints derived from the high energy variability, which implies that most of the high energy flux is transmitted, rather that Compton-scattered. This demonstrates the effectiveness of spectral analysis in constraining the geometric properties of the circumnuclear gas, and validates similar methods used for analyzing the spectra of other bright, Compton-thick AGN. The lower limits on the e-folding energy are between 200 − 300 keV, consistent with previous BeppoSAX, Suzaku and Swift BAT observations. The accretion rate, estimated from the X-ray luminosity and assuming a bolometric correction typical of type 2 AGN, is in the range approx. 0.1 − 0.3 lambda(sub Edd) depending on the flux state. The substantial observed X-ray luminosity variability of NGC4945 implies that large errors can arise from using single-epoch X-ray data to derive L/L(sub Edd) values for obscured AGNs.

galaxies: active aEuro" galaxies: individual (NGC4↗

NASA NTRS2019

Retrieving Aerosol Characteristics From the PACE Mission, Part 2: Multi-Angle and Polarimetry

The Plankton, Aerosol, Clouds, ocean Ecosystem (PACE) mission presents new opportunities and new challenges in applying observations of two complementary multi-angle polarimeters for the space-based retrieval of global aerosol properties.Aerosol remote sensing from multi-angle radiometric-only observations enables aerosol characterization to a greater degree than single-view radiometers, as demonstrated by nearly two decades of heritage instruments. Adding polarimetry to the multi-angle observations allows for the retrieval of aerosol optical depth, Angstrom exponent,parameters of size distribution, measures of aerosol absorption, complex refractive index and degree of non-sphericity of the particles, as demonstrated by two independent retrieval algorithms applied to the heritage POLarization and Directionality of the Earth's Reflectance (POLDER) instrument. The reason why this detailed particle characterization is possible is because a multi-angle polarimeter measurement contains twice the number of Degrees of Freedom of Signal (DFS) compared to an observation from a single-view radiometer. The challenges of making use of this information content involve separating surface signal from atmospheric signal, especially when the surface is optically complex and especially in the ultraviolet portion of the spectrum where we show the necessity of polarization in making that separation. The path forward is likely to involve joint retrievalsthat will simultaneously retrieve aerosol and surface properties, although advances will berequired in radiative transfer modeling and in representing optically complex constituents in those models. Another challenge is in having the processing capability that can keep pace with the output of these instruments in an operational environment. Yet, preliminaryalgorithms applied to airborne multi-angle polarimeter observations offer encouraging results that demonstrate the advantages of these instruments to retrieve aerosol layer height, particle single scattering albedo, size distribution and spectral optical depth, and also show the necessity of polarization measurements, not just multi-angle radiometricmeasurements, to achieve these results.

Remer, Lorraine A.↗

DOE OSTI2026

Side-Chain Nanophase Separation Broadens the Double-Gyroid Stability Window in PS–PODMA Diblock Copolymers

Expanding access to bicontinuous network phases in block copolymers remains an important challenge because the double gyroid (DG) phase is usually stable only within a narrow composition window in conventional diblock copolymers. Here, we show that poly(styrene-block-octadecyl methacrylate) (PS-b-PODMA) exhibits an unusually broad DG window. Small-angle X-ray scattering measurements across a wide composition range reveal lamellar and hexagonally packed cylindrical phases at higher polystyrene fractions. In contrast, the DG phase appears over 0.22 ≤ fPS ≤ 0.35, with DG/BCC and DG/HEX coexistence near fPS = 0.18 and 0.40, respectively. This broad DG window is much wider than those reported for neat diblock copolymers and is not readily explained by conformational asymmetry alone. Wide-angle X-ray scattering detects a characteristic signature of nanophase separation within the PODMA-rich domains, indicating that side-chain ordering introduces an additional internal length scale. These results suggest that hierarchical side-chain nanophase separation modifies packing frustration and curvature selection, thereby broadening DG stability and providing a new molecular design strategy for stabilizing complex network morphologies.

Seko, Tamio↗

NASA NTRS1974

Electromagnetic processes in the atmosphere of pulsars

The work consists of two parts. The first deals with the fine structure of radio pulses. Based on kinetic theory, processes occurring in the plasma shell of a pulsar when external electromagnetic radiation is present are investigated. It is shown that electromagnetic waves cause electrons to drift relative to ions, and initiate longitudinal oscillations. A dispersion equation describing the longitudinal oscillations in magnetized plasma is derived. Conditions for excitation of oscillations are found. Correlation functions of electron density are calculated, along with the coefficients of electromagnetic wave scattering. It is shown that variations in the amplitude of pulsar pulses are associated with scintillations caused by fluctuations in the plasma electron density. The second part of the study presents a mechanism for the radio emission of pulsars. The model of a rotating and a pulsating star, a neutron star with dipolar or more complex magnetic field, is examined.

Yukhimuk, A. K.↗

NASA NTRS1974

Geological study of the southern part of the Malagasy republic using ERTS orbital images

The author has identified the following significant results. The Malagasy stratigraphy and tectonic are very complex, but the results obtained using ERTS-1 images interpretation make credible some hypothesis recently proposed by geologists. Most of known fractures are identified and numerous new observations are made on these images in the field of linear fractures. Some of them extend or relay known fractures and many others are totally new even if scattered field observations make it possible to assume that they correspond to reality. In the domain of lithology different types of rocks are distinguished, but the results are better in sedimentary formations than in the basement.

Weecksteen, G.↗

NASA NTRS1981

Organized motion in turbulent flow

A review of organized motion in turbulent flow indicates that the transport properties of most shear flows are dominated by large-scale vortex nonrandom motions. The mean velocity profile of a turbulent boundary layer consists of a viscous sublayer, buffer layer, and a logarithmic outer layer; an empirical formula of Coles (1956) applies to various pressure gradients. The boundary layer coherent structure was isolated by the correlation methods of Townsend (1956) and flow visualization by direct observations of complex unsteady turbulent motions. The near-wall studies of Willmart and Wooldridge (1962) used the space-time correlation for pressure fluctuations at the wall under a thick turbulent boundary layer; finally, organized motion in free shear flows and transition-control of mixing demonstrated that the Reynolds number invariance of turbulence shows wide scatter.

Cantwell, B. J.↗

NASA NTRS2011

Aerosol Properties over the Indo-Gangetic Plain: A Mesoscale Perspective from the TIGERZ Experiment

High aerosol loading over the northern Indian subcontinent can result in poor air quality leading to human health consequences and climate perturbations. The international 2008 TIGERZ experiment intensive operational period (IOP) was conducted in the Indo \Gangetic Plain (IGP) around the industrial city of Kanpur (26.51degN, 80.23deg E), India, during the premonsoon (April-June). Aerosol Robotic Network (AERONET) Sun photometers performed frequent measurements of aerosol properties at temporary sites distributed within an area covering 50 sq km around Kanpur to characterize pollution and dust in a region where complex aerosol mixtures and semi \bright surface effects complicate satellite retrieval algorithms. TIGERZ IOP Sun photometers quantified aerosol optical depth (AOD) increases up to 0.10 within and downwind of the city, with urban emissions accounting for 10 C20% of the IGP aerosol loading on deployment days. TIGERZ IOP area \averaged volume size distribution and single scattering albedo retrievals indicated spatially homogeneous, uniformly sized, spectrally absorbing pollution and dust particles. Aerosol absorption and size relationships were used to categorize black carbon and dust as dominant absorbers and to identify a third category in which both black carbon and dust dominate absorption.Moderate Resolution Imaging Spectroradiometer (MODIS) AOD retrievals with the lowest quality assurance (QA > or = 0) flags were biased high with respect to TIGERZ IOP area \averaged measurements. MODIS AOD retrievals with QA 0 had moderate correlation (R(sup 2) = 0.52-69) with the Kanpur AERONET site, whereas retrievals with QA > 0 were limited in number. Mesoscale \distributed Sun photometers quantified temporal and spatial variability of aerosol properties, and these results were used to validate satellite retrievals.

Giles, David M.↗

DOE OSTI2024

Experimental Definition of the S = 1 π vs S = 2 σ Reactivity and S = 2 Character in the Ground State of an S = 1 Fe IV O Complex

Iron(IV)-oxo intermediates found in iron enzymes and artificial catalysts are competent for H atom abstraction in catalytic cycles. For S = 2 intermediates, both axial and equatorial approaches are well-established. The mechanism for S = 1 sites is not as well understood: an equatorial approach is more energetically favorable, and an axial approach requires crossing from the S = 1 to the S = 2 surface. Here, in this study, we use 1s2p resonant inelastic X-ray scattering (RIXS) and Fe L-edge X-ray absorption spectroscopy on the S = 1 [Fe IV O(TMC)(CH3CN)] 2+ and observe both S = 2 and S = 1 final states, which enables the experimental evaluation of the energetics of the axial and equatorial reactivity of an S = 1 Fe IV O center on its S = 2 vs S = 1 surface. The observation of S = 2 final states in the RIXS spectrum demonstrates significant S = 2 character spin–orbit mixed into the S = 1 ground state.

energy↗

DOE OSTI2025

Distinct effect of Kondo physics on crystal field splitting in electron and spin spectroscopies

Magnetic anisotropy is a key feature of rare earth materials from permanent magnets to heavy fermions. Here we explore the complex interplay of Kondo physics and anisotropy, and their effect on different experimental probes of magnetic anisotropy in a minimal 𝐽=3/2 Anderson impurity model using the numerical renormalization group. While anisotropy suppresses Kondo screening, virtual valence fluctuations enhance the anisotropy. We find distinct renormalization of the magnetic anisotropy measured via dynamical spin response (inelastic neutron scattering) versus electronic excitations in the impurity spectral function (resonant inelastic x-ray and scanning tunneling spectroscopy). The two measurement types have different responses and dependencies on the temperature and Kondo scales.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗