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At least 703 records · Page 39

Humidity-Dependent Electrostatic Charge Decay on Dielectric Surface in Enclosed Volumes

Electrostatic surface charge decay is investigated to determine loss mechanisms, the effect of humidity, enclosure size, and material. This work focuses on charging dielectric and metal surfaces close to the electrical breakdown threshold in atmospheric air under humid and dry conditions. After initial charging to a maximum potential of roughly 30 kV, the associated surface charge is allowed to decay because of recombining with ions from the natural background, resulting in decay times ranging from minutes to hours to days. Spheres with a radius of 50 mm consisting of varying materials (PTFE and metal as referenced later) are charged and tested at relative humidity levels, RH, of 10%, 35%, and 64%. It was found that the ion-ion pair production rate and the enclosure size affected the measured charge decay rate. The impact of air convection on charge decay in the open air (no enclosure) is discussed. The humidity increased the rate of charge decay on the metal and dielectric spheres. For example, in the first 25 minutes after charging, the total charge on the PTFE sphere decreased to 66%or 50% from its initial value in the 10% and 35% RH tests, respectively. An equivalent generation rate is found for the ions in the enclosure, with 10 and 24 ion pairs cm −3 s −1 being generated at a 5% and 49% relative humidity, respectively.

42 ENGINEERING↗

The Kepler Light Curve of V344 LYR: Constraining the Thermal-Viscous Limit Cycle Instability

We present time dependent modeling based on the accretion disk limit cycle model for a 90 d light curve of the short period SU UMa-type dwarf nova V344 Lyr taken by Kepler. The unprecedented precision and cadence (1 minute) far surpass that generally available for long term light curves. The data encompass a super outburst, preceded by three normal (i.e., short) outbursts and followed by two normal outbursts. The main decay of the super outburst is nearly perfectly exponential, decaying at a rate approx.12 d/mag, while the much more rapid decays of the normal outbursts exhibit a faster-than-exponential shape. We show that the standard limit cycle model can account for the light curve, without the need for either the thermal-tidal instability or enhanced mass transfer.

Cannizzo, J. K.↗

Characterization of core neutrals using passive measurements of the D α spectrum near the X -point in the DIII-D tokamak

New spectroscopic measurements of deuterium Balmer-α emission are used to infer the spatial distribution of neutral particles near the X-point in a diverted high confinement mode plasma. The charge exchange neutral spectroscopy (CENS) diagnostic—recently installed on the DIII-D tokamak—uses 15 lines of sight extending from the edge of the confined region (ρ ≈ 0.7) to the X-point in lower single-null plasmas. Each CENS line of sight is spectrally resolved around the deuterium Balmer-α wavelength (6561 Å) to measure the Doppler shift, line broadening, and intensity of Dα emission. Thermal line broadening is used to identify emission from neutrals undergoing charge-exchange (CX) with high temperature ions in the confined plasma. This spectral information allows a more accurate determination of the neutral density deeper inside the confined plasma compared to traditional filter-based diagnostics. We present two methods of analyzing CENS measurements: (1) fitting the spectrum from each view-chord separately, and (2) a tomographic method for inverting the neutral density over a 2D region of space using all CENS views collectively. The neutral density profile is found to decay exponentially in the radial direction with two scale-lengths. In the pedestal region the neutral density decays at a rate approximately equal to the local mean-free-path for CX collisions, $L_{n_\mathrm{D0}}\approx \lambda_\text{CX}$. Further inside the plasma the neutral density decays at a rate equal to the mean-free-path for ionization, $L_{n_\mathrm{D0}}\approx \lambda_\text{inz.}$. The separatrix $n_\mathrm{D0}$ value is found to be approximately $2\times10^{15}$ m−3. Based on results from the 2D inversion, the density of neutrals is found to increase along the separatrix approaching the X-point by a factor of $\approx 5\times$ over the region covered by the CENS diagnostic.

X-point neutrals↗

Rigid-Rod Sulfonated Polyamide as an Aqueous-Processable Binder for Li-Ion Battery Electrodes

Polymer binders are important components of most battery electrodes, ensuring high performance and long-term durability. Increasing demand for lithium-ion batteries in the automotive, stationary power, and portable electronics industries calls for a greener binder to replace poly(vinylidene difluoride) (PVDF). We evaluate the performance of aqueous solution-processed electrodes prepared with a rigid-rod polymer binder, poly(2,2'-disulfonyl-4,4'-benzidine terephthalamide) (PBDT). The polyamide backbone and double-helical configuration of PBDT give rise to its mechanical strength and rigidity, and its functional nature (H-bonding amides and sulfonates) can provide specific binding with electrode particles. LiFePO 4 electrodes prepared with 3 wt% PBDT show mechanical integrity and cycling stability, achieving over 1000 cycles at 4C rate with negligible capacity decay. These electrodes demonstrate comparable rate performance with their PVDF counterparts while eliminating fluorine from the electrode as well as the organic solvents needed for processing. Furthermore, this study reveals that PBDT holds great potential as a binder for advanced sustainable batteries.

25 ENERGY STORAGE↗

Single point modeling of rotating turbulent flows

A model for the effects of rotation on turbulence is proposed and tested. These effects which influence mainly the rate of turbulence decay are modeled in a modified turbulent energy dissipation rate equation that has explicit dependence on the mean rotation rate. An appropriate definition of the rotation rate derived from critical point theory and based on the invariants of the deformation tensor is proposed. The modeled dissipation rate equation is numerically well behaved and can be used in conjunction with any level of turbulence closure. The model is applied to the two-equation kappa-epsilon turbulence model and is used to compute separated flows in a backward-facing step and an axisymmetric swirling coaxial jets into a sudden expansion. In general, the rotation modified dissipation rate model shows some improvements over the standard kappa-epsilon model.

Hadid, A. H.↗

An extended variational method for the resistive wall mode in toroidal plasma confinement devices

The external-kink stability of a toroidal plasma surrounded by a rigid resistive wall is investigated. The well-known analysis of Haney and Freidberg is rigorously extended to allow for a wall that is sufficiently thick that the thin-shell approximation does not necessarily hold. A generalized Haney–Freidberg formula for the growth-rate of the resistive wall mode is obtained. Thick-wall effects do not change the marginal stability point of the mode but introduce an interesting asymmetry between growing and decaying modes. Growing modes have growth-rates that exceed those predicted by the original Haney–Freidberg formula. On the other hand, decaying modes have decay-rates that are less than those predicted by the original formula. The well-known Hu–Betti formula for the rotational stabilization of the resistive wall mode is also generalized to take thick-wall effects into account. Increasing wall thickness facilitates the rotational stabilization of the mode, because it decreases the critical toroidal electromagnetic torque that the wall must exert on the plasma. On the other hand, the real frequency of the mode at the marginal stability point increases with increasing wall thickness.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Simultaneous enhancement of thermally activated delayed fluorescence and photoluminescence quantum yield via homoconjugation

A critical challenge facing thermally activated delayed fluorescence (TADF) is to facilitate rapid and efficient electronic transitions while ensuring a narrow singlet–triplet energy gap (ΔE ST ) in a single luminophore. We present a TADF-active iptycene that clearly demonstrates that homoconjugation can be harnessed as a viable design strategy towards answering this challenge. A homoconjugated analogue of an established quinoxaline-based TADF luminophore has been produced by fusing three of these luminophores together across a shared triptycene core. Homoconjugation was confirmed by electrochemistry, and as a direct consequence of this phenomenon we observed synergistic improvements to photoluminescence quantum yield (Φ PL ), radiative rate of singlet decay ($k^{S}_{r}$), delayed fluorescence lifetime (τ TADF ), and rate of reverse intersystem crossing (k rISC ), all while narrowing the ΔE ST . The enhancement is rationalised with TD-DFT calculations including spin–orbit coupling (SOC). A facile synthesis, the ubiquity of the pyrazine motif in state-of-the-art TADF materials of all colours, and the extent of the overall performance enhancement leads to a great potential for generality.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Creep Strain and Strain Rate Response of 2219 Al Alloy at High Stress Levels

As a result of high localized plastic deformation experienced during proof testing in an International Space Station connecting module, a study was undertaken to determine the deformation response of a 2219-T851 roll forging. After prestraining 2219-T851 Al specimens to simulate strains observed during the proof testing, creep tests were conducted in the temperature range from ambient temperature to 107 C (225 F) at stress levels approaching the ultimate tensile strength of 2219-T851 Al. Strain-time histories and strain rate responses were examined. The strain rate response was extremely high initially, but decayed rapidly, spanning as much as five orders of magnitude during primary creep. Select specimens were subjected to incremental step loading and exhibited initial creep rates of similar magnitude for each load step. Although the creep rates decreased quickly at all loads, the creep rates dropped faster and reached lower strain rate levels for lower applied loads. The initial creep rate and creep rate decay associated with primary creep were similar for specimens with and without prestrain; however, prestraining (strain hardening) the specimens, as in the aforementioned proof test, resulted in significantly longer creep life.

Taminger, Karen M. B.↗

Absolute rate constant determinations for the deactivation of O/1D/ by time resolved decay of O/1D/ yields O/3P/ emission

Absolute rate constants for the deactivation of O(1D) atoms by some atmospheric gases have been determined by observing the time-resolved emission of O(1D) at 630 nm. O(1D) atoms were produced by the dissociation of ozone via repetitive laser pulses at 266 nm. Absolute rate constants for the relaxation of O(1D) at 298 K are reported for N2, O2, CO2, O3, H2, D2, CH4, HCl, NH3, H2O, N2O, and Ne. The results obtained are compared with previous relative and absolute measurements reported in the literature.

Davidson, J. A.↗

LED Intensity Decay Particle Tracking Velocimetry

A particle tracking velocimetry (PTV) system is demonstrated that eliminates the need for expensive lasers and cameras, and encodes the particle tracks with a known intensity variation which allows for high-resolution particle velocity and directionality determination. Using a light-emitting diode (LED) as the light source significantly reduces cost and allows for eye-safe operation, in comparison to traditional laser systems. The intensity variation control is passive, being dictated by the capacitance discharge rate in the LED pulsing circuit. The decay rate can be adjusted with the LED circuit capacitors/resistors, while the duration of the decay can be adjusted with the LED trigger pulse width. Because the intensity decay illumination is controlled by the LED, a single long exposure camera image is used to acquire images of the particle streaks, and there is no need for a more complicated and costly double-pulsing camera. With the intensity coding of the light, a single-camera/ single-LED system can identify particles entering of leaving the illumination plane, but cannot discern the direction toward or away from the camera. By using a two-color system, three-dimensionality of the particle tracks can be determined.

Joshua M Weisberger↗

Quantity of 135I Released from the AGR 5/6/7 Experiment

A series of four Advanced Reactor Technologies (ART) experiments have been conducted in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). From 2006 through 2020, these experiments supported the development and qualification of the new U.S. tristructural isotropic (TRISO) particle fuel for Very High Temperature Reactors (VHTR). Each Advanced Gas Reactor (AGR) experiment consisted of multiple fueled capsules, each plumbed for independent temperature control using a mix of helium and neon gases. The gas leaving a capsule was routed to individual Fission Product Monitor (FPM) detectors. For intact fuel particles, the TRISO particle coatings provide a substantial barrier to fission product release. However, particles with failed coatings, whether because of a minute percentage of initially defective particles, those which fail during irradiation, or those designed to fail (DTF) particles, can release fission products to the flowing gas stream. Because reactive fission product elements like iodine and cesium quickly deposit on cooler capsule components and piping structures as the effluent gas leaves the reactor core, only the noble fission gas isotopes of Kr and Xe tend to reach FPM detectors. The FPM system utilizes High Purity Germanium (HPGe) detectors coupled with a thallium activated sodium iodide NaI(Tl) scintillator. The HPGe detector provides individual isotopic information, while the NaI(Tl) scintillator is used as a gross count rate meter. During irradiation, the 135mXe concentration reaching the FPM detectors is from both direct fission and by decay of the accumulated 135I. About 2.5 hours after irradiation (ten 15.3 minute 135mXe half lives) the directly produced 135mXe has decayed and only the longer lived 135I remains as a source. Decay systematics dictate that 135mXe will be in secular equilibrium with its 135I parent, such that its production rate very nearly equals the decay rate of the parent, and its concentration in the flowing gas stream will appear to decay with the parent half life. This equilibrium condition enables the determination of the amount of 135I released from the fuel particles by measurement of the 135mXe at the FPM following reactor shutdown. In this paper, the 135I released will be reported.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Study of the far wake vortex field generated by a rectangular airfoil in a water tank

Underwater towing experiments were carried out with a rectangular airfoil of aspect ratio 5.3 at 4 and 8 deg angles of attack and at chord-based Reynolds numbers between 2 x 100,000 and 7.5 x 100,000. Quantitative measurements by means of the hydrogen bubble technique indicated lower peak swirl velocities in the range of 100 to 1000 lenghts downstream than have been measured in wind tunnel of flight tests. The maximum circumferential velocity decayed whereas the turbulent eddy viscosity increased. This behavior and other known rates of vortex decay are explained in terms of an analytical solution for the vortex problem with time varying eddy viscosity. It is shown that this case corresponds to nonequilibrium turbulent vortex flow.

Lezius, D. K.↗

Preliminary plume characteristics of an arcjet thruster

An experimental program initiated to characterize the near field of an arcjet plume is described. The complete emission spectrum from 3200 to 7200 A at the nozzle exit plane detected the electronically excited species N2, N2(+), NH, and H, indicating excitation, dissociation, ionization, and recombination in the nozzle. Axial intensity profiles indicated an exponential decay in excited state population for H(alpha), H(beta), and NH. The rate of axial decay indicated lower velocities for NH than H in the plume and population of the third excited energy state of hydrogen from the decay of higher energy levels. Rotational temperatures ranged from 750 K for N2 to 2500 K for NH. Based on these results, the arcjet plume is found to be a highly nonequilibrium plasma. Anode electrical configuration is found to have a large effect on the spectral intensities measured in the plume.

Manzella, David H.↗

Three-Phased Wake Vortex Decay

A detailed parametric study is conducted that examines vortex decay within turbulent and stratified atmospheres. The study uses a large eddy simulation model to simulate the out-of-ground effect behavior of wake vortices due to their interaction with atmospheric turbulence and thermal stratification. This paper presents results from a parametric investigation and suggests improvements for existing fast-time wake prediction models. This paper also describes a three-phased decay for wake vortices. The third phase is characterized by a relatively slow rate of circulation decay, and is associated with the ringvortex stage that occurs following vortex linking. The three-phased decay is most prevalent for wakes imbedded within environments having low-turbulence and near-neutral stratification.

Proctor, Fred H.↗

MicroBooNE investigations on the photon interpretation of the MiniBooNE low energy excess

The MicroBooNE experiment is a liquid argon time projection chamber with 85-ton active volume at Fermilab, operated from 2015 to 2020 to collect neutrino data from Fermilab's Booster Neutrino Beam. One of MicroBooNE's physics goals is to investigate possible explanations of the low-energy excess observed by the MiniBooNE experiment in $\nu_{\mu}\rightarrow \nu_{e}$ neutrino oscillation measurements. MicroBooNE has performed searches to test hypothetical interpretations of the MiniBooNE low-energy excess, including the underestimation of the photon background or instrinic $\nu_{e}$ background. This thesis presents MicroBooNE's searches for two neutral current (NC) single-photon production processes that contribute to the photon background of the MiniBooNE measurement: NC $\Delta$ resonance production followed by $\Delta$ radiative decay: $\Delta \rightarrow N\gamma$, and NC coherent single-photon production. Both searches take advantage of boosted decision trees to yield efficient background rejection, and a high-statistic NC $\pi^0$ measurement to constrain dominant background, and make use of MicroBooNE's first three years of data. The NC $\Delta \rightarrow N\gamma$ measurement yielded a bound on the $\Delta$ radiative decay process at 2.3 times the predicted nominal rate at 90\% confidence level(C.L.), disfavoring a candidate photon interpretation of the MiniBooNE low-energy excess as a factor of 3.18 times the nominal NC Δ radiative decay rate at the 94.8\% C.L. The NC coherent single photon measurement leads to the world's first experimental limit on the cross-section of this process below 1 GeV, of $1.49 \times 10^{-41} \text{cm}^2$ at 90\% C.L., corresponding to 24.0 times the nominal prediction.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Comments on laser-excited fluorescence of the hydroxyl radical: Relaxation coefficients at atmospheric pressure, appendix 5

The lifetime of the excited state of a atom or molecule is often determined from the rate of fluorescence decay originating as a function of buffer gas pressure, an accurate determination is made of the rates of collision induced transitions away from the excited state. Deconvolution can in principle be employed to resolve fluorescence times shorter than the response times of the system. However, attainable reproducibility and accuracy in actual experiments usually set a limit beyond which no meaningful results are expected. Prudence thus dictates that the results of deconvolution be viewed with extreme caution whenever fluorescence time much shorter than the response of times of the system are indicated.

Wang, C. C.↗

Search for Neutrino-Induced Neutral Current Delta Radiative Decay in MicroBooNE and a First Test of the MiniBooNE Low Energy Excess Under a Single Photon Hypothesis (submitted to PRL)

We report results from a search for neutrino-induced neutral current (NC) resonant Δ(1232) baryon production followed by Δ radiative decay, with a h0.8i GeV neutrino beam. Data corresponding to MicroBooNE’s first three years of operations (6.80×10 20 protons on target) are used to select single-photon events with one or zero protons and without charged leptons in the final state (1γ1p and 1γ0p, respectively). The background is constrained via an in-situ high-purity measurement of NC π 0 events, made possible via dedicated 2γ1p and 2γ0p selections. A total of 16 and 153 events are observed for the 1γ1p and 1γ0p selections, respectively, compared to a constrained background prediction of 20.5 ± 3.65(sys.) and 145.1 ± 13.8(sys.) events. The data lead to a bound on an anomalous enhancement of the normalization of NC Δ radiative decay of less than 2.3 times the predicted nominal rate for this process at the 90% confidence level (CL). The measurement disfavors a candidate photon interpretation of the MiniBooNE low-energy excess as a factor of 3.18 times the nominal NC Δ radiative decay rate at the 94.8% CL, in favor of the nominal prediction, and represents a greater than 50-fold improvement over the world’s best limit on single-photon production in NC interactions in the sub-GeV neutrino energy range.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Activation Analysis for the Inboard Region of FNSF Using SERPENT

This study describes an application of the SERPENT 2 code with the TENDL-2017 nuclear data library and the latest available model features of the Fusion Energy System Studies–Fusion Nuclear Science Facility (FNSF), to evaluate the activation of components after shutdown at 1, 10, and 100 years, assuming a plant lifetime of 8.5 full-power years. The primary parameters evaluated include the specific activity, decay heat, and waste disposal rating (WDR). The specific activity and decay heat are calculated with SERPENT 2 using a 360-deg model of the FNSF, while the WDR is calculated and classified based on the waste disposal limits established by the U.S. Nuclear Regulatory Commission under 10 CFR 61.55 as well as by using the Fetter approach. A python-based script developed for a previous high-level waste classification and analysis study was implemented and adapted to this research to calculate the WDR by comparing nuclide concentrations to the values established in 10 CFR 61.55 to generate a waste classification for each component surveyed. As only three short-lived isotopes have limitations for classifications beyond Class A, of which only 63Ni is present in appreciable quantities, there is a limit to the amount that short-lived isotopes contribute to the most significant waste analyzed here. In most cases, a handful of long-lived isotopes can be problematic, such as 59Ni and 94Nb, for example, which are solely responsible for multiple Class C classifications. The results herein reported heavily depend on the specific materials and mass/volume fractions in the specific model used in this study, which has changed and evolved since the inception of the FNSF concept and past studies. Furthermore, the more significant contributions of this study may be the development of a modeling and simulation toolkit and a strategy to perform these calculations, so to help evaluate and optimize future fusion facilities.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗