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At least 703 records · Page 39

Life Cycle Analysis of Lithium-Ion Batteries for Automotive Applications

In light of the increasing penetration of electric vehicles (EVs) in the global vehicle market, understanding the environmental impacts of lithium-ion batteries (LIBs) that characterize the EVs is key to sustainable EV deployment. This study analyzes the cradle-to-gate total energy use, greenhouse gas emissions, SOx, NOx, PM10 emissions, and water consumption associated with current industrial production of lithium nickel manganese cobalt oxide (NMC) batteries, with the battery life cycle analysis (LCA) module in the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model, which was recently updated with primary data collected from large-scale commercial battery material producers and automotive LIB manufacturers. The results show that active cathode material, aluminum, and energy use for cell production are the major contributors to the energy and environmental impacts of NMC batteries. However, this study also notes that the impacts could change significantly, depending on where in the world the battery is produced, and where the materials are sourced. In an effort to harmonize existing LCAs of automotive LIBs and guide future research, this study also lays out differences in life cycle inventories (LCIs) for key battery materials among existing LIB LCA studies, and identifies knowledge gaps.

25 ENERGY STORAGE↗

Fano-noise-limited CCDs

Recent developments of scientific CCDs have produced sensors that achieve ultra low read noise performance (less than 2 electrons rms) and near perfect charge transfer efficiency (0.9999996) without the addition of a fat-zero. This progress has now made it possible to achieve Fano-noise-limited performance in the soft X-ray where the detector's energy resolution is primarily limited by the statistical variation in the charge generated by the interacting X-ray photon. In this paper, Fano-noise-limited test data is presented for two different CCD types and a CCD derived estimate of the Fano factor is determined. By evaluating ultra low-modulation images (less than 1 electron peak-to-peak) it is shown that the CCD's global CTE is now superior to its read noise floor. To capitalize on this capability CCD manufacturers are now focusing their attention on reducing the noise floor below the 1 electron level thereby matching the sensor's CTE performance. This improvement, if accomplished, will push Fano-noise-limited performance for the CCD into the extreme ultra-violet.

Janesick, James↗

COMET: First mission progress

The COMmercial Experiment Transporter (COMET) is a set of hardware and related infrastructure used to support orbital experiments of the Commerical Centers for the Development of Space (CCDS's) and their industrial partners. During the three years since the program started, contracts have been signed, design reviews conducted on all components, experiments selected for the first mission, all hardware has been manufactured, the first phase of integrated testing of the satellite, the experiments, and the Launch Facility have all been completed. The program experienced several delays in 1993. A component failure in the Service Module during preparation for environmental testing in January resulted in an eight-week delay for the Service Module part of the FreeFlyer. Discovery of large overruns of the mass budget required a major revision of the mission profile for COMET 1. In the spring of 1993, Space Industries Incorporated (SII) and Westinghouse stopped work because of a lack of funds. EER continued to work toward completion of their launch systems. SII and Westinghouse resumed work in September 1993. Since resumption of work, a technical review of all systems to ascertain their state of readiness has been completed. No major problems were discovered. All systems are proceeding toward a launch date in the first quarter of 1994.

Pawlick, Joseph F., Jr.↗

Modular In-Chamber Electron Beam Welding – Process Planning: Welding, Cladding, Inspection, and Manufacturing

Electron beam welding (EBW) is commonly employed by industry today to join relatively thin section components. Industrial sectors which utilize the technology include; automotive, aircraft, aerospace, defense, medical, oil & gas, etc. The ability to produce single pass, thick section (up to 6 inches, 150mm) welds has also been available for more than 40 years; however, the technology has not been deployed for civil nuclear manufacturing and fabrication such as reactor pressure vessels, steam generators, or pressurizers. Instead, thick section joining is performed much in the same manner it has been for decades using submerged arc or gas tungsten arc welding processes. Recent research performed under U.S. Department of Energy (DOE) project DE-NE0008629 has demonstrated that the overall welding time to produce one major reactor pressure vessel (RPV) girth weld can be reduced from weeks to less than 90 minutes, while maintaining exceptional quality and inspection characteristics. The subject project (DE-NE0008846) investigates a modular in-chamber (MIC) EBW approach which allows various RPV sections to be joined within a “modular” chamber. The MIC-EBW approach utilizes individual modules that can be stacked and de-stacked to various heights to enable production girth welds to be performed at a given elevation. This report describes the various processing methodology necessary to complete major girth weldments for the NuScale Power small modular reactor including welding development, manufacturing, production sequence, inspection, and cladding.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Directed self-assembly of chiral liquid crystals into biomimetic bouligand structures in thin film

The Bouligand structure, renowned for its helicoidal arrangement and enhanced mechanical properties, has attracted significant research interest for its ability to impart enhanced strength to intrinsically soft materials. Biomimetic approaches have centered on fibrous structures in bulk materials, but translating this architecture into thin-film regime for miniaturized-wearable devices with programmable functions remains challenging. Here, we direct the self-assembly of cholesteric liquid crystals (CLCs) into hierarchical helical structures using chemically patterned surfaces. Alternating surface anchoring regions align uniform lying-down helices at the nanoscale, guiding a secondary microscale helical structure exhibiting both left- and right-handed twists. This mimetic Bouligand structure in CLCs enables optical modulation under applied field and strain with enhanced mechanical response. Simulations reveal the structural evolution from initial Bouligand configuration in LC layers to alternating twist helices. This research provides a basis for designing and manufacturing miniaturized or wearable devices with nanometer-scale precision in regulating electro-optical and mechanical properties. Bouligand structures, which offer strength in natural materials, are of interest but difficult to obtain. Here, the authors report the development of such structures by directed self-assembly of cholesteric single crystals into hierarchical helical structures, with the secondary structure having right and left-handed twists.

Bouligand structure↗

Real-time single-element-detection structured illumination optical metrology for laser powder bed fusion

Laser powder bed fusion (LPBF) is a type of metal additive manufacturing which could benefit from improved process monitoring to improve quality control. We demonstrate, for the first time to our knowledge, the coaxial monitoring of melt track formation in steel powder with spatial frequency modulation imaging (SPIFI), an enhanced-resolution imaging technique which uses a photodiode to record one-dimensional images. Using a custom live-display software and a high-speed SPIFI geometry, we offset the SPIFI field of view from the fusing beam to monitor different regions of the LPBF melt pool and surrounding area. This demonstrates the potential of SPIFI to monitor spatial features within the melt pool in real-time with increased data efficiency.

Hunter, Scott (ORCID:0009000886150312)↗

Modular Undersea Compressed Air Energy Storage (UCAES) System

This project has been devoted to the design, optimization, and cost analysis of a unique power plant with integral energy storage. The proposed facility combines a novel underwater compressed air energy storage (UCAES) system with a customized gas turbine generator, providing exceptional power management and overall efficiency. Unlike conventional CAES, opportunities for underwater storage are plentiful and proximal to the power grid. The UCAES system provides coastal and island communities a practical means for managing the volatility of large-scale wind and solar power resources. The result is higher renewable energy absorption and improved electrical reliability with reduced fossil fuel consumption. The UCAES power plant is composed of three major subsystems: The underwater air containment system (ACS), the air transport pipe (ATP), and the land-based power conversion system (PCS). The underwater ACS is made up of modular concrete shell units, structurally optimized for minimal material usage while employing conventional production methods and equipment. Each shell is designed to receive and control loose fill or gravel, serving as the ballast. The static nature of the final structures make them an asset to marine habitats and includes features intended to permit safe and cost-effective deployment. The ATP Connects the ACS modules to each other and to the on-land power conversion system and utilizes high density polyethylene (HDPE) pipe for low cost and long life. The PCS Houses the turbine-generator ‘expander modules’, with peak capacity of 12.3 MWe each, engineered from existing gas turbine equipment and includes electrically driven commercial 3-stage intercooled centrifugal compressors, each nominally drawing 6.6 MWe when matching the turbine flow requirements. The subsystems listed above are designed with the intent to serve as building-blocks to achieve a peak power output rating in the 40 to 120 MWe range, with 0.25 to 4 hours of energy storage capacity. The modular facility with integral energy storage provides some remarkable transient maneuvers and load-following features unachievable by competing technologies. The system can operate as a dispatchable power plant with a fuel-to-electric efficiency over 41%; substantially better that the average existing Hawaiian peak power generation assets. Optimal efficiency can be maintained while load-following due to modular PCS design and is operable with a range of liquid or gaseous fuels while meeting the most stringent California (CARB) emission standards. The system can operate as a peaking energy plant in discharge mode. Power ramp-up equivalent to 215% of continuous load rating within 1 second accomplished by simply turning off the electric compressor(s). Contrarily, the system can offer energy absorption during periods of grid surplus generation. The electric compressors may be sequenced on to absorb power within seconds. More moderate transitions are easily achieved with standard compressor control functions. The system offers unique features as compared to energy storage systems. ‘Round-trip efficiency’, as calculated by industry standard methods, is in the 90% range. The PCS equipment has a mean-time between overhauls of 80,000 hours, with maintenance costs of less than $0.005/kW-hr of electricity delivered. The underwater ACS structures and piping employ materials and designs specified to achieve a 75 year life. With the underwater containment modules qualified as a marine habitat, there would be no decommissioning costs. In conjunction with the engineering work invested in the design of the UCAES power plant, Brayton Energy has employed a team of manufacturing specialists, marine construction engineers, and power industry experts to create a comprehensive economic model that captures the many site-related variables and configuration options. The cost results and methodology have been validated by suppliers, engineers, and deployment specialists through a detailed case study on Hawaii. While creation of the parametric cost model was based on inputs specific to Hawaii, the proposed construction and deployment steps were chosen to be general enough to allow extrapolation across locations world-wide. Analysis of the proposed system shows it to be a viable option and addresses the principal challenges described by the Department of Energy by offering competitive costs, validated safety and reliability, consideration of the regulatory environment, and utilization of industry accepted practices and equipment. The UCAES system is recommended for immediate consideration in Hawaii. Estimation of time to complete planning, design, and construction of the facility is anticipated to take 3 to 5 years. Other coastal and island communities world-wide should realize similar benefits; as the results presented in this report are considered generally transferable to other locations.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Development and fabrication of a solar cell junction processing system

Modifications to the ground plane, to insure a good electrical return path during the pulse discharge, were made using a ring of beryllium copper finger stock attached to the underside of the aluminum ground plate. Experiments on annealing of wafers with ion implantation damage continued. The entire surface of 100 mm diameter wafers were annealed by one pulse for the standard implant (10 keV, phosphorus, 2x10 to the 15th power ions/sq cm). While samples are being fabricated into solar cells for electrical characterization, work is continuing on improvement of the electron beam uniformity and the optimization of the diode parameters. The engineering design was completed and the manufacturing detail drawings were released for fabrication. Assembly of the subcomponents for the exit and entrance locks is almost complete. These components include the cassettes, the indexing mechanisms, main doors, and wafer carrier transfer modules. The 'Y' track and three phase transition track sections are under final assembly and test.

Giesling, R.↗

Definition study for an advanced cosmic ray experiment utilizing the long duration exposure facility

To achieve the goals of cosmic ray astrophysics, an ultraheavy cosmic ray experiment on an LDEF reflight should be in an orbit with high inclination (approximately 57 deg) at approximately 230 nm for approximately 2 years near solar minimum (approximately 1986). It should fill 61 trays. Each tray should contain 4 modules of total active area 0.7 sq m, with a thermal blanket, thermal labyrinth mounts, aluminum honeycomb mechanical support, and total weight approximately 100 kg. Each module should contain interleaved CR39, Lexan, and thin copper sheets plus one event-thermometer canned in a thin metal cannister sealed with approximately 0.2 atm dry O2. The CR39 and Lexan should be manufactured to specifications and the sheet copper rolled to specifications. The event-thermometer should be a stiffened CR39 sheet that slides via bimetal strips relative to fixed CR39 sheet so that stack temperature can be read out for each event. The metal cannister can be collapsed at launch and landing, capturing the sliding assembly to prevent damage. An engineering study should be made of a prototype LDEF tray; this will include thermal and mechanical tests of detectors and the event thermometer.

Price, P. B.↗

Advanced rocket propulsion

Existing NASA research contracts are supporting development of advanced reinforced polymer and metal matrix composites for use in liquid rocket engines of the future. Advanced rocket propulsion concepts, such as modular platelet engines, dual-fuel dual-expander engines, and variable mixture ratio engines, require advanced materials and structures to reduce overall vehicle weight as well as address specific propulsion system problems related to elevated operating temperatures, new engine components, and unique operating processes. High performance propulsion systems with improved manufacturability and maintainability are needed for single stage to orbit vehicles and other high performance mission applications. One way to satisfy these needs is to develop a small engine which can be clustered in modules to provide required levels of total thrust. This approach should reduce development schedule and cost requirements by lowering hardware lead times and permitting the use of existing test facilities. Modular engines should also reduce operational costs associated with maintenance and parts inventories.

Obrien, Charles J.↗

Flexible polycrystalline thin-film photovoltaics for space applications

Polycrystalline thin-film photovoltaics (PV), such as CIS and CdTe, have received considerable attention recently with respect to space power applications. Their combination of stability, efficiency, and economy from large-scale monolithic-integration of modules can have significant impact on cost and weight of PV arrays for spacecraft and planetary experiments. An added advantage, due to their minimal thickness (approximately 6 microns sans substrate), is the ability to manufacture lightweight, flexible devices (approximately 2000 W/kg) using large-volume manufacturing techniques. The photovoltaic effort at Martin Marietta and ISET is discussed, including large-area, large-volume thin-film deposition techniques such as electrodeposition and rotating cylindrical magnetron sputtering. Progress in the development of flexible polycrystalline thin-film PV is presented, including evaluation of flexible CIS cells. In addition, progress on flexible CdTe cells is presented. Finally, examples of lightweight, flexible arrays and their potential cost and weight impact is discussed.

Armstrong, J. H.↗

Overview of Field Experience - Degradation Rates & Lifetimes

The way a PV module fails may depend not only on its design and the materials used in its construction, but also on the weather it experiences, the way it is mounted, and the quality control during its manufacture. This presentation gives an overview of Field Experience - what degradation rates and what lifetimes are being observed in various regions.

14 SOLAR ENERGY↗

A Proposal of Conducting Bioequivalence Trials with Gastric pH Modulators for Two Oral Formulations Demonstrating Different Dissolution Profiles at Elevated pH

In this paper, a special case for bioequivalence evaluation of oral formulations is discussed. Drug formulations with different forms of active moieties (e.g., free base and salt) may yield different dissolution characteristics and, thus, differ in absorption at elevated gastric pH . However, routine bioequivalence trials using subjects with normal gastric pH (i.e., ~ 1) may fail to identify these differences because dissolution/absorption profiles of the two formulations at normal gastric pH are similar. In the case of palbociclib, it is confirmedthat the free base and salt formulations showed different absorption in patients with different gastric pH . Significant reduction in drug absorption was observed only in patients with elevated gastric pH using free base formulation. The discovery that the free base had significantly reduced absorption hinged on the inclusion of enough patients with elevated gastric pH to detect a difference in a bioequivalence trial. This raises a concern, as demonstrated through simulation, that dissolution/absorption differences in other formulations could be missed in routine bioequivalence trials. Aside from differences in active pharmaceutical ingredients ( API s), other factors, such as changes in excipients or manufacturing methods, may also lead to exposure differences between formulations at elevated gastric pH . For formulations containing different forms of the same active moiety or the same API and showing different dissolution profiles at elevated pH (i.e., pH ~ 4–6.8), evaluation of bioequivalence with gastric pH modulators (e.g., a H 2 blocker) in addition to routine bioequivalence assessments may help to ensure therapeutic equivalence in patients with elevated gastric pH .

59 BASIC BIOLOGICAL SCIENCES↗

Highly Permeable Rubbery Thin Film Composite Membranes for CO2 Capture from Steel Mills

This presentation will report the rational design and fabrication of NETL’s highly permeable non-aging thin film composite (TFC) membranes for CO2 capture from various industrial point sources. This talk will also cover the design, computational fluid dynamic simulation, 3D printing, and permeation testing of plate-and-frame membrane modules for an upcoming field demonstration at U. S. Steel’s Edgar Thomson Plant in Braddock, PA. The field test will demonstrate membrane-based CO2 capture from a blast furnace for decarbonization of steel manufacturing for the first time in the U.S. A mobile gas permeation test unit is currently under design and construction for the field test, which is scheduled to take place in 2025.

Zhu, Lingxiang↗

Host-Directed, Bioelectronic Immunomodulation for Protection Against Emerging Pathogens

Acute care of patients with severe infections often relies on systemic administration of pharmaceuticals and monitoring of complex physiological symptoms to identify immune system dysfunction, which can lead to increased mortality. Furthermore, determining disease-specific treatment plans often leads to a delay in patient care. To address this, we proposed an immune modulation system that electrically detects and responds to a patient’s immune system status, creating an agnostic means of treating illness and infection. Two pieces of hardware were developed for this task: a minimally-invasive sensor and a vagus nerve stimulator. Stimulation of the vagus nerve is known to modulate the immune system. The sensor is a microfabricated, silicon-based microneedle array capable of interfacing with interstitial fluid to detect small molecules such as inflammatory proteins (cytokines) and pharmaceuticals (vancomycin). Process optimization to manufacture the needles refined the silicon etch process, creating needle patches long enough to penetrate skin and reach interstitial fluid. The needles were tested for mechanical strength and stability, and did not shatter when inserted into skin models. The needles are coated with a thin film metal, turning them into electrodes for electrochemical sensing of our target molecules. We hybridized aptamers to the surface of the electrode to act as the sensing layer and were able to detect changes in the conformation of the aptamer electrochemically in the presence of the target molecule. The stimulator was a cuff electrode that encircled the vagus nerve. Rodent studies were conducted in which rodents were exposed to an inflammatory event and vagus nerve stimulation (VNS) was applied. It was demonstrated that optimized electrical stimulation of the vagus nerve created measurably different levels of cytokines in blood samples, and certain cytokines released during the inflammatory event were either upregulated or downregulated. In sum, this project successfully developed new platforms and technologies that can, with further development, enable better temporal insight into biomarker changes in the body, letting healthcare providers know of possible immune system dysfunction before they are detected physiologically. We also demonstrated the value of VNS and its possible use in treating immune system response to inflammation and illness.

59 BASIC BIOLOGICAL SCIENCES↗

Annual Conference on Nuclear and Space Radiation Effects, 14th, College of William and Mary, Williamsburg, Va., July 12-15, 1977, Proceedings

Topics related to processing and hardness assurance are considered, taking into account the radiation hardening of CMOS technologies, technological advances in the manufacture of radiation-hardened CMOS integrated circuits, CMOS hardness assurance through process controls and optimized design procedures, the application of operational amplifiers to hardened systems, a hard off-the-shelf SG1524 pulse width modulator, and the gamma-induced voltage breakdown anomaly in a Schottky diode. Basic mechanisms are examined, giving attention to chemical and structural aspects of the irradiation behavior of SiO2 films on silicon, experimental observations of the chemistry of the SiO2/Si interface, leakage current phenomena in irradiated SOS devices, the avalanche injection of holes into SiO2, the low-temperature radiation response of Al2O3 gate insulators, and neutron damage mechanisms in silicon at 10 K. Other subjects discussed are related to radiation effects in devices and circuits, space radiation effects, and aspects of simulation, energy deposition, and dosimetry.

Stahl, R. H.↗

Overview of NASA space station activities

The architecture, functions, and human activities on-board a space station are discussed. A manned presence is regarded as essential for innovative actions and successful exploitation of weightless conditions. The station itself could be a cluster of modules for habitation, power, operations, docking, experimentation, and storage. Additionally, the station could provide an interface for free-flying platforms and teleoperated satellite services, as well as a base for establishing space-based manufacturing facilities. NASA has projected timelines that include initial development funding in 1987, full capabilities before the year 2000, and initial costs for minimum capabilities of $7.5-9 billion. Architecture, mission requirements, trade-offs, and concepts are currently being defined as a prelude to systems development. Attention is being given to participation by both the DoD and other governments, and to defining the capabilities of the station, including habitability, closed-loop life-support system, the scope of science application and data transfer, and the power requirements.

Tilton, E. L., III↗

BIOASPEN: System for technology development

The public version of ASPEN was installed in the VAX 11/750 computer. To examine the idea of BIOASPEN, a test example (the manufacture of acetone, butanol, and ethanol through a biological route) was chosen for simulation. Previous reports on the BIOASPEN project revealed the limitations of ASPEN in modeling this process. To overcome some of the difficulties, modules were written for the acid and enzyme hydrolyzers, the fermentor, and a sterilizer. Information required for these modules was obtained from the literature whenever possible. Additional support modules necessary for interfacing with ASPEN were also written. Some of ASPEN subroutines were themselves altered in order to ensure the correct running of the simulation program. After testing of these additions and charges was completed, the Acetone-Butanol-Ethanol (ABE) process was simulated. A release of ASPEN (which contained the Economic Subsystem) was obtained and installed. This subsection was tested and numerous charges were made in the FORTRAN code. Capital investment and operating cost studies were performed on the ABE process. Some alternatives in certain steps of the ABE simulation were investigated in order to elucidate their effects on the overall economics of the process.

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