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At least 703 records · Page 39

Thermal barrier coating life prediction model development

This program focuses on predicting the lives of two types of strain-tolerant and oxidation-resistant thermal barrier coating (TBC) systems that are produced by commercial coating suppliers to the gas turbine industry. The plasma-sprayed TBC system is composed of a low pressure, plasma sprayed applied, oxidation resistant NiCrAlY bond coating. The other system is an air plasma sprayed yttria (8 percent) partially stabilized zirconia insulative layer.

Strangman, T. E.↗

Thermal barrier coating life prediction model development

Thermal barrier coatings (TBCs) for turbine airfoils in high-performance engines represent an advanced materials technology with both performance and durability benefits. The foremost TBC benefit is the reduction of heat transferred into air-cooled components, which yields performance and durability benefits. This program focuses on predicting the lives of two types of strain-tolerant and oxidation-resistant TBC systems that are produced by commercial coating suppliers to the gas turbine industry. The plasma-sprayed TBC system, composed of a low-pressure plasma-spray (LPPS) or an argon shrouded plasma-spray (ASPS) applied oxidation resistant NiCrAlY (or CoNiCrAlY) bond coating and an air-plasma-sprayed yttria (8 percent) partially stabilized zirconia insulative layer, is applied by Chromalloy, Klock, and Union Carbide. The second type of TBC is applied by the electron beam-physical vapor deposition (EB-PVD) process by Temescal.

T E Strangman↗

Plasma etching a ceramic composite

Plasma etching is found to be a superior metallographic technique for evaluating the microstructure of a ceramic matrix composite. The ceramic composite studied is composed of silicon carbide whiskers (SiC(sub W)) in a matrix of silicon nitride (Si3N4), glass, and pores. All four constituents are important in evaluating the microstructure of the composite. Conventionally prepared samples, both as-polished or polished and etched with molten salt, do not allow all four constituents to be observed in one specimen. As-polished specimens allow examination of the glass phase and porosity, while molten salt etching reveals the Si3N4 grain size by removing the glass phase. However, the latter obscures the porosity. Neither technique allows the SiC(sub W) to be distinguished from the Si3N4. Plasma etching with CF4 + 4 percent O2 selectively attacks the Si3N4 grains, leaving SiC(sub W) and glass in relief, while not disturbing the pores. An artifact of the plasma etching reaction is the deposition of a thin layer of carbon on Si3N4, allowing Si3N4 grains to be distinguished from SiC(sub W) by back scattered electron imaging.

Hull, David R.↗

Application of powder densification models to the consolidation processing of composites

Unidirectional fiber reinforced metal matrix composite tapes (containing a single layer of parallel fibers) can now be produced by plasma deposition. These tapes can be stacked and subjected to a thermomechanical treatment that results in a fully dense near net shape component. The mechanisms by which this consolidation step occurs are explored, and models to predict the effect of different thermomechanical conditions (during consolidation) upon the kinetics of densification are developed. The approach is based upon a methodology developed by Ashby and others for the simpler problem of HIP of spherical powders. The complex problem is devided into six, much simpler, subproblems, and then their predicted contributions are added to densification. The initial problem decomposition is to treat the two extreme geometries encountered (contact deformation occurring between foils and shrinkage of isolated, internal pores). Deformation of these two geometries is modelled for plastic, power law creep and diffusional flow. The results are reported in the form of a densification map.

Wadley, H. N. G.↗

A Particle and Energy Balance Model of the Orificed Hollow Cathode

A particle and energy balance model of orificed hollow cathodes was developed to assist in cathode design. The model presented here is an ensemble of original work by the author and previous work by others. The processes in the orifice region are considered to be one of the primary drivers in determining cathode performance, since the current density was greatest in this volume (up to 1.6 x 10(exp 8) A/m2). The orifice model contains comparatively few free parameters, and its results are used to bound the free parameters for the insert model. Next, the insert region model is presented. The sensitivity of the results to the free parameters is assessed, and variation of the free parameters in the orifice dominates the calculated power consumption and plasma properties. The model predictions are compared to data from a low-current orificed hollow cathode. The predicted power consumption exceeds the experimental results. Estimates of the plasma properties in the insert region overlap Langmuir probe data, and the predicted orifice plasma suggests the presence of one or more double layers. Finally, the model is used to examine the operation of higher current cathodes.

Domonkos, Matthew T.↗

One Step Plasma Passivation and Precision Cleaning

Over the past several years, Kennedy Space Center (KSC) researchers developed two solvent-free techniques for precision cleaning of ground support equipment (GSE) that possess low commodity requirements and produce small or no waste streams. During testing of low-pressure air plasma as one of these cleaning techniques, physical changes in the surface of stainless steel test pieces were observed; cursory testing revealed that the test part had developed a thick oxide layer on the surface compared to untreated parts. This result indicated that the plasma process might not only serve as a green technology for precision cleaning of parts, but it may also passivate the surface at the same time. Current methodology in use at KSC’s Components Refurbishment & Chemical Analysis (CRCA) Facility for passivation of corrosion-resistant steels for aerospace applications follows an SAE International Standard, AMS2700, where parts are submerged in either a nitric acid or nitric acid/sodium dichromate bath at predetermined temperatures and contact times. These baths require constant testing to ensure effective treatment, use corrosive and carcinogenic chemicals, and produce hazardous waste. The passivation bath is one of the multiple steps employed at the facility, while cleaning with multiple environmentally-unfriendly solvents comprise several more steps before parts are recertified to a specific cleanliness level in their clean room. Based on the behavior of the stainless steel surface during cleaning optimization studies, it was believed that the plasma technology could be extended to passivation, combining what is currently many steps into a single, solvent- and waste-free system.

Paul Hintze↗

Linear theory of the Kelvin-Helmholtz instability in the low-latitude boundary layer

The feasibility is examined of establishing characteristic profiles across the magnetospheric low-latitude boundary layer for the Kelvin-Helmholtz mode so that these profiles can be compared with satellite observations or a latitudinal chain of ground stations. An anisotropic collisionless fluid model is used instead of conventional MHD, and the finite thickness of the boundary layer and the thickness and position of the current layer are taken into account. The instability is found to be enhanced by a decrease in the thickness of the shear layer and of the current layer and by the proximity of the 'current layer' to the outer edge of the shear layer. The velocity threshold for the onset of instability is insensitive to the thickness. Characteristic profiles of the variation of plasma and field parameters across the boundary are obtained, and the importance of parameters specifying the current layer position and thickness is demonstrated.

Rajaram, R.↗

Plasma CVD of Carbon Nanotubes

Carbon nanotubes(CNT) exhibit remarkable mechanical and unique electronic properties and thus have created excitement in the research community about their potential in electronics, computing, sensor and structural applications. Realization of these applications critically depends on the ability to control the properties(such as diameter, chirality) as well purity. We have investigated CNT growth using an inductively coupled plasma(ICP) process using hydrocarbon feedstock. The catalyst required for nanotube growth consists of thin sputtered layers of aluminum and iron(10 nm each) and aligned carbon nanotubes have been obtained. Optical emission diagnostics as well as a plasma modeling effort have been undertaken to understand growth mechanisms. This presentation will discuss growth characteristics under various pressure, power and feedgas compositions and our understanding from modeling and diagnostics.

Delzeit, Lance↗

The automated array assembly task of the low-cost silicon solar array project, phase 2

Several specific processing steps as part of a total process sequence for manufacturing silicon solar cells were studied. Ion implantation was identified as the preferred process step for impurity doping. Unanalyzed beam ion implantation was shown to have major cost advantages over analyzed beam implantation. Further, high quality cells were fabricated using a high current unanalyzed beam. Mechanically masked plasma patterning of silicon nitride was shown to be capable of forming fine lines on silicon surfaces with spacings between mask and substrate as great as 250 micrometers. Extensive work was performed on advances in plated metallization. The need for the thick electroless palladium layer was eliminated. Further, copper was successfully utilized as a conductor layer utilizing nickel as a barrier to copper diffusion into the silicon. Plasma etching of silicon for texturing and saw damage removal was shown technically feasible but not cost effective compared to wet chemical etching techniques.

Coleman, M. G.↗

Alteration of the ionosphere by man-made waves

In recent years powerful radio wave transmissions beamed at the ionosphere at frequencies somewhat below the penetration frequency of the F2 layer produced the following, mostly unexpected, spectacular effects: (1) artificial spread F seen on ionograms and implying the presence of large scale field-aligned irregularities in the ionospheric plasma density; (2) very strong additional absorption of probing waves reflected by the F2 layer; (3) field-aligned 'on frequency' scattering of UHF waves; (4) scattering of UHF waves by Langmuir waves which are believed to be parametrically excited; (5) the 630 nm airglow is artificially enhanced by a modifying wave of ordinary polarization but it is reduced in intensity by a modifying wave of extraordinary polarization; (6) the shape of the F2 layer is modified. The results of the observations are described and their tentative interpretation in terms of different parametric instabilities is outlined.

Fejer, J. A.↗

Transport of plasma across the magnetopause

It is here demonstrated numerically, by tracing test particle motions, that solar wind plasma particles can cross the magnetopause and get into the boundary layer if the tangential electric field in the magnetopause rest frame changes in concert with changes in the magnetic field as E = V x B for continuous earthward flow, whether or not the field lines are closed. Such a simultaneous change in the electric and magnetic fields is proposed as a key feature of flux transfer events (FTEs). It is argued that the FTE process could more aptly be described as a transient or impulsive transfer of plasma particles on a single flux tube over a localized region of the magnetopause, generally ending up on different flux tubes after the crossing. Thus, it is proposed that FTE should denote flux 'trade' event, rather than 'transfer'.

Heikkila, Walter J.↗

Generation of region 1 current by magnetospheric pressure gradients

The Rice Convection Model (RCM) is used to illustrate theoretical possibilities for generating region 1 Birkeland currents by pressure gradients on closed field lines in the Earth's magnetosphere. Inertial effects and viscous forces are neglected. The RCM is applied to idealized cases, to emphasize the basic physical ideas rather than realistic representation of the actual magnetosphere. Ionospheric conductance is taken to be uniform, and the simplest possible representations of the magnetospheric plasma are used. Three basic cases are considered: (1) the case of pure northward Interplanetary Magnetic Field (IMF), with cusp merging assumed to create new closed field lines near the nose of the magnetosphere, following the suggestion by Song and Russell (1992); (2) the case where Dungey-type reconnection occurs at the nose, but magnetosheath plasma somehow enters closed field lines on the dawnside and duskside of the merging region, causing a pressure-driven low-latitude boundary layer; and (3) the case where Dungey-type reconnection occurs at the nose, but region 1 currents flow on sunward drifting plasma sheet field lines. In case 1, currents of region 1 sense are generated by pressure gradients, but those currents do not supply the power for ionospheric convection. Results for case 2 suggest that pressure gradients at the inner edge of the low-latitude boundary layer might generate a large fraction of the region 1 Birkeland currents that drive magnetospheric convection. Results for case 3 indicate that pressure gradients in the plasma sheet could provide part of the region 1 current.

Yang, Y. S.↗

Terminator Double Layer Explorer (TerDLE): Examining the Near-Moon Lunar Wake

As the solar wind flows by the Moon, an antisunward-directed low-density wake forms as the plasma expands to fill in the trailing void in the plasma flow. Analytical modeling and modern plasma simulations suggest that plasma quasi-neutrality could possibly be broken close to the terminator obstruction as solar wind electrons expand into the wake ahead of the ions, leading to the formation of a standing (time-stationary) double layer. The objective of the Terminator Double Layer Explorer is to extend the fundamental understanding of the plasma expansion into the trailing near-vacuum wake region by (1) identifying any plasma expansion density anomalies at low altitudes near the terminator wake initiation region, (2) assessing the highly variable solar wind's effect on the low-altitude wake region, and (3) determining if plasma neutrality is maintained or lost during passages through the low-altitude expansion region. The mission concept uses a propulsion-driven CubeSat with ion spectrometer and plasma wave system in elliptical orbit about the Moon with periselene near the terminator. Over the course of the mission, the periselene decreases, placing the CubeSat ever closer to the terminator wake initiation location and the possible nonneutral region.

lunar science↗

Magnetic TRAnsition Region Probe (MTRAP)

MTRAP (Magnetic Transition Region Probe) will reveal the fine-scale physical processes in the Sun's magnetic transition region, the complex layer from the upper photosphere to the upper chromosphere/lower transition region. In the magnetic transition region plasma forces and magnetic forces are of comparable strength, which results in complex interplay of the two, which interplay governs the coupling of the convectively-driven deeper layers to the magnetically-driven upper transition region and inner corona. The fine-scale magnetic structure, processes, and events in the magnetic transition region are key to the genesis of the Sun's entire hot, dynamic outer atmosphere and to the initiation of large eruptive events. MTRAP will be a single spacecraft in Sun-synchronous Earth orbit. Because MTRAP will probe and measure the 3-D structure and dynamics of the magnetic field and plasma in the chromosphere and transition region with unprecedented resolution, the required telescope size and telemetry rates dictate that MTRAP be in Earth orbit, not in deep space. The observations will feature visible and infrared maps of vector magnetic and velocity fields in the magnetic transition region and photosphere. These will have large field of view (greater than 100,000 km), high resolution (greater than 100 km), and high sensitivity (greater than 30 G in transverse field). These observations of the lower atmosphere will be complemented by UV maps of the structure, velocity, and magnetic field (including the full vector field if technically feasible) higher up, in the upper chromosphere and lower transition region. MTRAP will also have an EUV imaging spectrograph observing coronal structure and dynamics in the same field of view with comparable resolution. Specific phenomena to be analyzed include spicules, bright points, jets, the base of plumes, and the triggering of eruptive flares and coronal mass ejections. Additional information is included in the original extended abstract.

Moore, R. L.↗

Thermal spray forming of refractory sample ampoule cartridges for single crystal growth space furnaces

A thermal spray process is being used to build up refractory metals and ceramics into a containment cartridge for high temperature, single crystal semiconductor growth experiments. This process uses high energy plasma inside a low pressure (100-200 torr) inert environment to apply layers of material onto a removable mandrel. A variety of materials are being characterized and evaluated against a demanding set of requirements, including high service temperature (1700 C), oxidation resistance, and resistance to liquid metal attack. Techniques to spray form refractory metals (tungsten, molybdenum, niobium, tantalum) and ceramics (alumina, boron nitride) are being developed in the Plasma Spray Cell at Marshall Space Flight Center. These plasma spray formed materials have been evaluated for mechanical properties, density, microstructure, and resistance to liquid metal attack. Forming techniques and the resultant mechanical and metallurgical properties will be presented.

Zimmerman, Frank↗

Thermal spray forming of refractory sample ampoule cartridges for single crystal growth space furnaces

A thermal spray process is being used to build up refractory metals and ceramics into a containment cartridge for high temperature, single crystal semiconductor growth experiments. This process uses high energy plasma inside a low pressure (100-200 torr) inert environment to apply layers of material onto a removable mandrel. A variety of materials are being characterized and evaluated against a demanding set of requirements, including high service temperature (1700 C), oxidation resistance, and resistance to liquid metal attack. Techniques to spray form refractory metals (tungsten, molybdenum, niobium, tantalum) and ceramics (alumina, boron nitride) are being developed in the Plasma Spray Cell at Marshall Space Flight Center. These plasma spray formed materials have been evaluated for mechanical properties, density, microstructure, and resistance to liquid metal attack. Forming techniques and the resultant mechanical and metallurgical properties are presented.

Zimmerman, Frank↗

Solar Array at Very High Temperatures: Ground Tests

Solar array design for any spacecraft is determined by the orbit parameters. For example, operational voltage for spacecraft in Low Earth Orbit (LEO) is limited by significant differential charging due to interactions with low temperature plasma. In order to avoid arcing in LEO, solar array is designed to generate electrical power at comparatively low voltages (below 100 V) or to operate at higher voltages with encapsulated of all suspected discharge locations. In Geosynchronous Orbit (GEO) differential charging is caused by energetic electrons that produce differential potential between coverglass and conductive spacecraft body in a kilovolt range. In such a case, weakly conductive layer over coverglass (ITO) is one of possible measures to eliminate dangerous discharges on array surface. Temperature variations for solar arrays in both orbits are measured and documented within the range of -150 C +110 C. This wide interval of operational temperatures is regularly reproduced in ground tests with radiative heating and cooling inside shroud with flowing liquid nitrogen. The requirements to solar array design and tests turn out to be more complicated when planned trajectory crosses these two orbits and goes closer to Sun. Conductive layer over coverglass causes sharp increase in parasitic current collected from LEO plasma, high temperature may cause cracks in encapsulating material (RTV), radiative heating of coupon in vacuum chamber becomes practically impossible above 150 C, conductivities of glass and adhesive go up with temperature that decrease array efficiency, and mechanical stresses grow up to critical magnitudes. A few test arrangements and respective results are presented in current paper. Coupons were tested against arcing in simulated LEO and GEO environments under elevated temperatures up to 200 C. The dependence of leakage current on temperature was measured, and electrostatic cleanness was verified for coupons with antireflection (AR) coating over ITO layer.

differential charging↗

Auroral magnetosphere-ionosphere coupling: A brief topical review

Auroral arcs result from the acceleration and precipitation of magnetospheric plasma in narrow regions characterized by strong electric fields both perpendicular and parallel to the earth's magnetic field. The various mechanisms that were proposed for the origin of such strong electric fields are often complementary Such mechanisms include: (1) electrostatic double layers; (2) double reverse shock; (3) anomalous resistivity; (4) magnetic mirroring of hot plasma; and (5) mapping of the magnetospheric-convection electric field through an auroral discontinuity.

Chiu, Y. T.↗