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Electrocatalytic Upgrading of Phenolic Compounds Observed after Lignin Pyrolysis
Not provided.
Production and purification of crystallized levoglucosan from pyrolysis of lignocellulosic biomass
Levoglucosan has significant potential in commercial applications for the synthesis of polymers, solvents and pharmaceuticals.
Techno-economic and greenhouse gas emission assessment of carbon negative pyrolysis technology
Carbon-negative energy removes carbon dioxide from the atmosphere while providing energy to society.
Influence of Pyrolysis Gas Composition and Reaction Kinetics on Leaf-Scale Fires
Not provided.
A Biomass Pyrolysis Oil as a Novel Insect Growth Regulator Mimic for a Variety of Stored Product Beetles
Abstract As fumigants face increasing regulatory restrictions, resistance, and consumer pushback, it is vital to expand the integrated pest management (IPM) chemical toolkit for stored products. The production of biomass derived insecticides (e.g., bio-oil fraction) from byproducts of biofuel production may be a promising alternative source of chemistries for controlling stored product insects. These potential insecticidal bio-oils were fractionated based on boiling points (ranging from 115 to 230°C in one series and 245–250°C in another). Fractions were analyzed using GC-MS, and were found to be unique in composition. The lethality of these fractions was tested on Tribolium castaneum, Tribolium confusum, and Oryzaephilus surinamensis (L.) (Coleoptera: Silvanidae). Fractions were tested at concentrations ranging from 5–260 mg/ml to screen for efficacy against adults for durations of 2–8 hr sprayed on concrete arenas. In addition, a separate assay evaluated adult emergence of larvae after 6 wk with supplemental food in arenas, while repellency was evaluated against four stored product insect species in a laminar wind tunnel. A greenhouse gas (GHG) emissions life cycle assessment was also performed, which found the use of the bio-oil fraction could reduce GHG emissions associated with the insecticide supply chain by 25–61% relative to a fossil-fuel based insecticide or pyrethroid. While adults were largely unaffected, we found that larval emergence was significantly suppressed compared to controls by roughly half or more. We also determined that there was minimal repellency to most fractions by most species. We conclude that the use of bio-oil fractions is a climate-friendly choice that may support IPM programs.
Investigation of Carbon Products Produced by Catalytic Methane and Ethane Pyrolysis
2023 Microscopy & Microanalysis poster presentation.
Electrically conductive and thermally stable SiC-TiC containing nanocomposites via flash pyrolysis
Not provided.
Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis August 2019 (Progress Report for FRD-17-002)
What we planned to accomplish this period: In the month of August we planned to get any comments or edits on the Site License Agreement from SPI for review, make further progress on the market assessment for the Wood-to-Bio-oil Market Report, and continue moving towards getting the subcontracts in place with Iowa State University and Frontline BioEnergy, LLC. What we actually accomplished this period: We finally received the updated Site License Agreement from SPI on August 21st. The only comments and edits on it are minor and should not take more than a couple of weeks of review internally (the only reason this is weeks instead of days is due to the Laboratory’s fiscal year end approaching on September 30, making for heavily increased workloads on our folks that review these documents, and making a few weeks, instead of days, more realistic) before we can pass it along to Iowa State University and Frontline BioEnergy, LLC.
Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis (FRD-17-002 Progress Report)
In the month of November, we planned to have the Site License Agreement with SPI back from them for final review and signatures, make further progress on the market assessment for the Wood-to-Bio-oil Market Report, and continue moving towards getting the subcontracts in place with Iowa State University and Frontline BioEnergy, LLC. The hope was to be able to get the finalized Site License Agreement back from SPI/Gary Blanc this month. Unfortunately, since we are still in the midst of fire season in California, and Gary is unavailable as a result, we did not. Thankfully, it does not appear that there will be any major difficulties with getting the agreement finalized and signed, once Gary is available again, as SPI is constant in their support and eagerness for this effort to go forward, so we are not concerned that this is a risk to the project at this time.
Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis, February 2020. Progress report for FRD-17-002
Planned and actual accomplishments are reported for February 2020, along with planning for the next period.
Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis, March 2020 (Progress Report for FRD-17-002)
In the month of March, we planned to have the Site License Agreement with SPI signed and fully executed, make further progress on the market assessment for the Wood-to-Bio-oil Market Report, and hoped to have the subcontracts in place with Iowa State University and Frontline BioEnergy, LLC. We also hoped to have the updated budget from Iowa State in order to send both updated sub-recipient budget sheets to the CAM for approval.
Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis (Progress Report for FRD-17-002)
In the month of April, we planned to have the Site License Agreement with SPI signed and fully executed, make further progress on the market assessment for the Wood-to-Bio-oil Market Report, and hoped to have the subcontracts in place with Iowa State University and Frontline BioEnergy, LLC once we have approval from the CAM. We also plan to have the updated budget from Iowa State in order to send both updated sub-recipient budget sheets to the CAM for approval.We continue to make more progress towards getting our subcontracts in place and received the requested adjustments to ISU’s budget sheets. These were sent to the CAM on 4/30/2020. As the COVID-19 situation is country-wide, we anticipate slower responses from our partners due to similar delays in their organizations to what we are experiencing internally. Although their response times will be slower, both ISU and Frontline are continuing to make good progress on their work for the demonstration in Iowa for this summer, which is assisting with keeping us on schedule for the overall effort. We are continuing to work on the required documents for our subcontracts – though neither will be placed before we receive official approval from our CAM – so that once we have approval, we can place them very quickly.
Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis (Progress Report)
In the month of May, we planned to have the Site License Agreement with SPI signed and fully executed, make further progress on the market assessment for the Wood-to-Bio-oil Market Report, and hoped to have the subcontracts in place with Iowa State University and Frontline BioEnergy, LLC once we ha approval from the CAM. We also planned to have the updated Advanced Reconciliation to the CAM for approval as requested.
Wood-to-Fuel for California's Transportation Sector using Autothermal Pyrolysis
A progress report for FRD-17-002 is provided.