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At least 703 records · Page 39

Some characteristics of polymers in composite materials and as electrical conductors

The characteristics of carbon fibers (CF) made from polyacrylonitrile (PAN) materials are discussed, together with research on conducting polymers. CF materials have better mechanical properties, chemical inertness, and higher stiffness than metallic materials but are subject to environmental instability, flammability, and delamination fatigue. Polymerization procedures for the monopolymer PAN are described, noting the use of SEM and X-ray diffraction techniques for studying the fiber structure. High modulus and strength of CF are caused by covalent sp(2) bonds in hexagonal carbon rings, which are stronger than the same links in diamonds. Details of the molecular chain structures and macroformations, stress-strain as a function of temperature, and thermosetting and glass transition temperatures of polymers are provided. Computational quantum chemistry techniques are being applied to studying electrical conductance in polymers, mainly to discover ways to stabilize the materials. Doped CH(x) has exhibited photovoltaic properties and other polymers have become superconductors at cryogenic temperatures.

Hansen, C. F.↗

Fast-Recovery, High-Voltage Power Diode

New family of fast-recovery high-voltage power diodes compatible with D60T and D7ST transistors developed. Have wide range of applications in spacecraft and aircraft electrical distribution equipment, dc/dc inverters, and ac motor controllers for high-horsepower electric motors operating from 480-volt ac lines. Fast-Recovery 1,200-V Power Diodes use chip of hexagonal geometry to maximize effective silicon area.

Sundberg, G.↗

Lightweight Electrical Insulation

Hollow plastic spheres expanded and fused together. Hollow, gasfilled plastic spheres piled in mold. Heating in vacuum softens and expands spheres, forcing them together into nearly regular hexagonal close packing. Foam used as lightweight, electrically insulating material in place of solid ceramic, glass, or polymer. Padding to protect against mechanical shocks another application for such dense, regular foam.

Schroeder, J. E.↗

Large amplitude forcing of a high speed 2-dimensional jet

The effect of large amplitude forcing on the growth of a high speed two dimensional jet was investigated experimentally. Two forcing techniques were utilized: mass flow oscillations and a mechanical system. The mass flow oscillation tests were conducted at Strouhal numbers from 0.00052 to 0.045, and peak to peak amplitudes up to 50 percent of the mean exit velocity. The exit Mach number was varied in the range 0.15 to 0.8. The corresponding Reynolds numbers were 8,400 and 45,000. The results indicate no significant change of the jet growth rate or centerline velocity decay compared to the undisturbed free jet. The mechanical forcing system consists of two counter rotating hexagonal cylinders located parallel to the span of the nozzle. Forcing frequencies up to 1,500 Hz were tested. Both symmetric and antisymmetric forcing can be implemented. The results for antisymmetric forcing showed a significant (75 percent) increase of the jet growth rate at an exit Mach number of 0.25 and a Strouhal number of 0.019. At higher rotational speeds, the jet deflected laterally. A deflection angle of 39 deg with respect to the centerline was measured at the maximum rotational speed.

Bernal, L.↗

Crystal Chemistry of Meteoritic Hibonites

The characteristics of cation vacancies and site occupancies of natural hibonites in meteors are discussed. Note is taken of the effect of the specific locations of the hibonites in the matrices on the crystal chemistry, electronic stabilities, and spectral features of the metal ions which replace the Al(3+). Hibonites form beta-alumina hexagonal cells with 26 cation sites. Fe cations are found in octahedral, tetrahedral, and five-fold coordinates. Fe(2+) is found in face-shared Al(3) octahedra, a siting explained in terms of ionic radius and crystal field stabilization energy criteria. Spectral colors are attributed to V(3+) and Ti(3+) field transitions at 400 and 700 nm, respectively, although the 700 nm line may arise from transitions of Ti(3+) to Ti(4+) or Fe(2+) to Fe(3+) during heating. Excesses of Mg-26 can be traced to decay of nebular Al-26.

Burns, R. G.↗

Penetrative cellular convection in a stratified atmosphere

In the present investigation of penetrative convection within a simple compressible model, the middle one of the three layers of differing stratification prior to the onset of convection is a convectively unstable polytrope bounded above and below by two stably stratified polytropes. One- and two-mode steady solutions with hexagonal planforms have been studied for Rayleigh numbers up to aobut 1000 times critical, and for a range of Prandtl numbers, horizontal wavenumbers, and stratifications. These indicate that the penetration into the lower stable layer by downward plumes is substantially larger in a stratified medium than in a Boussinesq fluid, and produces an extended region of adiabatic stratification. The strong asymmetry between upward and downward penetration in compressible media has major implications for the mixing of stable regions above and below stellar convection zones.

Massaguer, J. M.↗

Crystal chemistry of meteoritic hibonites

The characteristics of cation vacancies and site occupancies of natural hibonites in meteors are discussed. Note is taken of the effect of the specific locations of the hibonites in the matrices on the crystal chemistry, electronic stabilities, and spectral features of the metal ions which replace the Al(3+). Hibonites form beta-alumina hexagonal cells with 26 cation sites. Fe cations are found in octahedral, tetrahedral, and five-fold coordinations. Fe(2+) is found in face-shared Al(3) octahedra, a siting explained in terms of ionic radius and crystal field stabilization energy criteria. Spectral colors are attributed to V(3+) and Ti(3+) field transitions at 400 and 700 nm, respectively, although the 700 nm line may arise from transitions of Ti(3+) to Ti(4+) or Fe(2+) to Fe(3+) during heating. Excesses of Mg-26 can be traced to decay of nebular Al-26.

Burns, R. G.↗

New techniques for fusion bonding and replication for large glass reflectors

Lightweight, space-deployable glass honeycomb telescope primary mirror structures are produced by a novel method which involves the heating to softening temperature of many borosilicate or silica glass tube sections that are packed to form a honeycomb matrix and filled with a high expansion coefficient refractory sand. The close packed tubes yield a hexagonal-cell honeycomb. Attention is given to the results of an experiment in which a highly refractory master was used to shape a honeycomb of less refractory glass, employing a 1-micron thick, vacuum-deposited gold coating as a parting layer between the two.

Angel, J. R. P.↗

Steps toward 8m honeycomb mirror blanks. III - 1.8m honeycomb sandwich blanks cast from borosilicate glass

The design, fabrication techniques, and equipment used for producing two 1.8-m honeycomb sandwich blanks, eventually leading to production of 8-m blanks, are reported. The procedure employed 85 cast hexagonal tiles at the bottom section, affixed against flotation by SiC bolts. The two plano concave mirrors are 1.83 m thick, weight 500 kg, and are each designed for 19 supports of astatic-lever type. Both blanks are of high quality and with an adequately low bubble content; one is to be figured to high-precision 0.25-arcsecond images, and is to be tested on the Multiple Mirror Telescope. Construction of a spin-casting facility based on the same principle is being planned for test-fabricating spin-cast mirrors on a smaller scale.

Angel, J. R. P.↗

Prediction of structures and magnetic orientations in solid alpha and beta-O2

A quasi-harmonic-lattice-dynamics method coupled with a pattern-recognition optimization scheme is used to determine the minimum energy structures and magnetic orientations of solid oxygen. It is shown that the magnetic interaction is responsible for the stability of alpha-O2 with respect to beta-O2 at zero temperature and pressure. The calculated alpha-O2 lattice parameters, magnetic orientations, and sublimation energy are in good agreement with experiment. Phonon dispersion curves are calculated at vector k not equal to zero and the acoustic sound velocities are determined. The rms translational and orientational fluctuations from equilibrium are also calculated. The beta-O2 phase is described by constraining the magnetic moments so that the magnetic Hamiltonian preserves the hexagonal symmetry of the crystal. The calculated lattice parameters are in good agreement with the experiments, and a three-sublattice, quasi-helical magnetic orientation is predicted from structural and energetic considerations.

Etters, R. D.↗

Honeycomb panel heat pipe development for space radiators

An assessment of the honeycomb panel heat pipe concept as a moderate temperature range, low-mass, highly efficient radiator fin for the NASA Space Station is presented, based on test results for a thin-wall (0.46 mm) all-welded stainless steel sample with core depth of 63.5 mm and a hexagonal-cell size of 127.7 mm. The 0.61 x 3.05 m test segment, operating with methanol as a working fluid, exhibited a maximum heat transfer rate of 600 W at 50 C and was isothermal to within + or - 2 C almost entirely throughout the surface. Tilt testing, which comprised relocation of the heater along one edge of the panel, resulted in maximum power levels of 70 and 50 W at panel elevations of 12.7 and 25.4 mm, respectively. As-designed panel performance is predicted to be from 500 to 1000 W over the range of operating temperatures; better performance is predicted for an open-channel design.

Tanzer, H. J.↗

Internally Wrenching Nut

Less space needed for installation and removal. Nut for use with short bolts torqued with allen wrench. In contrast with standard hexagonal nuts, new nut requires no external wrench clearance on installation surface. Nut has many uses in assemblies where space is limited, especially in automotive and aircraft industries.

Cortes, R. G.↗

Storing Chemicals in Packed Spheres

Reactants released by crushing or puncturing. Agglomerated gas-filled spheres hexagonally close packed and sintered or glued together into rods strung together at ends. Rods fed into crushing machine to release material in spheres as needed.

Wang, T. G.↗

Surface Tension Induced Instabilities in Reduced Gravity: the Benard Problem

A Benard convection experiment has been set up, and the onset of convection in shallow layers of silicone oil two millimeters or less deep has been studied. The onset has been observed visually or has been determined by the break in the heat transfer curve which accompanies the onset of convection. The outcome of these experiments has been very surprising, from the point of view of theoretical expectations. The onset of convection at temperature differences far below the critical value for fluid depths smaller than 2mm was observed. The discrepancy between experiments and theory increases with decreasing fluid depth. According to theoretical considerations, the effects of surface tension become more important as the fluid depth is decreased. Actually, one observes that the onset of convection tales place in two stages. There is first an apparently surface tension driven instability, occuring at subcritical temperature differences according to conventional theory. If then the temperature difference is increased, a second instability occurs which transform the first pattern into conventional strong hexagonal Benard cells. The second instability is in agreement with the critical temperature gradients predicted by Nield.

Koschmieder, E.↗

High temperature dispersion strengthening of NiAl

A potential high temperature strengthening mechanism for alloys based on the intermetallic compound NiAl was investigated. This study forms part of an overall program at NASA Lewis Research Center for exploring the potential of alloys based on NiAl for high temperature applications. An alloy containing 2.26 at% Nb and produced by hot extrusion of blended powders was examined in detail using optical and electron microscopy. Interdiffusion between the blended Nb and NiAl powders results in the formation of intermediate phases. A fine dispersion of precipitates of a hexagonal, ordered NiAlNb phases in a matrix of NiAl can be produced and this results in strengthening of the alloy by interfering with dislocation motion at high temperature. These precipitates are, however, found to coarsen during the high temperature (1300 K) deformation at slow strain rates and this may impose some limitatioins on the use of this strengthening mechanism.

Sherman, M.↗

Stencils and problem partitionings: Their influence on the performance of multiple processor systems

Given a discretization stencil, partitioning the problem domain is an important first step for the efficient solution of partial differential equations on multiple processor systems. Partitions are derived that minimize interprocessor communication when the number of processors is known a priori and each domain partition is assigned to a different processor. This partitioning technique uses the stencil structure to select appropriate partition shapes. For square problem domains, it is shown that non-standard partitions (e.g., hexagons) are frequently preferable to the standard square partitions for a variety of commonly used stencils. This investigation is concluded with a formalization of the relationship between partition shape, stencil structure, and architecture, allowing selection of optimal partitions for a variety of parallel systems.

Reed, D. A.↗

Rheologies of H2O ices Ih, II, and III at high pressures - A progress report

Ordinary hexagonal ice (ice Ih) represents the stable crystalline form of H2O on the earth's surface. It is known that ice exists elsewhere in the solar system. Thus, several of the moons of Saturn and Jupiter are composed predominately of H2O and their surface temperatures are about 75 and 100 K. The pressures in the interior of some of the larger of the moons may be as high as 3 GPa. The involved pressures and temperatures extend far beyond the conditions over which the rheological laws for ice Ih can be confidently extrapolated. It is, therefore, necessary to obtain information regarding the rheologies of H2O ices in pressure and temperature ranges which had not yet been previously considered. Since 1981, over 100 triaxial compression tests have been conducted over a wide range of temperatures (77 to 258 K) and pressures (0.1 to 350 MPa). The present paper provides a progress report of these experiments.

Kirby, S. H.↗

The structure of small metal clusters

One metal atom surrounded by its 12 nearest neighbors is considered for both D(3d) (face-centered cubic-like) and D(3h) (hexagonal close-packed-like) geometries. For Al and Be, the neutral cluster and the positive and negative ions are considered for idealized (all bonds equal) and distorted geometries. The D(3d) geometry is found to be the lowest for Be13, while the D(3h) geometry is lower for Al13. This is the reverse of what is expected based upon the bulk metal structures, Be(hcp) and Al(fcc). Al13 is found to have only small distortions, while Be13 shows large distortions for both the D(3d) and D(3h) geometries. The ions have geometries which are similar to those found for the neutral systems. Both all-electron and effective core potential calculations were carried out on the X13 clusters; the agreement is very good.

Bauschlicher, C. W., Jr.↗