A microscopic and thermal study of the solidification of hexadecane Annual summary report, 21 Nov. 1968 - 31 Dec. 1969
Microscopic and thermal study of n-paraffins as phase change thermal control materials
Golden, J. O.↗
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Research of metal solidification in zero-g state
An experiment test apparatus that allows metal melting and resolidification in the three seconds available during free fall in a drop tower was built and tested in the tower. Droplets (approximately 0.05 cm) of pure nickel and 1090 steel were prepared in this fashion. The apparatus, including instrumentation, is described. As part of the instrumentation, a method for measuring temperature-time histories of the free floating metal droplets was developed. Finally, a metallurgical analysis of the specimens prepared in the apparatus is presented.
Aubin, W. M.↗
Electromagnetic containerless melting and solidification in the weightless environment
General facility concepts capable of processing the widest range of possible important containerless processing experiments within reasonable technology constraints are indicated. An important part of the work has been to make an up-to-date summary of these experiment possibilities. An attempt has been made to consider materials based on importance in terms of new scientific data or possible future commercial applications.
Frost, R. T.↗
Solidification in neutron star cores
A mathematical computation based on the t-matrix approach shows that a system of strongly interacting baryons under sufficiently high pressure (approximately 10 to the 30th power atm) and densities greater than 10 to the 15th power g/cu cm minimizes the energy by arranging the constituents in a lattice structure rather than in a fluid phase. The solution is given assuming an optimum spin arrangement, although all other possible arrangements would also satisfy the conditions for crystallization to occur.
Canuto, V.↗
External field effects on solidification - Macroscopic and microscopic models
Comparison of theoretical effects of magnetic and gravitational fields on melts of metals and semiconductors provides two kinds of insight into space processing materials problems. First, the task of comparing effects of the two fields yields mathematical models which may be used to estimate material properties and responses to processing under various field conditions. Then, by using these models, microgravity effects can be inferred from magnetic field data already obtained in laboratories on earth. Magnetohydrodynamics (static and oscillating fields) and the Free Volume Model are used to study macroscopic effects, and Sekerka's interface stability theory is used to show how external fields can affect microsegregation. It is demonstrated that the mathematical formalism is essentially the same for describing macroscopic effects of both microgravity and magnetic fields.
Miller, R. I.↗
Undercooling of materials during solidification in space
The theoretical and actual effect of undercooling on molten materials below the equilibrium solid us temperature was studied. Materials in the categories of pure metals, alloys, and compounds were examined: their commercial and scientific value and past experience in their undercooling were considered. The material properties influencing undercooling behavior are reviewed, specified, and categorized. The effects of gravity and its absence are investigated. It is shown that presence of heterogeneous nucleating agents is the main obstacle to achieving a large degree of undercooling.
Moak, D. P.↗
The influence of acceleration forces on nucleation, solidification, and deformation processes in tin single crystals
An apparatus was designed and assembled to directionally solidify single crystals under the influence of acceleration forces of various magnitudes. The investigation conducted showed that acceleration gradients produce a preferred growth orientation effect not previously observed for tin. Convection currents at approximately 5-g encourage multiple nucleation and subsequent random orientation of growth direction. Deformation effects such as recrystallization and twinning are observed at acceleration levels greater than 2-g.
Johnston, M. H.↗
Solidification kinetics
The vapor systems GeI2 and I2 and solid GeI4 were analyzed, using Raman spectroscopic techniques. The Raman bands of I2 and GeI4 were confirmed and Raman bands for GeI2 at 230 and 360 cm to the -1 power were reported. The application of the Raman techniques as a temperature probe in vapor transport kinetics was studied, and its feasibility is considered to be very good.
Mcnutt, R. C.↗
Flight 1 technical report for experiment 74-37 contained polycrystalline solidification in low-G
A .005 M solution of fluorescein in cyclohexanol was directionally solidified in a standard 10 x 10 x 45mm UV silica cuvette, using a bottom thermoelectric chilling device. Progress of the experiment was monitored by time lapse photography. During flight (SPAR I) the camera malfunctioned and only one quarter of the expected data were collected. Comparison of flight and ground specimens indicated that: (1) The dark green layer observed ahead of the solid-liquid interface which is most likely the solute-enriched zone, appears to be wider in the flight specimen; (2) Parasitic nucleation ahead of the solid-liquid interface in the flight sample led to an irregularly shaped interface, smaller grain size, equiaxed grain morphology and a larger average macroscopic growth rate; (3) The formation of equiaxed grains ahead of the solid-liquid interface in the flight specimen may be attributed to ordered islands within the liquid, which survived remelting because of the low degree of superheating (approximately equal to 1.5 C), did not settle because of reduced gravity and acted as nuclei during cooling.
Papaziak, J. M.↗
The influence of chromium content on the solidification characteristics and microstructure-property relationships in the directionally solidified gamma/gamma prime - delta eutectic
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Sheffler, K. D.↗
The direct observation of solidification as a function of gravity level
A saturated solution of NH4Cl was solidified on earth at 1 g and in a suborbital rocket flight at .00001 g. In the 1 g experiments, macrosegregation caused by the gravitational acceleration was marked. Nucleation started at the cold walls after which dendrites and dendritic debris were swept into the center of the cuvette by convective fluid flow. Secondary dendrite arms were oriented toward the cold wall. When solidified in low g, only four nuclei grew to form the complete casting. There were no free floating crystals or visible dendrite remelting. The lack of fluid flow allowed symmetrical dendrite growth into the fluid.
Johnston, M. H.↗
Preparation of amorphous ferromagnetic materials through containerless solidification
The work reported herein consists of: (1) the ground based experiments; (2) the analysis of the ground based specimens; (3) the flight experiment; (4) failure to melt analysis; and (5) recommendations and conclusions. The ground based experimental work yielded new results in terms of understanding the viscoelastic properties of ferromagnetic metallic glasses and the variation of viscosity through the glass transition temperature from metallic glass to crystalline solid. This last result was of importance in predicting what glass can be produced at lower quench rates.
Lord, A. E., Jr.↗
Convective heat transfer during dendritic solidification
Experiments on succinonitrile are described in which the dependence of dendritic growth velocity is studied as a function of orientation with respect to gravity. Growth rate measurements were carried out at a relatively small supercooling, requiring high specimen purity as well as extreme thermal stability and precision temperature measurement. The normalized growth velocity showed a dependence on orientation described by the ratio of observed growth velocity to that expected for convection-free growth being equal to 3.52 times the n-th power of Cos half the orientation angle, where n lies between 0.5 and 0.75.
Glicksman, M. E.↗
Traction and lubricant film temperature as related to the glass transition temperature and solidification
Does a traction fluid have to be a glass or solid under operating conditions. Infrared spectra on dynamic EHD contacts of several types of fluid were used to determine the surface and oil-film temperatures. Polarized spectral runs were made to study molecular alignment. Static glass transition pressures at appropriate temperatures were between 0.1 and 2.0 GPa, with the traction fluid showing the highest. In the EHD contact region, the traction fluid showed both the highest film temperatures as well as the greatest degree of molecular alignment. A plot of the difference between the film and surface temperatures vs shear rate resulted in a master plot valid for all the fluids. From this work, the authors propose a model of 'fluid' traction, where friction between parallel rough molecules provides the traction.
Lauer, J. L.↗
Solidification (crystal growth) in the presence of gravitational forces
The surface tension behavior of doped and undoped InSb melts was investigated as well as their temperature and composition dependence. Surface tension in InSb melts was determined using the sessile-drop technique covering the temperature range from 530 C to 880 C. A linear regression of the data obtained shows that the temperature dependence of sigma is 392- (T-530) x (7000) plus or minus 10 dyne/cm. The d sigma/d Tau for intrinsics InSb is less than that previously reported. On the basis of the surface tension data obtained, it is concluded that surface tension induced convective flow velocities in InSb under reduced gravity conditions range from zero to at most 1 cm/sec. Accordingly, no interference with dopant segregation can be expected during growth in space because the momentum boundary layer (at the crystal melt interface) associated with any Marangoni-type convective flows would, at the given growth rate, be significantly larger than the predicted diffusion boundary layer thickness.
Gatos, H. C.↗
Convection and diffusion effects during dendritic solidification
A report is presented of the first quantitative measurements of dendritic growth at supercooling levels where convection instead of diffusion is the controlling heat transfer mechanism. Precautions similar to that used in an investigation conducted by Glicksman et al. (1976) were taken to insure 'free' dendritic growth conditions. Dendritic growth velocity was measured as a function of growth orientation at seventeen supercoolings which ranged from 0.043 C to 2 C. Selected but representative measurements of velocity versus orientation angle are shown in a graph. The relative growth velocity of a downward growing dendrite is found to be greater than that of a diffusion-limited dendrite. This result is consistent with that expected from the enhanced heat transfer arising from natural convection.
Glicksman, M. E.↗
Gravitational influences on the liquid-state homogenization and solidification of aluminum antimonide
Typical commercial or laboratory-prepared samples of polycrystalline AlSb contain microstructural inhomogeneities of Al- or Sb-rich phases in addition to the primary AlSb grains. The paper reports on gravitational influences, such as density-driven convection or sedimentation, that cause microscopic phase separation and nonequilibrium conditions to exist in earth-based melts of AlSb. A triple-cavity electric furnace is used to homogenize the multiphase AlSb samples in space and on earth. A comparative characterization of identically processed low- and one-gravity samples of commercial AlSb reveals major improvements in the homogeneity of the low-gravity homogenized material.
Ang, C.-Y.↗
Preparation of monotectic alloys having a controlled microstructure by directional solidification under dopant-induced interface breakdown
Monotectic alloys having aligned spherical particles of rods of the minor component dispersed in a matrix of the major component are prepared by forming a melt containing predetermined amounts of the major and minor components of a chosen monotectic system, providing in the melt a dopant capable of breaking down the liquid solid interface for the chosen alloy, and directionally solidfying the melt at a selected temperature gradient and a selected rate of movement of the liquid-solid interface (growth rate). Shaping of the minor component into spheres or rods and the spacing between them are controlled by the amount of dopant and the temperature gradient and growth rate values. Specific alloy systems include Al Bi, Al Pb and Zn Bi, using a transition element such as iron.
Parr, R. A.↗