Search NASA⌕ Search

SEARCH · Search NASA

Results for “surface effect”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 703 records · Page 39

Effect of lunar surface material on radiation damage in mice (investigation of biological action of lunar surface material returned to earth by Luna 16 automatic station)

The effect was studied of lunar surface material from the Sea of Fertility on the radiation reaction (damage) in mice caused by exposure to ionizing radiation. The material was administered to the organism in three ways -- aerogenically, through the esophagus, or peritoneally. It was shown that administering the lunar surface material did not appreciably affect the death of the animals and the reaction of the peripheral blood caused by the action of radiation. In mice which prior to irradiation had been administered inhalationally or peritoneally the lunar surface material, a lag in the increment of bodyweight was observed.

Antipov, V. V.↗

Fatigue Behavior of Laser Powder Bed Fused HAYNES 214: Effects of Different Surface Treatments

In this study, under NASA’s Rapid and Analysis Manufacturing Propulsion Technology (RAMPT) project, effects of different surface post-treatments on surface texture and fatigue behavior of L-PBF Alloy 214 were investigated. Various subtractive SPTs including abrasive flow machining (AFM), machining (M), shot peening (SP), vapormatt (VM), dry electropolishing (DE), chemical milling (CM), chemical-mechanical polishing (CMP), electro chemical (ECP) were applied to study the variations of the surface texture, microstructure and uniaxial fatigue behavior under fully reversed strain-controlled condition at four different strain amplitudes of 0.005, 0.004, 0.003, and 0.0025 mm/mm. The insights gained regarding the relationship between structural and mechanical properties for different SPTs can help establish guidelines for selecting the most effective process to enhance the performance of Laser Powder Bed Fusion (L-PBF) Alloy 214, especially for critical aerospace applications.

Post-Processing↗

Electrochemical characterization of InP structures

Electrochemical (EC) techniques represent a simple and yet accurate method to characterize InP and related materials structures. With EC techniques, uncertainties in the measurements arising from factors such as surface effects, the composition and thickness of a front dead layer, the contacts, etc., can be significantly reduced when both a suitable electrolyte is used and the measuring conditions are carefully selected. In this work, the use of photoelectrochemical techniques with InP structures is reported. The work focuses on both the characterization and the optimization of structures grown by thermal diffusion and by epitaxial methods. Characterization of the structures is done by studying the variation in the density of surface states, number of defects, and net majority carrier concentration as a function of material removed. A step-by-step optimization process of n(sup +)p and p(sup+)n InP structures is also described. This involves the passivation and subsequent removal of damaged layers in order to extract the performance parameters of solar cells fabricated with these structures.

Faur, Maria↗

On Thermodynamic and Kinetic Mechanisms for Stabilizing Surface Solid Solutions

Many processes for energy storage rely on transformations between phases with strong separation tendencies. In these systems, performance limitations can arise from undesirable chemical and mechanical factors associated with the phase separation behavior. Solid solutions represent a desirable alternative, provided the conditions for their formation are known. In the present work, we invoke linear stability theory and diffuse-interface mesoscopic simulations to demonstrate that solid solutions can be stabilized near surface layers of phase-separating systems. Two factors are found to drive surface solid-solution formation: surface relaxation of solution self-strain energy and anisotropy of diffusion mobility. Using a strongly phase-separating LiXFePO4 particle as a model system, we show that the relaxation of the solution self-strain energy competes against the relaxation of the coherency strain energy to stabilize surface solid solutions. Our theoretical understanding also suggests that highly anisotropic diffusion mobility can provide an alternative kinetic route to achieve the same aim, with stabilizing behavior strongly dependent on the specific alignment of the surface orientation. Our findings provide fundamental guidance for manipulating solid-solution behavior in nanoscale structures, in which surface effects become especially significant. Beyond energy storage materials, our findings have important implications for understanding solid-solution formation in other phase-separating systems from metal alloys to ceramics.

25 ENERGY STORAGE↗

Automation of Overset Structured Mesh Generation onBoundary Representation Geometries

A scheme is presented for the automatic generation of structured overset meshes ongeometries that are defined by Boundary Representation (BRep) solids. The surface meshsystem consists of face, edge and node meshes corresponding to the three respective basicBRep entity types. A cut-cell method is introduced to improve robustness of the on-geometrydetermination test for a face mesh grid point. A geometric component tagging scheme is utilizedto enhance local grid point distribution on a configuration with a large range of geometricscales. A cap grid topology is automatically utilized around the trailing edge of wing and tailtips to enhance mesh quality and to enable more effective surface coverage. Robustness of thehyperbolic surface marching method is improved by replacing the point projection scheme witha walking scheme. Relaxation of surface grid spacing at concave corners enables automatedhigh quality hyperbolic volume mesh creation. Domain connectivity is automatically performedon the surface mesh system. A variety of test cases are presented including a re-entry capsule,two models of the Juncture Flow Experiment wing-body, five rotorcraft concept vehicles, andvarious components of the High-Lift Common Research Model from the High-Lift PredictionWorkshop 4.

TTT↗

Ocean Surface Flux Algorithm Effects on Tropical Indo-Pacific Intraseasonal Precipitation

Surface latent heat fluxes help maintain tropical intraseasonal precipitation. We develop a latent heat flux diagnostic that depicts how latent heat fluxes vary with the near-surface specific humidity vertical gradient (Δq) and surface wind speed (|V|). Compared to fluxes estimated from |V| and Δq measured at tropical moorings and the Coupled Ocean Atmosphere Response Experiment 3.0 (COARE3.0) algorithm, tropical latent heat fluxes in the National Center for Atmospheric Research CEMS2 and Department of Energy E3SMv1 models are significantly overestimated at |V| and Δq extrema. Madden–Julian oscillation (MJO) sensitivity to surface flux algorithm is tested with offline and inline flux corrections. The offline correction adjusts model output fluxes toward mooring-estimated fluxes; the inline correction replaces the original bulk flux algorithm with the COARE3.0 algorithm in atmosphere-only simulations of each model. Both corrections indicate reduced latent heat flux feedback to intraseasonal precipitation, in better agreement with observations, suggesting that model-simulated fluxes are overly supportive for maintaining MJO convection.

54 ENVIRONMENTAL SCIENCES↗

Rarefied solids

One important limit to creating low density materials is the objects' own weight. As a solid or colloidal matrix becomes more rarefied, gravity acts destructively to compress its suporting skeleton. We describe experimental results and propose a model which matches the low gravity behavior of rarefied or fractal solids. On parabolic airplane flights, we sought to demonstrate a key component of producing higher surface area fractals. Flight paths were selected to give a range of gravity levels: 0.01 g/g(sub 0) (low), 0.16 g(sub 0) (Lunar), 0.33 g/g(sub 0) (Martian), 1 g/g(sub 0) (Earth) and 1.8 g/g(sub 0) (high) (where g(sub 0) = 980 cm/sq s). Results using the model material of hydrophobic silica indicated that stable agglomeration of such tenuous objects can increase markedly in reduced gravity. Optical characterization revealed that fractal dimension changed directly with varying gravity. As measured by fractal dimension, effective surface area and roughness increased by 40% in low gravity. This finding supports the conclusion that relieving internal weight stresses on delicate aggregates can enhance their overall size (by two orders of magnitude) and internal surface area. We conclude that gravitational restructuring limits the overall size and void content of low-density solids. These sparse colloidal regimes may present new and technologically attractive physics, ranging from improved insulators, liquid-like tension in a 'solid' matrix, and characteristically low conductivities for sound and (8 to 14 micrometers wavelength) infrared radiation.

Noever, D. A.↗

Exploratory investigation of the effect of porous surfaces on hypersonic turbulent boundary layers

Four different test surfaces were studied to determine the effect of porous walls on the characteristics of a hypersonic turbulent flat-plate boundary layer. The investigation was an attempt to decrease the surface shear of the boundary layer by transmitting fluctuating pressure energy through the wall and absorbing it in a cavity beneath the wall. Pitot surveys were made at two locations, schlieren photographs of the boundary layer were taken, and hot-wire measurements in the flow above the boundary layer were made to determine whether the surfaces affected the turbulent boundary layer. Neither an increase nor a decrease in surface shear or boundary-layer growth was detected. Tabulations of the pitot data are included.

Watson, R. D.↗

Revealing the Transient Formation Dynamics and Optoelectronic Properties of 2D Ruddlesden–Popper Phases on 3D Perovskites

Using in situ photoluminescence measurements during the spin-coating and annealing steps, this study probes the formation of 2D layers on 3D triple cation perovskite films comparing phenylethylammonium and 2-thiophenemethylammonium iodide bulky cations. This study elucidates the formation mechanisms of the surface layers for both cases and reveals two regimes during 2D layer formation: a kinetic-driven and a thermodynamic-driven process. These driving forces result in different compositions of the 2D/3D interface for each treatment, namely, different ratios of pure 2D (n = 1) and quasi-2D (n > 1) structures. Further, this study shows that a higher ratio of quasi-2D phases is more beneficial for device performance, as pure-2D layers may hamper current extraction. Due to a more evenly distributed formation energy profile among 2D and quasi-2D phases, highly concentrated 2-thiophenemethylammonium iodide appears to be more suited for effective surface passivation than its phenylethylammonium analog.

36 MATERIALS SCIENCE↗

Unraveling the Formation Mechanism of a Hybrid Zr-Based Chemical Conversion Coating with Organic and Copper Compounds for Corrosion Inhibition

Environmental-friendly chromate-free, zirconium (Zr)-based conversion coating is a promising green technology for corrosion protection. Additives in the surface treatment provides critical functionalities and performance improvements; however, mechanistic understanding as of how the additives influence the coatings remains unclear. In this study, a new organic-inorganic hybrid Zrbased conversion coating which combines copper (Cu) compounds and polyamidoamine (PAMAM), taking advantages of a complementary nature of organic and inorganic additives. Here, a multimodal approach combining electron and X-ray characterization is applied to study the interaction of Cu 2+ and PAMAM and the resulting impacts on the coating formation. Adding PAMAM changed the surface morphology, thickness, distribution of Cu in the cluster and void formation of the coatings. High PAMAM (100-200 pm) leads to little conversion coating formation, and low PAMAM (0-25 ppm) shows voids formation under the coatings. Moreover, PAMAM incorporates in the coating in a form of PAMAM-Cu complex with a higher concentration towards the surface, provides an organic layer at the surface of the coating. X-ray absorption near-edge structure (XANES) spectroscopy shows a difference between the conventional and hybrid coating treatments in an alkaline solution to simulate the E-coat process, suggesting the contribution of PAMAM in the enhanced chemical stability in an alkaline environment. Therefore, an intermediate range of addition of PAMAM (50 ppm) is optimal to 1) avoid excessive voids formation, 2) promote some Cu cluster formation and thus enhancing the Zr-based coating formation and 3) incorporate organic components into the coating to improve the adhesion of the subsequent coatings. Overall, this work furthers our knowledge on the formation mechanism of an effective and environmentally friendly hybrid conversion coating for corrosion inhibition, demonstrating a critical processing-structureproperty relationship. This study will benefit future development of green and effective surface treatment technology.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Causes of and Solutions to Wind Speed Bias in NREL's 2020 Offshore Wind Resource Assessment for the California Pacific Outer Continental Shelf

This report provides the results of a detailed analysis into the causes of high wind speed bias in the 20-year wind resource data set for offshore California the National Renewable Energy Laboratory (NREL) released in 2020, herein called CA20. The data set was developed using the state-of-the-art Weather Research and Forecasting (WRF) model. Notably, no floating lidars were available at the time in offshore California to validate offshore hub-height wind speeds. In late 2020, the Pacific Northwest National Laboratory (PNNL) deployed two floating lidars in the California outer continental shelf (OCS), near the Bureau of Ocean Energy Management (BOEM) call areas of Humboldt and Morro Bay. Using these observations through 2021, NREL found considerable bias in modeled hub-height winds at both locations: up to +2 m/s at Humboldt over a 6-month period, and up to +1 m/s at Morro Bay over a one-year period. Upon the discovery of this bias, the Department of Energy (DOE) and BOEM funded NREL and PNNL to investigate the causes of, impacts of, and solutions to the bias in the CA20 data set. This report summarizes the findings of this research. We first investigated whether different WRF model setups could lead to reduced bias. We found that the choice of planetary boundary layer (PBL) scheme - which controls the vertical turbulent mixing of momentum, heat, and moisture in the lowermost part of the atmosphere - greatly affected hub-height wind speeds in the region. Specifically, switching from the Mellor-Yamada-Nakanishi-Niino (MYNN) scheme used in CA20 (and widely used across a range of operational and research weather models) to the less common Yonsei University (YSU) scheme nearly eliminated the bias at both the Humboldt and Morro Bay lidar locations. The large discrepancy between the MYNN- and YSU-modeled hub-height winds pointed towards the role of atmospheric stability. In general, PBL schemes agree well in conditions of high turbulence and mixing, normally referred to as "unstable" conditions. By contrast, PBL schemes start to diverge in "stable" conditions, where turbulence is low and thermal stratification (i.e., higher temperature air sitting on top of colder air) greatly suppresses vertical mixing. Under such conditions, winds aloft can decouple from surface effects and greatly accelerate, causing high wind speeds at hub-height and frequent low-level jets (LLJs). We determined that these stable conditions are in fact dominant in offshore California. The region is characterized by moderate-to-extreme stable stratification with a LLJ on average around 200 meters above sea-level. To our knowledge, no wind energy area globally has as strongly stable stratification as offshore California. Under these extreme conditions, we determined that the MYNN scheme models higher stability than YSU, resulting in less vertical turbulent mixing than YSU, allowing for the acceleration of hub-height winds, more intense LLJs, and higher-amplitude inertial oscillations. Using surface observations, we found that MYNN overestimates near-surface stability, whereas YSU tends to model stability better. We then considered several short-term case studies to assess additional meteorological drivers of the bias at Humboldt. We found that during synoptic scale northerly flows driven by the North Pacific High and inland thermal low, a coastal warm bias in the MYNN case studies contributes to the modeled wind speed bias by altering the boundary layer thermodynamics via a thermal wind mechanism. Given the strong performance of the YSU-based runs in offshore California, NREL has produced and published an updated version of the CA20 data set with YSU as the PBL scheme. This updated data set is now part of NREL's 2023 National Offshore Wind (NOW-23) data set, which covers all the U.S. offshore waters. The development and final validation of the NOW-23 data set in offshore California is documented in this report.

17 WIND ENERGY↗

Molecular beam scattering of ammonia from a dodecane flat liquid jet

The evaporation and scattering of ND 3 from a dodecane flat liquid jet are investigated and the results are compared with previous studies on molecular beam scattering from liquid surfaces. Evaporation is well-described by a Maxwell–Boltzmann flux distribution with a cos θ angular distribution at the liquid temperature. Scattering experiments at E i = 28.8 kJ mol -1 over a range of deflection angles show evidence for impulsive scattering and thermal desorption. Further, at a deflection angle of 90°, the thermal desorption fraction is 0.49, which is higher than that of other molecules previously scattered from dodecane and consistent with work performed on NH 3 scattering from a squalane-wetted wheel. ND 3 scattering from dodecane results in super-specular scattering, as seen in previous experiments on dodecane. The impulsive scattering channel is fitted to a “soft-sphere” model, yielding an effective surface mass of 55 amu and an internal excitation of 5.08 kJ mol -1 . Overall, impulsively scattered ND 3 behaves similarly to other small molecules scattered from dodecane.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Relationships between pigment composition variation and reflectance for plant species from a coastal savannah in California

Advances in imaging spectroscopy have indicated that remotely sensed reflectance measurements of the plant canopy may be used to identify and qualify some classes of canopy biochemicals; however, the manner in which differences in biochemical compositions translate into differences is not well understood. Most frequently, multiple linear regression routines have been used to correlate narrow band reflectance values with measured biochemical concentrations. Although some success has been achieved with such methods for given data sets, the bands selected by multiple regression are not consistent between data sets, nor is it always clear what physical or biological basis underlies the correlation. To examine the relationship between biochemical concentration and leaf reflectance signal we chose to focus on the visible spectrum where the primary biochemical absorbances are due to photosynthetic pigments. Pigments provide a range of absorbance features, occur over a range of concentrations in natural samples, and are ecophysiologically important. Concentrations of chlorophyll, for example, have been strongly correlated to foliar nitrogen levels within a species and to photosynthetic capacity across many species. In addition pigments effectively absorb most of the photosynthetically active radiation between 400-700 nm, a spectral region for which silicon detectors have good signal/noise characteristics. Our strategy has been to sample a variety of naturally occurring species to measure leaf reflectance and pigment compositions. We hope to extend our understanding of pigment reflectance effects to interpret small overlapping absorbances of other biochemicals in the infrared region. For this reason, selected samples were also tested to determine total nitrogen, crude protein, cellulose, and lignin levels. Leaf reflectance spectra measured with AVIRIS bandwidths and wavelengths were compared between species and within species and for differences between seasons, for changes in the the shape of the spectra. We attempt to statistically correlate these shape changes with differences in pigment compositions. In parallel with our comparisons of pigment composition and leaf reflectance, we have modified the PROSPECT leaf reflectance model to test the contributions of pigments or pigment group concentrations. PROSPECT considers a leaf as a multi-layer dielectric plane with an uneven surface. Jacquemoud adapted the basic analysis of Allen for surface effects, a leaf thickness factor, and the absorption of water and chlorophyll (actually all pigments) and the plant matrix. Our modifications to PROSPECT in the forward direction include breaking out the pigment concentration parameter into separate components for chlorophyll a and b and a number of xanthophylls and carotenes, and introducing a shift and convolution function to model the spread and shift from their in vitro measurements to their in vivo state. Further, we have considered how the matrix elements (i.e., all biochemicals and structural effects not modeled explicity) vary with species.

Ustin, Susan L.↗

Asymmetry in the Seasonal Cycle of Zonal-Mean Surface Air Temperature

At most latitudes, the seasonal cycle of zonal-mean surface air temperature is notably asymmetric: the length of the warming season is not equal to the length of the cooling season. The asymmetry varies spatially, with the cooling season being ∼40 days shorter than the warming season in the subtropics and the warming season being ∼100 days shorter than the cooling season at the poles. Furthermore, the asymmetry differs between the Northern Hemisphere and the Southern Hemisphere. Here, we show that these observed features are broadly captured in a simple model for the evolution of temperature forced by realistic insolation. The model suggests that Earth's orbital eccentricity largely determines the hemispheric contrast, and obliquity broadly dictates the meridional structure. Clouds, atmospheric heat flux convergence, and time-invariant effective surface heat capacity have minimal impacts on seasonal asymmetry. This simple, first-order picture has been absent from previous discussions of the surface temperature seasonal cycle.

seasonal cycle↗

Critical Slowing Down in Time-to-Extinction: An Example of Critical Phenomena in Ecology

We study a model for two competing species that explicitly accounts for effects due to discreteness, stochasticity and spatial extension of populations. The two species are equally preferred by the environment and do better when surrounded by others of the same species. We observe that the final outcome depends on the initial densities (uniformly distributed in space) of the two species. The observed phase transition is a continuous one and key macroscopic quantities like the correlation length of clusters and the time-to-extinction diverge at a critical point. Away from the critical point, the dynamics can be described by a mean-field approximation. Close to the critical point, however, there is a crossover to power-law behavior because of the gross mismatch between the largest and smallest scales in the system. We have developed a theory based on surface effects, which is in good agreement with the observed behavior. The course-grained reaction-diffusion system obtained from the mean-field dynamics agrees well with the particle system.

Gandhi, Amar↗

CDISC Remote Design Method to Simulate Aircraft Interference Effects for the CATNLF Flight Test

The Crossflow Attenuated Natural Laminar Flow (CATNLF)flight test is an experimental evaluation of a laminar flow design approach that will be conducted on a small transonic wing-like model suspended from the Centerline Instrumented Pylon (CLIP) underneath an F-15 vehicle. The upcoming flight testis anticipated to provide experimental data that may be useful for transition prediction code calibrations or laminar flow computational studies. For the computational results to be reliable, relevant aerodynamics must be included in the simulations. It has been shown that the F-15 vehicle produces a notable aerodynamic influence on the CATNLF test article, and that removing the F-15 vehicle from the simulation significantly alters the laminar flow behavior. Because the F-15 vehicle is not a publicly-releasable geometry, if the CATNLF flight test dataset is to be widely used by the community, an alternative method to ensure that the CATNLF test article flight configuration aerodynamics is properly modeled is required. The objective of this research is to use the CDISC aerodynamic design tool to perform a remote design of a surface that would replicate the aerodynamic influence on the CATNLF test article. This new design approach, referred to as the Equivalent Loading via Interference Surface Effects (ELISE), is presented in this paper, including the details on the design setup and results. The ELISE design successfully reproduced theF-15 influence on the CATNLF test article, with predicted transition location within an average of 4% chord of the full flight configuration. An off-design assessment is included for small perturbations in Mach and sideslip angle that suggest the ELISE design can cover a reasonable range of expected flight conditions with the same geometry. This paper is intended to explain the design approach, as well as show results that can be expected when utilizing the ELISE design method.

CDISC↗

CDISC Remote Design Method to Simulate Aircraft Interference Effects for the CATNLF Flight Test

The Crossflow Attenuated Natural Laminar Flow (CATNLF) flight test is an experimental evaluation of a laminar flow design approach that will be conducted on a small transonic wing-like model suspended from the Centerline Instrumented Pylon (CLIP) underneath an F-15 vehicle. The upcoming flight test is anticipated to provide experimental data that may be useful for transition prediction code calibrations or laminar flow computational studies. For the computational results to be reliable, relevant aerodynamics must be included in the simulations. It has been shown that the F-15 vehicle produces a notable aerodynamic influence on the CATNLF test article, and that removing the F-15 vehicle from the simulation significantly alters the laminar flow behavior. Because the F-15 vehicle is not a publicly-releasable geometry, if the CATNLF flight test dataset is to be widely used by the community, an alternative method to ensure that the CATNLF test article flight configuration aerodynamics is properly modeled is required. The objective of this research is to use the CDISC aerodynamic design tool to perform a remote design of a surface that would replicate the aerodynamic influence on the CATNLF test article. This new design approach, referred to as the Equivalent Loading via Interference Surface Effects (ELISE), is presented in this paper, including the details on the design setup and results. The ELISE design successfully reproduced the F-15 influence on the CATNLF test article, with predicted transition location within an average of 4% chord of the full flight configuration. An off-design assessment is included for small perturbations in Mach and sideslip angle that suggest the ELISE design can cover a reasonable range of expected flight conditions with the same geometry. This paper is intended to explain the design approach, as well as show results that can be expected when utilizing the ELISE design method.

CDISC↗

Catastrophic loss of stratospheric ozone in dense volcanic clouds

Rapid, localized loss of ozone is predicted to occur in the midlatitude and tropical stratosphere in the presence of very large concentrations of sulfate aerosols. Volcanic eruptions can increase the effective surface area of sulfuric acid so that heterogeneous reactions involving ClONO2, and secondarily N2O5, are able to suppress NO(x) abundances by more than a factor of 10 relative to gas phase chemistry. When NO(x) levels fall below a threshold, e.g., 0.6 ppb at 24 km in mid-latitudes, the chlorine-catalyzed loss of O3 proceeds at rates comparable to those during the formation of the Antarctic ozone hole, more than 50 ppb per day. If such losses occurred following the eruption of Mount Pinatubo in the most volcanically perturbed regions over the tropics and mid-latitudes, this model predicts that they are driven primarily by the suppression of NO(x) below these critical levels. The increase in stratospheric chlorine since El Chichon has made Mount Pinatubo more than twice as effective in causing rapid O3 loss.

Prather, Michael↗