Investigation of Reflections by the Moon's Surface of Meter Radiowaves
Reflection and scattering of meter radio waves by lunar surface - dielectric constant of lunar rocks
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Surface effects on the microwave backscatter and emission of snow
Measurements were performed with active and passive microwave sensors for both dry and wet snow conditions. A layer of Rayleigh scatterers with irregular surface boundaries is found to be a reasonable model for interpreting passive and active measurements in X- and Ku-bands. It was found that roughness had a significant effect on both backscatter and emission from wet snow; however, only a small effect was noted for dry snow.
Fung, A. K.↗
Specular scattering on a terrestrial playa and implications for planetary surface studies
Multiangle Advanced Solid State Array Spectroradiometer (ASAS) and Portable Apparatus for Rapid Acquisition of Bidirectional Observations of Land and Atmosphere (PARABOLA) visible and near infrared reflectance data covering the Lunar Lake playa, Nevada, were modeled using specular and volume scattering theory. The volume component used to model the data was based on the Hapke (1986) model and the specular scattering component was based on Fresnel reflection from surface facets with a distribution of tilts. Specular scattering was needed to explain the several-fold increase in reflectance observed at high phase angles in the solar principal plane. Results imply single scattering albedos of approximately 0.93 to 0.95, a real index of refraction value of approximately 1.52 (at a wavelength of 0.66 micron), a small imaginary index of refraction and an exponential facet tilt probability function for the playa. Electron micrographs showed th playa surface to consist of ensembles of smooth, micrometer-scale ellipsoidal particles on gently undulating topography at the millimeter to centimeter scale. The exponential probability function is consistent with this observation. Mars and the icy satellites are discussed as possible places to look for a significant specular scattering component.
Shepard, Michael K.↗
Cation valency in water-in-salt electrolytes alters the short- and long-range structure of the electrical double layer
Highly concentrated aqueous electrolytes (termed water-in-salt electrolytes, WiSEs) at solid-liquid interfaces are ubiquitous in myriad applications including biological signaling, electrosynthesis, and energy storage. This interface, known as the electrical double layer (EDL), has a different structure in WiSEs than in dilute electrolytes. Here, we investigate how divalent salts [zinc bis(trifluoromethylsulfonyl)imide, Zn(TFSI) 2 ], as well as mixtures of mono- and divalent salts [lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) mixed with Zn(TFSI) 2 ], affect the short- and long-range structure of the EDL under confinement using a multimodal combination of scattering, spectroscopy, and surface forces measurements. Raman spectroscopy of bulk electrolytes suggests that the cation is closely associated with the anion regardless of valency. Wide-angle X-ray scattering reveals that all bulk electrolytes form ion clusters; however, the clusters are suppressed with increasing concentration of the divalent ion. To probe the EDL under confinement, we use a Surface Forces Apparatus and demonstrate that the thickness of the adsorbed layer of ions at the interface grows with increasing divalent ion concentration. Multiple interfacial layers form following this adlayer; their thicknesses appear dependent on anion size, rather than cation. Importantly, all electrolytes exhibit very long electrostatic decay lengths that are insensitive to valency. It is likely that in the WiSE regime, electrostatic screening is mediated by the formation of ion clusters rather than individual well-solvated ions. This work contributes to understanding the structure and charge-neutralization mechanism in this class of electrolytes and the interfacial behavior of mixed-electrolyte systems encountered in electrochemistry and biology.
Science & Technology - Other Topics↗
Interactions between volume and surface EM waves in layered structures
Using light scattering spectroscopy, the interaction of Surface Plasmon Polariton SPP in silver films on a glass substrate is with the incident radiation and with optical phonons of an external medium in contact with the film. The mean free path and the field strength of SPP are determined. The same SPP plays an important role in light emitting tunnel junctions (LETJ) in which an electrical current is converted into Volume Electromagnetic Wave VEW. The efficiency of light emission from LETJ through a prism coupler rather than through surface roughness is discussed. The coupling between phonon surface polaritons (PhSP) and optical guided waves (OGW) in thin films of GaP is also examined.
Ushioda, S.↗
Direct SERDS sensing of molecular biomarkers in plants under field conditions
Molecular biomarkers such as microRNAs (miRNAs) play important roles in regulating various developmental processes in plants. Understanding these pathways will help bioengineer designing organisms for efficient biomass accumulation. Current methods for RNA analysis require sample extraction and multi-step sample analysis, hindering work in field studies. Recent work in the incorporation of nanomaterials for plant bioengineering research is leading the way of an agri-tech revolution. As an example, surface-enhanced Raman scattering (SERS)–based sensors can be used to monitor RNA in vivo. However, the use of SERS in the field has been limited due to issues with observing Raman signal over complex background. To this end, shifted-excitation Raman difference spectroscopy (SERDS) offers an effective solution to extract the SERS signal from high background based on a physical approach. In this manuscript, we report the first application of SERDS on SERS sensors. We investigated this technique on SERS sensor developed for the detection of a microRNA biomarker, miR858. We tested the technique on in vitro samples and validated the technique by detecting the presence of exogenous miR858 in plants directly under ambient light in a growth chamber. The possibility of moving the detection of nucleic acid targets outside the constraints of laboratory setting enables numerous important bioengineering applications. Finally, such applications can revolutionize biofuel production and agri-tech through the use of nanotechnology-based monitoring of plant growth, plant health, and exposure to pollution and pathogens.
09 BIOMASS FUELS↗
A theoretical study of radar backscatter from distributed targets with emphasis on polarization dependence
Mathematical framework for the electromagnetic scattering from random extended targets, such as terrain and sea surface, encompasses both power scattering and signal deplorization. It incorporates specular treatment of electromagnetic scattering as well as the electrical properties represented by surface impedance and polarization dependence.
Huynen, J. R.↗
Reionization and the cosmic microwave background in an open universe
If the universe was reionized at high reshift (z greater than or approximately equal to 30) or never recombined, then photon-electron scattering can erase fluctuations in the cosmic microwave background at scales less than or approximately equal to 1 deg. Peculiar motion at the surface of last scattering will then have given rise to new anisotropy at the 1 min level through the Vishniac effect. Here the observed fluctuations in galaxy counts are extrapolated to high redshifts using linear theory, and the expected anisotropy is computed. The predicted level of anisotropies is a function of Omega(sub 0) and the ratio of the density in ionized baryons to the critical density and is shown to depend strongly on the large- and small-scale power. It is not possible to make general statements about the viability of all reionized models based on current observations, but it is possible to rule out specific models for structure formation, particularly those with high baryonic content or small-scale power. The induced fluctuations are shown to scale with cosmological parameters and optical depth.
Persi, Fred M.↗
Magellan - Electrical and physical properties of Venus' surface
Magellan probes Venus'surface by 12.6-cm-wavelength vertical and oblique radar scattering and measures microwave thermal emission. Emissivity and root-mean-square slope maps between 330 deg and 30 deg E and 90 deg N and 80 deg S are dissimilar, although some local features are exceptions. Inferred surface emissivities typically are 0.85, but vary from 0.35 at Maxwell to 0.95 northeast of Gula Mons and other locations. Lowest emissivities appear in topographically high areas; this relation suggests that a phase change or differences in chemical weathering occur at about 6055-kilometer radius. Initial results indicate that there are significant variations in the surface scattering function.
Tyler, G. Leonard↗
Dynamics of Micropollutant Adsorption to Polystyrene Surfaces Probed by Angle-Resolved Second Harmonic Scattering
Angle-resolved second harmonic scattering is used to probe the adsorption dynamics of aqueous cationic and anionic dye molecules onto polystyrene surfaces. The adsorptions of malachite green to negatively charged polystyrene and naphthol yellow S to positively charged polystyrene are both highly favorable, with ΔG Ads values of -10.9 ± 0.2 and -10.27 ± 0.09 kcal/mol, respectively. A competitive displacement methodology was employed to obtain values for the adsorption free energies of various smaller neutral organic molecules, including the important micropollutant ascorbic acid, caffeine, and pentoxifylline. For charged adsorbers, electrostatic interactions appear to significantly contribute to adsorption behavior. However, electrostatic repulsion does not necessarily deter the adsorption of molecules with large uncharged moieties (e.g., surfactants). Lastly, in these cases, the mechanism of adsorption is dominated by van der Waals interactions, with the surface charge playing a relatively minor role.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Experimental measurement and theoretical modeling of microwave scattering and the structure of the sea surface influencing radar observations from space
The electromagnetic bias is an error present in radar altimetry of the ocean due to the non-uniform reflection from wave troughs and crests. A study of the electromagnetic bias became necessary to permit error reduction in mean sea level measurements of satellite radar altimeters. Satellite radar altimeters have been used to find the upper and lower bounds for the electromagnetic bias. This report will present a theory using physical optics scattering and an empirical model of the short wave modulation to predict the electromagnetic bias. The predicted electromagnetic bias will be compared to measurements at C and Ku bands.
Arnold, David↗
Surface roughness studies with DALLAS-detector array for laser light angular scattering
An attempt is made to develop a better mathematical description of optical scattering phenomena, in order to construct an optical scattering apparatus for reliable and routine measurements of roughness parameters without resorting to comparator standards. After a brief outline of optical scattering theory, a description is presented of an experimental instrument for measuring surface roughness which incorporates optical scattering principles. The instrument has a He-Ne laser which illuminates the test surface at a variable angle of incidence. Scattered light distribution is detected by an array of 87 fiber-optic sensors positioned in a rotating semicircular yoke. The output from the detector is digitized and analyzed in a laboratory computer. For a comparison with experimental data, theoretical distributions are calculated by substituting the roughness profiles into the operand of and integral equation for electromagnetic scattering developed by Beckmann and Spizzichino (1963). A schematic diagram of the instrument is provided and the general implications of the experimental results are discussed.
Vorburger, T. V.↗
Critical Reflectance Derived from MODIS: Application for the Retrieval of Aerosol Absorption over Desert Regions
Aerosols are tiny suspended particles in the atmosphere that scatter and absorb sunlight. Smoke particles are aerosols, as are sea salt, particulate pollution and airborne dust. When you look down at the earth from space sometimes you can see vast palls of whitish smoke or brownish dust being transported by winds. The reason that you can see these aerosols is because they are reflecting incoming sunlight back to the view in space. The reason for the difference in color between the different types of aerosol is that the particles arc also absorbing sunlight at different wavelengths. Dust appears brownish or reddish because it absorbs light in the blue wavelengths and scatters more reddish light to space, Knowing how much light is scattered versus how much is absorbed, and knowin~ that as a function of wavelength is essential to being able to quantify the role aerosols play in the energy balance of the earth and in climate change. It is not easy measuring the absorption properties of aerosols when they are suspended in the atmosphere. People have been doing this one substance at a time in the laboratory, but substances mix when they are in the atmosphere and the net absorption effect of all the particles in a column of air is a goal of remote sensing that has not yet been completely successful. In this paper we use a technique based on observing the point at which aerosols change from brightening the surface beneath to darkening it. If aerosols brighten a surface. they must scatter more light to space. If they darken the surface. they must be absorbing more. That cross over point is called the critical reflectance and in this paper we show that critical reflectance is a monotonic function of the intrinsic absorption properties of the particles. This parameter we call the single scattering albedo. We apply the technique to MODIS imagery over the Sahara and Sahel regions to retrieve the single scattering albedo in seven wavelengths, compare these retrievals to ground-based retrievals from AERONET instruments and compute error bars on each retrieval. The results show that we can retrieve single scattering albedo for pure dust to within +/-0.02 and mixtures of dust and smoke to within +/-0.03. No other space based instrument has achieved a retrieval of single scattering albedo that spans the spectrum from 0.47 microns to 2.13 microns and produces regional maps of aerosol absorption showing gradients and changes. Applied in a more operational fashion, such information will narrow uncertainties in estimating aerosol forcing on climate.
Wells, Kelley C.↗
Operando identification of site-dependent water oxidation activity on ruthenium dioxide single-crystal surfaces
Understanding the nature of active sites is central to controlling (electro)catalytic activity. Here we employed surface X-ray scattering coupled with density functional theory and surface-enhanced infrared absorption spectroscopy to examine the oxygen evolution reaction on RuO 2 surfaces as a function of voltage. At 1.5 V RHE , our results suggest that there is an –OO group on the coordinatively unsaturated ruthenium (Ru CUS ) site of the (100) surface (and similarly for (110)), but adsorbed oxygen on the Ru CUS site of (101). Density functional theory results indicate that the removal of –OO from the Ru CUS site, which is stabilized by a hydrogen bond to a neighbouring –OH (–OO–H), could be the rate-determining step for (100) (similarly for (110)), where its reduced binding on (100) increased activity. A further reduction in binding energy on the Ru CUS site of (101) resulted in a different rate-determining step (–O + H 2 O – (H + + e - ) → –OO–H) and decreased activity. Our study provides molecular details on the active sites, and the influence of their local coordination environment on activity.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Field experiment to measure the radiative characteristics of a hazy atmosphere
Preliminary results are presented of a field experiment to measure the effect of atmospheric aerosols on the upward radiance at aircraft and satellite altitudes. These measurements, made over Chesapeake Bay, were conducted simultaneously with measurements of aerosol optical characteristics, profile, and spatial distribution. The aerosol vertical optical thickness and the scattering phase function were determined along with profiles of the scattering coefficient, temperatures, and humidity. The results are used to quantify the atmospheric effect on the surface reflectivity as detected from space, including the adjacency effect, and to test theoretical radiative transfer models. The experimental results are also used to test procedures to measure the aerosol optical thickness, the scale height, and the absorption from satellite imagery, and to use the results to correct satellite imagery of the surface. Ground measurements of surface reflectivity and the scattering coefficient at the surface are compared with airborne results.
Kaufman, Y. J.↗
New very high resolution radar studies of the Moon
As part of an effort to further understand the geologic utility of radar studies of the terrestrial planets, investigators at the Hawaii Institute of Geophysics are collaborating with NEROC Haystack Observatory, MIT and the Jet Propulsion Laboratory in the analysis of existing 3.8 and 70 cm radar images of the Moon, and in the acquisition of new data for selected lunar targets. The intent is to obtain multi-polarization radar images at resolutions approaching 75 meters (3.8 cm wavelength) and 400 meters (70 cm wavelength) for the Apollo landing sites (thereby exploiting available ground truth) or regions covered by the metric camera and geochemical experiments onboard the command modules of Apollos 15, 16 and 17. These data were collected in both like- and cross-polarizations, and, in the case of the 70 cm data, permit the phase records to be used to assess the scattering properties of the surface. The distribution of surface units on the Moon that show a mismatch between the surface implied by like- and cross-polarized scattering data is being analyzed, based on the scattering models of Evans and Hagfors.
Mouginis-Mark, Peter J.↗
Classification of simple vegetation types using POLSAR image data
Mapping basic vegetation or land cover types is a fairly common problem in remote sensing. Knowledge of the land cover type is a key input to algorithms which estimate geophysical parameters, such as soil moisture, surface roughness, leaf area index or biomass from remotely sensed data. In an earlier paper, an algorithm for fitting a simple three-component scattering model to POLSAR data was presented. The algorithm yielded estimates for surface scatter, double-bounce scatter and volume scatter for each pixel in a POLSAR image data set. In this paper, we show how the relative levels of each of the three components can be used as inputs to simple classifier for vegetation type. Vegetation classes include no vegetation cover (e.g. bare soil or desert), low vegetation cover (e.g. grassland), moderate vegetation cover (e.g. fully developed crops), forest and urban areas. Implementation of the approach requires estimates for the three components from all three frequencies available using the NASA/JPL AIRSAR, i.e. C-, L- and P-bands. The research described in this paper was carried out by the Jet Propulsion Laboratory, California Institute of Technology under a contract with the National Aeronautics and Space Administration.
Freeman, A.↗
Microwave Remote Sensing Modeling of Ocean Surface Salinity and Winds Using an Empirical Sea Surface Spectrum
Active and passive microwave remote sensing techniques have been investigated for the remote sensing of ocean surface wind and salinity. We revised an ocean surface spectrum using the CMOD-5 geophysical model function (GMF) for the European Remote Sensing (ERS) C-band scatterometer and the Ku-band GMF for the NASA SeaWinds scatterometer. The predictions of microwave brightness temperatures from this model agree well with satellite, aircraft and tower-based microwave radiometer data. This suggests that the impact of surface roughness on microwave brightness temperatures and radar scattering coefficients of sea surfaces can be consistently characterized by a roughness spectrum, providing physical basis for using combined active and passive remote sensing techniques for ocean surface wind and salinity remote sensing.
Sea surface spectrum↗