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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Cleaner Air for Home and Office

Increased insulation has led to higher concentrations in homes and offices of toxic chemicals caused by emissions from synthetic building components. Recent NASA research regarding future interplanetary manned spacecraft has shown that certain plants can absorb gasses, reducing indoor air pollution. After working with water purifying water hyacinths, Dr. B. C. Wolverton at NSTL developed a carbon/plant filter system to remove chemicals, smoke, etc. Two companies have commercialized the system. Bio-safe provides plants, a bed of activated carbon and an air pump installed near the plant's roots. Pollutants are trapped by the charcoal and either digested by the roots or broken down by microorganisms. Purified air is then directed back into the room. Applied Indoor Resource Company markets Bio-Pure, which includes plants on a layer of patented soil medium with activated carbon. Legumes and mosses filter the air; a blower moves air through the filtering system for cleansing by microorganisms. Research at NSTL continues, and the system may eventually be enlarged.

Source record↗

Liquid trap seals thermocouple leads

Liquid trap seals thermocouple leads coming out of a brazing retort that operates with a controlled atmosphere so that air cannot enter the retort and hydrogen cannot escape. The trap is fastened to a duct welded to the retort. Thermocouple leads are led out through the duct and trap, with the fluid forming a gastight seal between the atmosphere and the retort.

Ruppe, E. P.↗

Evaluations of an Enhanced Total Hydrocarbon Analyzer With Complex Mixtures of Volatile Organic Compounds

From the earliest manned missions, the volatile organic compound (VOC) content of spacecraft air has been a concern because of a much greater potential for contamination than air in most terrestrial settings. First, the volume of air is small compared to the mass of man- made materials comprising the interior furnishings of the spacecraft. These man-made materials offgas VOCs trapped during manufacture. Second, the nitrogen fraction of the air is recycled. Any VOCs not scrubbed out with charcoal filters or aqueous condensate (mainly water expired by the crew) will accumulate in the air. Third, the crew emits metabolic VOCs. Fourth, experimental payloads can also offgas or accidentally release a VOC; in fact a major organic constituent of the atmosphere is the disinfectant isopropanol released from swabs used in medical experiments.

Cross, John H.↗

Formation of Cirrus Clouds near the Tropical Tropopause and Their Implications for Stratospheric Humidity, Radiation Budgets, and Climate

Optically-thin cirrus clouds are a nearly ubiquitous feature of the transition layer between the tropical troposphere and stratosphere (known as the Tropical Tropopause Layer). Given their high occurrence frequency, these clouds have significant impacts on the Earth's radiation budget, with a particularly strong influence on the outgoing longwave radiation. Further, ice crystal growth and sedimentation in these clouds dehydrates air in the cold TTL to very low water vapor mixing ratios. Since transport from the troposphere into the stratosphere occurs primarily through the tropical tropopause and the Brewer-Dobson circulation transports air from the TTL throughout the stratosphere, cloud processes in the TTL cold trap essentially regulate the humidity of the entire stratosphere. It has been shown that even small changes in stratospheric humidity can have significant impacts on the Earth's radiation budget and climate, with magnitudes comparable to anthropogenic changes in greenhouse gases. The humidity of air crossing the TTL cold trap depends to first order on tropical tropopause temperatures, but also on deep convection reaching the TTL, large-scale transport (in balance with TTL radiative heating), atmospheric waves, and cloud microphysical processes. Gaps in our understanding of TTL transport and cloud processes motivated the NASA Airborne Tropical TRopopause EXperiment (ATTREX). ATTREX used the long-range (16,000 km), high-altitude (20 km) Global Hawk unmanned aircraft system equipped with twelve instruments measuring clouds, water vapor, meteorological conditions, chemical tracers, chemical radicals, and radiation. I will discuss the physics of TTL cirrus formation and the impact of these clouds on water vapor and radiation budgets, including new results emerging from the ATTREX measurements.

Jensen, Eric↗

The effect of interstitial air on the in vitro thrombogenicity of ePTFE vascular grafts

Gas trapped in the interstices of the biomaterials used for vascular prostheses causes thrombosis, and the process of eliminating this gas is known as denucleation. An apparatus was developed for testing in the in vitro effects of denucleation on 4 mm I.D. expanded polytetrafluoroethylene (ePTFE) Vitagraft (Johnson and Johnson). The apparatus was designed to ensure that neither the blood nor the grafts came in contact with air. Blood from a single donor was incubated with control and denucleated grafts for 5, 10, 15, 20, and 30 minutes. The thrombus volume in the graft lumen was measured with a computer assisted videometric system. Little thrombus formed by 5 or 10 minutes, but there was less thrombus in the denucleated graft than in the control graft at all times. The differences were statistically significant at 15 and 20 minutes (p < 0.05). Denucleation nearly doubled the thrombus formation time. Thrombus was more adherent to denucleated grafts than to control grafts. These results are consistent with in vivo observations in the rat where denucleation decreased thrombus formation and increased patency duration.

NASA Discipline Number 04-10↗

Membrane-Based Gas Traps for Ammonia, Freon-21, and Water Systems to Simplify Ground Processing

Gas traps are critical for the smooth operation of coolant loops because gas bubbles can cause loss of centrifugal pump prime, interference with sensor readings, inhibition of heat transfer, and blockage of passages to remote systems. Coolant loops are ubiquitous in space flight hardware, and thus there is a great need for this technology. Conventional gas traps will not function in micro-gravity due to the absence of buoyancy forces. Therefore, clever designs that make use of adhesion and momentum are required for adequate separation, preferable in a single pass. The gas traps currently used in water coolant loops on the International Space Station are composed of membrane tube sets in a shell. Each tube set is composed of a hydrophilic membrane (used for water transport and capture of bubbles) and a hydrophobic membrane (used for venting of air bubbles). For the hydrophilic membrane, there are two critical pressures, the pressure drop and the bubble pressure. The pressure drop is the decrease in system pressure across the gas trap. The bubble pressure is the pressure required for air bubbles to pass across the water filled membrane. A significant difference between these pressures is needed to ensure complete capture of air bubbles in a single pass. Bubbles trapped by the device adsorb on the hydrophobic membrane in the interior of the hydrophilic membrane tube. After adsorption, the air is vented due to a pressure drop of approximately 1 atmosphere across the membrane. For water systems, the air is vented to the ambient (cabin). Because water vapor can also transport across the hydrophobic membrane, it is critical that a minimum surface area is used to avoid excessive water loss (would like to have a closed loop for the coolant). The currently used gas traps only provide a difference in pressure drop and bubble pressure of 3-4 psid. This makes the gas traps susceptible to failure at high bubble loading and if gas venting is impaired. One mechanism for the latter is when particles adhere to the hydrophobic membrane, promoting formation of a water layer about it that can blind the membrane for gas transport (Figure 1). This mechanism is the most probable cause for observed failures with the existing design. The objective of this project was to devise a strategy for choosing new membrane materials (database development and procedure), redesign of the gas trap to mitigate blinding effects, and to develop a design that can be used in ammonia and Freon-21 coolant loops.

Ritchie, Stephen M. C.↗

Direct Monitoring of Trace Atmospheric Species via Ion Trap Mass Spectrometry

There is an ever-increasing emphasis on the part of government agencies, academia, and industry on enhancing our understanding of atmospheric processes and assessing the impact of human activities on these processes. While issues such as the ozone hole and rising levels of greenhouse gases have received major attention. relatively little is known about the types, concentrations, sources, and sinks of hydrocarbons in the troposphere and stratosphere. Such information would be of tremendous utility in assessing the roles of various anthropogenic and biogenic processes on global carbon cycles. An ion trap mass spectrometer has been developed for monitoring trace levels of hydrocarbons in the atmosphere on NASA's DC-8 "flying laboratory". This aircraft is used to provide measurements in support of a number of "Mission to Planet Earth" activities and tropospheric chemistry experiments. In past missions, specific compounds have been monitored via highly specialized instrumentation, fast GO, or collection of whole air samples for subsequent ground-based analysis. The ion trap has several features. including small size. excellent sensitivity, and broad applicability, which make it highly atttrat:ive for atmospheric monitoring. The design of this instrument, its air sampling interface. and the various complications associated with aircraft-deployment will be described. Data showing the sensitivity of the instrument for detecting hydrocarbons at mixing ratios below one part-per-billion, and the use of MS/MS for direct, on-line, real-time monitoring will be presented.

Palmer, P. T.↗

Field sampling fine-vacuum system

Small portable pumping station, consisting of roughing pump, air cooled diffusion pump, and liquid nitrogen cold trap, permits onsite sampling followed by quantitative laboratory analysis of residual gases.

Fickey, E. W.↗

A general, cryogenically-based analytical technique for the determination of trace quantities of volatile organic compounds in the atmosphere

An analytical technique for the determination of trace (sub-ppbv) quantities of volatile organic compounds in air was developed. A liquid nitrogen-cooled trap operated at reduced pressures in series with a Dupont Nafion-based drying tube and a gas chromatograph was utilized. The technique is capable of analyzing a variety of organic compounds, from simple alkanes to alcohols, while offering a high level of precision, peak sharpness, and sensitivity.

Coleman, R. A.↗

Convective Transport to the Upper Troposphere and Lower Stratosphere Over the Asian Summer Monsoon as Observed During the 2022 ACCLIP Airborne Campaign

Deep convection in the Asian summer monsoon (ASM) rapidly transports boundary layer pollutants including ozone-depleting substances into the upper troposphere and lower stratosphere (UTLS). The confinement of the seasonal anticyclonic circulation in the UTLS over Asia initially traps the pollutants near the tropopause level, but air masses are subsequently transported throughout the global stratosphere and impact Earth’s climate. Characterizing the transport pathways and processes of these pollutants are critical for identifying source regions and quantifying regional contributions to global stratospheric concentrations. The Asian summer monsoon Chemical and Climate Impact Project (ACCLIP) was conducted in summer 2022 using two high-altitude aircraft (NSF NCAR Gulfstream V and the NASA WB-57) to obtain UTLS chemical composition and aerosol distribution for characterizing the impact of the ASM on global chemistry and climate. Backward trajectories from ACCLIP flight tracks were traced through time-varying, satellite-derived global convective cloud top altitude fields to investigate the convective air mass origins of the sampled air parcels. Analyses reveal that air masses lofted by convection within the ASM (South Asian summer monsoon) and near the edge of the of the ASM anticyclone (East Asian summer monsoon) contributed to the airborne observations. In this study, we present a summary of the transport statistics of UTLS air masses sampled during ACCLIP and discuss the implications of these results on our understanding of the role of ASM in global constituent transport.

Convective↗

An expert system/ion trap mass spectrometry approach for life support systems monitoring

Efforts to develop sensor and control system technology to monitor air quality for life support have resulted in the development and preliminary testing of a concept based on expert systems and ion trap mass spectrometry (ITMS). An ITMS instrument provides the capability to identify and quantitate a large number of suspected contaminants at trace levels through the use of a variety of multidimensional experiments. An expert system provides specialized knowledge for control, analysis, and decision making. The system is intended for real-time, on-line, autonomous monitoring of air quality. The key characteristics of the system, performance data and analytical capabilities of the ITMS instrument, the design and operation of the expert system, and results from preliminary testing of the system for trace contaminant monitoring are described.

Palmer, Peter T.↗

Design of components for growing higher plants in space

The overall goal of this project is to design unique systems and components for growing higher plants in microgravity during long-term space missions (Mars and beyond). Specific design tasks were chosen to contribute to and supplement NASA's Controlled Ecological Life Support System (CELSS) project. Selected tasks were automated seeding of plants, plant health sensing, and food processing. Prototype systems for planting both germinated and nongerminated seeds were fabricated and tested. Water and air pressure differences and electrostatic fields were used to trap seeds for separation and transport for planting. An absorption spectrometer was developed to measure chlorophyll levels in plants as an early warning of plant health problems. In the area of food processing, a milling system was created using high-speed rotating blades which were aerodynamically configured to produce circulation and retractable to prevent leakage. The project produced significant results having substantial benefit to NASA. It also provided an outstanding learning experience for the students involved.

Source record↗

Superconductive magnetic-field-trapping device

An apparatus which enables the establishment of a magnetic field in air that has the same intensity as the ones in ferromagnetic materials is described. The apparatus is comprised of a core of ferromagnetic material and is surrounded by a cylinder made of a material that has superconducting properties when cooled below a critical temperature. A method is provided for producing a magnetic field through the ferromagnetic core. The core can also be split and pulled apart when it is required that the center of the cavity be left empty.

Hildebrandt, A. F.↗

Plasma Assisted Nutrient Recovery from Inedible Biomass via Ash Leaching

Sustaining a human presence on the Moon, Mars, or deep space will require closing loops on many life support systems. Some form of agriculture will be required because plants produce the vitamins, antioxidants, and essential oils in our diets that degrade over time in stored foods. In addition, they provide dietary fiber, restore air, and purify water. Growing plants will require recycling nutrients trapped in inedible vegetation. Researchers at KSC have investigated the use of a thermal plasma with various carrier gases to thermally degrade inedible plant biomass for nutrient recovery. Previous work demonstrated a thermally degrading environment such as a muffle furnace improved nutrient recovery from inedible biomass prior to an acid leaching process. However, a muffle furnace is an inefficient process. We have explored the use of a small scale, thermal plasma for degradation of pellets to enhance the breakdown of plant stems, leaves, and debris to further close the nutrient loop. Plasma carrier gases such as carbon dioxide (CO2), nitrogen (N2), and air were used to explore variations in recovery and potential chemical by-products. Plasma processed inedible biomass was added to varying concentrations of acid solution for leaching of nutrients (e.g. potassium (K) , magnesium (Mg), calcium (Ca), and phosphorus (P)) for reuse in the crop production cycle. We also examined total N2 recovery. Results are presented showing the impact of plasma processing prior to acid leaching on recovery of plant nutrients.

Kenneth Engeling↗

Optical Tweezers and Optical Trapping Improved for Future Automated Micromanipulation and Characterization

Optical trap arrays are being developed at the NASA Glenn Research Center for holding, manipulating, and optically interrogating arrays of nanotube sensors. The trap arrays, for example, might be used to arrange arrays of chemical sensors for insertion onto a chip in liquid, air, and vacuum environments. Neural-network-controlled spatial light modulators (SLMs) are to generate and control the trap positions and trap profiles in three dimensions.

Wrbanek, Susan Y.↗

The NASA/National Space Science Data Center trapped radiation environment model program, 1964 - 1991

The major effort that NASA, initially with the help of the United States Air Force (USAF), carried out for 27 years to synthesize the experimental and theoretical results of space research related to energetic charged particles into a quantitative description of the terrestrial trapped radiation environment in the form of model environments is detailed. The effort is called the Trapped Radiation Environment Modeling Program (TREMP). In chapter 2 the historical background leading to the establishment of this program is given. Also, the purpose of this modeling program as established by the founders of the program is discussed. This is followed in chapter 3 by the philosophy and approach that was applied in this program throughout its lifetime. As will be seen, this philosophy led to the continuation of the program long after it would have expired. The highlights of the accomplishments are presented in chapter 4. A view to future possible efforts in this arena is given in chapter 5, mainly to pass on to future workers the differences that are perceived from these many years of experience. Chapter 6 is an appendix that details the chronology of the development of TREMP. Finally, the references, which document the work accomplished over these years, are presented in chapter 7.

Vette, James I.↗

Characteristics of a trapped-vortex (TV) combustor

The characteristics of a Trapped-Vortex (TV) combustor are presented. A vortex is trapped in the cavity established between two disks mounted in tandem. Fuel and air are injected directly into the cavity in such a way as to increase the vortex strength. Some air from the annular flow is also entrained into the recirculation zone of the vortex. Lean blow-out limits of the combustor are determined for a wide range of annular air flow rates. These data indicate that the lean blow-out limits are considerably lower for the TV combustor than for flames stabilized using swirl or bluff-bodies. The pressure loss through the annular duct is also low, being less than 2% for the flow conditions in this study. The instantaneous shape of the recirculation zone of the trapped vortex is measured using a two-color PIV technique. Temperature profiles obtained with CARS indicate a well mixed recirculation zone and demonstrate the impact of primary air injection on the local equivalence ratio.

Hsu, K.-Y.↗

Laboratory Studies of Fischer-Tropsch-Type Reactions and Their Implications for Organics in Asteroids and Comets

We have been studying Fischer-Tropsch type (FTT) reactions as a source for organic materials both in the gas phase of the solar nebula and incorporated into primitive comets and asteroids for almost 10 years, and over this time our concept has evolved greatly from the standard "catalytic" model to a much more robust chemical scenario. Our simulations have been conducted at temperatures that are much higher than we like, primarily for practical reasons such as the timescale of individual reactions, and we are just starting a series of measurements to allow us to measure reaction rates at temperatures from 873K down to as low as 373K. We have preliminary data on the carbon (d13C = -50) & nitrogen (d15N = +9.5) isotopic fractionation at 873K, but not on materials produced at lower temperature. Isotope values are on the VPDB scale for carbon and vs. Air for nitrogen. We have also investigated the noble gas trapping efficiency of the FTT process by adding a small amount of a noble gas mix to our standard synthesis mix. The noble gas ratio is 49:49:1:1::Ne:Ar:Kr:Xe. Xe and Kr are trapped at 873K and are more efficiently trapped at 673K with no isotopic fractionation at either temperature. Ar trapping is detected at 673K, but not at 873K. Ne has not yet been observed in our samples. The solar nebula was an extremely complex system, mixing materials from the innermost regions out to well into the zones where comets formed and thus mixing highly processed nebular materials with grains and coatings formed before the nebula began to collapse. Laboratory studies may provide the means to separate such diverse components based on carbon or nitrogen isotopic fractionation or the quantities of noble gases trapped in grain coatings and their thermal release patterns, among other observables. The ultimate goal of laboratory synthesis of nebular analogs is to provide the means to identifY the conditions under which natural samples were formed and the signatures of subsequent metamorphic events.

Nuth, Joseph↗