The Reactions of CH3+ with C2N2, CH2CHCN and HC3N: A Low Pressure/High Pressure Study
The association of CH3+ with the three molecules C2N2, CH2CHCN and HCCCN has been
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The association of CH3+ with the three molecules C2N2, CH2CHCN and HCCCN has been
Study of stress corrosion cracks in aluminum alloys reveals that crack initiation is greatly influenced by boundary orientation and directionality of the structure. In all crack susceptible materials, intergranular corrosion and stress corrosion cracking started and progressed in boundaries oriented perpendicularly to the stressing direction.
NASA's Tracking and Data Relay Satellite System (TDRSS) is now in its 23rd year of operations and its spacecraft fleet includes three second-generation spacecraft launched since the year 2000; a figure illustrates the first generation TDRSS spacecraft. During this time frame the TDRSS has provided communications relay support to a broad range of missions, with emphasis on low-earth-orbiting (LEO) spacecraft that include unmanned science spacecraft (e.g., Hubble Space Telescope), and human spaceflight (Space Shuttle and Space Station). Furthermore, the TDRSS has consistently demonstrated its uniqueness and adaptability in several ways. First, its S- and K-band services, combined with its multi-band/steerable single-access (SA) antennas and ground-based configuration flexibility, have permitted the mission set to expand to unique users such as scientific balloons and launch vehicles. Second, the bent-pipe nature of the system has enabled the introduction of new/improved services via technology insertion and upgrades at each of the ground terminals; a specific example here is the Demand Access Service (DAS), which, for example, is currently providing science-alert support to NASA science missions Third, the bent-pipe nature of the system, combined with the flexible ground-terminal signal processing architecture has permitted the demonstration/vaIidation of new techniques/services/technologies via a real satellite channel; over the past 10+ years these have, for example, included demonstrations/evaluations of emerging modulation/coding techniques. Given NASA's emerging Exploration plans, with missions beginning later this decade and expanding for decades to come, NASA is currently planning the development of a seamless, NASA-wide architecture that must accommodate missions from near-earth to deep space. Near-earth elements include Ground-Network (GN) and Near-Earth Relay (NER) components and both must efficiently and seamlessly support missions that encompass: earth orbit, including dedicated science missions and lunar support/cargo vehicles; earth/moon transit; lunar in-situ operations; and other missions within approximately 2 million km of earth (e.g., at the sun/earth libration points). Given that the NER is an evolution of TDRSS, one element of this NASA-wide architecture development activity is a trade study of future NER architecture candidates. The present paper focuses on trade study aspects associated with the NER, highlights study elements, and provides representative interim results.
Infrared and visible data from the Heat Capacity Mapping Mission (HCMM) satellite were used to study the intensity of the urban heat island, commonly defined as the temperature difference between the center of the city and the surrounding suburban and rural regions, as a function of changes in the season and changes in meteorological conditions in order to derive various parameters which may be used in numerical models for urban climate. The analysis was focused on the city of St. Louis; and in situ data from St. Louis was combined with HCMM data in order to derive the various parameters. The HCMM data were mapped onto a Mercator projection map of the city and ground temperatures were established using data corrected for the effects of atmospheric absorption. The corrected and uncorrected HCMM data were compared to determine the magnitude of the error induced by atmospheric effects.
The feasibility of a polygeneration plant at Kennedy Space Center was studied. Liquid hydrogen and gaseous nitrogen are the two principal products in consideration. Environmental parameters (air quality, water quality, biological diversity and hazardous waste disposal) necessary for the feasibility study were investigated. A National Environmental Policy Act (NEPA) project flow sheet was to be formulated for the environmental impact statement. Water quality criteria for Florida waters were to be established.
The use of infrared and visible data from the Heat Capacity Mapping Mission (HCMM) and in situ data to study the intensity of the urban heat island of Saint Louis is described. Analysis of HCMM data shows that an urban heat island exists day and night in all seasons when clear skies prevail. The lower albedo value of the urban region during the day suggests that the higher temperatures are due to more absorption of solar radiation. Preliminary analysis of in situ meteorological data was performed after merging with HCMM data, and surface roughness, the exchange coefficient, and the soil moisture were calculated.
The nonlinear stability of a two-dimensional single crystal of pure material in an undercooled melt is studied both analytically and numerically. The quasi-steady state approximation is used for the thermal fields, and the effects of different solid and liquid thermal conductivities, isotropic interfacial growth kinetics, and isotropic surface tension are included. The bifurcation analysis is performed by calculating the instantaneous value of the fundamental component of the local normal growth speed for an interface perturbed by a single Fourier shape component. Numerically, the fundamental component of the interfacial growth speed is found by Fourier analysis of the solution to an integrodifferential equation obeyed at the interface. Analytically, an expansion technique is used to derive a solvability condition defining each of these bifurcation points. The analytical and numerical results are in very close agreement. Almost all of the bifurcations are subcritical, and the results are presented by giving values of the Landau coefficient as a function of the different dimensionless parameters used in the model.
The physical characteristics of all crater-related streaks within the north equatorial zone of Mars (between 0 and 30 deg N) are studied. The survey includes 25% of the Martian surface area and covers the latitude band of major interest to the Viking missions. Nine characteristic parameters are measured for each of 2325 streaks, of which 82.3% are classified as light tone, 8.1% as dark tone, and 9.6% as mixed tone. The location of streaks in the investigated zone is considered together with the indicated wind regimes, and the characteristics of the streaks and of their associated craters are discussed. The results show that: (1) the streaks are not uniformly distributed throughout the north equatorial zone but are strongly concentrated in certain areas; (2) the density of streaks displays a significant latitude variation not apparently related to terrain type between 0 and 30 deg N; (3) the percentage of craters with streaks reaches a maximum between 10 and 15 deg N and falls off significantly toward both the equator and higher latitudes; and (4) the density of streaks correlates well with geological terrain type.
Separator materials, ceramic to metal seals, cell plate polarization and impregnation processes, and plaque sintering data for study of variables in manufacture of nickel cadmium cells
The instantaneous patterns of electric fields and currents in the high-latitude ionosphere are deduced by combining satellite and radar measurements of the ionospheric drift velocity, along with ground-based magnetometer observations for October 25, 1981. The period under study was characterized by a relatively stable southward interplanetary magnetic field (IMF), so that the obtained electric field patterns do reflect, in general, the state of sustained and enhanced plasma convection in the magnetosphere. During one of the satellite passes, however, an intense westward electrojet caused by a substorm intruded into the satellite (DE2) and radar (Chatanika, Alaska) field of view in the premidnight sector, providing a unique opportunity to differentiate the enhanced convection and substorm expansion fields. The distributions of the calculated electric potential for the expansion and maximum phases of the substorm show the first clear evidence of the coexistence of two physically different systems in the global convection pattern. The changes in the convection pattern during the substorm indicate that the large-scale potential distributions are indeed of general two-cell patterns representing the southward IMF status, but the night-morning cell has two positive peaks, one in the midnight sector and the other in the late morning hours, corresponding to the substorm expansion and the convection enhancement, respectively.
The bounds for the normalized associated Legendre functions P sub nm were studied to provide a rational basis for the truncation of the geopotential series in spherical harmonics in various orbital analyses. The conjecture is made that the largest maximum of the normalized associated Legendre function lies in the interval which indicates the greatest integer function. A procedure is developed for verifying this conjecture. An on-line algebraic manipulator, IAM, is used to implement the procedure and the verification is carried out for all n equal to or less than 2m, for m = 1 through 6. A rigorous proof of the conjecture is not available.
Three major topics were addressed, one theoretical and two observational. The topics were: (1) an attempt to understand the evolution of the large-amplitude magnetohydrodynamic (MHD) waves in the foreshock, using a nonlinear wave equation called the Derivative Nonlinear Schrodinger equation (henceforth DNLS) as a model, (2) using the extensive set of ISE data to test for the presence of various nonlinear wave processes which might be present, and (3) a study of plasma turbulence in the interstellar medium which might be physically similar to that in the solar wind. For these investigations we used radioastronomical techniques. Good progress was made in each of these areas and a separate discussion of each is given.
Solid propellant composition and rocket motor design effect on plasma microwave and visible light attenuation emitted by exhaust
Aerothermodynamic phenomena associated with reentry of manned spacecraft
Microwave attenuation magnitude associated with exhaust plasma of nonaluminized and aluminized composite propellant
Bibliography of technical reports on plasma sheath phenomena and communications blackout during vehicle atmospheric reentry
Process variables associated with manufacturing hermetically-sealed nickel-cadmium cells
Formation time, specific gravity of solution, and overcharge amount associated with electrochemical cleaning or formation operation in manufacturing nickel cadmium cells