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At least 73 records · Page 4

Zodiacal light surface brightness measurements by Atmosphere Explorer-C

The visible airglow photometer on the Atmosphere Explorer-C satellite has been used to map the zodiacal light surface brightness at the wavelengths monitored by the instrument: 3371, 4278, 5200, 5577, 6300, and 7319 A. The study constitutes a survey over this wavelength range, covering most of the celestial sphere from altitudes above the atmospheric emissions and free from atmospheric scattering and attenuation. The intensity variations reveal enhancements near elongations of 130 deg and possibly near 60 deg at all wavelengths. The intensity of the zodiacal light near the ecliptic pole is found to be about 30 S10 units. The color ratio with respect to the sun is found to be redder than the sun (0.7) at all elongations.

Torr, M. R.↗

Atmospheric infrared emission of ClONO2 observed by a balloon-borne Fourier spectrometer

ClONO2 was observed in high-resolution infrared emission spectra obtained on Nov. 6, 1984, by a balloon-borne Fourier spectrometer. The observations took place near 0300 LT at a latitude of 35 N. Spectral simulations are used to determine the mixing ratios of ClONO2. This analysis incorporates line by line calculations and new ClONO2 cross sections measured in the laboratory at 223 K. The inferred mixing ratios of ClONO2 are 1.3 + or - 0.45 ppb and 0.98 + or - 0.35 ppb at 14 and 34 mbar. One-dimensional photochemical model predictions are compared to the observations. The ClONO2 mixing ratio at 34 mbar appears to be larger than theory, while there is agreement at 14 mbar.

Massie, S. T.↗

Aerosols in Atmospheric Chemistry and Biogeochemical Cycles of Nutrients

Atmospheric aerosols have complex and variable compositions and properties.While scientific interest is centered on the health and climatic effects of atmospheric aerosols, insufficient attention is given to their involvement in multiphase chemistry that alters their contribution as carriers of nutrients in ecosystems. However, there is experimental proof that the nutrient equilibria of both land and marine ecosystems have been disturbed during the Anthropocene period. This review study first summarizes our current understanding of aerosol chemical processing in the atmosphere as relevant to biogeochemical cycles. Then it binds together results of recent modeling studies based on laboratory and field experiments, focusing on the organic and dust components of aerosols that account for multiphase chemistry, aerosol ageing in the atmosphere, nutrient (N, P, Fe) emissions, atmospheric transport, transformation and deposition. The human-driven contribution to atmospheric deposition of these nutrients, derived by global simulations using past and future anthropogenic emissions of pollutants, is put into perspective with regard to potential changes in nutrient limitations and biodiversity. Atmospheric deposition of nutrients has been suggested to result in human-induced ecosystem limitations with regard to specific nutrients. Such modifications favor the development of certain species against others and affect the overall functioning of ecosystems. Organic forms of nutrients are found to contribute to the atmospheric deposition of the nutrients N, P and Fe by 20%-40%, 35%-45% and 7%-18%, respectively. These have the potential to be key components of the biogeochemical cycles since there is initial proof of their bioavailability to ecosystems. Bioaerosols have been found to make a significant contribution to atmospheric sources of N and P, indicating potentially significant interactions between terrestrial and marine ecosystems. These results deserve further experimental and modeling studies to reduce uncertainties and understand the feedbacks induced by atmospheric deposition of nutrients to ecosystems.

dust↗

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH4) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH4 continue to increase, making CH4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO2). The relative importance of CH4 compared to CO2 depends on its shorter atmospheric lifetime, stronger warming potential, and variations in atmospheric growth rate over the past decade, the causes of which are still debated. Two major challenges in reducing uncertainties in the atmospheric growth rate arise from the variety of geographically overlapping CH4 sources and from the destruction of CH4 by short-lived hydroxyl radicals (OH). To address these challenges, we have established a consortium of multidisciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations). For the 2008–2017 decade, global methane emissions are estimated by atmospheric inversions (a top-down approach) to be 576 Tg CH4/yr (range 550–594, corresponding to the minimum and maximum estimates of the model ensemble). Of this total, 359 Tg CH4/yr or ∼ 60 % is attributed to anthropogenic sources, that is emissions caused by direct human activity (i.e. anthropogenic emissions; range 336–376 Tg CH4/yr or 50 %–65 %). The mean annual total emission for the new decade (2008–2017) is 29 Tg CH4/yr larger than our estimate for the previous decade (2000–2009), and 24 Tg CH4/yr larger than the one reported in the previous budget for 2003–2012 (Saunois et al., 2016). Since 2012, global CH4 emissions have been tracking the warmest scenarios assessed by the Intergovernmental Panel on Climate Change. Bottom-up methods suggest almost 30 % larger global emissions (737 Tg CH4/yr, range 594–881) than top-down inversion methods. Indeed, bottom-up estimates for natural sources such as natural wetlands, other inland water systems, and geological sources are higher than top-down estimates. The atmospheric constraints on the top-down budget suggest that at least some of these bottom-up emissions are overestimated. The latitudinal distribution of atmospheric observation-based emissions indicates a predominance of tropical emissions (∼ 65 % of the global budget, < 30° N) compared to mid-latitudes (∼ 30 %, 30–60° N) and high northern latitudes (∼ 4 %, 60–90° N). The most important source of uncertainty in the methane budget is attributable to natural emissions, especially those from wetlands and other inland waters. Some of our global source estimates are smaller than those in previously published budgets (Saunois et al., 2016; Kirschke et al., 2013). In particular wetland emissions are about 35 Tg CH4/yr lower due to improved partition wetlands and other inland waters. Emissions from geological sources and wild animals are also found to be smaller by 7 Tg CH4/yr by 8 Tg CH4/yr, respectively. However, the overall discrepancy between bottom-up and top-down estimates has been reduced by only 5 % compared to Saunois et al. (2016), due to a higher estimate of emissions from inland waters, highlighting the need for more detailed research on emissions factors. Priorities for improving the methane budget include (i) a global, high-resolution map of water-saturated soils and inundated areas emitting methane based on a robust classification of different types of emitting habitats; (ii) further development of process-based models for inland-water emissions; (iii) intensification of methane observations at local scales (e.g., FLUXNET-CH4 measurements) and urban-scale monitoring to constrain bottom-up land surface models, and at regional scales (surface networks and satellites) to constrain atmospheric inversions; (iv) improvements of transport models and the representation of photochemical sinks in top-down inversions; and (v) development of a 3D variational inversion system using isotopic and/or co-emitted species such as ethane to improve source partitioning.

methane budget↗

Global Impacts of Marine Methanethiol Emissions and Chemistry in the Atmosphere

Oceanic emissions of dimethyl sulfide (DMS) have long been known to influence aerosol particle composition, cloud condensation nuclei (CCN) concentration, and Earth’s radiative budget. However, the impact of oceanic emissions of methanethiol (MeSH), a sulfur compound produced by the same oceanic precursor as DMS, has been relatively less explored. The gas-phase oxidation of MeSH has a higher effective yield of SO 2 and a shorter oxidative lifetime compared to DMS, highlighting the relevance of this pathway for the modeled representation of particle formation, growth, and CCN abundance in the marine atmosphere. Here, we use the global chemical transport model GEOS-Chem to explore possible scenarios representative of specific environmental conditions and MeSH emission schemes based on previous experimental studies. We further implement and test previously reported chemical mechanisms for MeSH oxidation, along with additional improvements, highlighting key uncertainties and sensitivities for regional and global sulfur budgets. We place our results in the context of recent modeling updates to DMS chemistry and cloud processing, which further impact SO 2 production in the marine atmosphere in parallel with MeSH oxidation. Within the overall marine sulfur budget, our findings highlight that MeSH plays a significant role in SO 2 production in the marine atmosphere, contributing to regional surface layer concentration increases of up to 40–60%. These results point to the importance of MeSH for efforts aimed at improving the modeled representation of sulfur spatiotemporal patterns relevant to air quality predictions and climate impact assessments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tropospheric chemical models

The differences in atmospheric composition over the globe and the short- and long-term variations in this composition are the net effect of several atmospheric and biospheric processes: biospheric emissions, atmospheric circulation, atmospheric chemical transformations and finally deposition back to the surface. Accurate and realistic atmospheric chemistry and circulation models are essential to interpret the observed global distributions and trends of atmospheric species in terms of these underlying processes. Comparisons between model predictions and observations test current understanding of these processes and models used in conjunction with inverse methods allow deductions of the rates of these processes from the observations. With the planned inclusion of at least CO and CH4 observations on the Earth Observing System (EOS) satellites, together with the large global data set expected from in situ observations under the International Global Atmospheric Chemistry (IGAC) Project, the further development of global three-dimensional high-resolution atmospheric chemistry and circulation models in order to interpret this new data is a high-priority endeavor.

Prinn, R. G.↗

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH 4 ) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH 4 are continuing to increase, making CH 4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO 2 ). Assessing the relative importance of CH 4 in comparison to CO 2 is complicated by its shorter atmospheric lifetime, stronger warming potential, and atmospheric growth rate variations over the past decade, the causes of which are still debated. Two major difficulties in reducing uncertainties arise from the variety of geographically overlapping CH 4 sources and from the destruction of CH 4 by short-lived hydroxyl radicals (OH). To address these difficulties, we have established a consortium of multi-disciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Atmospheric Lyman-Alpha Emissions (ALAE)

The Atmospheric Lyman-Alpha Emissions (ALAE) experiment which is designed to measure atomic hydrogen and deuterium in the terrestrial atmosphere is described. The development of the instrument is a joint effort of the Service d'Aeronomie du CNRS in France and the Institut d'Aeronomie Spatiale in Belgium. This experiment will be part of the atmospheric science research payload flown on the Atmospheric Laboratory for Applications and Science (ATLAS 1) NASA mission planned for late 1990.

Bertaux, J. L.↗

VLA mapping of 1.35 cm water emission from the Mars atmospheric limb

We report preliminary results of 1.35 cm spectral line observations, in which we employed the NRAO Very Large Array (VLA) interferometer to map the horizontal and vertical distributions of water vapor around the Mars atmospheric limb in early Dec. of 1990. The increased atmospheric pathlengths presented near the limb of Mars and the high angular resolution afforded by the VLA at centimeter wavelengths lead to a remarkably sensitive, remote measurement of water in the atmosphere of Mars. We achieve approximately 300 km horizontal resolution on Mars, operating in the C configuration of the VLA, when Mars was 17.3 inches in diameter. This allows us to resolve the latitudinal and diurnal variations in atmospheric water emission around the limb of Mars. We derive the vertical distribution of atmospheric water from observed pressure broadening in the spectrally resolved lineshapes. These observations, which consist of two eight-hour integrations obtained on Dec. 3-4 and Dec. 6-7, correspond to late winter in the Northern Hemisphere of Mars (L sub s = 344 degrees).

Clancy, R. T.↗

Measurements of the anisotropy of the cosmic background radiation and diffuse galactic emission at millimeter and submillimeter wavelengths

The results of a balloon-borne observing program to measure the large angular scale brightness distribution of the 2.7 K cosmic background radiation (CBR) at millimeter and submillimeter wavelengths are reported. A new determination of the dipole anisotropy of the CBR is found with 3.40 + or - 0.42 mK toward alpha = 12.1 + or - 0.24 hr, delta = - 23 + or - 5 deg in a 1.2 to 8/cm band and 4.7 + or - 1.4 mK toward alpha = 9.9 + 1.7 or - 1.1 hr, delta = - 38 + or - 21 deg between 5 and 18/cm, where the amplitudes are listed as thermodynamic temperatures. New estimates of the absolute temperature in these two bands of 2.86 + or - 0.26 K and 3.01 + or - 0.31 are obtained under the assumption that the CBR has a Planck spectrum. The diffuse Galactic emission is fitted by a secant distribution in Galactic latitude, and the resulting Galactic pole antenna temperatures are given. Maps of sky brightness, measurements of zodiacal emission, and measurements of fluctuations of the atmospheric emission which dominates the noise budget are also presented.

Halpern, Mark↗

Experimental and Coupled-channels Investigation of the Radiative Properties of the N2 c4 (sup 1)Sigma+(sub u) - X (sup 1)Sigma+(sub g) Band System

The emission properties of the N2 c(sup prime)(sub 4) (sup 1)Sigma+(sub u) - Chi (sup 1)Sigma+(sub g) band system have been investigated in a joint experimental and coupled-channels theoretical study. Relative intensities of the c(sup prime)(sub 4) (sup 1)Sigma+(sub u)(0) - Chi (sup 1)Sigma+(sub g)(v(sub i)) transitions, measured via electron-impact-induced emission spectroscopy, are combined with a coupled-channel Schroedinger equation (CSE) model of the N2 molecule, enabling determination of the diabatic electronic transition moment for the c(sup prime)(sub 4) (sup 1)Sigma+(sub u) - Chi (sup 1)Sigma+(sub g) system as a function of internuclear distance. The CSE probabilities are further verified by comparison with a high-resolution experimental spectrum. Spontaneous transition probabilities of the c(sup prime)(sub 4) (sup 1)Sigma+(sub u) - Chi (sup 1)Sigma+(sub g) modeling atmospheric emission, can now be calculated reliably.

internuclear distance↗

Middle- and low-latitude emissions from energetic neutral atom precipitation seen from ATLAS 1 under quiet magnetic conditions

During the ATLAS 1 mission spectral observations were made at middle and low latitudes of features expected from the precipitation of energetic neutral atoms. The Imaging Spectrometric Observatory was used at night in the UV and visible with maximum gain. The tangent ray heights of the look directions ranged from near 100 km to near 200 km, and the geomagnetic conditions were quiet during the observations, which were made March 28 to April 3, 1992. The N2(+) 1N 391.4-nm and O I 130.4 and 135.6-nm emissions were observed at all latitudes, with lower emission rates at lower magnetic dip latitudes, except that enhancements in the O I lines were seen within 30 deg of the dip equator to radiative recombination of ionospheric plasma. The latitude profile observed for the N2(+) 1N emission did not show an equatorial or midlatitude peak. This implies that the source of energetic neutrals is more consistent with prompt charge exchange loss of freshly injected trapped ions with relatively low mirror heights (i.e., ions on higher L shells with equatorial pitch angle distributions nearly isotropic to the loss cone) than loss of highly eroded populations of particles with high mirror heights (i.e., ions on lower L shells with pancake equatorial pitch angle distributions). The N2(+) 1N emission rates have been compared with models of atmospheric emission due to fluxes of O/O(+) and H/H(+) in the thermosphere, as produced by energetic neutral oxygen or hydrogen atom precipitation. Energy deposition rates are inferred.

Tinsley, B. A.↗

Implementation of Cloud Retrievals for Tropospheric Emission Spectrometer (TES) Atmospheric Retrievals: Part 1. Description and Characterization of Errors on Trace Gas Retrievals

We develop an approach to estimate and characterize trace gas retrievals in the presence of clouds in high spectral measurements of upwelling radiance in the infrared spectral region (650-2260/cm). The radiance contribution of clouds is parameterized in terms of a set of frequency-dependent nonscattering optical depths and a cloud height. These cloud parameters are retrieved jointly with surface temperature, emissivity, atmospheric temperature, and trace gases such as ozone from spectral data. We demonstrate the application of this approach using data from the Tropospheric Emission Spectrometer (TES) and test data simulated with a scattering radiative transfer model. We show the value of this approach in that it results in accurate estimates of errors for trace gas retrievals, and the retrieved values improve over the initial guess for a wide range of cloud conditions. Comparisons are made between TES retrievals of ozone, temperature, and water to model fields from the Global Modeling and Assimilation Office (GMAO), temperature retrievals from the Atmospheric Infrared Sounder (AIRS), tropospheric ozone columns from the Goddard Earth Observing System (GEOS) GEOS-Chem, and ozone retrievals from the Total Ozone Mapping Spectrometer (TOMS). In each of these cases, this cloud retrieval approach does not introduce observable biases into TES retrievals.

aerosols↗