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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Spherical Indentation and Implementation of S 3 /P for yield stress determination of brittle materials

Here, a mathematically transparent and robust experimental method has been developed to estimate the yield stress of brittle materials through the analysis of depth-sensing spherical indentation. Employing Hertzian contact mechanics, an elastically invariant ratio based on the simple equation S 3 / P = 6RE r 2 , (where S and P are contact stiffness and indentation load, respectively) has been derived that enables more accurate and confident determination of the transition from elastic to inelastic deformation; a transition that the yield stress dictates and represents. Using two diamond spheres with radii of 3.2 and 8.6 μm, the indentation test method and analyses are applied to two vitreous silicates: Corning's HPFS 7980® fused silica and Vitro's Starphire® soda lime silicate. The estimated yield strengths are 8.15 GPa ± 2.5% for the fused silica and 6.1 GPa ± 3.3% for the soda-lime silicate, and both were independent of indenter radius. Verification of this new experimental method is demonstrated with an as-drawn titanium by showing equivalence of measured yield stress by its spherical indentation and that from uniaxial compression testing. This method will enable easier and more confident estimation of yield stress in brittle materials - a property that historically has been elusive to measure for these materials using common laboratory mechanical test methods.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Intermediate temperature brittleness of Ni based superalloy Nimonic263

Highlights: • Intermediate temperature brittleness of Nimonic263 is investigated. • Deformation mechanism changes from γ′ shearing to by-pass with increasing temperature. • The minimum ductility is the result of glide plane decohesion. - Abstract: Ni based superalloy Nimonic263 offers excellent resistance to corrosion and high temperatures, and as such can be used under an A-USC environment, which has extremely high temperatures and high pressure. To investigate the intermediate temperature brittleness that is the temperature dependence of this alloy, the tensile test was carried out at a constant cross head speed of 1 mm/min in the temperature range of room temperature to 900 °C. As the temperature increased during the test, the constant yield strength decreased sharply at 800 °C while the ductility began to decrease from 500 °C and then recovered after showing a minimum value at 800 °C. The results of the OM, SEM and TEM observations indicate that the deformation mechanism changed from γ′ shearing to by-pass as the temperature increased, and the minimum ductility resulted from decohesion of the glide plane.

36 MATERIALS SCIENCE↗
DOE OSTI2025

An FFT-based micromechanical model for gradient enhanced brittle fracture

Damage models incorporated within FFT-based micromechanical methods have received much attention recently because of the need to better understand and predict brittle and ductile fracture. An important aspect of a damage model is non-local regularization, which removes the mesh dependence of the predictions that otherwise become physically unacceptable upon grid refinement. In this work, the Helmholtz-type equation for non-local gradient regularization of a damage model on a distorted grid is solved using an FFT-based approach. Further, the resulting system of equations is solved using the Jacobi iterative method. The model is applied to simulate brittle fracture of an intermetallic. The influence of the time and space discretization, the length-scale parameter, and intermetallic crystallographic orientation on crack evolution is studied.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Finite element model for brittle fracture and fragmentation

A new computational model for brittle fracture and fragmentation has been developed based on finite element analysis of non-linear elasticity equations. The proposed model propagates the cracks by splitting the mesh nodes alongside the most over-strained edges based on the principal direction of strain tensor. To prevent elements from overlapping and folding under large deformations, robust geometrical constraints using the method of Lagrange multipliers have been incorporated. In conclusion, the model has been applied to 2D simulations of the formation and propagation of cracks in brittle materials, and the fracture and fragmentation of stretched and compressed materials.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2019

Statistically informed upscaling of damage evolution in brittle materials

The presence and growth of micro-cracks degrade the strength of brittle solids, greatly impacting the overall material response. Hence, the evolution of these micro-cracks must be accounted for in models describing the relationship between stress and strain so that accurate predictions of material failure can be made. The evolution of individual cracks and crack networks can be simulated with high-fidelity microscale models utilizing highly resolved meshes that can be computationally expensive to a point in which it limits the simulation scale. Hence, for many engineering applications that require simulations of large components, continuum-scale models, which cannot explicitly resolve individual cracks and thus lose important physical information, are required. In this work, we bridge these two scales by developing and implementing a continuum-scale effective moduli constitutive model that is informed by crack statistics generated from a high-fidelity model resolved using a finite-discrete element method (FDEM) implementation. Using statistical information describing the evolution of crack lengths and orientations, this model can capture the effects of brittle damage evolution without the need to resolve individual cracks. We have successfully captured the stress-strain behavior of the high-fidelity simulations using the statistics-based constitutive model shown through direct comparison of stress-strain curves. The curves match within error bars present in the strain-softening portions of the stress-strain curve of the high-fidelity results due to the statistical variation of the initial pre-existing crack network. In conclusion, the stress-strain curves are also compared to experimental results for similar loading conditions and show good qualitative agreement.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Experimental Relationship Between Compressional Wave Attenuation and Surface Strains in Brittle Rock

Linear ultrasonic testing (LUT) has been extensively used as a tool for the evaluation of damage processes in various materials ranging from synthetic metals to natural geomaterials, such as rocks. A key limitation of LUT-based damage studies to date is the lack of explicit evidence used in associating material damage with the changes in measured LUT attributes (e.g., ultrasonic wave amplitude and velocity). In this study, the evolution of the full-field strains in brittle rock specimens (Lyons sandstone) subjected to failure are analyzed in real time and linked with the changes in the ultrasonic wave amplitude in localized areas illuminated by ultrasonic beams, termed as the ultrasonic image areas. The noncontact optical full-field displacement measurement method of 2-D digital image correlation is implemented in combination with the LUT procedure to continuously track changes in the ultrasonic wave amplitude with the evolution of strains across the surface of the uniaxially loaded intact rock specimens. The ultrasonic amplitude showed near-linear correlation with the intensity of inelastic tensile strain recorded in the rock specimens. The results from the study corroborate that the ultrasonic changes are in fact influenced by the regions of tensile cracking, which is the primary inelastic deformation mechanism in brittle rocks.

15 GEOTHERMAL ENERGY↗
DOE OSTI2014

An electronic criterion for assessing intrinsic brittleness of metallic glasses

Bulk metallic glasses (BMGs) are characterized by a number of remarkable physical and mechanical properties. Unfortunately, these same materials are often intrinsically brittle, which limits their utility. Consequently, considerable effort has been expended searching for correlations between the phenomenologically complex mechanical properties of metallic glasses and more basic properties, such correlations might provide insight into the structure and bonding controlling the deformation properties of BMGs. While conducting such a search, we uncovered a weak correlation between a BMG’s work function and its susceptibility to brittle behavior. We argue that the basis for this correlation is a consequence of a component of the work function – the surface dipole – and a fundamental bond property related to the shape of the charge density at a bond critical point. Together these observations suggest that simple first principle calculations might be useful in the search for tougher BMGs.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Ductile-to-brittle transition in spallation of metallic glasses

In this paper, the spallation behavior of a binary metallic glass Cu{sub 50}Zr{sub 50} is investigated with molecular dynamics simulations. With increasing the impact velocity, micro-voids induced by tensile pulses become smaller and more concentrated. The phenomenon suggests a ductile-to-brittle transition during the spallation process. Further investigation indicates that the transition is controlled by the interaction between void nucleation and growth, which can be regarded as a competition between tension transformation zones (TTZs) and shear transformation zones (STZs) at atomic scale. As impact velocities become higher, the stress amplitude and temperature rise in the spall region increase and micro-structures of the material become more unstable. Therefore, TTZs are prone to activation in metallic glasses, leading to a brittle behavior during the spallation process.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Alternating brittle and ductile response of coherent twin boundaries in nanotwinned metals

Nanotwinned metals have opened exciting avenues for the design of high strength and high ductility materials. In this work, we investigate crack propagation along coherent twin boundaries in nanotwinned metals using molecular dynamics. Our simulations reveal that alternating twin boundaries exhibit intrinsic brittleness and ductility owing to the opposite crystallographic orientations of the adjoining twins. This is a startling consequence of the directional anisotropy of an atomically sharp crack along a twin boundary that favors cleavage in one direction and dislocation emission from the crack tip in the opposite direction. We further find that a blunt crack exhibits ductility in all cases albeit with very distinct deformation mechanisms and yield strength associated with intrinsically brittle and ductile coherent twin boundaries.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Brittle-to-ductile transition of lithiated silicon electrodes: Crazing to stable nanopore growth

Using first principle calculations, we uncover the underlying mechanisms explaining the brittle-to-ductile transition of Li{sub x}Si electrodes in lithium ion batteries with increasing Li content. We show that plasticity initiates at x = ∼ 0.5 with the formation of a craze-like network of nanopores separated by Si–Si bonds, while subsequent failure is still brittle-like with the breaking of Si–Si bonds. Transition to ductile behavior occurs at x ⩾ 1 due to the increased density of highly stretchable Li–Li bonds, which delays nanopore formation and stabilizes nanopore growth. Collapse of the nanopores during unloading of the Li{sub x}Si alloys leads to significant strain recovery.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Chaotic state to self-organized critical state transition of serrated flow dynamics during brittle-to-ductile transition in metallic glass

We study serrated flow dynamics during brittle-to-ductile transition induced by tuning the sample aspect ratio in a Zr-based metallic glass. The statistical analysis reveals that the serrated flow dynamics transforms from a chaotic state characterized by Gaussian-distribution serrations corresponding to stick-slip motion of randomly generated and uncorrelated single shear band and brittle behavior, into a self-organized critical state featured by intermittent scale-free distribution of shear avalanches corresponding to a collective motion of multiple shear bands and ductile behavior. The correlation found between serrated flow dynamics and plastic deformation might shed light on the plastic deformation dynamic and mechanism in metallic glasses.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2025

On the bulk compaction of brittle granular materials, Part II: Representing interparticle comminution by K COMP

An applied and empirical compaction fracture resistance parameter, K COMP , was developed to represent the compression-induced interparticle-comminution response of granular brittle materials (e.g., ceramic or glass particles). The development of K COMP is an outcome from Part I of this three-paper series. The K COMP represents a continuum response of compaction fracture resistance and was adapted from established Griffith linear elastic fracture mechanics theory. From that, the K COMP relates macroscopically applied compressive stress to a corresponding inverse-square-root representative particle size, where the latter is estimated from an entire particle size distribution or specific surface area measurement. In conclusion, the K COMP value was not constant over a wide range of stresses for all examined brittle granular materials, and this is indicative of a change in the dominant mode of permanent deformation at higher compaction stresses.

brittle↗
DOE OSTI2026

C‐Cracking of Brittle‐Material Spheres From Eccentric Hertzian Contact

Contact of brittle-material spheres can occur while they are manufactured, handled, or used in operation as roller elements or in deformably processed composite material. Statistically, the directional contact between two spheres will nearly always be oblique or eccentric in an unconfined and mobile sphere population. Although analyses of oblique contact exist, the portrayal of its maximum (tensile) first principal stress ( S 1 ) field is lacking. This information is needed for improved judgment of the prospect of crack initiation. Given these, the S 1 due to eccentric contact and subsequent crack initiation was analyzed using finite element analysis (FEA) and corroborative demonstration of c-crack creation. The FEA shows that an asymmetric S 1 field is created about the contact patch and is caused by superimposed shear intrinsic to eccentric contact. A crack will initiate if the maximum S 1 exceeds the material's tensile strength, and its field will cause the crack to propagate and arrest to form a C-shaped crack, or c-crack. C-crack initiation trends with lower applied forces, with greater amount of contact eccentricity, higher coefficient of friction, and smaller spherical radius. Finally, these metrics deserve recognition, especially when c-cracked brittle-material spheres are used in a system whose functionality or reliability is potentially compromised by the c-cracks.

Hertzian contact↗
DOE OSTI2023

A robust interface finite element formulation for modeling brittle material failure problems

Abstract Failure of many brittle materials and structures can be modeled using interface‐oriented finite elements combined with intrinsic cohesive zone models. The discontinuous Galerkin (DG) finite element method provides an innovative framework for modeling brittle crack propagation with zero‐thickness interface elements, which can accommodate extrinsic cohesive laws to avoid the artificial compliance required in intrinsic cohesive models. However, robust formulations and implementations of DG methods are critical in alleviating the well‐known convergence issues for both crack nucleation and propagation with reduced instability. This paper presents a robust interface element formulation by modifying the incomplete interior penalty Galerkin (IIPG) method, which successfully avoids the initial element interface penetration across elements that occurs prior to crack nucleation, and thereby greatly reduces the instability issue as cracks open. We further verified and validated our implementation by using a bar tension test and a beam fracturing benchmark. The robustness of our proposed interface element method was demonstrated by a micromechanics fiber/matrix debonding problem with 64 fibers embedded in a bulk matrix.

Liu, Ruijie↗
DOE OSTI2021

Flaw-insensitive fracture of a micrometer-sized brittle metallic glass

Brittle materials, such as oxide glasses, are usually very sensitive to flaws, giving rise to a macroscopic fracture strength that is much lower than that predicted by theory. The same applies to metallic glasses (MGs), with the important difference that these glasses can exhibit certain plastic strain prior to catastrophic failure. Here we consider the strongest metallic alloy known, a ternary Co 55 Ta10B 35 MG. In this work, we show that this macroscopically brittle glass is flaw-insensitive at the micrometer scale. This discovery emerges when testing pre-cracked specimens with self-similar geometries, where the fracture stress does not decrease with increasing pre-crack size. The fracture toughness of this ultra-strong glassy alloy is further shown to increase with increasing sample size. Both these findings deviate from our classical understanding of fracture mechanics, and are attributed to a transition from toughness-controlled to strength-controlled fracture below a critical sample size.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Quasi-brittle porous material: Simulated effect of stochastic air void structure on compressive strength

Highlights: • A simulation procedure to study the effect of porosity on the compressive strength of a quasi-brittle material is introduced • Based on the simulated results, the relationship between compressive strength and air void fraction (porosity) is presented. • A linear relationship was achieved between the cubic root of porosity and the simulated compressive strength. The effect of porosity comprised of spherical air voids on the compressive strength of quasi-brittle material was studied via simulations. The simulated porous structures were based on pore size distributions of two mortar samples measured by X-ray microtomography. While the simulation method set practical limits on the size of sample, the base of the statistics was established by simulating 128 small structures generated by sampling from pore structures of two mortars. By studying the application of the classical strength-porosity formulas to the simulated data, a new simple model was formed. A linear relationship was achieved between the cubic root of air void fraction (porosity) and the simulated compressive strength. The reasons for scattering of simulated strength around fitted trend remained unresolved in this study; no clear dependence on pore number or other distribution properties was observed. With the presented simulation approach, the dependence of compressive strength on porosity is achieved independently of disturbances that occur in experimental studies creating understanding of compressional behavior of low porosity materials.

36 MATERIALS SCIENCE↗
DOE OSTI2022

The role of surface forces in environment-enhanced cracking of brittle solids

Fracture initiation and propagation in brittle materials is promoted in surface-reactive (sorptive) environments, a phenomenon known as subcritical crack growth (SCG). Laboratory measured crack-propagation velocity vs. stress intensity factor relationships typically exhibit highly nonlinear, multi-stage characteristics that are sensitive to environmental factors such as adsorbate concentration and temperature. For practical purposes, empirical relationships (e.g., a power law) have been used to describe this complex phenomenon. However, how the overall SCG behavior emerges from the underlying fundamental processes near the crack tip, such as the interaction of the crack surfaces separated by only a few nanometers and mass transport within the nano-confined space, is still not well understood. This paper develops a mechanistic, surface-force-based fracture theory (SFFT) which integrates surface force models, fluid transport models, and linear elastic fracture mechanics to quantitatively explain the multi-stage characteristics of SCG in brittle solids. A numerical model is developed based on SFFT and solved through an implicit partitioned scheme for efficiency and modularity. The results are validated by Wiederhorn's data on crack propagation in soda-lime glasses at a wide range of relative humidity levels. We show that, for the first time, the entire range of an SCG curve can be captured by a single physics-based model. The predicted SCG curves reveal that the development of repulsive disjoining pressure behind the crack tip can be responsible for the reduced apparent fracture toughness in a sorptive environment. In conclusion, the shape of the SCG curve, and its changes with respect to the environment, is found to critically depend on the assumed transport models.

36 MATERIALS SCIENCE↗
DOE OSTI2022

A phase-field model of quasi-brittle fracture for pressurized cracks: Application to UO 2 high-burnup microstructure fragmentation

Here, in this paper, we present a phase-field model of quasi-brittle fracture with pressurized cracks, with dedicated applications for polycrystalline materials. The model is formulated as a minimization problem within the variational framework. The external work done by pressure on the crack surfaces is included in the objective function. Several careful modeling choices lead to a regularization-length-independent critical strength. The model is constructed to give a softening response with an underlying linear traction-separation law. The pressure-dependent softening response and the regularization of the prescribed pressure are demonstrated with a (quasi) one-dimensional numerical analysis. In a two-dimensional numerical analysis under plane strain assumptions, the critical stress corresponding to crack propagation (as predicted by our quasi-brittle fracture model) is compared with linear elastic fracture mechanics (LEFM) analytical solutions. Our model is further utilized to simulate fission-gas-induced fragmentation of the UO 2 high-burnup structure (HBS). Simulation results show that pressurized bubbles can cause crack nucleation and propagation, and that the bubble size and the surrounding external pressure affect the critical pressure corresponding to crack nucleation. Simulations of a partial HBS at different recrystallization stages show that different grain structures (due to recrystallization) also influence crack paths and fragmentation morphology.

36 MATERIALS SCIENCE↗