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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Summary report is described of historical documentation and detailed design data for development of silver-zinc battery for use on Surveyor spacecraft. Electrical and physical characteristics of battery models are included, along with data on qualification, acceptance, solar-thermal-vacuum, mission simulation testing, and actual flight performance.
In this paper the problem of building trust in the online safety prediction of an fixed wing small electric unmanned aerial vehicles (e-UAV) for remaining flying time is addressed. A series of flight tests are described to verify the performance of the remaining flying time prediction algorithm. The estimate of remaining flying time is used to activate an alarm when the predicted remaining time falls below a threshold of two minutes. This updates the pilot to transition to the landing sequence of the flight profile. A second alarm is activated when the battery state of charge (SOC) falls below a specified safety limit threshold. This SOC threshold is the point at which the battery energy reserve would no longer safely support enough aborted landing attempts. During the test flights, the motor system is operated with the same predefined timed airspeed profile for each test. To test the robustness of the developed prediction algorithm, partial tests were performed with and remaining were performed without a simulated power train fault. To simulate a partial power train fault in the e-UAV the pilot engages a resistor bank at a specified time during the test flight. The flying time prediction system is agnostic of the pilot's activation of the fault and must adapt to the vehicle's state. The time at which the limit threshold on battery SOC is reached, it is then used to measure the accuracy of the remaining flying time predictions. This is demonstrated through comparing results from two battery models being developed. Accuracy requirements for the alarms are considered and the results discussed.
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When developing this course several years back I asked myself, "What do I think the TFAWS community needs to know about lithium-ion batteries and why should they care?" I think the answers to these questions can be boiled down to the following statements: 1. Lithium-ion (Li-ion) battery electrical performance and efficiency are heavily driven by thermal conditions. 2. Li-ion battery assemblies can experience single cell thermal runaway events which can lead to cell-to-cell propagation; these are thermally driven failure events that can be controlled with effective thermal management systems. 3. Knowledge of BOTH Li-ion battery fundamentals AND traditional thermal design principles are required to develop safe battery assemblies that are both gravimetrically and volumetrically optimized.This year the Short Course on Lithium-ion Batteries will be presented in a 2-part series. The first portion, "Fundamentals, Battery Safety, and Thermal Runaway," will focus on educating participants on the fundamental aspects of Li-ion batteries and on battery safety related topics (i.e. thermal runaway, cell-to-cell propagation, safe handling practices, et...). The second portion, "Practical Thermal Simulation Techniques," will provide participants with a real time demonstration of how to use Thermal Desktop to model of Li-ion battery assemblies. This part of the lesson will cover geometry simplification, mesh development, boundary conditions, and heat loads for both nominal operations (charge and discharge) and for thermal runaway events.
A mathematical model for the charge and discharge of a sealed nickel-cadmium (Ni-Cd) battery is presented. The model is used to study the effect of transport properties of the electrolyte and kinetic parameters of the electrode reactions on the cell performance during the charge and discharge period. The model can also be used to demonstrate the changes of cell performance during cycling. Some comparisons between model predictions and experimental results indicate that the model predictions appear to fit the experimental data well. Sensitivity analyses illustrate that the sealed nickel-cadmium battery operates under activation control. It is also shown theoretically that oxygen generated on the positive electrode during charge is reduced electrochemically on the negative electrode.
A computer model of the nickel-cadmium (Ni-Cd) battery cell has been developed. This one-dimensional macrohomogeneous model predicts performance for Ni-Cd battery cells based on electrochemical phenomena. Reaction rates, concentrations, current densities, porosities, and potentials are predicted over a range of conditions. A description of the model, some initial results, and plans for continued development are presented.
A generalized code applicable to many different electrochemical systems and geometric designs is discussed. The code is to be set up so that physical property data such as thermal conductivity, viscosity, density, and configuration (e.g. physical dimensions) are the input data. Thus, by changing these parameters many different battery configurations can be handled. The outputs, as a function of time and space, are voltage, current, temperature, pressure, velocity, and species concentration.
This invention develops a mathematical model to describe battery behavior during individual discharge cycles as well as over its cycle life. The basis for the form of the model has been linked to the internal processes of the battery and validated using experimental data. Effects of temperature and load current have also been incorporated into the model. Subsequently, the model has been used in a Particle Filtering framework to make predictions of remaining useful life for individual discharge cycles as well as for cycle life. The prediction performance was found to be satisfactory as measured by performance metrics customized for prognostics for a sample case. The work presented here provides initial steps towards a comprehensive health management solution for energy storage devices.
The performance of a Ni-Cd battery was evaluated and the cyclic battery controls to be used on the ATM batteries were determined. Cell and battery performance models were developed which to predict the performance of the secondary Ni-Cd batteries on the ATM. Capacity degradation and charge acceptance characteristics were considered. Mathematical models for each of these operating areas were developed based on data from two separate test programs. The capacity degradation model describes the expected usable battery capacity as a function of time, temperature, and depth-of-discharge. The charge acceptance model describes the cell charge acceptance as a function of charge rate, temperature, and state of charge. The models were designed for computer use and to facilitate possible battery modification. They can be used to predict expected performance or to compare real time performance during flight.
Electric aviation faces a major challenge of avoiding potentially catastrophic consequences of the battery’s thermal runaway while keeping the weight of the battery low. Detection of early warning signals of battery failures requires accurate monitoring of the battery’s health throughout its lifespan. However, identifying the parameters of the battery from field data is notoriously difficult. We investigate this problem within the framework of modeling the temperature dynamics of a Li-ion cell during tests simulating loading in electric aircraft flights. It is found that the parameters of a higher-fidelity physics-based thermal model cannot be identified from the simulated flight data. To resolve this issue, we reduce the higher-fidelity thermal model to a model with fewer parameters. The resulting reduced-order model can predict temperature dynamics accurately and is identifiable throughout the cell’s lifespan which allows using the model’s parameters to monitor the state-of-health of the aging cell and detect anomalies in thermal behavior.
A two-dimensional thermal model for spirally wound batteries has been developed. The governing equation of the model is the energy balance. Convective and insulated boundary conditions are used, and the equations are solved using a finite element code called TOPAZ2D. The finite element mesh is generated using a preprocessor to TOPAZ2D called MAZE. The model is used to estimate temperature profiles within a spirally wound D-size cell. The model is applied to the lithium/thionyl chloride cell because of the thermal management problems that this cell exhibits. Simplified one-dimensional models are presented that can be used to predict best and worst temperature profiles. The two-dimensional model is used to predict the regions of maximum temperature within the spirally wound cell. Normal discharge as well as thermal runaway conditions are investigated.
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A mathematical model is described which predicts the service life of nickel-cadmium batteries designed for geosynchronous orbit satellites. Regression analysis technique is used to analyze orbital data on second generation trickle charged batteries. The model gives average cell voltage as a function of design parameters, operating parameters and time. The voltage model has the properties of providing a good fit to the data, good predictive capability, and agreement with known battery performance characteristics. Average cell voltage can be predicted to within 0.02 volts for up to 8 years. This modeling shows that these batteries will operate reliably for 10 years. Third-generation batteries are expected to operate even longer.
The TERRA spacecraft was launched in December 1999 from Vandenberg Air Force Base, becoming the flagship of NASA's Earth Observing System program to gather data on how the planet's processes create climate. Originally planned as a 5 year mission, it still provides valuable science data after nearly 10 years on orbit. On October 13th, 2009 at 16:23z following a routine inclination maneuver, TERRA experienced a battery cell failure and a simultaneous failure of several battery heater control circuits used to maintain cell temperatures and gradients within the battery. With several cells nearing the minimum survival temperature, preventing the electrolyte from freezing was the first priority. After several reset attempts and power cycling of the control electronics failed to reestablish control authority on the primary side of the controller, it was switched to the redundant side, but anomalous performance again prevented full heater control of the battery cells. As the investigation into the cause of the anomaly and corrective action continued, a battery thermal model was developed to be used in determining the control ability remaining and to simulate and assess corrective actions. Although no thermal model or detailed reference data of the battery was available, sufficient information was found to allow a simplified model to be constructed, correlated against pre-anomaly telemetry, and used to simulate the thermal behavior at several points after the anomaly. It was then used to simulate subsequent corrective actions to assess their impact on cell temperatures. This paper describes the rapid development of this thermal model, including correlation to flight data before and after the anomaly., along with a comparative assessment of the analysis results used to interpret the telemetry to determine the extent of damage to the thermal control hardware, with near-term corrective actions and long-term operations plan to overcome the anomaly.
The modelling behavior of Zn-AgO batteries during high rates of discharge is covered. The long term model-objectives are: to determine local heat generation rates and the removal of heat.
Extensions are presented for a mathematical model of an Ni-CD cell (Fan and White, 1991). These extensions consist of intercalation thermodynamics for the nickel electrode and oxygen generation and reduction reactions during charge and overcharge. The simulated results indicate that intercalation may be important in the nickel electrode and that including the oxygen reactions provides a means of predicting the efficiency of the cell on charge and discharge.
The search for safe, reliable, and compact high-capacity energy storage devices has led to increased interest in all-solid-state battery research. The use of solid electrolytes provides enhanced safety and durability due to their reduced flammability and increased mechanical strength compared to organic liquid electrolytes. Still, the use of solid electrolytes remains challenging. Computational modeling plays a substantial role in addressing these challenges. A particle dynamics electromechanical model for simulating electrochemical processes in a solid-state battery cathode will be presented. The model presents cathode microstructure at the particle level as a mixture of ionically conductive solid electrolyte particles, electrically conductive carbon additives, and cathodic reactant particles. After densification, the particle connectivity is analyzed to reconstruct the complex electric network connecting reactant particles with an anodic and cathodic current collectors through the electrolyte and carbon particles. The Kirchhoff’s matrix equation describing this electric network, is solved to obtain values of various critical parameters, such as the overall conductivity of the cathode for lithium ions and electrons, cathodic reactant material utilization, and the distribution of the electric current and voltages within the cathode. In addition, by representing the reactant particles as electrolyte or galvanic microcells governed by the Butler-Volmer electrochemical equation, the overall performance of battery cells during charge or discharge processes, respectively, can be predicted for a given cathodic powder composition. The presented model, executed on a high-performance computing architecture, essentially provides a valuable guidance in designing and developing future solid-state batteries.
Recently there is a growing interest in the aviation sector to reduce air and noise pollution. Electrochemical energy storage devices such as batteries coupled with a distributed electric propulsion system can reduce noise concerns as well as emissions and allow the concept of Urban Air Mobility to come to fruition. The battery performance needs to improve considerably compared from current state-of-art Li-ion battery (about 200Wh/Kg) to realize all-electric passenger jet for short flights (up to 690 miles). NASA is exploring lithium-oxygen battery chemistry to power hybrid (battery powered electrical system) and all-electric aircraft for short distance and long-distance flights. Li-O2 is one of the advanced Li-ion technologies that promise to provide specific energy of more than 750Wh/Kg. For this presentation, we present our work on improving power density of Li-O2 batteries through the use of multiphysics simulations. Next, a path is outlined to port these model to simulate performance for a new battery chemistry for space application, Li-CO2. Li-CO2 uses carbon dioxide as the active material instead of oxygen. Although this technology is in its early development, the offers two benefits: it can be used as a CO2 scrubber, as oxygen is one of the by-products on charging, and as a backup or a standalone battery for various Mars or Venus missions, where the carbon dioxide content in the atmosphere is high and need battery to operate at higher temperatures.