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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

A remote sensing evaluation of potential for sinkhole occurrence

The relationship between lowering of the water table and sinkhole development in Pierson and in Hillsborough County, Florida was investigated. The locations of recently developed (1973) collapses were examined with respect to lineaments or fracture traces that are expressed in the terrain and visible in aerial photography and satellite imagery. It was anticipated that these relationships would provide the basis for establishment of criteria for mapping those land areas that have the greatest potential for sinkhole development. A very good correlation was found between mapped lineament intersections and known location of sinkhole occurrences for both study areas. This indicates that lineament and fracture trace mapping may be very useful in locating zones with the greatest potential for sinkhole development. It is further shown that this information is quite beneficial in land use planning applications.

Casper, J.↗

Process for Making a Noble Metal on Tin Oxide Catalyst

To produce a noble metal-on-metal oxide catalyst on an inert, high-surface-area support material (that functions as a catalyst at approximately room temperature using chloride-free reagents), for use in a carbon dioxide laser, requires two steps: First, a commercially available, inert, high-surface-area support material (silica spheres) is coated with a thin layer of metal oxide, a monolayer equivalent. Very beneficial results have been obtained using nitric acid as an oxidizing agent because it leaves no residue. It is also helpful if the spheres are first deaerated by boiling in water to allow the entire surface to be coated. A metal, such as tin, is then dissolved in the oxidizing agent/support material mixture to yield, in the case of tin, metastannic acid. Although tin has proven especially beneficial for use in a closed-cycle CO2 laser, in general any metal with two valence states, such as most transition metals and antimony, may be used. The metastannic acid will be adsorbed onto the high-surface-area spheres, coating them. Any excess oxidizing agent is then evaporated, and the resulting metastannic acid-coated spheres are dried and calcined, whereby the metastannic acid becomes tin(IV) oxide. The second step is accomplished by preparing an aqueous mixture of the tin(IV) oxide-coated spheres, and a soluble, chloride-free salt of at least one catalyst metal. The catalyst metal may be selected from the group consisting of platinum, palladium, ruthenium, gold, and rhodium, or other platinum group metals. Extremely beneficial results have been obtained using chloride-free salts of platinum, palladium, or a combination thereof, such as tetraammineplatinum (II) hydroxide ([Pt(NH3)4] (OH)2), or tetraammine palladium nitrate ([Pd(NH3)4](NO3)2).

Davis, Patricia↗

Control of the Diameter and Chiral Angle Distributions during Production of Single-wall Carbon Nanotubes

Many applications of single wall carbon nanotubes (SWCNT), especially in microelectronics, will benefit from use of certain (n,m) nanotube types (metallic, small gap semiconductor, etc.). However, as produced SWCNT samples are polydispersed, with many (n,m) types present and typical approximate 1:2 metal/semiconductor ratio. It has been recognized that production of SWCNTs with narrow 'tube type populations' is beneficial for their use in applications, as well as for the subsequent sorting efforts. In the present work, SWCNTs were produced by a pulsed laser vaporization (PLV) technique. The nanotube type populations were studied with respect to the production temperature with two catalyst compositions: Co/Ni and Rh/Pd. The nanotube type populations were measured via photoluminescence, UV-Vis-NIR absorption and Raman spectroscopy. It was found that in the case of Co/Ni catalyst, decreased production temperature leads to smaller average diameter, exceptionally narrow diameter distribution, and strong preference toward (8,7) nanotubes. The other nanotubes present are distributed evenly in the 7-30 deg chiral angle range. In the case of Rh/Pd catalyst, a decrease in the temperature leads to a small decrease in the average diameter, with the chiral angle distribution skewed towards 30 o and a preference toward (7,6), (8,6) and (8,7) nanotubes. However, the diameter distribution remains rather broad. These results demonstrate that PLV production technique can provide at least partial control over the nanotube (n,m) populations. In addition, these results have implications for the understanding the nanotube nucleation mechanism in the laser oven.

Nikolaev, Pavel↗

Effects of sounding temperature assimilation on weather forecasting - Model dependence studies

In comparing various methods for the assimilation of remote sounding information into numerical weather prediction (NWP) models, the problem of model dependence for the different results obtained becomes important. The paper investigates two aspects of the model dependence question: (1) the effect of increasing horizontal resolution within a given model on the assimilation of sounding data, and (2) the effect of using two entirely different models with the same assimilation method and sounding data. Tentative conclusions reached are: first, that model improvement as exemplified by increased resolution, can act in the same direction as judicious 4-D assimilation of remote sounding information, to improve 2-3 day numerical weather forecasts. Second, that the time continuous 4-D methods developed at GLAS have similar beneficial effects when used in the assimilation of remote sounding information into NWP models with very different numerical and physical characteristics.

Ghil, M.↗

Lunar beneficiation

Natural concentrations of industrially valuable minerals are far less likely to be found on the Moon than on the Earth. But that is all the more reason for devising beneficiation processes to concentrate and extract the useful mineral components in lunar rocks and soils. As an example of a useful mineral that can be beneficiated, it has been estimated that ilmenite abundance accounts for 15 and 20 percent of the volume of the Apollo 11 and 17 basalts and 2 and 5 percent by volume in the Apollo 11 and 17 soils. Reduction of lunar ilmenite with hydrogen imported from Earth appears to one of the more practical schemes for obtaining lunar oxygen. While the reported concentrations are significant, a more highly concentrated ilmenite extract would improve the efficiency of the reduction process. The topics covered include electrostatic concentration, magnetic concentration, lunar soil sizing, and electrical sizing.

Agosto, William N.↗

Process for making a noble metal on tin oxide catalyst

A quantity of reagent grade tin metal or compound, chloride-free, and high-surface-area silica spheres are placed in deionized water, followed by deaerating the mixture by boiling and adding an oxidizing agent, such as nitric acid. The nitric acid oxidizes the tin to metastannic acid which coats the spheres because the acid is absorbed on the substrate. The metastannic acid becomes tin oxide upon drying and calcining. The tin-oxide coated silica spheres are then placed in water and boiled. A chloride-free precious metal compound in aqueous solution is then added to the mixture containing the spheres, and the precious metal compound is reduced to a precious metal by use of a suitable reducing agent such as formic acid. Very beneficial results were obtained using the precious metal compound tetraammine platinum(II) hydroxide.

Upchurch, Billy T.↗

The effects of structural flap-lag and pitch-lag coupling on soft inplane hingeless rotor stability in hover

A 1.62-m-diameter rotor model was tested in hover to examine the effects of structural flap-lag and pitch-lag coupling on isolated rotor blade lead-lag stability. Flap-lag coupling was introduced by inclining the principal axes of the blade structure up to 60 degrees. Pitch-lag coupling was obtained either alone or in combination with flap-lag coupling through the use of skewed flexural hinges. The principal results confirm the predictions of theory, and show that both structural flap-lag and pitch-lag coupling when used separately are beneficial to blade stability. Moreover, when the couplings are combined, the lead-lag damping is significantly greater than it would be if the individual contributions were superimposed. Pitch-flap coupling is shown to have only a minor effect on blade lead-lag damping. Differences between theory and experiment observed at zero blade pitch and flexure angles during the initial testing were determined in a second test to be caused by stand flexibility. Other differences between theory and experiment warrant further investigation.

Bousman, William G.↗

Optimized Coolant-Flow Diverter For Increased Bearing Life

Coolant-flow diverter for rolling-element bearings in cryogenic turbopump designed to enhance cooling power of flow in contact with bearings and thereby reduce bearing wear. Delivers jets of coolant as close as possible to hot spots at points of contact between balls and race. Also imparts swirl that enhances beneficial pumping effect. Used with success in end ball bearing of high-pressure-oxidizer turbopump.

Subbaraman, Maria R.↗

Alkyl Pyrocarbonate Electrolyte Additives for Performance Enhancement of Li Ion Cells

Lithium ion rechargeable batteries are being developed for various aerospace applications under a NASA-DoD Interagency program. These applications require further improvements in several areas, specifically in the cycle life for LEO and GEO satellites and in the low temperature performance for the Mars Lander and Rover missions. Accordingly, we have been pursuing research studies to achieve improvement in the low temperature performance, long cycle life and active life of Li ion cells. The studies are mainly focused on electrolytes, to identify newer formulations of new electrolyte additives to enhance Li permeability (at low temperatures) and stability towards the electrode. The latter approach is particularly aimed at the formation suitable SEI (solid electrolyte interphase) on carbon electrodes. In this paper, we report the beneficial effect of using alkyl pyrocarbonates as electrolyte additives to improve the low temperature performance of Li ion cells.

Smart, M. C.↗

X-ray digital imaging petrography of lunar mare soils: modal analyses of minerals and glasses

It is essential that accurate modal (i.e., volume) percentages of the various mineral and glass phases in lunar soils be used for addressing and resolving the effects of space weathering upon reflectance spectra, as well as for their calibration such data are also required for evaluating the resource potential of lunar minerals for use at a lunar base. However, these data are largely lacking. Particle-counting information for lunar soils, originally obtained to study formational processes, does not provide these necessary data, including the percentages of minerals locked in multi-phase lithic fragments and fused-soil particles, such as agglutinates. We have developed a technique for modal analyses, sensu stricto, of lunar soils, using digital imaging of X-ray maps obtained with an energy-dispersive spectrometer mounted on an electron microprobe. A suite of nine soils (90 to 150 micrometers size fraction) from the Apollo 11, 12, 15, and 17 mare sites was used for this study. This is the first collection of such modal data on soils from all Apollo mare sites. The abundances of free-mineral fragments in the mare soils are greater for immature and submature soils than for mature soils, largely because of the formation of agglutinitic glass as maturity progresses. In considerations of resource utilization at a lunar base, the best lunar soils to use for mineral beneficiation (i.e., most free-mineral fragments) have maturities near the immature/submature boundary (Is/FeO approximately or = 30), not the mature soils with their complications due to extensive agglutination. The particle data obtained from the nine mare soils confirm the generalizations for lunar soils predicted by L.A. Taylor and D.S. McKay (1992, Lunar Planet Sci. Conf. 23rd, pp. 1411-1412 [Abstract]).

NASA Discipline Exobiology↗

Robust Feedback Control of Flow Induced Structural Radiation of Sound

A significant component of the interior noise of aircraft and automobiles is a result of turbulent boundary layer excitation of the vehicular structure. In this work, active robust feedback control of the noise due to this non-predictable excitation is investigated. Both an analytical model and experimental investigations are used to determine the characteristics of the flow induced structural sound radiation problem. The problem is shown to be broadband in nature with large system uncertainties associated with the various operating conditions. Furthermore the delay associated with sound propagation is shown to restrict the use of microphone feedback. The state of the art control methodologies, IL synthesis and adaptive feedback control, are evaluated and shown to have limited success for solving this problem. A robust frequency domain controller design methodology is developed for the problem of sound radiated from turbulent flow driven plates. The control design methodology uses frequency domain sequential loop shaping techniques. System uncertainty, sound pressure level reduction performance, and actuator constraints are included in the design process. Using this design method, phase lag was added using non-minimum phase zeros such that the beneficial plant dynamics could be used. This general control approach has application to lightly damped vibration and sound radiation problems where there are high bandwidth control objectives requiring a low controller DC gain and controller order.

Heatwole, Craig M.↗

Sensitivity Analysis for Atmospheric Infrared Sounder (AIRS) CO2 Retrieval

The Atmospheric Infrared Sounder (AIRS) is a thermal infrared sensor able to retrieve the daily atmospheric state globally for clear as well as partially cloudy field-of-views. The AIRS spectrometer has 2378 channels sensing from 15.4 micrometers to 3.7 micrometers, of which a small subset in the 15 micrometers region has been selected, to date, for CO2 retrieval. To improve upon the current retrieval method, we extended the retrieval calculations to include a prior estimate component and developed a channel ranking system to optimize the channels and number of channels used. The channel ranking system uses a mathematical formalism to rapidly process and assess the retrieval potential of large numbers of channels. Implementing this system, we identifed a larger optimized subset of AIRS channels that can decrease retrieval errors and minimize the overall sensitivity to other iridescent contributors, such as water vapor, ozone, and atmospheric temperature. This methodology selects channels globally by accounting for the latitudinal, longitudinal, and seasonal dependencies of the subset. The new methodology increases accuracy in AIRS CO2 as well as other retrievals and enables the extension of retrieved CO2 vertical profiles to altitudes ranging from the lower troposphere to upper stratosphere. The extended retrieval method for CO2 vertical profile estimation using a maximum-likelihood estimation method. We use model data to demonstrate the beneficial impact of the extended retrieval method using the new channel ranking system on CO2 retrieval.

sensitivity analysis↗

The Friendly Argument Notation (FAN)

This document defines and explains through examples the Friendly Argument Notation (FAN). FAN builds on previous work investigating text-based ways to express arguments [2, 3]. Its primary intended use is for creating and evaluating arguments about safety-critical systems, especially the types of arguments common within safety and assurance cases [4], but nothing in its design constrains its use to that domain. Compared to existing notations commonly used within this domain (for example [6]), FAN corresponds more closely to traditional argument concepts (for example [1]), allows greater flexibility in expression, provides for including counter-arguments, and requires less knowledge of computer-science-specific concepts. Only time and use will determine how beneficial these differences are in practice. This paper concentrates on showing how FAN looks to someone who is using it manually to develop or assess arguments. A later document will concentrate on providing the information necessary for software tools to be created for FAN.

arugment↗

The Roles of Beneficiation in Lunar Work

Natural feedstocks used for any process are intrinsically variable. They may also contain deleterious components or low concentrations of desired fractions. For these three reasons it is standard industrial practice to beneficiate feedstocks. This is true across all industries which trans-form raw materials into standardized units. On the Moon there are three natural resources: vacuum, radiation and regolith. To utilize in situ resources on the Moon it is reasonable to presume some beneficiation of the regolith (ground rock) resource will be desirable if not essential. As on Earth, this will require fundamental understanding of the physics and chemistry of the relevant processes, which are exceeding complex in detail. Further, simulants are essential test articles for evaluation of components and systems planned for lunar deployment. Simulants are of course made from geologic feedstocks. Therefore, there is variation, deleterious components and incorrect concentrations of desired fractions in the feedstocks used for simulants. Thus, simulant production can benefit from beneficiation of the input feedstocks. Beneficiation of geologic feedstocks is the subject of extractive metallurgy. Clearly, NASA has two discrete interests pertaining to the science and technology of extractive metallurgy.

Rickman, Doug L.↗

Orbital construction demonstration study. Volume 1: Executive summary

A conceptual design and program plan for an Orbital Construction Demonstration Article (OCDA), that can be used for technology growth and verification, and as the construction facility for a variety of large structures is presented. The OCDA design includes a large work platform, a rotating manipulator boom, a 250 kw solar array, and a core module of subsystems with a total mass of 37,093 kg, that can be assembled in three shuttle flights. An analysis of OCDA continued utility potential indicates that a shuttle tended platform with 250 kW of power can effectively be used to construct highly beneficial antenna systems and large demonstration articles that advance solar power satellite technologies. The construction of 100 m parabolic reflectors for use as a radiometer for measuring soil moisture and water salinity was found to be within the capabilities of OCDA concept. With 252 fixed beams for high population centers, and 16 scanning beams for rural areas, the antenna has the potential to significantly improve U.S. space based communications systems. The OCDA, that is slightly increased in size, was found adequate to build a large 2 MW solar array which, when coupled to a transmit antenna, demonstrate power transfer from space to ground.

Source record↗

Integrating Beneficiation into Regolith Conveyance Systems

Regolith conveyance includes hauler/dumpers, hoppers, augers, pneumatic transport subsystems, and other elements. The features of the conveyance and the time the material stream spend in conveyance may be used synergistically to perform beneficiation, pre-processing (such as heating), and other tasks, thus reducing the mass and complexity of the overall ISRU system. Since the cost of spaceflight is largely driven by the cost of launching mass out of Earth's gravity well, the conveyance system should be leveraged in this way to the maximum extent.

Metzger, Philip T.↗

Considerations for policy on man-made debris propagation control

The present rates of man-made, space object propagation are such that there is a real probability of self propagation which, if uncontrolled can lead to a serious limitation to future uses of spacecraft for beneficial purposes. Effective control over the debris issue requires adoption and adherence to policy at a world wide level (any one nation's unknowing, selfish or deliberately adverse action can conceivably jeopardize other useful applications of space satellites for years into the future). The near-term environment may not seriously jeopardize the near-term missions. However, absence of control and/or nonadherence to a control policy in the near-term can result in a debris environment that can severely limit long - term mission opportunities. The data upon which these observations are based continues to be investigated. These investigations tend to validate the preceding observations and emphasize the need for near-term action to establish responsible control policy and implementation actions.

Fielder, D.↗