Results for “Blueprint” — Page 4

NASA NTRS2018

Aero-Propulsion Control Research in Support of NASA Aeronautics Research Strategic Thrusts

In the past few years, NASA (National Aeronautics and Space Administration) Aeronautics Research Mission Directorate (ARMD) has introduced and updated a â€œNew Blueprint for Transforming Global Aviationâ€ . This blueprint consists of six NASA Aeronautics Research Strategic Thrusts â€" â€œThe updated vision is designed to ensure that through NASA's aeronautical research the United States will maintain its leadership in the sky and sustain aviation so that it remains a key economic driver and cultural touchstone for the nation.â€ In mid-2016, technology development roadmaps were developed by ARMD for each of the strategic research thrusts and these roadmaps are continually being updated based on feedback from the broader aeronautics research community. The NASA Aeronautics research vision is implemented through a set of 4 programs â€" Advanced Air Vehicles Program (AAVP), Airspace Operations and Safety Program (AOSP), Integrated Aviation Systems Program (IASP), and Transformative Aeronautics Concepts Program (TACP). The Intelligent Control and Autonomy Branch (ICAB) at NASA Glenn Research Center (GRC) in Cleveland, Ohio, is leading and participating in various projects in partnership with other organizations within GRC and across NASA, the U.S. aerospace industry, and academia to develop advanced controls and health management technologies for aero-propulsion systems that will help meet the goals of the ARMD programs. These efforts are primarily under the various projects under AAVP, AOSP, and TACP. The ICAB current research tasks in support of ARMD program are described in this paper. The paper provides motivation, background, technical approach and recent accomplishments for these tasks, as well as a couple of tasks completed in the previous fiscal year.

Propulsion Control↗

NASA NTRSDate not supplied

Software for Optical (Laser) Ground Station Monitor and Control

Previous NASA laser communication missions have been supported by ground terminals specific to the mission. The Low-Cost Optical Terminal project (LCOT) aims to serve as a commercial off-the-shelf (COTS), reusable, and modular optical ground terminal prototype, provide a blueprint for future optical ground terminals, and enable optical communication experiments with a variety of spacecraft from Low Earth Orbit to lunar orbit. The goal of the internship was the development of LCOT’s Gimbal Monitor and Control (GMC) application, within the LCOT Monitor and Control Subsystem (MCS). Mount control software PWI4 was provided by mount and gimbal vendor Planewave Instruments; developed in Python, GMC integrates and interfaces with PWI4 using third party libraries such as Protobuf and RabbitMQ. As a stand in for the Monitor and Control Subsystem (MCS), a test Graphical User Interface (GUI) was created to send commands to and receive telemetry from the GMC application; these commands and telemetry are sent through the RabbitMQ message bus as Protobuf encoded messages. GMC then interfaces with PWI4 which passes along desired commands and telemetry to and from a vendor provided mount and gimbal simulator. The GMC software developed allows LCOT’s Monitor and Control Subsystem (MCS) to take advantage of the existing mount control software, advancing LCOT’s efforts in the development of the MCS. The MCS and GMC software developed will contribute to LCOT’s goal as a flexible and modular optical ground terminal prototype and blueprint, which supports development towards a potential optical ground terminal network.

space communications↗

NASA NTRSDate not supplied

Characterization of in-Space Propulsion Trade Space to Support Initial Human Mars Segment

The National Aeronautics and Space Administration’s Exploration Systems Development Mission Directorate has been developing architecture concepts for human missions to Mars in alignment with the agency’s Moon to Mars blueprint objectives. The focus of the Architecture Development Office has been to decompose the blueprint objectives into the characteristics and needs for both lunar and Mars missions and develop functional needs to enable an integrated end-to-end mission architecture. One of the key components of a human Mars mission is the in-space transportation system that delivers crew and cargo to Mars vicinity and return crew safely back to Earth. The Mars Architecture Team has been evaluating four in-space transportation options to satisfy this functional need: 1) Hybrid Nuclear Electric/ Chemical Propulsion, 2) Nuclear Thermal Propulsion, 3) Hybrid Solar Electric/ Chemical Propulsion, and 4) All-Chemical propulsion. To answer the question “which transportation option is best?” decision makers will need to understand the performance characteristics—and limitations—for each architecture in the context of their preferred metric. Each option could be considered “better” than the others, depending on whether the primary selection criteria is fast, cheap, maximum cross-government applicability, maximizes commercial capabilities, and/or any other desired metrics. The Mars Architecture Team has completed considerable analysis on the Hybrid Nuclear Electric/Chemical Propulsion concept over the past three years. The Space Nuclear Propulsion program has also conducted significant work on the Nuclear Thermal Propulsion concept. The Hybrid Solar Electric/Chemical Propulsion concept, derived from technology planned for the Gateway program, was originally configurated for minimum vehicle stack mass (and, hence, minimum Earth-launched mass/cost), leveraging a highly efficient propulsion system on a minimum energy Conjunction Class trajectory. Historically, All-Chemical concepts were considered impractical due to the enormous propellant mass required, even for minimum energy Conjunction Class/long stay mission opportunities. However, considering the emerging commercial heavy-lift capabilities, the concept must be reevaluated across a range of concepts that leverage reusable launch vehicle capabilities to reduce the cost of launching large quantities of transportation elements needed for missions of various duration. This paper aims to provide an overview of the in-space transportation assessment work that is on-going within NASA.

Mars↗

NASA NTRSDate not supplied

Characterization of in-Space Propulsion Trade Space to Support Initial Human Mars Segment

The National Aeronautics and Space Administration’s Exploration Systems Development Mission Directorate has been developing architecture concepts for human missions to Mars in alignment with the agency’s Moon to Mars blueprint objectives. The focus of the Architecture Development Office has been to decompose the blueprint objectives into the characteristics and needs for both lunar and Mars missions and develop functional needs to enable an integrated end-to-end mission architecture. One of the key components of a human Mars mission is the in-space transportation system that delivers crew and cargo to Mars vicinity and return crew safely back to Earth. The Mars Architecture Team has been evaluating four in-space transportation options to satisfy this functional need: 1) Hybrid Nuclear Electric/ Chemical Propulsion, 2) Nuclear Thermal Propulsion, 3) Hybrid Solar Electric/ Chemical Propulsion, and 4) All-Chemical propulsion. To answer the question “which transportation option is best?” decision makers will need to understand the performance characteristics—and limitations—for each architecture in the context of their preferred metric. Each option could be considered “better” than the others, depending on whether the primary selection criteria is fast, cheap, maximum cross-government applicability, maximizes commercial capabilities, and/or any other desired metrics. The Mars Architecture Team has completed considerable analysis on the Hybrid Nuclear Electric/Chemical Propulsion concept over the past three years. The Space Nuclear Propulsion program has also conducted significant work on the Nuclear Thermal Propulsion concept. The Hybrid Solar Electric/Chemical Propulsion concept, derived from technology planned for the Gateway program, was originally configurated for minimum vehicle stack mass (and, hence, minimum Earth-launched mass/cost), leveraging a highly efficient propulsion system on a minimum energy Conjunction Class trajectory. Historically, All-Chemical concepts were considered impractical due to the enormous propellant mass required, even for minimum energy Conjunction Class/long stay mission opportunities. However, considering the emerging commercial heavy-lift capabilities, the concept must be reevaluated across a range of concepts that leverage reusable launch vehicle capabilities to reduce the cost of launching large quantities of transportation elements needed for missions of various duration. This paper aims to provide an overview of the in-space transportation assessment work that is on-going within NASA.

Mars↗

NASA NTRSDate not supplied

A Comparative Assessment of Evolvable Martian ISRU Propellant Production for Future Human Missions

In 2022, NASA released its “Moon to Mars Strategy and Objectives Development” document, containing top-level goals and objectives designed to create a blueprint for sustained human presence and exploration throughout the solar system. One objective in this “blueprint” calls for the demonstration of “…Mars ISRU capabilities to support an initial human Mars exploration campaign.” NASA is looking at both the benefits and liens of this concept, as one of several trade space aspects under consideration, for inclusion in the overall architecture of the human exploration of Mars. This paper summarizes results from a series of Martian ISRU-focused trade studies from 2023 and 2024. These studies cover five different approaches to providing propellants for returning crew and equipment from the surface of Mars, using several different combinations of propellants delivered (from Earth) and produced from Martian feedstock material. For comparison purposes, the same ISRU infrastructure elements were used across all options wherever possible. The equipment mass, power, operational complexity, and time needed to produce some or all of these propellants have been quantified and compared when used in a common mission scenario. Analysis results for each option are discussed. Performance parameters for these options are compared side-by-side and observations made, including the positive and negative aspects of each case. The possibility of evolving from a simpler ISRU case to more complex cases that would potentially lead to more sustainable operations are also discussed. While no single case emerged as “better” in all aspects when compared to the others, there are distinct advantages and disadvantages that did emerge when comparing the results generated from a common set of assumptions for all cases. Consequently, specific mission objectives may determine which of these advantages or disadvantages are important for choosing among the cases that could benefit any particular mission or campaign.

Mars↗

NASA NTRSDate not supplied

A Comparative Assessment of Evolvable Martian ISRU Propellant Production for Future Human Missions

In 2022, NASA released its “Moon to Mars Strategy and Objectives Development” document, containing top-level goals and objectives designed to create a blueprint for sustained human presence and exploration throughout the solar system. One objective in this “blueprint” calls for the demonstration of “…Mars ISRU capabilities to support an initial human Mars exploration campaign.” NASA is looking at both the benefits and liens of this concept, as one of several trade space aspects under consideration, for inclusion in the overall architecture of the human exploration of Mars. This paper summarizes results from a series of Martian ISRU-focused trade studies from 2023 and 2024. These studies cover five different approaches to providing propellants for returning crew and equipment from the surface of Mars, using several different combinations of propellants delivered (from Earth) and produced from Martian feedstock material. For comparison purposes, the same ISRU infrastructure elements were used across all options wherever possible. The equipment mass, power, operational complexity, and time needed to produce some or all of these propellants have been quantified and compared when used in a common mission scenario. Analysis results for each option are discussed. Performance parameters for these options are compared side-by-side and observations made, including the positive and negative aspects of each case. The possibility of evolving from a simpler ISRU case to more complex cases that would potentially lead to more sustainable operations are also discussed. While no single case emerged as “better” in all aspects when compared to the others, there are distinct advantages and disadvantages that did emerge when comparing the results generated from a common set of assumptions for all cases. Consequently, specific mission objectives may determine which of these advantages or disadvantages are important for choosing among the cases that could benefit any particular mission or campaign.

Propellant↗

DOE OSTI2024

An Action Plan for Rail Energy and Emissions Innovation

The Action Plan for Rail Energy and Emissions Innovation proposes actions to reduce and nearly eliminate emissions in the U.S. rail sector, in line with the U.S. economy-wide goal of net-zero greenhouse gas (GHG) emissions by 2050. It also proposes actions to leverage the rail system to reduce emissions from other modes. The national goal of achieving a zero-emission freight system by 2050 draws our attention to the fact that freight transport cannot be addressed simply mode by mode, but it should instead be treated as an interdependent system. This is especially true when pursuing decarbonization. This action plan presents how both rail transport and decarbonization intersect with our national transportation decarbonization blueprint, the decarbonization of the freight system, and national transmission goals. The intended audience of this report is the stakeholders who will advance rail decarbonization in a just and economical way by propelling the suite of actions listed here. This includes government at all levels, rail companies, locomotive manufacturers, labor unions, Amtrak, and more.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2023

Macroscale Fabrication of Lightweight and Strong Porous Carbon Foams through Template-Coating Pair Design

Manufacturing of low-density-high-strength carbon foams can benefit the construction, transportation, and packaging industries. One successful route to lightweight and mechanically strong carbon foams involves pyrolysis of polymeric architectures, which is inevitably accompanied by drastic volumetric shrinkage (usually >98%). As such, a challenge of these materials lies in maintaining bulk dimensions of building struts that span orders of magnitude difference in length scale from centimeters to nanometers. Here, this work demonstrates fabrication of macroscale low-density-high-strength carbon foams that feature exceptional dimensional stability through pyrolysis of robust template-coating pairs. The template serves as the architectural blueprint and contains strength-imparting properties (e.g., high node density and small strut dimensions); it is composed of a low char-yielding porous polystyrene backbone with a high carbonization-onset temperature. The coating serves to imprint and transcribe the template architecture into pyrolytic carbon; it is composed of a high char-yielding conjugated polymer with a relatively low carbonization-onset temperature. The designed carbonization mismatch enables structural inheritance, while the decomposition mismatch affords hollow struts, minimizing density. The carbons synthesized through this new framework exhibit remarkable dimensional stability (≈80% dimension retention; ≈50% volume retention) and some of the highest specific strengths (≈0.13 GPa g -1 cm 3 ) among reported carbon foams derived from porous polymer templates.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Polysulfamates as “Macroisosteres” of Polyurethanes with Improved Degradability

Abstract Addressing the environmental persistence of plastics requires the development of next‐generation polymers that combine high performance with enhanced degradability. Progress toward this grand challenge has been impeded, in part, by the absence of a general blueprint for the macromolecular design of such materials. Herein, we introduce a “macroisostere” design strategy, where the carbonyl group (–CO–) in polyurethanes (PUs) is replaced with a sulfonyl group (–SO 2 –), resulting in a virtually unknown family of polymers called polysulfamates. This approach, inspired by the use of bioisosteres in drug discovery, aims to preserve key interchain interactions that contribute to thermomechanical performance while enhancing the hydrolytic lability of the polymer backbone. The optimization of a Sulfur(VI) Fluoride Exchange (SuFEx) polymerization allowed the synthesis of ten polysulfamates structurally analogous to common PUs. Comparative analysis of one PU and its polysulfamate analog showed that this isosteric substitution increases thermal stability, slightly lowers the glass transition temperature, and retains similar hardness and reduced Young's modulus. Notably, the S(VI)‐based polysulfamate demonstrated significantly enhanced hydrolytic degradability. These results highlight the potential of the “macroisostere” approach as a generalizable strategy for designing high‐performance, degradable alternatives to traditional plastics.

Chemistry↗

DOE OSTI2022

Structure- and Interaction-Based Design of Anti-SARS-CoV-2 Aptamers

Aptamer selection against novel infections is a complicated and time-consuming approach. Synergy can be achieved by using computational methods together with experimental procedures. In this study, we aim to develop a reliable methodology for a rational aptamer in silico et vitro design. The new approach combines multiple steps: (1) Molecular design, based on screening in a DNA aptamer library and directed mutagenesis to fit the protein tertiary structure; (2) 3D molecular modeling of the target; (3) Molecular docking of an aptamer with the protein; (4) Molecular dynamics (MD) simulations of the complexes; (5) Quantum-mechanical (QM) evaluation of the interactions between aptamer and target with further analysis; (6) Experimental verification at each cycle for structure and binding affinity by using small-angle X-ray scattering, cytometry, and fluorescence polarization. By using a new iterative design procedure, structure- and interaction-based drug design (SIBDD), a highly specific aptamer to the receptor-binding domain of the SARS-CoV-2 spike protein, was developed and validated. The SIBDD approach enhances speed of the high-affinity aptamers development from scratch, using a target protein structure. The method could be used to improve existing aptamers for stronger binding. This approach brings to an advanced level the development of novel affinity probes, functional nucleic acids. It offers a blueprint for the straightforward design of targeting molecules for new pathogen agents and emerging variants.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2022

Building an Integrated Ecosystem of Computational and Observational Facilities to Accelerate Scientific Discovery

Future scientific discoveries will rely on flexible ecosystems that incorporate modern scientific instruments, high performance computing resources, parallel distributed data storage, and performant networks across multiple, independent facilities. In addition to connecting physical resources, such an ecosystem presents many challenges in logistics and accessibility, especially in orchestrating computations and experiments that span across leadership computing systems and experimental instruments. Past efforts have typically been application-specific or limited to interfaces for computing resources. This paper proposes a general framework for integrating computation resources and instrument operations, addressing challenges in code development/execution, data staging and collection, software stack, control mechanisms, resource authorization and governance, and hardware integration. We also describe a demonstration use case wherein a Bayesian optimization algorithm running on an edge computing resource guides a scanning probe microscope to autonomously and intelligently characterize a material sample. This science edge ecosystem framework will provide a blueprint for federating multi-institutional, disparate resources and orchestrating scientific workflows across them to enable next-generation discoveries.

Somnath, Suhas↗

DOE OSTI2023

Chlorophylls as primary electron acceptors in reaction centers

Photosynthetic Reaction Centers (RCs) can be considered blueprints for highly efficient energy transfer. Embedded with an array of cofactors, including (bacterio)chlorophyll ((B)Chl) and (B)pheophytin ((B)Pheo) molecules, RCs function with a high quantum yield that spans a wide spectral range. Understanding the principles that underlie their function can influence the design of the next generation of artificial photosynthetic devices. We are particularly interested in the factors that influence the early stages of light-driven charge separation in RCs. With the recent publication of several highly anticipated RC structures and advanced computational methods available, it is possible to probe both the geometric and electronic structures of an array of RCs. In this chapter, we review the electronic and geometric structures of the (B)Chl and (B)Pheo primary electron acceptors from fiveRCs, comprising both Type I and Type II RCs and representing both heterodimeric and homodimeric systems. We showcase the dimeric A0•- state of Type I RCs, whereby the unpaired electron is delocalized, to various extents, over two (B)Chl molecules (B)Chl2 and (B)Chl3. This delocalization is controlled by several factors, including the structure of the (B)Chls, interactions with the surrounding protein matrix, and the orientation and distances of the cofactors themselves. In contrast, the primary acceptors of Type II RCs are entirely monomeric, with electron density residing solely on the (B)Pheo. We compare the natural design of the primary acceptors of the Type I and Type II RCs from both an evolutionary and application based perspective.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

DuctGPT: A Generative Transformer for Forward Screening of Ductile Refractory Multi-Principal Element Alloys

Designing ductile materials for extreme environments such as fusion reactors requires a deep understanding of the complex interplay between electronic structure, mechanical stability, and wide compositional space. Here, in this work, we introduce DuctGPT, a physics-informed, GPT-powered machine learning platform that enables rapid and accurate prediction of ductility across a wide range of refractory multi-principal element alloys (MPEAs). Trained on both experimental and high-fidelity computational data, DuctGPT integrates descriptors such as density of states at the Fermi level, elastic constants, and valence electron concentration to capture the fundamental mechanisms governing ductile versus brittle behavior. Using this framework, we screen over 1000 compositions in of body-centered cubic (BCC) MPEAs, including two new alloy classes, i.e., NbTa-rich (NbTa $>$ 50 at.%) NbTa-Ti-V and W-rich ($>$ 50 at.%) W-Ti-V MPEAs, to rapidly identify promising alloy compositions with enhanced ductility. Validation against experimental data confirms the model's ability to predict ductility with high fidelity and low uncertainty. By leveraging conversational AI and robust physical modeling, DuctGPT provides a blueprint for the next generation of alloy design assistants, enabling human-AI collaboration in the accelerated discovery of ductile, high-performance materials for fusion, aerospace, and advanced manufacturing.

AI/ML↗

DOE OSTI2021

Single pot catalyst strategy to branched products via adhesive isomerization and hydrocracking of polyethylene over platinum tungstated zirconia

Hydrocracking is an insufficiently explored route for chemical recycling of plastics waste. Platinum tungstated zirconia (Pt-WZr) was used in a batch reactor at low temperatures of 250 °C and 30 bar H 2 pressure for 1-24 h reaction times using low-density polyethylene (LDPE, M w ~76 kDa). We find Pt-WZr is a bifunctional catalyst for LDPE hydrocracking leading to higher value branched fuel- and lubricant-ranged alkanes. Here we demonstrate that the catalyst metal-to-acid site molar ratio (MAB) shifts the product distribution to larger cracked products and increases the isomerization degree in the residual polymer. We propose a new adhesive isomerization mechanism between the metal and Brønsted acid sites in parallel with slow polymer chain cracking, caused by competitive adsorption of the polymer over the liquid products and stereochemical hindrance of methines. This study provides a blueprint on how to engineer effective catalysts for hydrocracking polyolefin plastic wastes using the MAB as a catalyst descriptor.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Analyzing the impact of design factors on solar module thermomechanical durability using interpretable machine learning techniques

Solar modules in utility-scale systems are expected to maintain decades of lifetime to rival conventional energy sources. However, cyclic thermomechanical loading often degrades their long-term performance, highlighting the importance of effective design to mitigate thermal expansion mismatches between module materials. Given the complex composition of solar modules, isolating the impact of individual components on overall durability remains a challenging task. In this work, we analyze a comprehensive data set that comprises bill-of-materials (BOM) and thermal cycling power loss from 251 distinct module designs to identify the predominant design factors and their impacts on the thermomechanical durability of modules. The methodology of our analysis combines machine learning modeling (random forest) and Shapley additive explanation (SHAP) to correlate design factors with power loss and interpret the model’s decision-making. The interpretation reveals that silicon type (monocrystalline or polycrystalline), encapsulant thickness, busbar numbers, and wafer thickness predominantly influence the degradation. With lower power loss of around 0.6% on average in the SHAP analysis, monocrystalline cells present better durability than polycrystalline cells. This finding is further substantiated by statistical testing on our raw data set. The SHAP analysis also demonstrates that while thicker encapsulants lead to reduced power loss, further increasing their thickness over around 0.6 to 0.7 mm does not yield additional benefits, particularly for the front side one. In addition, other important BOM features such as the number of busbars are analyzed. This study provides a blueprint for utilizing explainable machine learning techniques in a complex material system and can potentially guide future research on optimizing the design of solar modules.

14 SOLAR ENERGY↗

DOE OSTI2021

Structural basis for IL-12 and IL-23 receptor sharing reveals a gateway for shaping actions on T versus NK cells

Interleukin-12 (IL-12) and IL-23 are heterodimeric cytokines that are produced by antigen-presenting cells to regulate the activation and differentiation of lymphocytes, and they share IL-12Rβ1 as a receptor signaling subunit. In this paper, we present a crystal structure of the quaternary IL-23 (IL-23p19/p40)/IL-23R/IL-12Rβ1 complex, together with cryoelectron microscopy (cryo-EM) maps of the complete IL-12 (IL-12p35/p40)/IL-12Rβ2/IL-12Rβ1 and IL-23 receptor (IL-23R) complexes, which reveal “non-canonical” topologies where IL-12Rβ1 directly engages the common p40 subunit. We targeted the shared IL-12Rβ1/p40 interface to design a panel of IL-12 partial agonists that preserved interferon gamma (IFNγ) induction by CD8+ T cells but impaired cytokine production from natural killer (NK) cells in vitro. These cell-biased properties were recapitulated in vivo, where IL-12 partial agonists elicited anti-tumor immunity to MC-38 murine adenocarcinoma absent the NK-cell-mediated toxicity seen with wild-type IL-12. Thus, the structural mechanism of receptor sharing used by IL-12 family cytokines provides a protein interface blueprint for tuning this cytokine axis for therapeutics.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2021

Isolation and characterization of cross-neutralizing coronavirus antibodies from COVID-19+ subjects

SARS-CoV-2 is one of three coronaviruses that have crossed the animal-to-human barrier and caused widespread disease in the past two decades. The development of a universal human coronavirus vaccine could prevent future pandemics. We characterize 198 antibodies isolated from four COVID-19+ subjects and identify 14 SARS-CoV-2 neutralizing antibodies. One targets the N-terminal domain (NTD), one recognizes an epitope in S2, and 11 bind the receptor-binding domain (RBD). Three anti-RBD neutralizing antibodies cross-neutralize SARS-CoV-1 by effectively blocking binding of both the SARS-CoV-1 and SARS-CoV-2 RBDs to the ACE2 receptor. Using the K18-hACE transgenic mouse model, we demonstrate that the neutralization potency and antibody epitope specificity regulates the in vivo protective potential of anti-SARS-CoV-2 antibodies. All four cross-neutralizing antibodies neutralize the B.1.351 mutant strain. Thus, our study reveals that epitopes in S2 can serve as blueprints for the design of immunogens capable of eliciting cross-neutralizing coronavirus antibodies.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2025

A fully light-driven approach to separate carbon dioxide from emission streams

Carbon capture from industrial point sources is an essential component of the global effort to mitigate climate risks. However, traditional approaches require significant energy input—often provided, counterproductively, by fossil fuel combustion. Using sunlight directly as the energy source would significantly improve the energy efficiency of carbon capture processes. Herein, we report the first fully visible-light-driven CO 2 separation system, in which carbon capture is achieved via the photoenolization/addition reaction of inexpensive 2-methylbenzophenone with CO 2 , and CO 2 release is realized through an intramolecular photodecarboxylation reaction. Finally, this system operates isothermally, works with natural sunlight, and facilitates CO 2 removal from natural gas flue emissions, providing a blueprint for other non-thermal chemical separations.

Ahmad, Bayu I. Z. [Cornell Univ., Ithaca, NY (Unit↗