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Estimation of Critical Temperature for Surface Ion Currents from Electron Emission Data

A method of calculating a relation for the critical surface temperature for ion current emission is presented. The method is based on the S-shaped electron emission curves for surfaces in the presence of ionizable vapors and upon the assumptions of thermodynamic equilibrium involved in the Saha-Langmuir relation. A comparison of the critical temperatures so calculated with the relation obtained from actual ion emission data on the cesium-tungsten system shows good agreement over a wide current density range. Critical temperatures for cesium ion current densities of 0.21 and 1.9 amperes per square centimeter calculated by this method are presented for surfaces of rhenium, molybdenum, tantalum, and niobium. Tentative relations of the form log j equals A (sub p) plus (B (sub p) over T) are presented for these same systems, where j is the ion current density, A (sub p) and B (sub p) are constants, and T is the temperature.

ELECTRON EMISSION

Experimental and theoretical investigation for the suppression of the plasma arc drop in the thermionic converter

Ion generation and recombination mechanisms in the cesium plasma as they pertain to the advanced mode thermionic energy converter were studied. The decay of highly ionized cesium plasma was studied in the near afterglow to examine the recombination processes. Very low recombination in such a plasma may prove to be of considerable importance in practical converters. The approaches of external cesium generation were vibrationally excited nitrogen as an energy source of ionization of cesium ion, and microwave power as a means of resonant sustenance of the cesium plasma. Experimental data obtained so far show that all three techniques - i.e., the non-LTE high-voltage pulsing, the energy transfer from vibrationally excited diatomic gases, and the external pumping with a microwave resonant cavity - can produce plasmas with their densities significantly higher than the Richardson density. The implication of these findings as related to Lam's theory is discussed.

Shaw, D. T.