Search NASA⌕ Search

SEARCH · Search NASA

Results for “CFCs”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

59 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2022

Faster Tropical Upper Stratospheric Upwelling Drives Changes in Ozone Chemistry

Tropospheric trends in long-lived source gases N2O and the chlorofluorocarbons (CFCs) cause trends in O3 through changes in their reactive product gases. Transport affects the product gases because it controls the distribution of the long-lived source gases. We find that large changes in tropical upwelling 10-5 hPa since 2012 have strengthened the northern branch of the upper stratospheric (UpS) transport circulation, dramatically altering the abundances of N2O and its odd nitrogen product gases, NOx and HNO3. Increased upwelling is connected to stronger and more frequent Quasi-Biennial Oscillation easterly winds at 10 hPa and above. We use simulations with and without time varying MERRA2 meteorology to quantify the impact of dynamical changes on O3 loss via the NOx and ClOx cycles. We find that dynamical impacts on these cycles explain the mid-stratospheric tropical O3 increase and Arctic UpS O3 decrease since 2005.

Middle atmosphere chemistry and composition↗
NASA NTRSDate not supplied

Faster Tropical Upper Stratospheric Upwelling is Driving Changes in Ozone Chemistry

Trends in N2O and the chlorofluorocarbons (CFCs) cause trends in O3 through changes in their reactive product gases, NOx and ClOx, but transport plays an important role because it controls the distribution of the long‐lived source gases that produce ozone‐destroying radicals. In this study we show that increased tropical upwelling 10‐5 hPa from 2013‐2021 has changed upper stratospheric (UpS) composition and shifted the balance of O3 loss processes. We use N2O, HNO3, NOx, temperature and O3 data from the Aura Microwave Limb Sounder (MLS) and the SCI‐Sat Atmospheric Chemistry Experiment Fourier Transport Spectrometer (ACE‐FTS) over a 16‐year period to show how changes in reactive nitrogen species affected gas phase ozone chemistry above 30 hPa between June 2013‐May 2021 compared to the previous 8 years, June 2005‐May 2013. We use 2 simulations of the Global Modeling Initiative (GMI) chemistry transport model (CTM), with and without time varying MERRA2 meteorology, to understand how dynamical changes during this 16‐yr period affected O3 through changes in loss via the NOx and ClOx cycles. We also identify the role that the quasi‐biennial oscillation (QBO) in tropical zonal winds plays in the UpS composition changes. We find large increases in tropical upwelling and poleward transport in the northern branch of the UpS transport circulation since 2013 that dramatically increased the abundance of the N2O and its odd nitrogen product gases, NOx and HNO3. O3 loss by NOx in the Arctic UpS increased due to dynamically driven composition change, explaining the observed weak O3 recovery in that region since 2005. The increased upwelling also drove decreases in tropical NOx, leading to increased tropical O3 from 12‐6 hPa.

middle atmosphere chemistry and composition↗
NASA NTRS2016

Southern Polar Ozone in MERRA-2

MERRA-2 provides a good representation of the year-to-year variations and the long-term changes in total ozone column over Antarctica for the entire data record, beginning in 1980. When MLS data are introduced into MERRA-2 in 2004, agreement with independent data improves compared to earlier years when the SBUV observations were assimilated.

MERRA-2↗
NASA NTRS1996

A Comparison of Measurements from ATMOS and Instruments Aboard the ER-2 Aircraft: Halogenated Gases

We compare the mixing rations of N 2 O, CFC-11, CFC-12, CCI 4 , SF 6 , and HCI in the mid-latitude stratosphere measured by the ATMOS Fourier transform spectrometer with in situ measurements acquired aboard the NASA ER-2 aircraft during November 1994. Good agreement is found between ATMOS and in situ correlations of CFC-11, CFC-12, and SF 6 with N 2 O. ATMOS observations of CCI 4 are approx. 15 percent higher than the ER-2 data, but within the systematic uncertainties.

N2O↗