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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Ester oxidation on an aluminum surface using chemiluminescence

The oxidation characteristics of a pure ester (trimethyolpropane triheptanoate) were studied by using a chemiluminescence technique. Tests were run in a thin film microoxidation apparatus with an aluminum alloy catalyst. Conditions included a pure oxygen atmosphere and a temperature range of 176 to 206 C. Results indicated that oxidation of the ester (containing .001 M diphenylanthracene as an intensifier) was accompanied by emission of light. The maximum intensity of light emission was a function of the amount of ester, the concentration of intensifier, and the test temperature. The induction period, or the time to reach one-half of maximum intensity was inversely proportional to test temperature. Decreases in light emission at the later stages of a test were caused by depletion of the intensifier.

Jones, William R., Jr.↗
NASA NTRS1986

Near-midnight observations of nitric oxide delta- and gamma-band chemiluminescence

Chemiluminescent nightglow emission of the nitric oxide delta and gamma bands was measured from a sounding rocket launched on April 27, 1981, near local midnight. The integrated band emission rates for this near zenith observation above 205 km were less than 10 Rayleighs. The solar zenith angle was 127 deg. The branching ratio from the C2Pi state to the A2Sigma(+) state of NO was determined from comparison of the total emission rate of the delta band system to that of the gamma band system and found to be 0.30 + or - 0.06. The branching ratios within each of the band systems were found to be consistent with previous theoretical and experimental determinations. The vertical atomic nitrogen distribution, derived with the use of a model atmosphere, was found to have a peak density of 2.0 x 10 to the 7th atoms/cu cm at an altitude of 205 km. The analysis of these data indicate the presence of residual NO emission above 270 km at local midnight on the order of 1 Rayleigh of total band emission.

Tennyson, P. D.↗
NASA NTRS1987

A preliminary study of ester oxidation on an aluminum surface using chemiluminescence

The oxidation characteristics of a pure ester (trimethyolpropane triheptanoate) were studied by using a chemiluminescence technique. Tests were run in a thin-film micro-oxidation apparatus with an aluminum alloy catalyst. Conditions included a pure oxygen atmosphere and a temperature range of 176 to 206 C. Results indicated that oxidation of the ester (containing 10 to the minus 3rd power M diphenylanthracene as an intensifier) was accompanied by emission of light. The maximum intensity of light emission (I sub max) was a function of the amount of ester, the concentration of intensifier, and the test temperature. The induction period or the time to reach one-half of maximum intensity (t sub 1/2) was an inverse function of test temperature. Decreases in light emission at the later stages of a test were caused by depletion of the intensifier.

Jones, William R., Jr.↗
NASA NTRS1994

First ozone profiles measured with electrochemical and chemiluminescent sondes, developed in Russia

Results obtained with experimental balloon electrochemical and chemiluminescent ozonesondes are summarized and estimated as quite satisfactory. The average normalization factor for the electrochemical ozonesonde obtained in 1991 at four Soviet balloon routine network stations is 1.069+.073 (in 17 flights). Some ozone profiles obtained in summer 1991 at Volgograd are discussed together with corresponding meteorological data.

Zuyaguintsev, Anatoly M.↗
NASA NTRS1998

Fiber-Optic Chemiluminescent Biosensors for Monitoring Aqueous Alcohols and Other Water Quality Parameters

A "reagentless" chemiluminescent biosensor and method for the determination of hydrogen peroxide, ethanol and D-glucose in water is disclosed. An aqueous stream is basified by passing it through a solid phase base bed. Luminol is then dissolved in the basified effluent at a controlled rate. Oxidation of the luminol is catalyzed by the target chemical to produce emitted light. The intensity of the emitted light is detected as a measure of the target chemical concentration in the aqueous stream. The emitted light can be transmitted by a fiber optic bundle to a remote location from the aqueous stream for a remote reading of the target chemical concentration.

Verostko, Charles E.↗
NASA NTRS1971

Application of a Chemiluminescence Detector for the Measurement of Total Oxides of Nitrogen and Ammonia in the Atmosphere

By means of the thermal conversion of nitrogen dioxide to the nitric oxide, the chemiluminescent nitric oxide monitor, based on the nitric oxide plus ozone reaction, may be used for monitoring nitrogen dioxide plus nitric oxide (NO(x)). Under conditions previously described, ammonia is also converted to nitric oxide and therefore interferes. A metal surface, gold wool or stainless steel, operated at two different temperatures has been used to convert only nitrogen dioxide or nitrogen dioxide plus ammonia. Quantitative conversion of nitrogen dioxide to nitric oxide has been obtained at temperatures as low as 200 C. Conversion of ammonia is effected at temperatures of 300 C or higher. By the addition of a converter the basic nitric oxide monitor may be used for measuring NO(x) or NO(x) plus ammonia. As an alternate mode, for a fixed high temperature, a specific scrubber is described for removing NH3 without affecting NO2 concentrations.

Hodgeson, J. A.↗
NASA NTRS2001

Flame Chemiluminescence Rate Constants for Quantitative Microgravity Combustion Diagnostics

Absolute excited state concentrations of OH(A), CH(A), and C2(d) were determined in three low pressure premixed methane-air flames. Two dimensional images of chemiluminescence from these states were recorded by a filtered CCD camera, processed by Abel inversion, and calibrated against Rayleigh scattering, Using a previously validated 1-D flame model with known chemistry and excited state quenching rate constants, rate constants are extracted for the reactions CH + O2 (goes to) OH(A) + CO and C2H + O (goes to) CH(A) + CO at flame temperatures. Variations of flame emission intensities with stoichiometry agree well with model predictions.

Luque, Jorge↗
NASA NTRSDate not supplied

Characterization of Reactant Refill and Detonation Wave Dynamics in a GOx/Natural-gas RDRE Using Simultaneous High Repetition-Rate OH-PLIF and Chemiluminescence

The potential application of rotating detonation engines (RDEs) in rocket combustors hinges on a fundamental understanding of detonation wave structure and injector characteristics with fuel and oxidizer compositions relevant in rocket systems. Simultaneous 300 kHz-rate broadband OH* chemiluminescence and OH-PLIF imaging is employed in a fully optically accessible Natural Gas-GOx rotating detonation rocket engine (RDRE) to visualize reactant refill dynamics and detonation wave structure. A custom-built KTP-type optical parametric oscillator (OPO) is coupled with a nanosecond high-repetition-rate burst-mode laser to output284 nm light and target excitation of the Q1(9) transition in the OH radical. Significant deflagrative burning is observed throughout the chamber as a consequence of the oxygen-rich environment. Trailing Azimuthal Reflected Shock Combustion (ARSC) system, similar to those in a H2-air RDE are observed, burning unburned reactants in the region immediately following the primary detonation wave. Contact burning, as indicated in this study, does not seem to be a primary loss mechanism. The simultaneous measurement of OH and OH* show that axial locations exist in the refill process where OH radicals are present, and produced due to shear layer induced deflagration, however, these zones do not produce excited state OH*. While a deeper understanding of the underlying physics in RDRE systems requires further investigation, this work highlights a first-of-its-kind visualization of the turbulent combustion product field and reactant refill characteristics in this highly unsteady environment.

Propulsion↗
DOE OSTI2023

Consideration of Non-Ideal Detonation Regimes Influenced by Wave Modes in a Water-Cooled Rotating Detonation Engine Using OH Chemiluminescence

Within this study, the presence and proportion of ideal and non-ideal combustion regimes is compared across a variety of process conditions and wave modes. Large-scale data analysis seeks to summarize proportional heat release associated with commensal, parasitic, and detonative combustion averaged across individual traces of OH* chemiluminescent data acquired at the detonation plane. Means of regime partitioning based on the anatomy of the time-resolved OH* signal are proposed to ensure consistent analysis throughout the current and future studies concerning combustion regimes.

Johnson, Kristyn↗
NASA NTRS1970

Simple chamber facilitates chemiluminescent detection of bacteria

Test chamber enables rapid estimation of bacteria in a test sample through the reaction of luminol and an oxidant with the cytochrome C portion of certain species of bacteria. Intensity of the light emitted in the reaction is a function of the specific bacteria in the test sample.

Marts, E. C.↗
NASA NTRS1974

Chemiluminescent measurement of atmospheric acid

The design and construction of a gas phase acid sensitive analyzer are reported. These studies showed that the chemical system was a practical analytical method. A complete instrument was developed and prepared for field testing. A Titan 3-C rocket was scheduled for launching on February 11, 1974. Through preparations made by NASA Langley the instrument was set up to monitor the acid concentration in the rocket exhaust. Due to adverse wind conditions no acid was detected. This entire trip is described in detail.

Stedman, D. H.↗
NASA NTRS1977

Chemiluminescent reactions of sulfur /3P2/ atoms in cryogenic matrices - S + O2 yields SO2 /a3 B1/

Results are reported for thermoluminescence studies of reactions of sulfur atoms in cryogenically deposited solid argon through in situ photolysis of OCS. Analysis of the thermoluminescence spectrum that resulted from photolysis and heating of matrices in which O2 was codeposited with an OCS/Ar mixture shows that the emitter contained oxygen derived from the added O2 and that little SO2 accumulated during photolysis. The observed absence of thermoluminescence or fluorescence in either of the allowed transitions of excited SO2 is taken as definitive evidence that ground-state sulfur atoms can insert into the oxygen molecule with effectively zero activation energy.

Long, S. R.↗
NASA NTRS1981

Chemiluminescence of nitric oxide

Measurements of the intensities of the delta and gamma bands of nitric oxide in the nighttime terrestrial thermosphere are presented and used to infer the rate coefficient for the transition from the C 2 Pi to the A 2 Sigma + states. The nightglow spectrum was observed between 1900 and 2300 A at a resolution of 15 A by a rocket-borne scanning 1/4-m spectrometer pointing north at an apogee of 150 km. Progressions of the delta, gamma and epsilon bands are identified on the spectra by the construction of synthetic spectra, and the contributions of resonance fluorescence to the total band intensities are calculated. Finally, the ratio of the sum of the gamma bands for v-prime = 0 to the sum of the delta bands for v-prime = 0 is used to derive a branching ratio of 0.21 + or - 0.04 to the A 2 Sigma + state, which yields a probability for the C-A transition of 5.6 + or - 1.5 x to the 6th/sec.

Sharp, W. E.↗