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NASA NTRS1991

Chemical studies of H chondrites. III - Regolith evolution of the Fayetteville chondrite parent

Radiochemical neutron concentration analysis was used to determine Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Sb, Se, Te, Tl, and Zn contents in consortium samples of solar gas and track-rich dark matrix. Data obtained confirmed that the matrix is chemically homogeneous. Most dark clasts had similar mean trace element concentrations as the matrix but were compositionally much more heterogeneous. It is concluded that material incorporated with soil and compacted to form the dark portion of Fayetteville included soil-melt, the odd C2M fragment, and dark and light clasts which escaped comminution.

Xiao, Xiaoyue↗
NASA NTRS1993

Noble gases in twenty Yamato H-chondrites: Comparison with Allan Hills chondrites and modern falls

Concentration and isotopic composition of noble gases have been measured in 20 H-chrondrites found on the Yamato Mountains ice fields in Antarctica. The distribution of exposure ages as well as of radiogenic He-4 contents is similar to that of H-chrondrites collected at the Allan Hills site. Furthermore, a comparison of the noble gas record of Antarctic H-chrondrites and finds or falls from non-Antarctic areas gives no support to the suggestion that Antarctic H-chrondrites and modern falls derive from differing interplanetary meteorite populations.

Loeken, TH.↗
NASA NTRSDate not supplied

Anomalous and Ungrouped Carbonaceous Chondrites in the US Antarctic Meteorite Collection and their Potential Relevance to Ryugu and Bennu

With two different carbonaceous asteroid sample return missions in full swing, attention has focused on what connections can be made between the asteroid samples and the wide range of carbonaceous chondrite meteorites in worldwide collections. The US Antarctic meteorite collection contains nearly 1000 carbonaceous chondrites of various types including many in well-established groups as well as ungrouped, unusual or anomalous groups [1]. Some of the latter have been included in, or are possibly related to, recently proposed new carbonaceous chondrite classifications – CA and CY chondrites [2,3]. In addition to these, there are numerous ungrouped samples that have properties intermediate between established groups (like CM and CO; [4]), distinct from any other groups [5], or have anomalous properties that might be attributable to parent body processes such as heating, fluid interaction, or impacts [6]. Some CM anomalous or ungrouped chondrites share spectral features with Ryugu, which has a small hydration peak arguably due to hydrated minerals left after either impact heating or shock in carbonaceous chondrites [7]. PCA 91008, PCA 02012, GRO 95566, and LEW 85311 are all CMs that have experienced heating or metamorphism that may be due to impacts, solar radiation, or radiogenic decay [6]. These samples all have low H contents, C/H (bulk), and low 17O [6,8] and may hold clues to understanding the mineralogy of Ryugu, or interpretations of its spectral properties. WIS 91600, on the other hand, appears to be related to several other highly altered CM [6], and shares properties with the newly proposed CY chondrites [6]. An understanding of this grouplet will also aid in the interpretation of Bennu samples which have strong hydration features. In addition, ungrouped carbonaceous chondrites may provide valuable insights into the aqueous alteration potentially recorded in Bennu and Ryugu samples; such as the relatively moderate aqueous alteration recognized and dated at 4-5 myr after CAIs in MAC 88107 (C2-ungrouped) by [9] to the extensive aqueous alteration apparent in MIL 090292 (C1-ungrouped) [10]. Finally, LON 94101/94102 is a brecciated CM chondrite with numerous lithologies. Its appearance is similar to some of the brecciated lithologies visible at the surface of Bennu and Ryugu [11]. Although CM chondrites with multiple lithologies are common (e.g., [12]), the lithologies are often difficult to resolve at the hand specimen scale and only after some detailed e-beam characterization are the subtle lithologic differences evident (e.g., [13]). LON 94102 contains visibly distinct clasts at the hand specimen scale, relatively rare for CM breccias. The largest CM chondrites by mass from the U.S. Antarctic meteorite collection may provide insights into the extent of brecciation and heterogeneity within more typical CM chondrite-like source asteroids. For example, recent curation CT scans [14] show possible clasts within in a subsplit of ALH 83100 (CM1/2) which is the largest CM chondrite or CM chondrite pairing group in the U.S. Antarctic collection with an original mass of 3.019 kg. Similar work on additional subsplits or meteorites may aid our understanding of heterogeneity within CM chondrites from Antarctica. Initial classification of CM chondrites in U.S. Antarctic meteorite collection includes preliminary pairing when petrographically similar CM chondrites that have been previously found in the same field area. The two largest CM chondrite preliminary pairing groups by mass are the ALH 83102 (CM2) pairing group with an original mass of 2.554 kg and the EET 96005 (CM2) pairing group with an original mass of 1.125 kg. However, preliminary pairing groups assigned at classification—intrinsically— do not include stones that are petrographically distinct. Rigorous pairing group studies of CM chondrites from specific field sites are needed to investigate if there is unrecognized heterogeneity in CM chondrites from Antarctica that may represent common asteroid impactors (pre-atmospheric entry asteroids/meteoroids). Detailed pairing studies have the potential to recognize initial stones with multiple lithologies and investigate if there are stones that only sample one of those respective lithologies in the collection. These groups of heated CMs, extensively hydrated CMs, intermediate between CM and CO chondrites, and brecciated samples are all potentially relevant to Bennu and Ryugu samples, where heating, hydration, and brecciation have all come into play. These bodies might also be comprised of material intermediate to CM and CO chondrites, or at least distinct from the well-established CC groups. These small and unusual groups of carbonaceous chondrites may help to unlock new information about early solar system processes and aid in the understanding of the evolution of these carbonaceous asteroids.

meteorites↗
NASA NTRS2020

Sierra Gorda 009: A New Member of the Metal-Rich G Chondrites Grouplet

We investigated the metal-rich chondrite Sierra Gorda (SG) 009, a member of the new G chondrite grouplet (also including NWA 5492, GRO 95551). G chondrites contain 23% metal, very reduced silicates, and rare oxidized mineral phases (Mg-chromite, FeO-rich pyroxene). G chondrites are not related to CH-CB chondrites, based on bulk O, C and N isotopic compositions, mineralogy and geochemistry. G chondrites have no fine-grained matrix or matrix lumps enclosing hydrated material typical for CH-CB chondrites. G chondrites’ average metal compositions are similar to H chondrites. Siderophile and lithophile geochemistry indicate sulfidization and fractionation of the SG 009 metal and silicates, unlike NWA 5492 and GRO 05551. The G chondrites have average O isotopic compositions DELTA 17O >0 ‰ ranging between bulk enstatite (E) and ordinary (O) chondrites. An Al-rich chondrule from SG 009 has DELTA 17O <0 ‰ indicating some heterogeneity in oxygen isotopic composition of G chondrite components. SG 009’s bulk carbon and nitrogen isotopic compositions correspond to E and O chondrites. Neon isotopic composition reflects a mixture of cosmogenic and solar components, and cosmic ray exposure age of SG 009 is typical for O, E, and R chondrites. G chondrites are closely related to O, E, and R chondrites and may represent a unique metal-rich parent asteroid containing primitive and fractionated material from the inner Solar System. Oxidizing and reducing conditions during SG 009 formation may be connected with a chemical micro-environment and possibly could indicate that G chondrites may have formed by a planetesimal collision resulting in the lack of matrix.

chondrite↗
NASA NTRS1995

The classification and complex thermal history of the enstatite chondrites

We have carried out instrumental neutron activation analysis of 11 enstatite chondrites and electron microprobe analyses of 17 enstatite chondrites, most of which were previously little described. We report here the third known EH5 chondrite (LEW 88180) and an unusual EL6 chondrite (LEW 87119), new data on four EL3 chondrites (ALH 85119, EET 90299, PCA 91020, and MAC 88136, which is paired with MAC 88180 and MAC 88184), the second EL5 chondrite (TIL 91714), and an unusual metal-rich and sulfide-poor EL3 chondrite (LEW 87223). The often discussed differences in mineral composition displayed by the EH and EL chondrites are not as marked after the inclusion of the new samples in the database, and the two classes apparently experienced a similar range of equilibrium temperatures. However, texturally the EL chondrites appear to have experienced much higher levels of metamorphic alteration than EH chondrites of similar equilibration temperatures. Most of the petrologic type criteria are not applicable to enstatite chondrites and, unlike the ordinary chondrites, texture and mineralogy reflect different aspects of the meteorite history. We therefore propose that the existing petrologic type scheme not be used for enstatite chondrites. We suggest that while 'textural type' reflects peak metamorphic temperatures, the 'mineralogical type' reflects equilibration during postmetamorphic (probably regolith) processes. Unlike the ordinary chondrites and EH chondrites, EL chondrites experienced an extensive low-temperature metamorphic episode. There are now a large number of enstatite meteorite breccias and impact melts, and apparently surface processes were important in determining the present nature of the enstatite chondrites.

Zhang, Yanhong↗
NASA NTRS2019

3-μm Reflectance Spectroscopy of Carbonaceous Chondrites Under Asteroid-Like Conditions

We measured 3-μm reflectance spectra of 21 meteorites that represent all carbonaceous chondrite types available in terrestrial meteorite collections. The measurements were conducted at the Laboratory for Spectroscopy under Planetary Environmental Conditions (LabSPEC) at the Johns Hopkins University Applied Physics Laboratory (JHU APL) under asteroid-like conditions (vacuum at room temperature after slight overnight heating at T < 400 K). This is the most comprehensive 3-μm dataset of carbonaceous chondrites ever acquired in environments similar to the ones experienced by asteroids. The 3-μm reflectance spectra are extremely important for direct comparisons with and appropriate interpretations of reflectance data from ground-based telescopic and spacecraft observations of asteroids. We found good agreement between 3-μm spectral characteristics of carbonaceous chondrites and carbonaceous chondrite classifications. The 3-μm band is diverse, indicative of varying composition, thus suggesting that these carbonaceous chondrites experienced distinct parent body aqueous alteration and metamorphism environments. The spectra of CI chondrites, from which significant amount of water adsorbed under ambient conditions was removed, are consistent with Mg-serpentine and clay minerals. The high abundances of organics in CI chondrites is also associated with the mineralogy of these chondrites, oxyhydroxides- and complex clay minerals-rich. CM chondrites, which are cronstedtite-rich, have shallower 3-μm band than CI chondrites, suggesting they experienced less aqueous alteration. CR chondrites showed moderate aqueous alteration relative to CI and CM chondrites. CV chondrites, except for Efremovka, have a very shallow 3-μm band, consistent with their lower phyllosilicate proportions. CO chondrites, like most CVs, have a very shallow 3-μm spectra that suggest they experienced minor aqueous alteration. The 3-μm band in CH/CBb is deep and broad centered ~ 3.11 μm, possibly due the high abundance of FeNi metal and presence of heavily hydrated clasts in these chondrites. The 3-μm spectra of Essebi (C2-ung) and EET 83226 are more consistent with CM chondrites’ spectra. The 3-μm spectra of Tagish lake (C2-ung), on the other hand, are consistent with CI chondrites. None of these spectral details could have been resolved without removing the adsorbed water before acquiring spectra.

Driss Takir↗
NASA NTRS1996

Pyroxene structures, cathodoluminescence and the thermal history of the enstatite chondrites

In order to explore the thermal history of enstatite chondrites, we examined the cathodoluminescence (CL) and thermoluminescence (TL) properties of 15 EH chondrites and 21 EL chondrites, including all available petrographic types, both textural types 3-6 and mineralogical types alpha-delta. The CL properties of EL3(alpha) and EH3(alpha) chondrites are similar. Enstatite grains high in Mn and other transition metals display red CL, while enstatite with low concentrations of these elements show blue CL. A few enstatite grains with greater than 5 wt% FeO display no CL. In contrast, the luminescent properties of the metamorphosed EH chondrites are very different from those of metamorphosed EL chondrites. While the enstatites in metamorphosed EH chondrites display predominantly blue CL, the enstatites in metamorphosed EL chondrites display a distinctive magenta CL with blue and red peaks of approximately equal intensity in their spectra. The TL sensitivities of the enstatite chondrites correlate with the intensity of the blue CL and, unlike other meteorite classes, are not simply related to metamorphism. The different luminescent properties of metamorphosed EH and EL chondrites cannot readily be attributed to compositional differences. But x-ray diffraction data suggests that the enstatite in EH5(gamma),(delta) chondrites is predominantly disordered orthopyroxene, while enstatite in EL6(beta) chondrites is predominantly ordered orthopyroxene. The difference in thermal history of metamorphosed EL and EH chondrites is so marked that the use of single 'petrographic' types is misleading, and separate textural and mineralogical types are preferable. Our data confirm earlier suggestions that metamorphosed EH chondrites underwent relatively rapid cooling, and the metamorphosed EL chondrites cooled more slowly and experienced prolonged heating in the orthopyroxene field.

Zhang, Yanhong↗
NASA NTRS1994

Carbonates in the Kaidun chondrite

Kaidun is a remarkable chondrite breccia fall containing lithic clasts that span a wide range of chondrite groups including C and E chondrites, as well as having clasts with characteristics not yet found in existing chondrite samples. The dominant lithology in Kaidun appears to be CR chondritic, consonant with recent O isotope data. The carbonates in Kaidun are presented as one mineralogical basis for comparing it to the other hydrated chondrites and to better understand its relative alteration history. The four polished thin sections of Kaidun studied contained a variety of lithologies that we classified into four groups -- CR, E, CM-like, and dark inclusions (DIs). DIs contain sulfide and magnetite morphologies that superficially resemble CI chondrites, and some of the previously reported CI lithologies in Kaidun may be what we term DIs. Carbonates were found in all lithologies studied. Carbonates in Kaidun are similar in composition to those in CR chondrites. Some of the DIs in Kaidun, previously characterized as CI, have carbonates similar to those in CR chondrites and are unlike those in CI or CM chondrites. Most carbonates in Kaidun and CR chondrites are calcites, some of which formed at temperatures above 250 C. Dolomite is less common and some may be metastable. Alteration temperatures in the Renazzo CR chondrite were estimated to be approximately 300 C, based on O isotope fractionation between phyllosilicates and magnetite. Temperatures of up to 450 C were proposed for the alteration of a CR-like dark inclusion in Kaidun, based on the presence of hydrothermal pentlandite veins. The alteration temperatures for Kaidun and the other CR chondrites are considerably higher than those suggested for CI or CM parent bodies.

Weisberg, M. K.↗
NASA NTRS1999

Thermally Mobile Trace Elements in Carbonaceous Chondrites from Cold and Hot Deserts

Some decades ago, Anders and co-workers used RNAA to classify a number of trace elements as being volatile during nebular condensation and accretion into primitive objects based upon their strong depletion in (equilibrated) ordinary chondrites relative to C1 chondrites. Such elements, e.g. Ag, Bi, Cd, Cs, In, Se, Te, Tl, Zn and others, exhibit nearly constant, C1-normalized atomic abundances in C2 (CM2) and in C3 chondrites. They interpreted the near-constancy of these abundances according to a 2-component model in which volatiles were introduced into carbonaceous (and other) chondrites as Cl material which was diluted with differing proportions of high-temperature (i.e. volatile-free) components. In this view, mean volatile element abundances of 0.48 in C2 and 0.24-0.29 x C1 in C3 chondrites indicated that C2 and C3 chondrites are, respectively, about 1:1 and 1:2-3 mixtures of Cl-like and high temperature materials. More recently, C1 normalized abundances of such volatile elements are nearly constant in most C2-6 chondrites (i.e. 25 non-Antarctic meteorites, nearly all falls, and 36 Antarctic finds) consistent with a 2- component mixing model. However, rather than being quantized, mean volatile element contents in each chondrite define a continuum from 0.92-0.14 x Cl for these 61 chondrites. A few carbonaceous chondrites - the first having been the NIPR consortium samples B-7904, Y-82162 and Y-86720 - show an altered pattern: many of the volatile elements in each exhibit the usual constancy of C1-normalized atomic abundances, but modified by further depletion of Cd and other elements like Tl and Bi. These are the most mobile trace elements, i.e. those most readily vaporized and lost from primitive meteorites during week-long heating at greater than or equal to 400 C under low ambient pressures (initially 10 (exp -5) atm H2), simulating metamorphic conditions in a primitive parent body. Similarities between mobile element data for B-7904, Y-82162 and Y-86720 with those for Murchison heated at 500-700 C suggest that these Antarctic C1 and C2-like chondrites were metamorphosed at temperatures like these in the interiors of their parent bodies. Metamorphic temperatures inferred from RNAA data and textural/mineralogic alterations are internally consistent, agreeing with those evident in heated Murchison samples. These 3 chondrites were also heated late in their histories since all have lost cosmogenic 3-He, presumably during close solar approach, and B-7904 and Y-86720 seem also to have lost substantial proportions of radiogenic He-4 and Ar-40, cf. data. Similarities in spectral reflectance data for C-, G-, B- and F- asteroids, for these meteorites and for heated Murchison samples suggest that thermally metamorphosed interior materials in these asteroids were excavated by impacts and re-deposited on them, forming their present surfaces. Establishment of the thermal metamorphic histories of carbonaceouis chondrites, then, is essential to establishing the evolution and present-day nature of C-type and related asteroids.

Lipschutz, M. E.↗
NASA NTRS2000

Thermally Mobile Trace Elements in Carbonaceous Chondrites From Cold and Hot Deserts

Some decades ago, Anders and co-workers used RNAA to classify a number of trace elements as being volatile during nebular condensation and accretion into primitive objects based upon their strong depletion in (equilibrated) ordinary chondrites relative to C1 chondrites. Such elements, e.g. Ag, Bi, Cd, Cs, In, Se, Te, Tl, Zn and others, exhibit nearly constant, C1-normalized atomic abundances in C2 (CM2) and in C3 chondrites. They interpreted the near-constancy of these abundances according to a 2-component model in which volatiles were introduced into carbonaceous (and other) chondrites as C1 material which was diluted with differing proportions of high-temperature (i.e. volatile-free) components. In this view, mean volatile element abundances of 0.48 in C2 and 0.24-0.29 x C1 in C3 chondrites indicated that C2 and C3 chondrites are, respectively, about 1:1 and 1:2-3 mixtures of C1-like and high temperature materials. More recently, Xiao and Lipschutz found that C-normalized abundances of such volatile elements are nearly constant in most C2-6 chondrites (i.e. 25 non-Antarctic meteorites, nearly all falls, and 36 Antarctic finds) consistent with a 2-component mixing model. However, rather than being quantized, mean volatile element contents in each chondrite define a continuum from 0.92-0.14 x C1 for these 61 chondrites. A few carbonaceous chondrites, the first having been the NIPR consortium samples B-7904, Y-82162 and Y-86720, show an altered pattern: many of the volatile elements in each exhibit the usual constancy of C1-normalized atomic abundances, but modified by further depletion of Cd and other elements like Tl and Bi. These are the most mobile trace elements, i.e. those most readily vaporized and lost from primitive meteorites during week-long heating at greater than or equal to 400 C under low ambient pressures (initially 10(exp -5) atm H2), simulating metamorphic conditions in a primitive parent body. Similarities between mobile element data for B-7904, Y-82162 and Y-86720 with those for Murchison heated at 500-700 C, suggest that these Antarctic C1 - and C2-like chondrites were metamorphosed at temperatures like these in the interiors of their parent bodies. Metamorphic temperatures inferred from RNAA data and textural/mineralogic alterations are internally consistent, agreeing., with those evident in heated Murchison samples. These 3 chondrites were also heated late in their histories since all have lost cosmogenic He-3, presumably during close solar approach, and B-7904 and Y-86720 seem also to have lost substantial proportions of radiogenic He-4 and Ar-40 cf. data in. Similarities in spectral reflectance data for C-, G-, B- and F- asteroids, for these meteorites and for heated Murchison samples suggest that thermally metamorphosed interior materials in these asteroids were excavated by impacts and re-deposited on them, forming their present surfaces. Establishment of the thermal metamorphic histories of carbonaceous chondrites, then, is essential to establishing the evolution and present-day nature of C-type and related asteroids.

Lipschutz, M. E.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Carbonaceous Chondrites

The titles in this section include: 1) A Quantitative NMR Analysis of Phosphorus in Carbonaceous and Ordinary Chondrites; 2) An Infrared Study of the Matrices of CI1 and CM2 Chondrites; 3) A Study of the Morphology, Composition and Mineral Associations of Fe-Ni Sulphides in CM Carbonaceous Chondrites; 4) Aqueous Alteration Mineralogy in CM Carbonaceous Chondrites; 5) In Situ Location and Characterization of Carbon-bearing Phases in Carbonaceous; 6) Chondrites: Insights from Yamato 791198, a Weakly-altered CM2 Chondrite; 7) Unique Texture in EET 83389: Clues to Formation of Fine Grained Rims in CM Chondrites; 8) Amoeboid Olivine Aggregates in the NWA 760 CV3 Chondrite; 9) Petrologic Type of CV3 Chondrites as Revealed by Raman Spectroscopy of Organic Matter; 10) A First Look at Acfer 324: Evidence for Another CR 3 Chondrite? 11) Hydrogen Isotopic Composition of the Bencubbin Meteorite; 12) The Fountain Hills Meteorite: A New CBa Chondrite from Arizona; 13) Shock Effects in the Metal-rich Chondrites QUE 94411, Hammadah al Hamra 237 and Bencubbin; 14) Mineralogy and Petrology of Al-rich Objects in the CH Carbonaceous Chondrite North West Africa 739.

Source record↗