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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Investigating Drivers of Particulate Matter Pollution Over India and the Implications for Radiative Forcing With GEOS-Chem-TOMAS15

Ambient fine particulate matter (PM 2.5 ) concentrations in India frequently exceed 100 μg/m 3 during fall and winter pollution episodes. We use the GEOS-Chem chemical transport model with the TwO-Moment Aerosol Sectional microphysics scheme with 15 size bins (TOMAS15) to assess PM 2.5 composition and impacts on radiation and cloud condensation nuclei (CCN) during pollution episodes as compared to the seasonal (October-December) average. We conduct high resolution (0.25° × 0.3125°) nested-domain simulations over India for short-duration, high-PM2.5 episodes in the fall of 2015 and 2017. The simulations capture the magnitude and spatial patterns of pollution episodes measured by surface monitors (r PM2.5 = 0.69) although aerosol optical depth is underestimated. During the episodes, near-surface organic matter (OM), black carbon (BC), and secondary inorganic aerosol concentrations increase from seasonal averages by up to 36, 7, and 7 μg/m 3 , respectively. Episodic aerosol increases enhance cooling by lowering the top-of-atmosphere clear-sky direct radiative effect (DRE TOA ) during the 2015 episode (−6 W/m 2 ), with a smaller impact during the 2017 episode (−1 W/m 2 ). Differences in DRE TOA reflect larger increases in scattering aerosols in the column during the 2015 episode (+17 mg/m 2 ) than in 2017 (+13 mg/m 2 ), while absorbing aerosol column enhancements are smaller (+3 mg/m2) in both years. Changes in shortwave radiation at the surface (SW sfc ) are spatially similar to DRE TOA and mostly negative during both episodes. CCN enhancements (0.2% supersaturation) during these episodes occur across the western Indo-Gangetic Plain, coincident with higher PM 2.5 concentrations. Changes in DRE TOA , SW sfc , and CCN during high-PM 2.5 episodes may have implications for crops, the hydrologic cycle, and surface temperature.

PM2.5↗

Deepak Condenser Model (DeCoM)

Development of the DeCoM comes from the requirement of analyzing the performance of a condenser. A component of a loop heat pipe (LHP), the condenser, is interfaced with the radiator in order to reject heat. DeCoM simulates the condenser, with certain input parameters. Systems Improved Numerical Differencing Analyzer (SINDA), a thermal analysis software, calculates the adjoining component temperatures, based on the DeCoM parameters and interface temperatures to the radiator. Application of DeCoM is (at the time of this reporting) restricted to small-scale analysis, without the need for in-depth LHP component integrations. To efficiently develop a model to simulate the LHP condenser, DeCoM was developed to meet this purpose with least complexity. DeCoM is a single-condenser, single-pass simulator for analyzing its behavior. The analysis is done based on the interactions between condenser fluid, the wall, and the interface between the wall and the radiator. DeCoM is based on conservation of energy, two-phase equations, and flow equations. For two-phase, the Lockhart- Martinelli correlation has been used in order to calculate the convection value between fluid and wall. Software such as SINDA (for thermal analysis analysis) and Thermal Desktop (for modeling) are required. DeCoM also includes the ability to implement a condenser into a thermal model with the capability of understanding the code process and being edited to user-specific needs. DeCoM requires no license, and is an open-source code. Advantages to DeCoM include time dependency, reliability, and the ability for the user to view the code process and edit to their needs.

Patel, Deepak↗

Cloud/climate sensitivity experiments

A study of the relationships between large-scale cloud fields and large scale circulation patterns is presented. The basic tool is a multi-level numerical model comprising conservation equations for temperature, water vapor and cloud water and appropriate parameterizations for evaporation, condensation, precipitation and radiative feedbacks. Incorporating an equation for cloud water in a large-scale model is somewhat novel and allows the formation and advection of clouds to be treated explicitly. The model is run on a two-dimensional, vertical-horizontal grid with constant winds. It is shown that cloud cover increases with decreased eddy vertical velocity, decreased horizontal advection, decreased atmospheric temperature, increased surface temperature, and decreased precipitation efficiency. The cloud field is found to be well correlated with the relative humidity field except at the highest levels. When radiative feedbacks are incorporated and the temperature increased by increasing CO2 content, cloud amounts decrease at upper-levels or equivalently cloud top height falls. This reduces the temperature response, especially at upper levels, compared with an experiment in which cloud cover is fixed.

Roads, J. O.↗

Photochemistry of Saturn's Atmosphere: Hydrocarbon Chemistry and Comparisons with ISO Observations - 1

To investigate the details of hydrocarbon photochemistry on Saturn, we have developed a one-dimensional diurnally averaged model that couples hydrocarbon and oxygen photochemistry, molecular and eddy diffusion, radiative transfer, and condensation. The model results are compared with observations from the Infrared Space Observatory (ISO) to place tighter constraints on molecular abundances, to better define Saturn's eddy diffusion coefficient profile, and to identify important chemical schemes that control the abundances of the observable hydrocarbons in Saturn's upper atmosphere. From the ISO observations, we determine that the column 12 densities of CH3, CH3C2H, and C4H2 above 10 mbar are 4 (sup +2) (sub -1.5) x 10 (exp 13) cm (sup -2), (1.1 plus or minus 0.3) x 10 (exp 15) cm (exp -2), and (1.2 plus or minus 0.3) x 10 (exp 14) cm (sup -2), respectively. The observed ISO emission features also indicate C2H2 mixing ratios of 1.2 (sup +0.9) (sub -0.6) x 10 (exp -6) at 0.3 mbar and (2.7 plus or minus 0.8) x 10 (exp -7) at 1.4 mbar, and a C2H6 mixing ratio of (9 plus or minus 2.5) x 10 (exp -6) at 0.5 mbar. Upper limits are provided for C2H4, CH2CCH2, C3H8, and C6H2 sensitivity of the model results to variations in the eddy diffusion coefficient profile, the solar flux, the CH4 photolysis branching ratios, the atomic hydrogen influx, and key reaction rates are discussed in detail. We find that C4H2 and CH3C2H are particularly good tracers of important chemical processes and physical conditions in Saturn's upper atmosphere, and C2H6 is a good tracer of the eddy diffusion coefficient in Saturn's lower stratosphere. The eddy diffusion coefficient must be smaller than approximately 3 x 10 (exp 4) sq cm s (sup -1) at pressures greater than 1 mbar in order to reproduce the C2H6 abundance inferred from ISO observations. The eddy diffusion coefficients in the upper stratosphere could be constrained by observations of CH3 radicals if the low-temperature chemistry of CH3 were better understood. We also discuss the implications of our modeling for aerosol formation in Saturn's lower stratosphere-diacetylene, butane, and water condense between approximately 1 and 300 mbar in our model and will dominate stratospheric haze formation at nonauroral latitudes. Our photochemical models will be useful for planning observational sequences and for analyzing data from the upcoming Cassini mission.

Moses, Julianne I.↗

Radio Heating of Lunar Soil to Release Gases

A report proposes the development of a system to collect volatile elements and compounds from Lunar soil for use in supporting habitation and processing into rocket fuel. Prior exploratory missions revealed that H2, He, and N2 are present in Lunar soil and there are some indications that water ice may also be present. The proposed system would include a shroud that would be placed on the Lunar surface. Inside the shroud would be a radio antenna aimed downward. The antenna would be excited at a suitably high power and at a frequency chosen to optimize the depth of penetration of radio waves into the soil. The radio waves would heat the soil, thereby releasing volatiles bound to soil particles. The escaping volatiles would be retained by the shroud and collected by condensation in a radiatively cooled vessel connected to the shroud. It has been estimated that through radio-frequency heating at a power of 10 kW for one day, it should be possible to increase the temperature of a soil volume of about 1 cubic m by about 200 C -- an amount that should suffice for harvesting a significant quantity of volatile material.

Chui, Talso↗

CVB: the Constrained Vapor Bubble Capillary Experiment on the International Space Station MARANGONI FLOW REGION

The Constrained Vapor Bubble (CVB) is a wickless, grooved heat pipe and we report on a full- scale fluids experiment flown on the International Space Station (ISS). The CVB system consists of a relatively simple setup a quartz cuvette with sharp corners partially filled with either pentane or an ideal mixture of pentane and isohexane as the working fluids. Along with temperature and pressure measurements, the two-dimensional thickness profile of the menisci formed at the corners of the quartz cuvette was determined using the Light Microscopy Module (LMM). Even with the large, millimeter dimensions of the CVB, interfacial forces dominate in these exceedingly small Bond Number systems. The experiments were carried out at various power inputs. Although conceptually simple, the transport processes were found to be very complex with many different regions. At the heated end of the CVB, due to a high temperature gradient, we observed Marangoni flow at some power inputs. This region from the heated end to the central drop region is defined as a Marangoni dominated region. We present a simple analysis based on interfacial phenomena using only measurements from the ISS experiments that lead to a predictive equation for the thickness of the film near the heated end of the CVB. The average pressure gradient for flow in the film is assumed due to the measured capillary pressure at the two ends of the liquid film and that the pressure stress gradient due to cohesion self adjusts to a constant value over a distance L. The boundary conditions are the no slip condition at the wall interface and an interfacial shear stress at the liquid- vapor interface due to the Marangoni stress, which is due to the high temperature gradient. Although the heated end is extremely complex, since it includes three- dimensional variations in radiation, conduction, evaporation, condensation, fluid flow and interfacial forces, we find that using the above simplifying assumptions, a simple successful model can be developed.

heat pipes↗

Titanium-Water Thermosyphon Gamma Radiation Effects and Results

Titanium-water thermosyphons are being considered for use in heat rejection systems for fission power systems. Their proximity to the nuclear reactor will result in some exposure to gamma irradiation. Non-condensable gas formation from radiation may breakdown water over time and render a portion of the thermosyphon condenser inoperable. A series of developmental thermosyphons were operated at nominal operating temperature with accelerated gamma irradiation exposures on the same order of magnitude that is expected in eight years of heat rejection system operation. Temperature data were obtained during exposure at three locations on each thermosyphon; evaporator, condenser, and condenser end cap. Some non-condensable gas was evident, however thermosyphon performance was not affected because the non-condensable gas was compressed into the fill tube region at the top of the thermosyphon, away from the heat rejecting fin. The trend appeared to be an increasing amount of non-condensable gas formation with increasing gamma irradiation dose. Hydrogen is thought to be the most likely candidate for the non-condensable gas and hydrogen is known to diffuse through grain boundaries. Post-exposure evaluation of selected thermosyphons at temperature and in a vacuum chamber revealed that the non-condensable gas likely diffused out of the thermosyphons over a relatively short period of time. Further research shows a number of experimental and theoretical examples of radiolysis occurring through gamma radiation alone in pure water.

Sanzi, James L.↗

Global Airborne Sampling Reveals a Previously Unobserved Dimethyl Sulfide Oxidation Mechanism in the Marine Atmosphere

Dimethyl sulfide (DMS), emitted from the oceans, is the most abundant biological source of sulfur to the marine atmosphere. Atmospheric DMS is oxidized to condensable products that form secondary aerosols that affect Earth’s radiative balance by scattering solar radiation and serving as cloud condensation nuclei. We report the atmospheric discovery of a previously unquantified DMS oxidation product, hydroperoxymethyl thioformate (HPMTF, HOOCH2SCHO), identified through global-scale airborne observations that demonstrate it to be a major reservoir of marine sulfur. Observationally constrained model results show that more than 30% of oceanic DMS emitted to the atmosphere forms HPMTF. Coincident particle measurements suggest a strong link between HPMTF concentration and new particle formation and growth. Analyses of these observations show that HPMTF chemistry must be included in atmospheric models to improve representation of key linkages between the biogeochemistry of the ocean, marine aerosol formation and growth, and their combined effects on climate.

DMS gas-phase oxidation product↗

Photoabsorption and photodissociation of molecules important in the interstellar medium

Photoabsorption and fluorescence cross sections of molecules important in the interstellar medium were measured in the 90 to 200 nm region using synchrotron radiation, excimer laser, and condensed discharge lamps as light sources. The quantitative spectroscopic data are currently needed for the modeling of formation and destruction rates of molecules by the interstellar radiation field. Fluorescences from excited photofragments produced by vacuum ultraviolet radiation of molecules are dispersed to identify the emitting species. The fluorescence data are useful for the identification of emission sources in interstellar clouds.

Lee, Long C.↗

Ideal condensations due to perpendicular thermal conduction in a sheared magnetic field

Cool condensations generated by a radiative thermal instability in a sheared magnetic field have previously been the bases of solar filament formation models. Through the assumption of fully anisotropic heat flow, a new set of condensation modes are here obtained which become singular in the limit of vanishing perpendicular thermal conductivity. The growth rates are noted to typically be greater than those reported previously for sheared field condensations. The fastest growth is exhibited by modes possessing the fewest oscillations.

Van Hoven, G.↗

A dynamic solar-electric power/thermal control system for spacecraft.

This paper describes a solar-electric power and active thermal control system for spacecraft with solar energy to electricity conversion efficiency of more than 20%. Briefly, the solar heat energy is absorbed by flat plate collectors yielding above 70% of the energy incident for conversion by an organic condensing cycle. The cycle operates between 132 and 6.67 deg C. The working fluid is F-114 which flows through a solar collector to absorb heat, then through a regenerator and into the radiator where it is condensed to a liquid. The cold liquid flows through two paths, one providing regenerator cooling, the other providing spacecraft thermal control. The system total weight is about 170kg/kW of electrical energy produced. The dynamic system replaces batteries by a thermal capacitor for eclipse period energy storage, thereby eliminating many battery charging and control problems as well as improving efficiency and weight characteristics of the system.

Davis, B. K.↗

A numerical simulation of magnetic reconnection and radiative cooling in line-tied current sheets

Radiative MHD equations are used for an optically thin plasma to carry out a numerical experiment related to the formation of 'postflare' loops. The numerical experiment starts with a current sheet that is in mechanical and thermal equilibrium but is unstable to both tearing-mode and thermal-condensation instabilities. The current sheet is line-tied at one end to a photospheric-like boundary and evolves asymmetrically. The effects of thermal conduction, resistivity variation, and gravity are ignored. In general, reconnection in the nonlinear stage of the tearing-mode instability can strongly affect the onset of condensations unless the radiative-cooling time scale is much smaller than the tearing-mode time scale. When the ambient plasma is less than 0.2, the reconnection enters a regime where the outflow from the reconnection region is supermagnetosonic with respect to the fast-mode wave speed. In the supermagnetosonic regime the most rapidly condensing regions occur downstream of a fast-mode shock that forms where the outflow impinges on closed loops attached to the photospheric-like boundary. A similar shock-induced condensation might occur during the formation of 'postflare' loops.

Forbes, T. G.↗

Space shuttle orbiter mechanical refrigeration system

A radiator/condenser was designed which is efficient in both condensation (refrigeration) and liquid phase (radiator) operating modes, including switchover from the refrigeration mode to the radiator mode and vice versa. A method for predicting the pressure drop of a condensing two-phase flow in zero-gravity was developed along with a method for predicting the flow regime which would prevail along the condensation path. The hybrid refrigeration system was assembled with the two radiator/condenser panels installed in a space environment simulator. The system was tested under both atmospheric and vacuum conditions. Results of the tests are presented.

Williams, J. L.↗

The Role of Long-Lived Greenhouse Gases as Principal LW Control Knob that Governs the Global Surface Temperature for Past and Future Climate Change

The climate system of the Earth is endowed with a moderately strong greenhouse effect that is characterized by non-condensing greenhouse gases (GHGs) that provide the core radiative forcing. Of these, the most important is atmospheric CO2. There is a strong feedback contribution to the greenhouse effect by water vapor and clouds that is unique in the solar system, exceeding the core radiative forcing due to the non-condensing GHGs by a factor of three. The significance of the non-condensing GHGs is that once they have been injected into the atmosphere, they remain there virtually indefinitely because they do not condense and precipitate from the atmosphere, their chemical removal time ranging from decades to millennia. Water vapor and clouds have only a short lifespan, with their distribution determined by the locally prevailing meteorological conditions, subject to Clausius-Clapeyron constraint. Although solar irradiance is the ultimate energy source that powers the terrestrial greenhouse effect, there has been no discernible long-term trend in solar irradiance since precise monitoring began in the late 1970s. This leaves atmospheric CO2 as the effective control knob driving the current global warming trend. Over geological time scales, volcanoes are the principal source of atmospheric CO2, and the weathering of rocks is the principal sink, with the biosphere participating as both a source and a sink. The problem at hand is that human industrial activity is causing atmospheric CO2, to increase by 2 ppm per year, whereas the interglacial rate has been 0.005 ppm per year. This is a geologically unprecedented rate to turn the CO2 climate control knob. This is causing the global warming that threatens the global environment.

Greenhouse effect↗

Direct Radiative Effect of Mineral Dust on the Development of African Easterly Wave in Late Summer, 2003-2007

Episodic events of both Saharan dust outbreaks and African Easterly Waves (AEWs) are observed to move westward over the eastern tropical Atlantic Ocean. The relationship between the warm, dry, and dusty Saharan Air Layer (SAL) on the nearby storms has been the subject of considerable debate. In this study, the Weather Research and Forecasting (WRF) model is used to investigate the radiative effect of dust on the development of AEWs during August and September, the months of maximum tropical cyclone activity, in years 2003-2007. The simulations show that dust radiative forcing enhances the convective instability of the environment. As a result, most AEWs intensify in the presence of a dust layer. The Lorenz energy cycle analysis reveals that the dust radiative forcing enhances the condensational heating, which elevates the zonal and eddy available potential energy. In turn, available potential energy is effectively converted to eddy kinetic energy, in which local convective overturning plays the primary role. The magnitude of the intensification effect depends on the initial environmental conditions, including moisture, baroclinity, and the depth of the boundary layer. We conclude that dust radiative forcing, albeit small, serves as a catalyst to promote local convection that facilitates AEW development.

Ma, Po-Lun↗

Extraction and Capture of Water from Martian Regolith Experimental Proof-of-Concept

A novel concept for extraction of water from the Mars soil in a real-time, open-air process was demonstrated in a Mars environment chamber. The concept breadboard uses radiative heating to bake off water from exposed soil contained in a bin. An enclosure, intended to mimic the bottom of a rover, covers the bin. A fan continuously blows the Mars atmospheric gases through the enclosure to collect the evolved water while a tiller was used to churn up moist subsurface soil. These initial tests verified concept feasibility. The sweep gas generated by commercially available muffin fans at 7 Torr was sufficient to transfer water vapor into a condenser flow loop. The radiative heating, while non-optimized, heated the soil surface to 60 C to generate water vapor. A rototiller working through the soil bin brought sufficient amounts of new moist soil to the heated surface to show an increase in rate of water extraction.

Mars Exploration↗