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Large Meteorite Impacts and Planetary Evolution

Topics considered include: Petrography, geochemistry and geochronology; impact-induced hydrothermal base metal mineralization; nickel-and platinum group element -enriched quartz norite in the latest jurassic morokweng impact structure, south Africa; extraterrestrial helium trapped in fullerenes in the sudbury; synthetic aperture radar characteristics of a glacially modified meltsheet; the chicxulub seismic experiment; chemical compositions of chicxulub impact breccias; experimental investigation of the chemistry of vaporization of targets in relation to the chicxulub impact; artificial ozone hole generation following a large meteoroid impact into an oceanic site; three dimensional modeling of impactite bodies of popigai impact crater, Russia.

Source record↗

Anhydrite EOS and Phase Diagram in Relation to Shock Decomposition

In the context of the Chicxulub impact, it became recently obvious that experimental and theoretical research on the shock behavior of sulfates is essential for an assessment of the role of shock-released gases in the K/T mass extinction. The Chicxulub crater is the most important large impact structure where the bolide penetrated a sedimentary layer with large amounts of interbedded anhydrite (Haughton has also significant anhydrite in the target). The sulfuric gas production by shock compression/decompression of anhydrite is an important issue, even if the size of Chicxulub crater is only half of the so far assumed size. The comparison of experimental data for anhydrite, shocked with different techniques at various laboratories, reveals large differences in the threshold pressures for melting and decomposition. To gain insight into this issue, we have made a theoretical investigation of the thermodynamic properties of anhydrite. The project includes the review of data published in the last 40 years - reasons to study anhydrite cover a wide field of interests: from industrial problems of cement and ceramic production to the analysis of nuclear underground explosions in salt domes, conducted in the USA and USSR in the 1970th.

Ivanov, B. A.↗

Lunar and Planetary Science XXXV: Impacts on Mars and Earth

The session "Impacts on Mars and Earth" included the following reports:A Timescale for Major Events in Early Mars Crustal Evolution; Impact Craters in Arabia Terra, Mars; Ancient Giant Basin/Aquifer System in the Arabia Region, Mars; Small Crater Morphology Within Gusev Crater and Isidis Planitia: Evidence for Widespread Secondaries on Mars; Martian Surface Properties: Inferences from Resolved Differences in Crater Geometries; Asymmetric Ramparts of Secondary Craters in Cerberus, Mars: Interpretation and Implications for Local Stratigraphy; Depth to Diameter Relationships of Craters in the High Latitudes (70 -80 ) of Mars: Implications for Geologic History of Those Areas; Impact Cratering on Mars: Search for Target Influence on Morphology; Starting Conditions for Hydrothermal Systems Underneath Martian Craters: Hydrocode Modeling; Impact-induced Hydrothermal System at the Sudbury Crater: Duration, Temperatures, Mechanics, and Biological Implications; Major and Trace Element Variations in Impact Crater Clay from Chicxulub, Lonar, and Mistastin, Implications for the Martian Soil; Stable Isotopes and Hydrothermal Fluid Source in the Yaxcopoil-1 Borehole, Chicxulub Impact Structure, Mexico; and Chicxulub Impact Melts: Geochemical Signatures of Target Lithology Mixing and Post-Impact Hydrothermal Fluid Processes.

Source record↗

The Cretaceous-Tertiary (K/T) impact: One or more source craters?

The Cretaceous-Tertiary (K/T) boundary is marked by signs of a worldwide catastrophe, marking the demise of more than 50 percent of all living species. Ever since Alvarez et al. found an enrichment of IR and other siderophile elements in rocks marking the K/T boundary and interpreted it as the mark of a giant asteroid (or comet) impact, scientists have tried to understand the complexities of the K/T boundary event. The impact theory received a critical boost by the discovery of shocked minerals that have so far been found only in association with impact craters. One of the problems of the K/T impact theory was, and still is, the lack of an adequate large crater that is close to the maximum abundance of shocked grains in K/T boundary sections, which was found to occur in sections in Northern America. The recent discovery of impact glasses from a K/T section in Haiti has been crucial in establishing a connection with documented impact processes. The location of the impact-glass findings and the continental nature of detritus found in all K/T sections supports at least one impact site near the North American continent. The Manson Impact Structure is the largest recognized in the United States, 35 km in diameter, and has a radiometric age indistinguishable from that of the Cretaceous-Tertiary (K/T) boundary. Although the Manson structure may be too small, it may be considered at least one element of the events that led to the catastrophic loss of life and extinction of many species at that time. A second candidate for the K/T boundary crater is the Chicxulub structure, which was first suggested to be an impact crater more than a decade ago. Only recently, geophysical studies and petrological (as well as limited chemical) analyses have indicated that this buried structure may in fact be of impact origin. At present we can conclude that the Manson crater is the only confirmed crater of K/T age, but Chicxulub is becoming a strong contender; however, detailed geochemical, geochronological, and isotopic data are necessary to provide definitive evidence.

Koeberl, Christian↗

Projectile-target mixing in melted ejecta formed during a hypervelocity impact cratering event

Tektites contain little to no projectile contamination while, in contrast, some distal ejecta deposits can be relatively projectile-rich (e.g. the Cretaceous-Tertiary (K-T) boundary clay). This compositional difference motivated an experimental study of hypervelocity target-projectile mixing processes. We hope to scale up the results from these experiments and apply them to terrestrial impact structures like the Chicxulub Crater, Yucutan, Mexico, the leading contender as the site for the impact that caused the mass extinction that marks the K-T boundary. Shock decomposition of the approximately 500m thickness of anhydrite, or greater thickness of limestone, in the target rocks at Chicxulub may have been a critical mechanism for either global cooling via SO3, and subsequently H2SO4, formation, or possibly, global warming via increased CO2 formation. Understanding target-projectile mixing processes during hypervelocity impact may permit more accurate estimates of the amount of potentially toxic, target-derived material reaching stratospheric heights.

Evans, Noreen Joyce↗

Biospheric effects of a large extraterrestrial impact: Case study of the Cretaceous/Tertiary boundary crater

The Chicxulub Crater in Yucatan, Mexico, is the primary candidate for the impact that caused mass extinctions at the Cretaceous/Tertiary boundary. The target rocks at Chicxulub contain 750 to 1500 m of anhydrite (CaSO4), which was vaporized upon impact, creating a large sulfuric acid aerosol cloud. In this study we apply a hydrocode model of asteroid impact to calculate the amount of sulfuric acid produced. We then apply a radiative transfer model to determine the atmospheric effects. Results include 6 to 9 month period of darkness followed by 12 to 26 years of cooling.

Pope, Kevin O.↗

Shock-induced devolatization of calcium sulfate and implications for K-T extinctions

Calcium sulfate devolatization during the impact at Chicxulub, Mexico and dispersal in the stratosphere of the resultant sulfuric acid aerosol have been suggested as a possible mechanism for the Cretaceous-Tertiary extinctions. In this paper, we investigated two shock-induced devolatization reactions of calcium sulfate up to 42 GPa in the laboratory: CaSO4 + SiO2 yields CaSiO3 + SO3(degassed) and CaSO4 yields CaO + SO2(degassed) + 1/2 O2(degassed). We found both to proceed to a much less extent than calculated by equilibrium thermodynamic calculations. Reaction products are found to be 10(exp -2) times those calculated for equilibrium. Consequently our estimate of the amount of sulfur oxides degassed into the atmosphere from shock devolatization of CaS04 in the Chicxulub lithographic section (6x10(exp 15)-2x10(exp 16)g in sulfur mass) is lower by a factor of 70 to 400 than previous estimates; the related environmental stress arising from the resultant global cooling of approximately 4 K and fallout of acid rain does not appear to suffice to explain the widespread K-T extinctions.

Chen, Guangqing↗

Biospheric effects of a large extraterrestrial impact: Case study of the cretaceous/tertiary boundary crater

The Chicxulub impact crater, buried in the Yucatan carbonate platform in Mexico, is the site of the impact purported to have caused mass extinctions at the Cretaceous/Tertiary (K/T) boundary. A recently discovered Chicxulub ejecta deposit in Belize contains evidence of carbonate vaporization and precipitation from the vapor plume. Sulfate clasts are almost absent in the Belize ejecta, but are abundant in the coarse ejecta near the crater rim, hwich may reflect the greater abundance of sulfates deep in the target section. The absence of sulfate precipitates in Belize may indicate that most of the vaporized sulfur was deposited in the upper atmosphere. Hydrocode modeling of the impact indicates that between 0.4 to 7.0 x 10(exp 17) g of sulfur were vaporized by the impact in sulfates. Laser experiments indicate that SO2, SO3, and SO4 are produced, and that complex chemical reactions between plume constituents occur during condensation. The sulfur released as SO3 or SO4 converted rapidly into H2HO4 aerosol. A radiative transfer model coupled with a model of coagulation predicts that the aerosol prolonged the initial blackout period caused by impact dust only if it contained impurities. The sulfur released as SO2 converted to aerosol slowly due to the rate limiting oxidation of SO2. Radiative transfer calculations combined with rates of acid production, coagulation, and diffusion indicate that solar transmission was reduced to 10-20 percent of normal for a period of 8-13 years. This reduction produced a climate forcing (cooling) of -300 Wm(exp -2), which far exceeded the +8 Wm(exp -2) greenhouse warming caused by the CO2 released through the vaporization of carbonates, and therefore produced a decade of freezing and near-freezing temperatures. Several decades of moderate warming followed the decade of severe cooling due to the long residence time of CO2. The prolonged impact winter may have been a major cause of the K/T extinctions.

Pope, Kevin O.↗

Shock-induced devolatilization of calcium sulfate and implications for K-T extinctions

The devolatilization of calcium sulfate, which is present in the target rock of the Chicxulub, Mexico impact structure, and dispersal in the stratosphere of the resultant sulfuric acid aerosol have been suggested as a possible mechanism for the Cretaceous-Tertiary extinctions. We measured the amount of SO2 produced from two shock-induced devolatilization reactions of calcium sulfate up to 42 GPa in the laboratory. We found both to proceed to a much lower extent than calculated by equilibrium thermodynamic calculations. Reaction products are found to be approx. 10(exp -2) times those calculated for equilibrium. Upon modeling the quantity of sulfur oxides degassed into the atmosphere from shock devolatilization of CaSO4 in the Chicxulub lithographic section, the resulting 9 x 10(exp 16) to 6 x 10(exp 17) g (in sulfur mass) is lower by a factor of 10-100 than previous upper limit estimates, the related environmental stress arising from the resultant global cooling and fallout of acid rain is insufficient to explain the widespread K-T extinctions.

Chen, Guangqing↗

Hydrothermal Processes and Mobile Element Transport in Martian Impact Craters - Evidence from Terrestrial Analogue Craters

Hydrothermal alteration and chemical transport involving impact craters probably occurred on Mars throughout its history. Our studies of alteration products and mobile element transport in ejecta blanket and drill core samples from impact craters show that these processes may have contributed to the surface composition of Mars. Recent work on the Chicxulub Yaxcopoil-1 drill core has provided important information on the relative mobility of many elements that may be relevant to Mars. The Chicxulub impact structure in the Yucatan Peninsula of Mexico and offshore in the Gulf of Mexico is one of the largest impact craters identified on the Earth, has a diameter of 180-200 km, and is associated with the mass extinctions at the K/T boundary. The Yax-1 hole was drilled in 2001 and 2002 on the Yaxcopoil hacienda near Merida on the Yucatan Peninsula. Yax-1 is located just outside of the transient cavity, which explains some of the unusual characteristics of the core stratigraphy. No typical impact melt sheet was encountered in the hole and most of the Yax-1 impactites are breccias. In particular, the impact melt and breccias are only 100 m thick which is surprising taking into account the considerably thicker breccia accumulations towards the center of the structure and farther outside the transient crater encountered by other drill holes.

Newsom, H. E.↗

Noril'sk/Siberian plateau basalts and Bahama hot spot: Impact triggered?

Twenty-eight years after one of us argued that Sudbury was an astrobleme, this interpretation has only recently attained wide acceptance; not so for the view that the Sudbury Cu/Ni sulfide ores are cosmogenic. Other research has provided the triggering of plateau basalts by super-large impacts a modicum of respectability. The recent apparent successful tying in of the K/T extinctions to the Chicxulub astrobleme in the Yucatan encourages the search for an impact event that may have caused the other two major post-Paleozoic extinctions (P/Tr, Tr/J). This gives us heart to offer two further outrageous hypotheses. The cosmogenic concept for the Sudbury ore deposite remains viable because it is giant, nonultramafic, and unique (except for Noril'sk). The Triassic/Jurassic boundary catastrophic extinctions have been attributed to the Manicouagan asteroidal impact, but recent radiometric dating indicates these events are diachronous (Manicouagan astrobleme 212 +/- 2 Ma and Tr/J boundary 200 Ma).

Deitz, R. S.↗

Isotopic signatures of black tektites from the K-T boundary on Haiti - Implications for the age and type of source material

An isotopic study was carried out to characterize the type of black tektites from the Cretaceous-Tertiary (K-T) boundary on Haiti (the first reasonably well-preserved impact-derived material recovered from the K-T boundary), in order to help characterize the tektite source material (i.e., the type of rocks that were melted and ejected during the impact event(s) at around 64.5 Ma). Results show that the isotopic data and all of the element concentration data obtained are consistent with an andesitic-dacitic composition for the tektites and their source material. The Nd isotopic data suggest that the source rocks were not older than Silurian (T(chur) = 400 Ma) in age, and were composed largely of young (less than 1080 Ma) crustal material. Of the suspected K-T boundary impact sites, both the Manson (Iowa) and Chicxulub (Yucatan) structures occur in suitable lithologies to yield the Haitian black tektites.

Premo, W. R.↗

Arroyo el Mimbral, Mexico, K/T unit: Origin as debris flow/turbidite, not a tsunami deposit

Coarse, spherule-bearing, elastic units have been discovered at 10 marine sites that span the K/T boundary in northeastern Mexico. We examined one of the best exposed sites in Arroyo el Mimbral, northwest of Tampico. The Mimbral outcrop displays a layered elastic unit up to 3 m thick enclosed by marly limestones of the Mendez (Latest Maastrichian) and Velasco (Earliest Danian) Formations. At its thickest point, this channelized elastic unit is comprised of 3 subunits: (1) a basal, poorly-sorted, ungraded calcareous spherule bed 1 m thick containing relict impact glass and shocked mineral grains, (2) a massive set of laminated calcite-cemented sandstones up to 2 m thick with plant debris at its base, (3) capped by a thin (up to 20 cm) set of rippled sandstone layers separated by silty mudstone drapes containing a small (921 pg/g) iridium anomaly. This tripartite elastic unit is conformably overlain by marls of the Velasco Formation. We also visited the La Lajilla site east of Ciudad Victoria; its stratigraphy is similar to Mimbral's, but its elastic beds are thinner and less extensive laterally. The Mimbral elastic unit has been interpreted previously as being deposited by a megawave or tsunami produced by an asteroid impact on nearby Yucatan (Chicxulub crater). However, a presumed 400-m paleodepth of water at the Mimbral site, channeling of the spherule subunit into the underlying Mendez Formation marls, and the overtopping of the basal, spherule-bearing subunit by the laminated sandstone subunit, all suggest a combined debris flow/turbidite origin for this elastic unit similar to that proposed for Upper Pleistocene sand/silt beds occurring elsewhere in the Gulf of Mexico. In this latter model, the sediment source region for the elastic unit is the lower continental shelf and slope escarpment. For the K/T unit at Mimbral, we propose that thick ejecta blanket deposits composed mostly of spherules were rapidly loaded onto the lower shelf and slope from an impact-generated ejecta curtain.

Bohor, Bruce F.↗

Modelling of dispersal and deposition of impact glass spherules from the Cretaceous-Tertiary boundary deposit

The dispersal of glass spherules or tektites from a bolide impact with the Earth is modelled as ballistic trajectories in standard atmosphere. Ballistic dispersal of Cretaceous-Tertiary boundary impact glass spherules found in Haiti and Mimbral, Mexico requires a fireball radius in excess of 50 km but less than 100 km to account for the observed distribution. Glass spherules from 1 and up to 8 mm in diameter have been found at the KT boundary at Beloc in Haiti, at Mimbral, Mexico, and at DSDP Sites 536 and 540 in the Gulf of Mexico corresponding to paleodistances of 600 to 1000 km from the Chicxulub crater. In Haiti the basal and major glass-bearing unit at the KT boundary is attributed to fallout on basis of sedimentologic features. When compared with theoretical and observed dispersal of volcanic ejecta, the grain size versus distance relationship of the KT boundary tektite fallout is extreme, and rules out a volcanic fallout origin. At a comparable distance from source, the KT impact glass spherules are more than an order of mangitude coarser than ejecta of the largest known volcanic events. We model the dispersal of KT boundary impact glass spherules as ballistic ejecta from a fireball generated by the impact of a 10 km diameter bolide. Mass of ejecta in the fireball is taken as twice the bolide mass. Melt droplets are accelerated by gas flow in the fireball cloud, and leave the fireball on ballistic trajectories within the atmosphere, subject to drag, depending on angle of ejection and altitude. The model for ballistic dispersal is based on equations of motion, drag and ablation for silicate spheres in standard atmosphere.

Espindola, J. M.↗

Some implications of large impact craters and basins on Venus for terrestrial ringed craters and planetary evolution

Approximately 950 impact craters have been identified on the surface of Venus, mainly in Magellan radar images. From a combination of Earth-based Arecibo, Venera 15/1, and Magellan radar images, we have interpreted 72 as unequivocal peak-ring craters and four as multiringed basins. The morphological and structural preservation of these craters is high owing to the low level of geologic activity on the venusian surface (which is in some ways similar to the terrestrial benthic environment). Thus these craters should prove crucial to understanding the mechanics of ringed crater formation. They are also the most direct analogs for craters formed on the Earth in Phanerozoic time, such as Chicxulub. We summarize our findings to date concerning these structures.

Mckinnon, W. B.↗

Field guide to Cretaceous-tertiary boundary sections in northeastern Mexico

This guide was prepared for the field trip to the KT elastic sequence of northeastern Mexico, 5-8 February 1994, in conjunction with the Conference on New Developments Regarding the KT Event and Other Catastrophes in Earth History, held in Houston, Texas. The four-day excursion offers an invaluable opportunity to visit three key outcrops: Arroyo El Mimbral, La Lajilla, and El Pinon. These and other outcrops of this sequence have recently been interpreted as tsunami deposits produced by the meteorite impact event that produced the 200 to 300-km Chicxulub basin in Yucatan, and distributed ejecta around the world approximately 65 m.y. ago that today is recorded as a thin clay layer found at the K/T boundary. The impact tsunami interpretation for these rocks has not gone unchallenged, and others examining the outcrops arrive at quite different conclusions: not tsunami deposits but turbidites; not KT at all but 'upper Cretaceous.' Indeed, it is in hopes of resolving this debate through field discussion, outcrop evaluation, and sampling that led the organizers of the conference to sanction this field trip. This field guide provides participants with background information on the KT clastic sequence outcrops and is divided into two sections. The first section provides regional and logistical context for the outcrops and a description of the clastic sequence. The second section presents three representative interpretations of the outcrops by their advocates. There is clearly no way that these models can be reconciled and so two, if not all three, must be fundamentally wrong. Readers of this guide should keep in mind that many basic outcrop observations that these models are based upon remain unresolved. While great measures were taken to ensure that the information in the description section was as objective as possible, many observations are rooted in interpretations and the emphasis placed on certain observations depends to some degree upon the perspective of the author.

Keller, Gerta↗

Journey to the end of the dinosaur era: A society expedition to Belize

The impact of the extraterrestrial object that formed the Chicxulub crater in the northwestern Yucatan peninsula of Mexico is the leading suspect for the extinction of the dinosaurs. This article reports on a Planetary Society expedition to Albion Island in the Rio Hondo region of Belize to investigate evidence supporting the impact theory.

Ocampo, Adriana↗

Impact Cratering Calculations

Understanding the physical processes of impact cratering on planetary surfaces and atmospheres as well as collisions of finite-size self-gravitating objects is vitally important to planetary science. The observation has often been made that craters are the most ubiquitous landform on the solid planets and the satellites. The density of craters is used to date surfaces on planets and satellites. For large ringed basin craters (e.g. Chicxulub), the issue of identification of exactly what 'diameter' transient crater is associated with this structure is exemplified by the arguments of Sharpton et al. (1993) versus those of Hildebrand et al. (1995). The size of a transient crater, such as the K/T extinction crater at Yucatan, Mexico, which is thought to be the source of SO,-induced sulfuric acid aerosol that globally acidified surface waters as the result of massive vaporization of CASO, in the target rock, is addressed by our present project. The impact process excavates samples of planetary interiors. The degree to which this occurs (e.g. how deeply does excavation occur for a given crater diameter) has been of interest, both with regard to exposing mantle rocks in crater floors, as well as launching samples into space which become part of the terrestrial meteorite collection (e.g. lunar meteorites, SNC's from Mars). Only in the case of the Earth can we test calculations in the laboratory and field. Previous calculations predict, independent of diameter, that the depth of excavation, normalized by crater diameter, is d(sub ex)/D = 0.085 (O'Keefe and Ahrens, 1993). For Comet Shoemaker-Levy 9 (SL9) fragments impacting Jupiter, predicted excavation depths of different gas-rich layers in the atmosphere, were much larger. The trajectory and fate of highly shocked material from a large impact on the Earth, such as the K/T bolide is of interest. Melosh et al. (1990) proposed that the condensed material from the impact upon reentering the Earth's atmosphere induced. radiative heating, and producing global firestorms. The observed reentry splash of the SL-9 impact-induced plumes that reimpact Jupiter (Boslough et al., 1994) supported Melosh's K/T model. The fate of early primitive planetary atmospheres during the latter stages of planetary accretion, resulting from impactors in the 100 to 103 km diameter require modeling, e.g. Newman et al. (1997). Ahrens (1990; 1993) and Chen and Ahrens (1997) found that upon delivery of most of the impact energy to the solid planet, very large ground motions arise, which couple sufficient kinetic energy to the atmosphere to cause substantial atmospheric escape. The trade-off of this model with that of Cameron (1997) who suggests that atmospheric blow-off occurs as a result of the massive impact-induced heating of the atmosphere and Pepin (1997) who uses this heating event to model differential hydrodynamic loss of lighter atmospheric gases, requires further research.

Ahrens, Thomas J.↗