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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Preprocessing Affords 3D Crystalline Poly(3-hexylthiophene) Structure

The aggregation and crystallization of poly(3-hexylthiophene- 2,5-diyl) (P3HT), a representative active layer material used for organic field-effect transistor (OFET) applications, are influenced by the solution pretreatment and deposition process. This study explores vibration-assisted convective deposition for the fabrication of OFETs in comparison to spin coating, blade coating, and convective deposition without vibration. The ultraviolet–visible spectroscopic analysis demonstrates that convective deposition, especially assisted with vibration, leads to a greater degree of intrachain interactions, longer conjugation length, and enhanced polymer backbone planarization. When the P3HT solution is preprocessed via sonication and aging, the P3HT films exhibit J-like aggregation, and (h11) peaks can be observed through grazing-incidence wide-angle X-ray scattering, suggesting an ordered 3D crystalline structure. OFETs based on such films exhibit high mobilities (up to 0.14 cm 2 V –1 s –1 ). The results point to the sensitivity of P3HT charge transport behavior to the intramolecular interactions and backbone planarity and further deepen our understanding of the relationship between processing, aggregates, molecular ordering, and resultant device properties.

36 MATERIALS SCIENCE↗
NASA NTRS2007

Observed Enhancement of Reflectivity and Electric Field in Long-Lived Florida Anvils

A study of two long-lived Florida anvils showed that reflectivity greater than 20 dBZ increased in area, thickness and sometimes magnitude at mid-level well downstream of the convective cores. In these same regions electric fields maintained strengths greater than 10 kV m(sup -1) for many tens of minutes and became quite uniform over tens of kilometers. Millimetric aggregates persisted at 9 to 10 km for extended times and distances. Aggregation of ice particles enhanced by strong electric fields might have contributed to reflectivity growth in the early anvil, but is unlikely to explain observations further out in the anvil. The enhanced reflectivity and existence of small, medium and large ice particles far out into the anvil suggest that an updraft was acting, perhaps in weak convective cells formed by instability generated from the evaporation and melting of falling ice particles. We conclude that charge separation must have occurred in these anvils, perhaps at the melting level but also at higher altitudes, in order to maintain fields greater than 10 kV m(sup -1) at 9 to 10 km for extended periods of time over large distances. We speculate that charge separation occurred as a result of ice-ice particle collisions (without supercooled water being present) via either a noninductive or perhaps even an inductive mechanism, given the observed broad ice particle spectra, the strong pre-existing electric fields and the many tens of minutes available for particle interactions. The observations, particularly in the early anvil, show that the charge structure in these anvils was quite complex.

Dye, James E.↗
NASA NTRS1990

Chaotic, subduction-like downflows in a spherical model of convection in the earth's mantle

Model calculations are described for a compressible fluid in a three-dimensional spherical shell with 80 percent of the surface heat flow generated within the model mantle. The numerical solutions are strongly chaotic, with surface planforms dominated by long curvilinear downflows reminiscent of the descending slabs in the earth's mantle. The results suggest that descending slabs play an important part in driving mantle convection, and that their chaotic evolution may influence the spatial and temporal behavior of plates and thus the dispersal and aggregation of continents.

Glatzmaier, Gary A.↗
NASA NTRS2004

Magnetic Control of Convection during Protein Crystallization

An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular Crystals for diffraction analyses has been the central focus for bio-chemists, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitants, other possible phases of the protein, foreign particles, the walls of container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and Sedimentation as is achieved in "microgravity", we have been able to dramatically affect the movement and distribution of macromolecules in the fluid, and thus their transport, f o d o n of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. We postulate that limited convection in a magnetic field will provide the environment for the growth of high quality crystals. The approach exploits the variation of fluid magnetic susceptibility with counteracts on for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteract terrestrial gravity. The genera1 objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. The paper will report on the experimental results using paramagentic salts and solutions in magnetic fields and compare them to analyticalpr~ctions.

Ramachandran, N.↗
NASA NTRS2003

Using Strong Magnetic Fields to Control Solutal Convection

An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular crystals for diffraction analyses has been the central focus for biochemists, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitants, other possible phases of the protein, foreign particles, the walls of the container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and sedimentation, as is achieved in microgravity , we have been able to dramatically affect the movement and distribution of macromolecules in the fluid, and thus their transport, formation of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. We postulate that limited convection in a magnetic field will provide the environment for the growth of high quality crystals. The approach exploits the variation of fluid magnetic susceptibility with concentration for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteracts terrestrial gravity. The general objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. The paper will report on the experimental results using paramagnetic salts and solutions in magnetic fields and compare them to analytical predictions.

Ramachandran, N.↗
DOE OSTI2022

A multi-scale time-series dataset of anthropogenic heat from buildings in Los Angeles County

The dataset contains hourly Anthropogenic heat (AH) from buildings in Los Angeles County, based on weather data from 2018. The hourly AH is aggregated at three spatial resolutions: 450m x 450m grid, 12km x 12km grid, and census tract. The AH is broken down into three components: building envelope surface convection, heating, ventilation, and air conditioning (HVAC) system heat release, and zone exfiltration and exhaust air heat loss. The dataset is created with the physics-based EnergyPlus building energy models to calculate individual buildings' AH considering WRF-UCM simulated microclimate conditions. Please refer to the paper "A multi-scale time-series dataset of anthropogenic heat from buildings in Los Angeles County" for more information about the data generation workflow and the data validation procedure. The data set contains two folders: the "output_data" folder holds the simulation results (EP_output and EP_output_csv), building metadata (building_metadata.geojson and building_metadata.csv), aggregated heat emission and energy consumption time-series data (hourly_heat_energy), and geographical data (geo_data) associated with the GEOID referenced in heat and energy consumption data. The "input_data" folder contains the raw data used to generate files in the "output_data" folder as well as data sets used in the validation. The code repository (https://github.com/IMMM-SFA/xu_etal_2022_sdata) holds the processing scripts for data curation, validation, and visualization.

Energy↗
NASA NTRS2002

Countering Solutal Buoyant Convection with High Magnetic Fields

An important component in biotechnology, particularly in the area of protein engineering and rational drug design is the knowledge of the precise three-dimensional molecular structure of proteins. The quality of structural information obtained from X-ray diffraction methods is directly dependent on the degree of perfection of the protein crystals. As a consequence, the growth of high quality macromolecular crystals for diffraction analyses has been the central focus for biochemist, biologists, and bioengineers. Macromolecular crystals are obtained from solutions that contain the crystallizing species in equilibrium with higher aggregates, ions, precipitant, other possible phases of the protein, foreign particles, the walls of the container, and a likely host of other impurities. By changing transport modes in general, i.e., reduction of convection and sedimentation, as is achieved in microgravity, we have been able to dramatically effect the movement and distribution of macromolecules in the fluid, and thus their transport, formation of crystal nuclei, and adsorption to the crystal surface. While a limited number of high quality crystals from space flights have been obtained, as the recent National Research Council (NRC) review of the NASA microgravity crystallization program pointed out, the scientific approach and research in crystallization of proteins has been mainly empirical yielding inconclusive results. We postulate that we can reduce convection in ground-based experiments and we can understand the different aspects of convection control through the use of strong magnetic fields and field gradients. We postulate that limited convection in a magnetic field will provide the environment for the growth of high quality crystals. The approach exploits the variation of fluid magnetic susceptibility with concentration for this purpose and the convective damping is realized by appropriately positioning the crystal growth cell so that the magnetic susceptibility force counteracts terrestrial gravity. The general objective is to test the hypothesis of convective control using a strong magnetic field and magnetic field gradient and to understand the nature of the various forces that come into play. Specifically we aim to delineate causative factors and to quantify them through experiments, analysis and numerical modeling. The paper will report on the current status of the investigation and discuss results from the experimental and modeling efforts.

Ramachandran, N.↗
DOE OSTI2024

Convective and Orographic Origins of the Mesoscale Kinetic Energy Spectrum

The mesoscale spectrum describes the distribution of kinetic energy in the Earth's atmosphere between length scales of 10 and 400 km. Since the first observations, the origins of this spectrum have been controversial. At synoptic scales, the spectrum follows a –3 spectral slope, consistent with two-dimensional turbulence theory, but a shallower –5/3 slope was observed at the shorter mesoscales. The cause of the shallower slope remains obscure, illustrating our lack of understanding. Through a novel coarse-graining methodology, we are able to present a spatio-temporal climatology of the spectral slope. We find convection and orography have a shallowing effect and can quantify this using “conditioned spectra.” These are typical spectra for a meteorological condition, obtained by aggregating spectra where the condition holds. This allows the investigation of new relationships, such as that between energy flux and spectral slope. Potential future applications of our methodology include predictability research and model validation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1985

A calculation of the Rosseland mean opacity of dust grains in primordial solar system nebulae

The Rosseland mean opacity owing to grains was calculated as a function of temperature and density for nebulae having solar elemental abundances. The values of the mean opacity were evaluated with a generalized formulation allowing for anisotropic scattering. The values of the mean opacity do not depend sensitively on the choice of the particle size distribution function, provided that there are few particles having sizes in excess of several tens of microns. The results indicate that thermal convection in primordial nebulae occurs over broader ranges of altitudes at low temperatures than at high temperatures, and for size distributions for which extensive aggregation has not yet occurred.

Pollack, J. B.↗
DOE OSTI2023

Cooling flow regime of a plasma thermal quench

A large class of Laboratory, Space, and Astrophysical plasmas is nearly collisionless. When a localized energy or particle sink, for example, in the form of a radiative cooling spot or a black hole, is introduced into such a plasma, it can trigger a plasma thermal collapse, also known as a thermal quench in tokamak fusion. Here we show that the electron thermal conduction in such a nearly collisionless plasma follows the convective energy transport scaling in itself or in its spatial gradient, due to the constraint of ambipolar transport. As a result, a robust cooling flow aggregates mass toward the cooling spot and the thermal collapse of the surrounding plasma takes the form of four propagating fronts that originate from the radiative cooling spot, along the magnetic field line in a magnetized plasma. The slowest one, which is responsible for deep cooling, is a shock front.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2002

Characteristics of Vertical Profiles of Reflectivity and Doppler Derived From TRMM Field Campaigns

The TRMM Precipitation Radar (PR) measures the vertical profile of reflectivity from which the surface rain rate is estimated after attenuation corrections in the 2A21 algorithm. Characteristics of the vertical reflectivity profile is important for various reasons ranging from scientific to instrument algorithms. It is well known that different types of precipitation such as stratiform or convection, have different heating profiles. The vertical profile of reflectivity can provide information on precipitation classification. The vertical reflectivity structure also provides information on precipitation processes such as growth and aggregation. In terms of TRMM algorithms, an independent estimate of the vertical profiles are also extremely important since the PR returns can be attenuated in the rain layer near the surface. Corrections for attenuation are required in the lowest few kilometers, necessitating some assumptions about the rain size distributions and the reflectivity profile below the lowest measurement unaffected by the surface return. Furthermore, some assumptions about the vertical reflectivity profile are required for Ground Validation (GV) radars, since their lowest scan may be 1 or more kilometers above the surface. Statistics on the vertical reflectivity and Doppler structure are presented from the ER-2 Doppler Radar (EDOP) which participated in several TRMM field campaigns (TEFLUN-A, TEFLUN-B, and LBA) and CAMEX-3. The ER-2 aircraft overflew diverse precipitation types during these campaigns. EDOP is an X-band (9.6 GHz) radar for which returns are less attenuated than at the TRMM PR frequency. The EDOP profiles are first corrected for attenuation using the SRT method. The data from all the ER-2 campaigns are then classified by type (convection, stratiform, and other) and then statistics were performed on the vertical reflectivity and Doppler profiles in the form of CFAD's. These CFADs are compared and discussed. The computed CFAD's indicate significant differences as a function of precipitation type and location (hurricane versus non-hurricane, Brazil versus Florida). The implications of these profiles will be discussed.

Starr, David OC.↗
NASA NTRS1994

Regional rainfall climatologies derived from Special Sensor Microwave Imager (SSM/I) data

Climatologies of convective precipitation were derived from passive microwave observations from the Special Sensor Microwave Imager using a scattering-based algorithm of Adler et al. Data were aggregated over periods of 3-5 months using data from 4 to 5 years. Data were also stratified by satellite overpass times (primarily 06 00 and 18 00 local time). Four regions (Mexico, Amazonia, western Africa, and the western equatorial Pacific Ocean (TOGA COARE area) were chosen for their meteorological interest and relative paucity of conventional observations. The strong diurnal variation over Mexico and the southern United States was the most striking aspect of the climatologies. Pronounced morning maxima occured offshore, often in concativities in the coastline, the result of the increased convergence caused by the coastline shape. The major feature of the evening rain field was a linear-shaped maximum along the western slope of the Sierra Madre Occidental. Topography exerted a strong control on the rainfall in other areas, particularly near the Nicaragua/Honduras border and in Guatemala, where maxima in excess of 700 mm/month were located adjacent to local maxima in terrain. The correlation between the estimates and monthly gage data over the southern United States was low (0.45), due mainly to poor temporal sampling in any month and an inadequate sampling of the diurnal cycle. Over the Amazon Basin the differences in morning versus evening rainfall were complex, with an alternating series of morning/evening maxima aligned southwest to northeast from the Andes to the northeast Brazilian coast. A real extent of rainfall in Amazonia was slightly higher in the evening, but a maximum in morning precipitation was found on the Amazon River just east of Manaus. Precipitation over the water in the intertropical convergence zone (ITCZ) north of Brazil was more pronounced in the morning, and a pronounced land-/sea-breeze circulation was found along the northeast coast of Brazil. Inter-comparison of four years revealed 1992 to be the driest over Amazonia, with about a 23% decrease in mean rate compared to the 4-year mean estimated rain rate.

Negri, Andrew J.↗
NASA NTRSDate not supplied

A Long-Term GOES Satellite Overshooting Cloud Top and Anvil Cloud Climatology Over South America

The modern-era GOES satellite series began in 1994 with the GOES-8 satellite, and was augmented in 2018 with higher spatial resolution and more frequent imaging when GOES-16 became operational. GOES imagery has provided forecasters and researchers new perspectives into cloud top patterns associated with severe convection, and the ability to better forecast convection in regions without adequate ground-based weather radar coverage. While much attention has been given to convection over North America, convection over South America can be equally, if not more, intense and frequent. Recent studies have demonstrated that overshooting cloud tops (OT) and surrounding anvil clouds can be detected within infrared satellite imagery. Relative storm updraft intensity metrics such as the tropopause-relative infrared brightness temperature, the prominence of an OT relative to its surrounding anvil, and cloud top height can also be derived using automated methods combined with reanalysis data. These automated OT detection and intensity estimation methods have recently been applied to all GOES images collected over South America, in combination with the MERRA-2 reanalysis, from 1995 to 2022 at NASA Langley within a project supported by the NASA Applied Sciences Disasters program. Innovative aggregation methods have merged these products into daily, monthly, annual, and multi-annual composites, with hourly time bins, at ~4 km pixel spacing to enable researchers a new opportunity to study South American convective processes throughout the diurnal cycle. These products have recently become publicly available from NASA. This presentation will overview this new dataset, and novel insights into South American convection depicted by the data.

Kristopher Bedka↗
NASA NTRS1981

Hotspots, polar wander, Mesozoic convection and the geoid

The geoid bears little relation to present tectonic features of the earth other than trenches. The Mesozoic supercontinent of Pangea, however, apparently occupied a central position in the Atlantic-African geoid high. This and the equatorial Pacific geoid high contain most of the world's hotspots. The plateaus and rises in the western Pacific formed in the Pacific geoid high and this may have been the early Mesozoic position of Pacifica, the fragments of which are now the Pacific rim portions of the continents. Geoid highs which are unrelated to present subduction zones may be the former sites of continental aggregations and mantle insulation and, therefore, hotter than normal mantle. The pent-up heat causes rifts and hotspots and results in extensive uplift, magmatism, fragmentation and dispersal of the continents and the subsequent formation of plateaus, aseismic ridges and seamount chains. Convection in the uppermantle would then be due to lateral temperature gradients as well as heating from below and would be intrinsically episodic.

Anderson, D. L.↗
NASA NTRS2010

Genesis of Pre-Hurricane Felix (2007): The Role of the Easterly Wave Critical Layer - Part 1

The formation of pre Hurricane Felix (2007) in a tropical easterly wave is examined in a two-part study using the Weather Research and Forecasting (WRF) model with a high-resolution nested grid configuration that permits the representation of cloud system processes. The simulation commences during the wave stage of the precursor African easterly-wave disturbance. Here the simulated and observed developments are compared, while in Part II of the study various large-scale analyses, physical parameterizations, and initialization times are explored to document model sensitivities. In this first part the authors focus on the wave/vortex morphology, its interaction with the adjacent intertropical convergence zone complex, and the vorticity balance in the neighborhood of the developing storm. Analysis of the model simulation points to a bottom-up development process within the wave critical layer and supports the three new hypotheses of tropical cyclone formation proposed recently by Dunkerton, Montgomery, and Wang. It is shown also that low-level convergence associated with the ITCZ helps to enhance the wave signal and extend the "wave pouch" from the jet level to the top of the atmospheric boundary layer. The region of a quasi-closed Lagrangian circulation within the wave pouch provides a focal point for diabatic merger of convective vortices and their vortical remnants. The wave pouch serves also to protect the moist air inside from dry air intrusion, providing a favorable environment for sustained deep convection. Consistent with the authors' earlier findings, the tropical storm forms near the center of the wave pouch via system-scale convergence in the lower troposphere and vorticity aggregation. Components of the vorticity balance are shown to be scale dependent, with the immediate effects of cloud processes confined more closely to the storm center than the overturning Eliassen circulation induced by diabatic heating, the influence of which extends to larger radii.

Wang, Zhuo↗
NASA NTRSDate not supplied

Toward The Development of Hailstorm Climatologies Derived From Reanalyses and Infared/Passive Microwave Satellite Imagers

Geostationary satellite imagers, such as those of the Geostationary Operational Environmental Satellite (GOES) and Meteosat series, provide both historical and near-real-time observations of cloud top patterns that are commonly associated with severe convection. Environmental conditions favorable for severe weather are thought to be represented well by reanalyses. Predicting exactly where convection and costly storm hazards like hail will occur using models or satellite imagery alone, however, is extremely challenging. The multivariate combination of satellite-observed cloud patterns with reanalysis environmental parameters, linked to United States Next Generation Weather Radar- (NEXRAD-) estimated Maximum Expected Size of Hail (MESH) using a deep neural network (DNN), enables estimation of potentially severe hail likelihood for any observed storm cell. These estimates are specifically designed to make hail likelihood distinctions based on satellite-indicated points of deep convection within environments favorable for storm development. We seek an approach that can be used to estimate climatological hailstorm frequency and risk throughout the historical satellite data record. This presentation demonstrates that statistical distributions of convective parameters from satellite and reanalysis show separation between non-severe/severe hailstorm classes for predictors including overshooting cloud top temperature and area characteristics, convective available potential energy, vertical wind shear, 500 hPa temperature, mid-level lapse rate, precipitable water, and convective inhibition. These complex, multivariate predictor relationships are exploited within a DNN to produce a hail likelihood metric with a critical success index of 0.504 and Heidke skill score of 0.403, which is exceptional among recent analogous hail studies. Furthermore, applications of the DNN to select case studies demonstrate good qualitative agreement between hail likelihood and MESH. These hail classifications are aggregated across an 11-year GOES-12/13 image database to derive a hail frequency and severity climatology, which denotes the Central Plains, the Midwest, and northwestern Mexico as being the most hail-prone regions within the domain studied. Opportunities for training and applying DNN-based hailstorm predictions to recently developed GOES-8/10/12/13/16 and Meteosat Second Generation convective storm detection and characterization climatologies over South America and South Africa, respectively, will also be presented.

Kristopher Bedka↗
DOE OSTI2021

How much information on precipitation is contained in satellite infrared imagery?

Satellite infrared (IR) brightness temperature providing information on the characteristics of cloud tops is one of the primary input data used for estimating precipitation from satellites. Thus, the natural questions to ask are: Does IR imagery contain more information about precipitation in some regions more than others? What are the factors that lead to such differences? Should we expect the amount of information provided by IR imagery to change with respect to temporal or spatial aggregation? Comprehensive analysis of the accuracy of satellite-based precipitation estimates obtained from any given algorithm may provide qualitative answers to the above questions. However, such an approach only offers conclusions within the limited context of the algorithm used to obtain precipitation estimates; that is, patterns caused by the inherent information content of IR imagery are inextricable from those induced by assumptions embedded in the precipitation estimation algorithm. Here, we address the abovementioned questions from a different perspective using an information-theoretic measure, free of structural assumptions and general to a wide range of relationships, to characterize the average and seasonal dependence between IR imagery provided by satellite sensors in the spectral range (10.7–11.5 μm) and precipitation rates in the contiguous United States (CONUS) across distinct temporal and spatial scales. We analyze a total of more than 1.3 billion pairs of IR and precipitation observations over CONUS, and we observe interesting patterns. First, we show that there is a strong inverse relationship (ρ = - 0.73) between the information content of IR data and the number of no-rain observations; however, its robustness varies regionally and seasonally with less significant correlation during the warm season. Second, we demonstrate that the intuitive relationship of increasing dependence between IR and precipitation as a result of temporal or spatial aggregation exhibits a diminishing returns behavior. For instance, temporal aggregation from 1 to 3 h increases the dependence approximately 7 times as much as temporal aggregation from 12 to 24 h. Furthermore, we quantitatively examine and re-confirm several statements previously reported in the literature such as the strong association between IR and precipitation in convective storms and the low association in orographic rainfall. Finally, we conclude by illustrating the potential of the analysis in diagnosis of operational algorithms for estimating precipitation from IR brightness temperature. The findings of this study pinpoint spatial domains and time scales at which IR is not an adequate proxy for estimating precipitation. Thus, they can potentially guide the development of operational algorithms that utilize satellite Infrared imagery for estimating, downscaling and data fusion of precipitation. Finally, the analysis presented here opens up the possibility of developing new methodologies for diagnosis of satellite-based precipitation estimation algorithms.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Particle dynamics of nanoplastics suspended in water with soil microparticles: insights from small angle neutron scattering (SANS) and ultra-SANS

Small-angle neutron scattering (SANS) and ultra-SANS (USANS) were employed to understand the aggregation behavior and observe the size reduction for nanoplastics (NPs) formed from a biodegradable mulch film, and microparticles of vermiculite (V), an artificial soil, suspended in water in the presence of low convective shear (ex situ stirring) prior to measurements. Neutron contrast matching was employed to minimize the signal of V (by 100-fold) and thereby isolate the signal due to NPs in the neutron beam, as the contrast match point (CMP) for V (67 vol% deuteration of water) differed from that of NPs by more than 20%. The original NPs' size distribution was bimodal: <200 nm and 500–1200 nm, referred to as small and large NPs, i.e., SNPs and LNPs, respectively. In the absence of V, SNPs formed homoaggregates at higher concentrations that decreased with stirring time, while the size of LNPs remained unchanged. The presence of V at 2-fold lower concentration than NPs did not change the size of SNPs but reduced the size of LNPs by nearly 2-fold as stirring time increased. Because the size of SNPs and LNPs did not differ substantially between CMP and 100% D 2 O solvents, it is evident that SNPs and LNPs are mainly composed of NPs and not V. In conclusion, the results suggest that LNPs are susceptible to size reduction through collisions with soil microparticles via convection, yielding SNPs near soil–water interfaces within vadose zones.

Nanoplastics↗