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NASA NTRS1999

Physiologic and Functional Responses of MS Patients to Body Cooling Using Commercially Available Cooling Garments

Personal cooling systems are widely used in industrial and aerospace environments to alleviate thermal stress. Increasingly they are also used by heat sensitive multiple sclerosis (HSMS) patients to relieve symptoms and improve quality of life. There are a variety of cooling systems commercially available to the MS community. However, little information is available regarding the comparative physiological changes produced by routine operation of these various systems. The objective of this study was to document and compare the patient response to two passive cooling vests and one active cooling garment. The Life Enhancement Technology, Inc. (LET) lightweight active cooling vest with cap, the MicroClimate Systems (MCS) Change of Phase garment, and the Steele Vest were each used to cool 13 male and 13 female MS subjects (31 to 67 yr.) in this study. The subjects, seated in an upright position at normal room temperature (approximately 22 C), were tested with one of the cooling garments. Oral, fight and left ear temperatures were logged manually every 5 min. An-n, leg, chest and rectal temperatures; heart rate; and respiration were recorded continuously on a U.F.I., Inc. Biolog ambulatory monitor. Each subject was given a series of subjective and objective evaluation tests before and after cooling. The LET and Steele vests test groups had similar, significant (P less than 0.01) cooling effects on oral and ear canal temperature, which decreased approximately 0.4 C, and 0.3 C, respectively. Core temperature increased (N.S.) with all three vests during cooling. The LET vest produced the coldest (P less than 0.01) skin temperature. Overall, the LET vest provided the most improvement on subjective and objective performance measures. These results show that the garment configurations tested do not elicit a similar thermal response in all MS patients. Cooling with the LET active garment configuration resulted in the lowest body temperatures for the MS subjects; cooling with the MCS vest was least effective. For functional responses, the LET test group performed better than the other two vests.

Ku, Yu-Tsuan E.↗

NASA NTRS2000

Physiologic Responses Produced by Active and Passive Personal Cooling Vests

Personal thermoregulatory systems which provide chest cooling are used in the industrial and aerospace environments to alleviate thermal stress. However, little information is available regarding the physiologic and circulatory changes produced by routine operation of these systems. The objectives of this study were to document and compare the subjects' response to three cooling vests in their recommended configurations. The Life Enhancement Tech (LET) lightweight active cooling vest with cap, the MicroClimate Systems Change of Phase garment (MCS), and the Steele Vest were each used to cool the chest regions of 12 male and 8 female Healthy subjects (21 to 69 yr.) in this study. The subjects, seated in an upright position at normal room temperature (approx. 22 C), were tested for 60 min. with one of the cooling garments. The LET active garment had an initial coolant fluid inlet temperature of 60 F, and was ramped down to 50 F. Oral, right and left ear canal temperatures were logged manually every 5 min. Arm, leg, chest and rectal temperatures; heart rate; and respiration were recorded continuously on a U.F.I., Inc. Biolog ambulatory monitor. For men, all three vests had similar, significant cooling effects. Decreases in the average rectal temperature, oral temperature, and ear canal temperatures were approximately 0.2 C, 0.2 C and 0.1 C, respectively. In contrast to the men, the female subjects wearing the MCS and Steel vests had similar cooling responses in which the core temperature remained elevated and oral and ear canal temperatures did not drop. The LET active garment cooled most of the female subjects in this study; rectal, oral and ear temperature decreased about 0.2 C, 0.3 C and 0.3 C, respectively. These results show that the garment configurations tested do not elicit a similar thermal response in all subjects. A gender difference is evident. The LET active garment configuration was most effective in decreasing temperatures of the female subjects; the MCS vest was least effective. For male subjects, the three vests appear to be more nearly equivalent. The active garment system under study included a cooling cap, which may account for some of the difference in response.

Ku, Yu-Tsuan E.↗

NASA NTRS1972

Chemical fractionation in iron meteorites and its interpretation.

Published analyses of trace and minor elements in iron meteorites have been compiled and the distributions interpreted with the chemical groups defined by Wasson. When each element is plotted against Ni on log scales, groups are often clearly resolved with all the members of a group falling within the limits of sampling and analytical error on a straight line. Two fractionations have occurred, a primary event which established the bulk composition of each group and a secondary event which fractionated the elements within each group. Group I appears to have escaped the secondary fractionation. An examination of possible fractionation mechanisms suggests that the secondary process took place during solidification of iron cores in the parent bodies. The elements Ir, Os, Pt, Ru and Rh would be enriched in the early Ni-poor solid whilst As, Au, Co, Mo, P, Pd and Sb would concentrate in later solid and produce the observed positive correlations with Ni.-

Scott, E. R. D.↗

NASA NTRS2004

Discovery of Extremely Embedded X-ray Sources in the R Coronae Australis Star Forming Core

We detected three extremely embedded X-ray sources in the R Corona Australis (R CrA) star forming core, IRS 7 region. Two weak X-ray sources are associated with the VLA centimeter radio sources 10E & W, whereas the third brightest source detected in the two XMM-Newton observations on March 2003 has no counterpart at any wavelengths. The large K-band upper-limit (19.4m) measured with the University of Hawaii 88-inch Telescope and strong absorption derived in X-rays (N(sub H) approx. 2.8 x 10(exp 23)/sq cm equivalent to A(sub v) approx. 180 m) indicate that the source is younger than typical Class I protostars, i.e. a Class 0 protostar or an intermittent phase between Class 0 and Class I protostars. The X-ray luminosity was less than one thirtieth (log L(sub x) less than or approx. equals 29.3 ergs/s) in the former Chandra observation in October 2000, which suggests that the X-ray activity, probably generated by magnetic activity, is triggered by an intermittent mass accretion episode such as FU Ori type outbursts. Because the source was detected at high significance in the XMM-Newton observations (approx. 2,000 cnts), X-ray properties of such young protostars can be well investigated for the first time. The light curves were constant in the 1st observation and increased linearly by a factor of two during 30 ksec in the 2nd observation. Both spectra showed iron K lines originated in hot thin-thermal plasma and fluorescence by cold gas. They can be reproduced by an absorbed thin-thermal plasma model with a Gaussian component at 6.4 keV (kT approx. 3-4 keV, L(sub x) approx. 7-20 x 10(exp 30) ergs/s). The rising timescale of the light curves in the 2nd observation was too slow for magnetically generated X-ray flares, whereas large equivalent width of the fluorescence iron K line in the 1st observation (approx. 810 eV) requires strong partial covering of the X-ray source. These results suggest that a confined hot (perhaps accretion) spot on the protostellar core was behind the star in the 1st observation and just appeared in the 2nd observation due to the core rotation with period of greater than or approx. 22.8 days, which is much slower than the break-up velocity previously assumed for young protostars. This means that the source had quiescent X-ray activity during the observations with an order of magnitude stronger level than Class I (older) protostars. We also consider whether the X-ray source associated with 10E could be shock heated plasma by a collision of a jet emanating from the tentative Class 0 object.

Hamaguchi, Ken-Ji↗

NASA NTRS1983

A note on compressibility and energy cascade in turbulent molecular clouds

Observed velocity-size correlations are reexamined in the light of an improved theory of turbulent energy cascade that is developed. It is shown that observed velocity-size correlations cannot be compared with the Kolmogorov law, which is based on incompressible turbulent flow. The fact that the log v-log(l/rho) scaling law (v the turbulent velocity, l the associated region size, and rho the fluid density) predicted for compressible energy cascade is always steeper than that observed in molecular clouds indicates the injection rather than the dissipation of mechanical energy at smaller scales of motion. It is also shown that the concept of strict energy cascade may not be generally applicable in the interstellar medium. The agreement between theory and observation turns out to be best for small cool clouds and cloud cores, suggesting that, for these regions at least, the dominant process in establishing the observed v-l-rho correlation is a turbulent energy cascade.

Fleck, R. C., Jr.↗

NASA NTRS2001

Determining CDOM Absorption Spectra in Diverse Aquatic Environments Using a Multiple Pathlength, Liquid Core Waveguide System

We evaluated the accuracy, sensitivity and precision of a multiple pathlength, liquid core waveguide (MPLCW) system for measuring colored dissolved organic matter (CDOM) absorption in the UV-visible spectral range (370-700 nm). The MPLCW has four optical paths (2.0, 9.8, 49.3, and 204 cm) coupled to a single Teflon AF sample cell. Water samples were obtained from inland, coastal and ocean waters ranging in salinity from 0 to 36 PSU. Reference solutions for the MPLCW were made having a refractive index of the sample. CDOM absorption coefficients, aCDOM, and the slope of the log-linearized absorption spectra, S, were compared with values obtained using a dual-beam spectrophotometer. Absorption of phenol red secondary standards measured by the MPLCW at 558 nm were highly correlated with spectrophotometer values and showed a linear response across all four pathlengths. Values of aCDOM measured using the MPLCW were virtually identical to spectrophotometer values over a wide range of concentrations. The dynamic range of aCDOM for MPLCW measurements was 0.002 - 231.5 m-1. At low CDOM concentrations spectrophotometric aCDOM were slightly greater than MPLCW values and showed larger fluctuations at longer wavelengths due to limitations in instrument precision. In contrast, MPLCW spectra followed an exponential to 600 nm for all samples.

Miller, Richard L.↗

NASA NTRS2000

Determining CDOM Absorption Spectra in Diverse Coastal Environments Using a Multiple Pathlength, Liquid Core Waveguide System. Measuring the Absorption of CDOM in the Field Using a Multiple Pathlength Liquid Waveguide System

We evaluated the accuracy, sensitivity and precision of a multiple pathlength, liquid core waveguide (MPLCW) system for measuring colored dissolved organic matter (CDOM) absorption in the UV-visible spectral range (370-700 nm). The MPLCW has four optical paths (2.0, 9.8, 49.3, and 204 cm) coupled to a single Teflon AF sample cell. Water samples were obtained from inland, coastal and ocean waters ranging in salinity from 0 to 36 PSU. Reference solutions for the MPLCW were made having a refractive index of the sample. CDOM absorption coefficients, a(sub CDOM), and the slope of the log-linearized absorption spectra, S, were compared with values obtained using a dual-beam spectrophotometer. Absorption of phenol red secondary standards measured by the MPLCW at 558 nm were highly correlated with spectrophotometer values (r > 0.99) and showed a linear response across all four pathlengths. Values of a(sub CDOM) measured using the MPLCW were virtually identical to spectrophotometer values over a wide range of concentrations. The dynamic range of a(sub CDOM) for MPLCW measurements was 0.002 - 231.5/m. At low CDOM concentrations (a(sub 370) < 0.1/m) spectrophotometric a(sub CDOM) were slightly greater than MPLCW values and showed larger fluctuations at longer wavelengths due to limitations in instrument precision. In contrast, MPLCW spectra followed an exponential to 600 nm for all samples. The maximum deviation in replicate MPLCW spectra was less than 0.001 absorbance units. The portability, sampling, and optical characteristics of a MPLCW system provide significant enhancements for routine CDOM absorption measurements in a broad range of natural waters.

Miller, Richard L.↗

NASA NTRS2011

A Combined Subaru/VLT/MMT 1-5 Micrometer Study of Planets Orbiting HR 8799: Implications For Atmospheric Properties, Masses and Formation

We present new 1-1.25 micron (z and J band) Subaru/IRCS and 2 micron (K band) VLT/NaCo data for HR 8799 and a rereduction of the 3-5 micron MMT/Clio data first presented by Hinz et al. Our VLT/NaCo data yield a detection of a fourth planet at a projected separation of approximately 15 AU--"HR 8799e ." We also report new, albeit weak detections of HR 8799b at 1.03 micron and 3.3 micron. Empirical comparisons to field brown dwarfs show that at least HR 8799b and HR 8799c, and possibly HR 8799d, have near-to-mid-IR colors/ magnitudes significantly discrepant from the L/T dwarf sequence. Standard cloud deck atmosphere models appropriate for brown dwarfs provide only (marginally) statistically meaningful fits to HR 8799b and c for unphysically small radii. Models with thicker cloud layers not present in brown dwarfs reproduce the planets' spectral energy distributions far more accurately and without the need for resealing the planets' radii. Our preliminary modeling suggests that HR 8799b has log(g) = 4-4.5, T(sub eff) = 900 K. while HR 8799c, d, and (by inference) e have log(g) = 4-4.5, T(sub eff) = 1000-1200 K. Combining results from planet evolution models and new dynamical stability limits implies that the masses of HR 8799b, c, d, and e are 6-7 M(sub j), 7-10 M(sub j), 7-10 M(sub j), and 7-10 M(sub j). "Patchy" cloud prescriptions may provide even better fits to the data and may lower the estimated surface gravities and masses. Finally, contrary to some recent claims, forming the HR 8799 planets by core accretion is still plausible, although such systems are likely rare.

Currie, Thayne↗

NASA NTRS1993

The distance to the Large Magellanic Cloud - Constraints from Cepheids in Large Magellanic Cloud star clusters

We have used recent observational data for the Cepheids in the rich, young LMC clusters NGC 1866 and NGC 2031 to constrain the cluster distances with the mass-equivalency (ME) method. The basis of this approach is to fix the cluster distances by requiring the Cepheid evolutionary and pulsational masses to be equal. Using evolutionary models incorporating a mild amount of core and envelope overshooting along with recent pulsational models, we derive distance moduli of 18.51 +/- 0.21 and 18.32 +/- 0.20 for NGC 1866 and NGC 2031, respectively. The quoted errors are dominated by the uncertainties in the heavy element abundances of the clusters (assumed to be 0.3 dex for both clusters), with a smaller contribution due to the apparently intrinsic spread in the masses of the Cepheids in each cluster. For the ME method, we find that Delta(m-M)(0)/Delta sub Z(1) = 0.69, where Z(1) = log (Z/0.016). This result implies that the cluster distances can be determined to better than +/- 5 percent if the cluster abundances can be measured to better than about +/- 0.15 dex.

Bertelli, Gianpaolo↗

NASA NTRSDate not supplied

cFS Test Framework (CTF)

NASA's Core Flight System (cFS) provides a generic flight software framework architecture for developing flight software. As the cFS framework has gained popularity over the years within the flight software community, supporting software tools have been developed to assist in the design, development, testing and verification of flight software. The cFS Test Framework (CTF) is a recently developed cFS tool with capabilities to develop and run automated test and verification scripts against flight software targets. The CTF tool parses and executes JSON-based test scripts containing test instructions, while logging and reporting the results. CTF utilizes a plugin-based architecture to allow developers to extend CTF with new test instructions, external interfaces, and custom functionality. To interface with flight software, CTF parses a set of CCSDS message definition files to create the necessary command and telemetry structures for use during the test run. Additionally, CTF also supports interfacing with multiple cFS instances, allowing a test script to verify requirements that involve multiple flight software targets. Lastly, CTF provides support for executing test scripts against FSW running on remote or embedded hardware. This allows CTF to execute the same test scripts across different target configurations throughout the development process. In this presentation, we will introduce the cFS Test Framework (CTF) architecture, discuss the history of cFS testing frameworks, and present the features and capabilities currently provided by CTF. Lastly, we will show a demo of the CTF tool being used to execute test scripts against flight software.

Aly I Shehata↗

NASA NTRSDate not supplied

CFS Test Framework

cfs↗

NASA NTRS2012

Active Region Moss: Doppler Shifts from Hinode/EIS Observations

Studying the Doppler shifts and the temperature dependence of Doppler shifts in moss regions can help us understand the heating processes in the core of the active regions. In this paper we have used an active region observation recorded by the Extreme-ultraviolet Imaging Spectrometer (EIS) onboard Hinode on 12-Dec- 2007 to measure the Doppler shifts in the moss regions. We have distinguished the moss regions from the rest of the active region by defining a low density cut-off as derived by Tripathi et al. (2010). We have carried out a very careful analysis of the EIS wavelength calibration based on the method described in Young, O Dwyer and Mason (2012). For spectral lines having maximum sensitivity between log T = 5.85 and log T = 6.25 K, we find that the velocity distribution peaks at around 0 km/s with an estimated error of 4 km/s. The width of the distribution decreases with temperature. The mean of the distribution shows a blue shift which increases with increasing temperature and the distribution also shows asymmetries towards blue-shift. Comparing these results with observables predicted from different coronal heating models, we find that these results are consistent with both steady and impulsive heating scenarios. Further observational constraints are needed to distinguish between these two heating scenarios.

Tripathi, Durgesh↗

NASA NTRS1995

Far-ultravoilet and optical spectrscopy of the detached white dwarf-M binary RE J1629+780

We present optical and far-ultraviolet observations, including IUE high- and low-dispersion spectroscopy, of the (DA2+dM4-5) close binary, RE J1629+780, a very bright ROSAT EUV source. The optical data reveal emission reversals in the cores of the Balmer lines, which vary in strength but reveal no evidence of wavelength shifts reflecting orbital motion, suggesting that the red dwarf and the white dwarf are widely separated. Thus it is unlikely that irradiation plays a dominant role in the activity of the red dwarf. One dramatic increase in the intensity of the H-beta emission strength in the course of one hour indicates that the observed intensity variations are most likely related to flare activity on the red dwarf. Our analysis of Balmer and Lyman alpha features yield T(sub eff) = 42,500 +/- 1300 K and log g = 7.6 +/- 0.3 for the DA2 white dwarf, which is consistent with the overall 900 to 3200 A energy distribution derived from Voyager and IUE low-dispersion spectra. Our analysis of three IUE echelle spectra reveal numerous lines of interstellar origin. Using a total of 13 interstellar matter (ISM) features we find a mean radial velocity of -13.57 +/- 1.66 km/s for the interstellar features. However, we found no evidence of trace metal absorbers levitated or accreted in the white-dwarf photosphere nor any evidence of circumstellar or wind features. We estimate a lower limit hydrogen layer mass of 2.1 x 10(exp -15) solar mass for a stratified atmosphere based upon the nondetection of He II (1640). Tighter constraints on the helium abundance and the hydrogen layer mass, from EUV and X-ray data, are presented for both homogeneous and stratified atmospheric configurations.

Sion, Edward M.↗

NASA NTRS2020

Comparison of Raindrop Size Distribution between NASA’s S-Band Polarimetric Radar and Two-Dimensional Video Disdrometers

The ground-based-radar-derived raindrop size distribution (DSD) parameters—mass-weighted drop diameter Dmass and normalized intercept parameter NW—are the sole resource for direct validation of the National Aeronautics and Space Administration (NASA) Global Precipitation Measurement (GPM) mission Core Observatory satellite-based retrieved DSD. Both Dmass and NW are obtained from radar-measured reflectivity ZH and differential reflectivity ZDR through empirical relationships. This study uses existing relationships that were determined for the GPM ground validation (GV) program and directly compares the NASA S-band polarimetric radar (NPOL) observables of ZH and ZDR and derivedDmass and NW with those calculated by two-dimensional video disdrometer (2DVD). The joint NPOL and 2DVD datasets were acquired during three GPM GV field campaigns conducted in eastern Iowa, southern Appalachia, and western Washington State. The comparative study quantifies the level of agreement for ZH, ZDR, Dmass, and log(NW) at an optimum distance (15–40 km) from the radar as well as at distances greater than 60 km from radar and over mountainous terrain. Interestingly, roughly 10%–15% of the NPOL ZH–ZDR pairs were well outside the envelope of 2DVD-estimated ZH–ZDR pairs. The exclusion of these pairs improved the comparisons noticeably.

Ali Tokay↗

NASA NTRS1999

Physiologic and thermal responses of male and female patients with multiple sclerosis to head and neck cooling

Personal cooling systems are used to alleviate symptoms of multiple sclerosis and to prevent increased core temperature during daily activities. The objective of this study was to determine the thermal and physiologic responses of patients with multiple sclerosis to short-term maximal head and neck cooling. A Life Support Systems, Inc. Mark VII portable cooling system and a liquid cooling helmet were used to cool the head and neck regions of 24 female and 26 male patients with multiple sclerosis in this study. The subjects, seated in an upright position at normal room temperature (approximately 22 degrees C), were cooled for 30 min by the liquid cooling garment, which was operated at its maximum cooling capacity. Oral, right, and left ear temperatures and cooling system parameters were logged manually every 5 min. Forearm, calf, chest, and rectal temperatures, heart rate, and respiration rate were recorded continuously on a U.F.I., Inc. Biolog ambulatory monitor. This protocol was performed during the winter and summer to investigate the seasonal differences in the way patients with multiple sclerosis respond to head and neck cooling. No significant differences were found between the male and female subject group's mean rectal or oral temperature responses during any phase of the experiment. The mean oral temperature decreased significantly (P < 0.05) for both groups approximately 0.3 degrees C after 30 min of cooling and continued to decrease further (approximately 0.1-0.2 degrees C) for a period of approximately 15 min after removal of the cooling helmet. The mean rectal temperatures decreased significantly (P < 0.05) in both male and female subjects in the winter studies (approximately 0.2-0.3 degrees C) and for the male subjects during the summer test (approximately 0.2 degrees C). However, the rectal temperature of the female subjects did not change significantly during any phase of the summer test. These data indicate that head and neck cooling may, in general, be used to reduce the oral and body temperatures of both male and female patients with multiple sclerosis by the approximate amount needed for symptomatic relief as shown by other researchers. However, thermal response of patients with multiple sclerosis may be affected by gender and seasonal factors, which should be considered in the use of liquid cooling therapy.

NASA Discipline Environmental Health↗

NASA NTRS2020

Comparison of Raindrop Size Distribution between NASA's S-Band Polarimetric Radar and Two-Dimensional Video Disdrometers

The ground-based-radar-derived raindrop size distribution (DSD) parameters—mass-weighted drop diameter D mass and normalized intercept parameter NW—are the sole resource for direct validation of the National Aeronautics and Space Administration (NASA) Global Precipitation Measurement (GPM ) mission Core Observatory satellite-based retrieved DSD. Both D mass and NW are obtained from radar-measured reflectivity Z Hand differential reflectivity ZDR through empirical relationships. This study uses existing relationships that were determined for the GPM ground validation (GV) program and directly compares the NASA S-band polarimetric radar (NPOL) observables of Z Hand Z DR and derived D mass and NW with those calculated by two-dimensional video disdrometer (2DVD). The joint NPOL and 2DVD datasets were acquired during three GPM GV field campaigns conducted in eastern Iowa, southern Appalachia, and western Washington State. The comparative study quantifies the level of agreement for ZH, ZDR, D mass, and log (NW) at an optimum distance (15–40 km) from the radar as well as at distances greater than 60 km from radar and over mountainous terrain. Interestingly, roughly 10%–15% of the NPOLZH–Z DR pairs were well outside the envelope of 2DVD-estimatedZH–Z DR pairs. The exclusion of these pairs improved the comparisons noticeably.

Ali Tokay↗

NASA NTRS2012

Fault Tolerance Middleware for a Multi-Core System

Fault Tolerance Middleware (FTM) provides a framework to run on a dedicated core of a multi-core system and handles detection of single-event upsets (SEUs), and the responses to those SEUs, occurring in an application running on multiple cores of the processor. This software was written expressly for a multi-core system and can support different kinds of fault strategies, such as introspection, algorithm-based fault tolerance (ABFT), and triple modular redundancy (TMR). It focuses on providing fault tolerance for the application code, and represents the first step in a plan to eventually include fault tolerance in message passing and the FTM itself. In the multi-core system, the FTM resides on a single, dedicated core, separate from the cores used by the application. This is done in order to isolate the FTM from application faults and to allow it to swap out any application core for a substitute. The structure of the FTM consists of an interface to a fault tolerant strategy module, a responder module, a fault manager module, an error factory, and an error mapper that determines the severity of the error. In the present reference implementation, the only fault tolerant strategy implemented is introspection. The introspection code waits for an application node to send an error notification to it. It then uses the error factory to create an error object, and at this time, a severity level is assigned to the error. The introspection code uses its built-in knowledge base to generate a recommended response to the error. Responses might include ignoring the error, logging it, rolling back the application to a previously saved checkpoint, swapping in a new node to replace a bad one, or restarting the application. The original error and recommended response are passed to the top-level fault manager module, which invokes the response. The responder module also notifies the introspection module of the generated response. This provides additional information to the introspection module that it can use in generating its next response. For example, if the responder triggers an application rollback and errors are still occurring, the introspection module may decide to recommend an application restart.

Some, Raphael R.↗

NASA NTRS2004

Determining the Oxygen Fugacity of Lunar Pyroclastic Glasses Using Vanadium Valence - An Update

We have been developing an oxygen barometer based on the valence state of V (V(2+), V(3+), V(4+), and V(5+)) in solar system basaltic glasses. The V valence is determined by synchrotron micro x-ray absorption near edge structure (XANES), which uses x-ray absorption associated with core-electronic transitions (absorption edges) to reveal a pre-edge peak whose intensity is directly proportional to the valence state of an element. XANES has advantages over other techniques that determine elemental valence because measurements can be made non-destructively in air and in situ on conventional thin sections at a micrometer spatial resolution with elemental sensitivities of approx. 100 ppm. Recent results show that fO2 values derived from the V valence technique are consistent with fO2 estimates determined by other techniques for materials that crystallized above the IW buffer. The fO2's determined by V valence (IW-3.8 to IW-2) for the lunar pyroclastic glasses, however, are on the order of 1 to 2.8 log units below previous estimates. Furthermore, the calculated fO2's decrease with increasing TiO2 contents from the A17 VLT to the A17 Orange glasses. In order to investigate these results further, we have synthesized lunar green and orange glasses and examined them by XANES.

Karner, J. M.↗