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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Comparative assessment of new oxygen carrier materials for gas switching reforming of natural gas: Techno-economics assessment, life cycle analysis, and experimental insights

The increasing demand for hydrogen and the CO 2 intensity of natural gas (NG) reforming motivate the development of low-carbon-emission hydrogen production technologies. Gas Switching Reforming (GSR) with integrated CO 2 capture, a technology based on Chemical Looping Reforming (CLR), has been experimentally proven and shows potential for scale-up. In this study, select oxygen carriers (OC) (NiO/Al 2 O 3 , Fe 2 O 3 -CeO 2 /Al 2 O 3 , and magnetite) were tested in methane steam reforming in a fixed bed reactor to determine their relative reactivities under relevant conditions for GSR (800 °C, 7 bar total pressure). Process models were then developed to perform techno-economic analysis (TEA) of GSR for hydrogen production (GSR-H 2 ) and a combined cycle (GSR-CC) in which high-purity H 2 is fired in a gas turbine to produce electricity. Operating at 10 bar and 1100 °C and with the additional recovery steps implemented increased H 2 production by ∼ 30% and improved efficiency relative to prior studies. For GSR-H 2 , the levelized cost of hydrogen (LCOH) is 1.61–1.64 $/kg-H 2 , competitive with a reference SMR case, though operating and maintenance costs are higher due to increased electricity demand. GSR-CC has a significantly higher levelized cost of electricity (LCOE) than its reference NGCC (natural gas combined cycle) plant, suggesting it is less competitive; however, increasing production scale could make it more attractive. Life-cycle results for GSR-H 2 indicate NG consumption drives ∼ 75% of total global warming impacts (∼2.3 kg CO 2 eq/kg H 2 ). An environmental, health, and safety screening suggests iron-based carriers are comparatively safer, whereas NiO may pose greater risks. Overall, GSR-H 2 is a scalable, competitive option for hydrogen production using nickel and non-nickel OC.

03 NATURAL GAS

U.S. Average Corn Ethanol Production Baseline for 45Q Life Cycle Analysis Version 1.0 (2018-2022)

U.S. Average Benchmark life cycle inventory documentation for ethanol production for calendar years 2018 - 2022. The documentation includes a technical report describing data sources and statistical methods used and an Excel file showing calculations. The calculations performed are used in the 45Q benchmark json-ld dataset, compatible with the NETL CO2U LCA Guidance Toolkit. Summary impact results will be included in the NETL CO2U LCA Documentation Spreadsheet within the Toolkit. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=55ab21f1-9238-4b63-9a7a-ae1a4cfa7b05.

09 BIOMASS FUELS

U.S. Average Market Carbon Dioxide Production Baseline Documentation For 45Q Life Cycle Analysis: Version 1.0 (2018-2022)

U.S. Average Benchmark life cycle inventory documentation for market carbon dioxide production for calendar years 2018 - 2022. The documentation includes a technical report describing data sources and statistical methods used and an Excel file showing calculations. The calculations performed are used in the 45Q benchmark json-ld dataset, compatible with the NETL CO2U LCA Guidance Toolkit. Summary impact results will be included in the NETL CO2U LCA Documentation Spreadsheet within the Toolkit. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=21915ba8-d2cf-43ea-b9b2-1d76363a46a7

29 ENERGY PLANNING, POLICY, AND ECONOMY

Cooled Gas Turbine and Combined Cycle Analysis for NH 3 -CH 4 Fuel Mixes (Up to 100% NH 3 )

In this study, a cooled gas turbine (GT) analysis was conducted for varying levels of ammonia (NH 3 ) blends with methane. The ultimate goal is to have a gas turbine design that can be used for all the fuel blends (including 100% NH 3 ) without any changes to the system. The technological developments in the cooling system, gas turbine design, and materials that will be required for NH 3 combustion were identified and analyzed in this study to develop an advanced gas turbine design for NH 3 fuels. The study includes a combined cycle performance analysis with the NH 3 fuel blends using the advanced gas turbine design developed in this study. A techno-economic analysis was conducted for analyzing the impact of the NH 3 fuels on the levelized cost of electricity and cost sensitivities to fuel price and capacity factor.

20 FOSSIL-FUELED POWER PLANTS

Life Cycle Analysis of Enhanced Rock Weathering

This study aims to evaluate the life cycle impacts of weathering agricultural fields in the U.S. Midwest with igneous rock (dunite/olivine) and industrial waste minerals using literature and estimated data from a techno-economic analysis (TEA). The GWP impact with igneous rock and industrial waste materials ranges 34–263 and 23–180 kg CO2-eq/tonne CO2 sequestered, respectively, with comminution and transportation as the main environmental hotspots for igneous rock, and transportation for industrial waste.

Izar-Tenorio, Jorge

A Life Cycle Analysis Framework for Point Source Capture Systems

NETL studies the costs and benefits of PSC for electricity, industry, and mobile applications. Mobile point source capture (MPSC) and storage applied to freight modes captures emissions directly from exhaust. This poster presents a framework for conducting LCA of PSC systems applied to heavy-duty trucks, freight trains, and marine vessels. The framework defines a wheels-to-storage (gate-to-grave) boundary, including energy demands (electricity, heat, and cooling requirements), solvent use and cycling, onboard system components, carbon storage in a saline aquifer, and upstream manufacturing impacts for equipment, with a suggested functional unit of 1 tonne-km. Potential data sources for analysis include material, energy, and operational data from Oak Ridge National Laboratory, GREET (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) model, and scientific literature. The suggested analytical approach includes comparison to publicly available business-as-usual systems without capture across all modes of transportation, sensitivity to composition of the capture solvent, and sensitivity to capture rate variation, all of which would support a wholistic PSC business case analysis. For future consideration, analysis can be augmented with consideration of different sources of electricity (e.g., nuclear), fuel substitution, deploying supportive infrastructure such as pipeline offloading points, and downstream applications like enhanced oil recovery (EOR).

life cycle analysis (LCA)

A study of dynamic energy equations for Stirling cycle analysis

An analytical and computer study of the dynamic energy equations that describe the physical phenomena that occurs in a Stirling cycle engine. The basic problem is set up in terms of a set o hyperbolic partial differential equations. The characteristic lines are determined. The equations are then transformed to ordinary differential equations that are valid along characteristic lines. Computer programs to solve the differential equations and to plot pertinent factors are described.

Larson, V. H.

Life Cycle Analysis of Greenhouse Gas Emissions of Clean Fuels with the R&D GREET 2024 Model

This document summarizes research on the life cycle greenhouse gas (GHG) emissions rates from the production and use of clean fuels to support a new version of the Research and Development Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (R&D GREET) model, R&D GREET 2024 In this effort, Argonne National Laboratory (ANL) focuses on clean fuel pathways that are readily available in the market or are emerging in the near term. The selected pathways represent clean fuel technologies that convert biomass- and/or waste-based feedstocks to liquid and/or gaseous fuels for the transportation sector and other potential uses. The pathways are configured in R&D GREET 2024 with up-to-date feedstock-to-fuel life cycle inventory (LCI) data. Additionally, a new tab has been added to R&D GREET 2024 called “Clean Fuels” which allows the user to easily change inputs and access LCA results. Argonne does not warrant that the results presented in this report are consistent with the requirements of any particular regulatory or incentive program. Users interested in specific programs that reference GREET are encouraged to review guidance specific to those programs if and when it is available to determine appropriate means of compliance and contact the relevant responsible agencies for those specific policies or programs.

09 BIOMASS FUELS

A thermochemical data bank for cycle analysis

The use of a computer program PAC-2 to produce a thermodynamic data bank for various materials used in water splitting cycles is described. The sources of raw data and a listing of 439 materials for which data are available are presented. The use of the data bank in conjunction with two other programs, CEC-72 and HYDRGN, is also discussed. The integration of these three programs implement an evaluation procedure for thermochemical water splitting cycles. CEC-72 is a program used to predict the equilibrium composition of the various chemical reactions in the cycle. HYDRGN is a program which is used to calculate changes in thermodynamic properties, work of separation, amount of recycle, internal heat regeneration, total thermal energy, and process thermal efficiency for a thermochemical cycle.

Carty, R. H.

A thermochemical data bank for cycle analysis

The use of the computer program PAC-2 to produce a thermodynamic data bank for various materials used in water-splitting cycles is described. The sources of raw data and a listing of 439 materials for which data are presently available are presented. This paper also discusses the use of the data bank in conjunction with two other programs, CEC-72 and HYDRGN. The integration of these three programs implement an evaluation procedure for thermochemical water splitting cycles. CEC-72 is a program used to predict the equilibrium composition of the various chemical reactions in the cycle. HYDRGN is a program which is used to calculate changes in thermodynamic properties, work of separation, amount of recycle, internal heat regeneration, total thermal energy and process thermal efficiency for a thermochemical cycle.

Carty, R.

Upconversion of non-recycled MSW paper fractions into biochar via slow pyrolysis and life cycle analysis: Pathways to net negative GHG emission

This study presents an integrated and sustainable approach to valorizing non-recycled municipal solid waste (MSW), a heterogeneous and underutilized waste stream destined for landfilling, by converting it into valuable biochar resources. Specifically, we investigated the upcycling of nonrecycled paper waste based on compositional analysis into four major fractions: high cellulose, high lignin, high contamination, and high ash content papers. These fractions were then homogenized and subjected to slow pyrolysis. The high cellulose fraction (36.1 %) was the most abundant, and contained 66.7 % cellulose, while the high lignin fraction showed the highest lignin (12.1 %) and carbon content (44 %), resulting in highest energy value of 17.4 MJ kg −1 . Biochar yields ranged from 25.6 % to 35.6 %, with the high ash fraction producing the highest yield and alkalinity (pH ≈ 11.2) due to its higher mineral content. Elemental analysis revealed enhanced carbon content up to 76.9 % and reduced oxygen and hydrogen, confirming effective carbonization. The high lignin-derived biochar showed the highest aromatic carbon content (82.8 %) and greater structural stability, while contaminated and ash-rich fractions exhibited dense, low-porosity surfaces due to the presence of contaminants and minerals. Spectroscopic analysis revealed degradation of carbohydrates, disappearance of cellulose peaks and formation of aromatic and mineral derived phases. The scaled life cycle process yielded a global warming potential (GWP) of 119.3 kg CO 2 -eq per ton of dry paper waste, offset by soil carbon sequestration of − 556.41 kg CO 2 -eq, resulting in a net impact of − 427.36 kg CO 2 -eq. This represents a net carbon removal exceeding by ~186 % the emissions associated with landfilling paper waste with electricity generation.

09 BIOMASS FUELS

Environmental life-cycle analysis of hydrogen technology pathways in the United States

Hydrogen is a zero-carbon energy carrier with potential to decarbonize industrial and transportation sectors, but its life-cycle greenhouse gas (GHG) emissions depend on its energy supply chain and carbon management measures (e.g., carbon capture and storage). Global support for clean hydrogen production and use has recently intensified. In the United States, Congress passed several laws that incentivize the production and use of renewable and low-carbon hydrogen, such as the Bipartisan Infrastructure Law (BIL) in 2021 and the Inflation Reduction Act (IRA) in 2022, which provides tax credits of up to $3/kg depending on the carbon intensity of the produced hydrogen. A comprehensive life-cycle accounting of GHG emissions associated with hydrogen production is needed to determine the carbon intensity of hydrogen throughout its value chain. In the United States, Argonne’s R&D GREET ® (Greenhouse Gases, Regulated emissions, and Energy use in Technologies) model has been widely used for hydrogen carbon intensity calculations. This paper describes the major hydrogen technology pathways considered in the United States and provides data sources and carbon intensity results for each of the hydrogen production and delivery pathways using consistent system boundaries and most recent technology performance and supply chain data.

Elgowainy, Amgad

Life-Cycle Analysis of Residential Windows Retrofits: Net GHG Emission Reduction and Payback Periods

Windows are a critical envelope component that plays an important role in the overall performance and environmental impact of a building life cycle. These implications can be embedded in the window lifecycle related to its design, manufacturing, raw materials and transportation, performance during the building’s use (operational), replacements, maintenance and end-of-life. Windows may impact 25% of the heating and cooling energy use, 10% of total building energy use and 45% of the envelope heat transfer (Harris 2022). The impacts of windows on the energy consumption of buildings have been extensively discussed, however, its embodied life-cycle impacts, such as greenhouse gas (GHG) emissions, and the trade-offs between the embodied and its operational emissions are less explored. Understanding the life cycle impacts of windows may subsidize decision making process and inform the development of emerging windows technologies. BTO’s Windows Program has played an important role to increase the adoption of emerging technologies as high-performance windows in the U.S. (Harris 2022) and to consider the GHG emission impacts of the those windows is an important aspect that can support the strategic objectives and the performance targets from the national blueprint for decarbonizing the buildings sector and to reduce the on-site emissions and embodied life cycle emissions from building materials and construction (US DOE 2024).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI

Life cycle analysis of hydrogen production via methane pyrolysis using plasma arc

Steam methane reforming of natural gas is the primary method of producing hydrogen in the United States, accounting for 95% of all hydrogen produced there. Methane pyrolysis, an alternative production pathway that decomposes natural gas into solid carbon and hydrogen, both eliminates CO 2 emissions associated with methane reforming and allows for additional income from carbon black. A life-cycle inventory of this process has been developed using ASPEN Plus to model the methane pyrolysis (plasma arc) process. From well to gate, hydrogen production via methane pyrolysis produces 2.78 kg CO 2 e/kg H 2 of greenhouse gas emissions using mass allocation of emissions between hydrogen and carbon black coproducts. The well-to-gate emissions are mainly driven by electricity consumption (∼38 kW h/kg H 2 ), which accounts for 81% of the emissions; if renewable electricity is used, well-to-gate emissions can be reduced to −0.448 kg CO 2 e/kg H 2 .

08 HYDROGEN

Chaos in the sunspot cycle - Analysis and prediction

The variability of solar activity over long time scales, given semiquantitatively by measurements of sunspot numbers, is examined as a nonlinear dynamical system. First, a discussion of the data set used and the techniques utilized to reduce the noise and capture the long-term dynamics inherent in the data is presented. Subsequently, an attractor is reconstructed from the data set using the method of time delays. The reconstructed attractor is then used to determine both the dimension of the underlying system and also the largest Lyapunov exponent, which together indicate that the sunspot cycle is indeed chaotic and also low dimensional. In addition, recent techniques of exploiting chaotic dynamics to provide accurate, short-term predictions are utilized in order to improve upon current forecasting methods and also to place theoretical limits on predictability extent. The results are compared to chaotic solar-dynamo models as a possible physically motivated source of this chaotic behavior.

Mundt, Michael D.

Thermodynamic Cycle Analysis of Magnetohydrodynamic-Bypass Airbreathing Hypersonic Engines

Established analyses of conventional ramjet/scramjet performance characteristics indicate that a considerable decrease in efficiency can be expected at off-design flight conditions. This can be explained, in large part, by the deterioration of intake mass flow and limited inlet compression at low flight speeds and by the onset of thrust degradation effects associated with increased burner entry temperature at high flight speeds. In combination, these effects tend to impose lower and upper Mach number limits for practical flight. It has been noted, however, that Magnetohydrodynamic (MHD) energy management techniques represent a possible means for extending the flight Mach number envelope of conventional engines. By transferring enthalpy between different stages of the engine cycle, it appears that the onset of thrust degradation may be delayed to higher flight speeds. Obviously, the introduction of additional process inefficiencies is inevitable with this approach, but it is believed that these losses are more than compensated through optimization of the combustion process. The fundamental idea is to use MHD energy conversion processes to extract and bypass a portion of the intake kinetic energy around the burner. We refer to this general class of propulsion system as an MHD-bypass engine. In this paper, we quantitatively assess the performance potential and scientific feasibility of MHD-bypass airbreathing hypersonic engines using ideal gasdynamics and fundamental thermodynamic principles.

Litchford, Ron J.