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Results for “DIFFERENTIAL THERMAL ANALYZER”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

A two-dimensional thermal analysis of a new high-performance tubular solar collector

The first of two articles are presented which describe and analyze the thermal performance of a vacuum tube solar collector. The assumptions and mathematical modeling are presented. The problem is reduced to the formulation of two simultaneous linear differential equations characterizing the collector thermal behavior. After applying the boundary conditions, a general solution is obtained which is found similar to the general Hottel, Whillier and Bliss form but with a complex flow factor.

Lansing, F. L.↗
NASA NTRS1981

Analysis of a high-performance tubular solar collector

This article analyzes the thermal performance of a new vacuum tube solar collector. The assumptions and mathematical modeling are presented. The problem is reduced to the formulation of two simultaneous linear differential equations characterizing the collector thermal behavior. After applying the boundary conditions, a general solution is obtained which is found similar to the general Hottel, Whillier and Bliss form, but with a complex flow factor. The details of the two-dimensional thermal model of the solar collector at steady state is also presented to include the computer simulation and the performance parameterization. Comparison of the simulated performance with the manufacturer's test data showed good agreement at wide ranges of operating conditions.

Lansing, F. L.↗
NASA NTRS1997

Temperature Distribution in a Composite of Opaque and Semitransparent Spectral Layers

The analysis of radiative transfer becomes computationally complex for a composite when there are multiple layers and multiple spectral bands. A convenient analytical method is developed for combined radiation and conduction in a composite of alternating semitransparent and opaque layers. The semi- transparent layers absorb, scatter, and emit radiation, and spectral properties with large scattering are included. The two-flux method is used, and its applicability is verified by comparison with a basic solution in the literature. The differential equation in the two-flux method Is solved by deriving a Green's function. The solution technique is applied to analyze radiation effects in a multilayer zirconia thermal barrier coating with internal radiation shields for conditions in an aircraft engine combustor. The zirconia radiative properties are modeled by two spectral bands. Thin opaque layers within the coating are used to decrease radiant transmission that can degrade the zirconia insulating ability. With radiation shields, the temperature distributions more closely approach the opaque limit that provides the lowest metal wall temperatures.

Siegel, Robert↗
NASA NTRS2009

Stability of Detached Solidification

Bridgman crystal growth can be conducted in the so-called "detached" solidification regime, where the growing crystal is detached from the crucible wall. A small gap between the growing crystal and the crucible wall, of the order of 100 micrometers or less, can be maintained during the process. A meniscus is formed at the bottom of the melt between the crystal and crucible wall. Under proper conditions, growth can proceed without collapsing the meniscus. The meniscus shape plays a key role in stabilizing the process. Thermal and other process parameters can also affect the geometrical steady-state stability conditions of solidification. The dynamic stability theory of the shaped crystal growth process has been developed by Tatarchenko. It consists of finding a simplified autonomous set of differential equations for the radius, height, and possibly other process parameters. The problem then reduces to analyzing a system of first order linear differential equations for stability. Here we apply a modified version of this theory for a particular case of detached solidification. Approximate analytical formulas as well as accurate numerical values for the capillary stability coefficients are presented. They display an unexpected singularity as a function of pressure differential. A novel approach to study the thermal field effects on the crystal shape stability has been proposed. In essence, it rectifies the unphysical assumption of the model that utilizes a perturbation of the crystal radius along the axis as being instantaneous. It consists of introducing time delay effects into the mathematical description and leads, in general, to stability over a broader parameter range. We believe that this novel treatment can be advantageously implemented in stability analyses of other crystal growth techniques such as Czochralski and float zone methods.

Mazuruk, K.↗
NASA NTRS1984

Crystallization of calcia-gallia-silica glasses

A thermal image furance is presently used to study the critical cooling rate for glass formation, and the kinetics of crystallization, of the compositions 18.4CaO-(81.6-X)Ga2O3-XSiO2, where X = 3, 6, 9, and 13.8. Crystallization was studied nonisothermally, and the data were analyzed in light of the Avrami (1939) equation. Critical cooling rate and crystallization activation energy are both found to decrease with increasing silica content, and the results obtained by the present technique are noted to agree with those obtained on the basis of differential thermal analysis measurements.

Ray, C. S.↗
NASA NTRS1993

Thermal Analyzer for Planetary Soil (TAPS): an in Situ Instrument for Mineral and Volatile-element Measurements

Thermal Analyzer for Planetary Soil (TAPS) offers a specific implementation for the generic thermal analyzer/evolved-gas analyzer (TA/EGA) function included in the Mars Environmental Survey (MESUR) strawman payload; applications to asteroids and comets are also possible. The baseline TAPS is a single-sample differential scanning calorimeter (DSC), backed by a capacitive-polymer humidity sensor, with an integrated sampling mechanism. After placement on a planetary surface, TAPS acquires 10-50 mg of soil or sediment and heats the sample from ambient temperature to 1000-1300 K. During heating, DSC data are taken for the solid and evolved gases are swept past the water sensor. Through ground based data analysis, multicomponent DSC data are deconvolved and correlated with the water release profile to quantitatively determine the types and relative proportions of volatile-bearing minerals such as clays and other hydrates, carbonates, and nitrates. The rapid-response humidity sensors also achieve quantitative analysis of total water. After conclusion of soil-analysis operations, the humidity sensors become available for meteorology. The baseline design fits within a circular-cylindrical volume less than 1000 cm(sup 3), occupies 1.2 kg mass, and consumes about 2 Whr of power per analysis. Enhanced designs would acquire and analyze multiple samples and employ additional microchemical sensors for analysis of CO2, SO2, NO(x), and other gaseous species. Atmospheric pumps are also being considered as alternatives to pressurized purge gas.

Gooding, J. L.↗
NASA NTRS1980

Systems improved numerical differencing analyzer

Program solves physical problems governed by diffusion-type equations, provided that equations can be modeled by lumped-parameter representation. Program is used for thermal analysis, and could be adapted to solve Fourier, Poisson, and Laplace differential equations. Program is in FORTRAN IV and Assembler for execution on UNIVAC 1100-series or CYBER 175.

Source record↗
NASA NTRS1981

Longwave infrared observation of urban landscapes

An investigation is conducted regarding the feasibility to develop improved methods for the identification and analysis of urban landscapes on the basis of a utilization of longwave infrared observations. Attention is given to landscape thermal behavior, urban thermal properties, modeled thermal behavior of pavements and buildings, and observed urban landscape thermal emissions. The differential thermal behavior of buildings, pavements, and natural areas within urban landscapes is found to suggest that integrated multispectral solar radiant reflectance and terrestrial radiant emissions data will significantly increase potentials for analyzing urban landscapes. In particular, daytime satellite observations of the considered type should permit better identification of urban areas and an analysis of the density of buildings and pavements within urban areas. This capability should enhance the utility of satellite remote sensor data in urban applications.

Goward, S. N.↗
NASA NTRS1987

A comparison of adiabatic and diabatic forcing in an intense extratropical cyclone system

The roles of adiabatic and diabatic forcings in the development of a cyclone are examined. The two types of height tendency equations (classical quasi-geostrophic and extended forms) employed to solve for height tendency are described. The extended equation, in which geostrophic wind is replaced with observed wind, the effects of diabatic heating are added, and three-dimensional varying static stability is permitted, is utilized to analyze the evolution of the January 9-11, 1975 cyclone event. The analysis reveals that vorticity advection has a primary effect on the movement and propagation of the wave system; the differential thermal advection has a secondary, but significant role in wave development; latent heating effects are minimal; and the vertical advection of static stability slows the propagation and development of the wave.

Tsou, Chih-Hua↗
NASA NTRS2010

Thermal and Evolved Gas Analysis of Calcite Under Reduced Operating Pressures: Implications for the 2011 MSL Sample Analysis at Mars (SAM) Instrument

The Mars Science Laboratory (MSL) is scheduled for launch in 2011. The science objectives for MSL are to assess the past or present biological potential, to characterize the geology, and to investigate other planetary processes that influence habitability at the landing site. The Sample Analysis at Mars (SAM) is a key instrument on the MSL payload that will explore the potential habitability at the landing site [1]. In addition to searching for organic compounds, SAM will have the capability to characterized evolved gases as a function of increasing temperature and provide information on the mineralogy of volatile-bearing phases such as carbonates, sulfates, phyllosilicates, and Fe-oxyhydroxides. The operating conditions in SAM ovens will be maintained at 30 mb pressure with a He carrier gas flowing at 1 sccm. We have previously characterized the thermal and evolved gas behaviors of volatile-bearing species under reduced pressure conditions that simulated operating conditions of the Thermal and Evolved Gas Analyzer (TEGA) that was onboard the 2007 Mars Phoenix Scout Mission [e.g., 2-8]. TEGA ovens operated at 12 mb pressure with a N2 carrier gas flowing at 0.04 sccm. Another key difference between SAM and TEGA is that TEGA was able to perform differential scanning calorimetry whereas SAM only has a pyrolysis oven. The operating conditions for TEGA and SAM have several key parameter differences including operating pressure (12 vs 30 mb), carrier gas (N2 vs. He), and carrier gas flow rate (0.04 vs 1 sccm). The objectives of this study are to characterize the thermal and evolved gas analysis of calcite under SAM operating conditions and then compare it to calcite thermal and evolved gas analysis under TEGA operating conditions.

Lauer, H. V. Jr.↗
NASA NTRS1999

Differential Scanning Calorimetry and Evolved Gas Analysis of Hydromagnesite

Volatile-bearing minerals (e.g., Fe-oxyhydroxides, phyllosilicates, carbonates and sulfates) may be important phases on the surface of Mars. In order to characterize these phases the Thermal and Evolved Gas Analyzer (TEGA) flying on the Mars'98 lander will perform analyses on surface samples from Mars. Hydromagnesite [Mg5(CO3)4(OH)2.4H2O] is considered a good standard mineral to examine as a Mars soil analog component because it evolves both H2O and CO2 at temperatures between 0 and 600 C. Our aim here is to interpret the DSC signature of hydromagnesite under ambient pressure and 20 sccm N2 flow in the range 25 to 600 C. The DSC curve for hydromagnesite under the above conditions consists of three endothermic peaks at temperatures 296, 426, and 548 and one sharp exotherm at 511 C. X-ray analysis of the sample at different stop temperatures suggested that the exotherm corresponded with the formation of crystalline magnesite. The first endotherm was due to dehydration of hydromagnesite, and then the second one was due to the decomposition of carbonate, immediately followed by the formation of magnesite (exotherm) and its decomposition to periclase (last endotherm). Evolution of water and CO2 were consistent with the observed enthalpy changes. A library of such DSC-evolved gas curves for putative Martian minerals are currently being acquired in order to facilitate the interpretation of results obtained by a robotic lander.

Lauer, H. V., Jr.↗
NASA NTRS1996

Effect of Pt Doping on Nucleation and Crystallization in Li2O.2SiO2 Glass: Experimental Measurements and Computer Modeling

Heterogeneous nucleation and its effects on the crystallization of lithium disilicate glass containing small amounts of Pt are investigated. Measurements of the nucleation frequencies and induction times with and without Pt are shown to be consistent with predictions based on the classical nucleation theory. A realistic computer model for the transformation is presented. Computed differential thermal analysis data (such as crystallization rates as a function of time and temperature) are shown to be in good agreement with experimental results. This modeling provides a new, more quantitative method for analyzing calorimetric data.

Narayan, K. Lakshmi↗
NASA NTRS1988

Energy spectra of plasma sheet ions and electrons from about 50 eV/e to about 1 MeV during plamsa temperature transitions

ISEE-1 charged-particle measurements obtained during eight plasma temperature transitions (PTTs) in 1978-1979 are compiled in tables and graphs and analyzed in detail, comparing the ion and electron differential energy spectra with the predictions of theoretical models. PTTs are defined as approximately 1-h periods of low bulk plasma velocity and steadily increasing or decreasing thermal energy. A Maxwellian distribution is found to be inadequate in describing the PTT energy spectra, but velocity-exponential and kappa distributions are both successful, the latter especially at higher energies. The power-law index kappa varies from PTT to PTT, but the high-energy spectral index and overall shape of the distribution remain constant during a PTT; both spatial and temporal effects are observed.

Christon, S. P.↗
DOE OSTI2020

A MEMS dynamic mechanical analyzer for in situ viscoelastic characterization of 3D printed nanostructures

Cellular metamaterial structures with sub-micron features have shown the ability to become excellent energy absorbing materials for impact mitigation due to the enhanced mechanical properties of materials at the nanoscale. However, in order to optimize the design of these energy absorbing metamaterial structures we need to be able to measure the dynamic properties of the sub-micron features such as storage and loss moduli and the loss factor. Therefore, at scale testing is required to capture the scale, temperature, and strain rate dependent material properties of these nanoscale materials. This study presents the design, fabrication, and calibration of a MEMS-based dynamic mechanical analyzer (DMA) that can be directly integrated with the two photon lithography (TPL) process commonly used to fabricate metamaterial structures with nanoscale features. The MEMS-based DMA consists of a chevron style thermal actuator used to generate a tensile load on the structure and two differential capacitive sensors on each side of the structure used to measure load and displacement. This design demonstrated 1.5 ± 0.75 nm displacement resolution and 104 ± 52 nN load resolution, respectively. Dynamic mechanical analysis was successfully conducted on a single nanowire feature printed between the load and displacement stages of the MEMS device with testing frequencies ranging between 0.01–10 Hz and testing temperatures ranging between 22 °C–47 °C. These initial tests on an exemplar TPL part demonstrate that the printed nanowire behaves as a viscoelastic material wherein the transition from glassy to viscous behavior has already set in at the room temperature.

42 ENGINEERING↗
DOE OSTI2022

Experimental study of the impact of scavenging efficiency on diesel combustion in an opposed-piston two-stroke engine

The opposed-piston two-stroke (OP2S) engine is a promising alternative powertrain technology that can offer thermal and brake efficiency improvements over conventional four-stroke engines. In recent years, many of the technical barriers of the OP2S engine architecture have been overcome. However, there is still a need for fundamental studies to provide insight into the scavenging and combustion processes of the OP2S engine to help design and operate the most efficient combustion systems using this engine architecture. This work aims to provide such insights by analyzing experimental data collected on a 3-cylinder, 4.9 L OP2S engine. Specifically, a scavenging efficiency sweep, an engine speed sweep with a constant scavenging efficiency, and an engine speed with a constant pressure differential across the engine were studied in detail. It was found that in diesel combustion, as the scavenging efficiency decreased, the increase in temperature of the hot, internal residuals resulted in a significant increase in heat transfer. Despite lowering pumping losses, this resulted in an overall decrease in brake efficiency. When the bulk thermodynamic conditions of two different scavenging efficiency cases (67% and 72%) were matched at port closing, the lower scavenging efficiency case still displayed a 0.7 percentage point penalty in net thermal efficiency and an increase in engine-out indicated specific emissions of NOx of 18% due to residual stratification in the cylinder. The results presented in this work show that the optimal breathing strategy in diesel combustion on an OP2S engine architecture is one that results in a slightly under-scavenged environment at port closing. However, the results did show potential system-level efficiency benefits of decreasing scavenging efficiency, meaning that alternative fuels and combustion strategies without the constraints of diesel combustion could achieve system-level efficiency gains by running significantly under-scavenged.

Engineering↗
NASA NTRS2001

Earth-Atmospheric Coupling During Strong Earthquakes by Analyzing MODIS Data

Interactions between the Earth and the atmosphere during major earthquakes (M greater than 5) are the subject of this investigation. Recently a mechanism has been proposed predicting the build-up of positive ground potentials prior to strong earthquake activity. Connected phenomena include: transient conductivity of rocks, injection of currents, possibly also electromagnetic emission and light emission from high points at the surface of the Earth. To understand this process we analyze vertical atmospheric profiles, land surface and brightness (temperature) data, using the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard NASA's Terra satellite launched in December 1999. MODIS covers the entire Earth every 1-2 days in 36 wavelength bands (20 visible and 16 infrared) at different spatial resolutions (250 m, 500 m, and 1 km). Using MODIS data we look for correlations between the atmospheric dynamics and solid Earth processes for the January 2001 strong earthquakes in San Salvador and India. As part of the build-up of positive grounds potential, an IR luminescence is predicted to occur in the 8-12 micrometer band. We use the MODIS data to differentiate between true "thermal" signals and IR luminescence. Indeed, on the basis of a temporal and spatial distribution analysis, a thermal anomaly pattern is found that appears to be related to the seismic activity. Aerosol content and atmospheric instability parameters also change when ground charges build up causing ion emission and leading to a thin aerosol layer over land. We analyze the aerosol content, atmospheric pressure, moisture profile and lifted index. Anomalous trends have been identified in few days prior to the main shocks. The significance of this observation should be explored further using other data sets.

Ouzounov, Dimitar↗
NASA NTRSDate not supplied

A Survey of ISS and Visiting Vehicle Returned Surfaces for Environmental Characterization and Computer Model Development

The Orbital Debris Engineering Model (ORDEM) developed by the NASA Orbital Debris Program Office (ODPO) is a data-driven model — extensive radar, optical, laboratory, and in situ measurement data sets have been used to build the model since its earliest versions. A salient aspect of professional software development is the verification and validation (V&V) process. Verification answers the question “Is the model built correctly?” while validation addresses the question “Did we build the correct model?” Less extensive, reserved, or independent data sets serve the validation requirement. Due to the dynamic nature of the orbital debris environment, it is critical to use contemporaneous data sources that represent the current environment to support ORDEM development and validation. ORDEM has utilized in situ data collected from Space Shuttle and Hubble Space Telescope surface inspections, now over a decade old. This historical dataset is fundamental for providing baseline in situ measurement data for sizes between 10 to 300 microns, but new data sources are being evaluated using returned surfaces from or near the International Space Station (ISS). This paper reviews a general microscopic survey of ISS soft goods, the Pressurized Mating Adapter 2 (PMA-2) blanket, and a limited-scope feasibility study conducted on the Space Exploration Technologies Corporation (SpaceX) Dragon capsule’s Thermal Protection System (TPS) material. The PMA-2 blanket, exposed to the space environment between 09 July 2013 and 25 February 2015, is an approximately 3.7 m2-area blanket composed of a betacloth outer layer and multiple ballistic fabric inner layers. The SpaceX Cargo Dragon capsule regularly visited the ISS from 2012 through 2020 and potentially provides a timely and well-characterized source of data for modeling purposes. The capsule’s lateral surfaces use SpaceX Proprietary Ablative Material (SPAM) TPS material, a syntactic foam, for thermal management during all mission phases. Seven SPAM extracted samples have been analyzed to date. This paper will provide an overview of the characterization completed for impact features by size, depth, impactor diameter, and the impactor residues chemical analyses, allowing a differentiation between micrometeoroids and orbital debris and a categorization by mass density and density class. Impactor diameter is estimated using damage equations generated from ground-based hypervelocity impact testing. The orbital debris impactors are compared to the current ORDEM 3.2 model of the environment at ISS altitudes. We briefly discuss the meteoroid impactors, including constituents and mass densities, in the general context of current models.

Phillip Anz-meador↗