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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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COBE battery overview: History, handling, and performance

The following topics are presented in viewgraph format: Cosmic Background Explorer (COBE) mission background; battery background and specifications; cell history; battery mechanical/structural design; battery test data; and flowcharts of the various battery approval procedures.

Yi, Thomas

The Growth of Zeolites A, X and Mordenite in Space

Zeolites are a class of crystalline aluminosilicate materials that form the backbone of the chemical process industry worldwide. They are used primarily as adsorbents and catalysts and support to a significant extent the positive balance of trade realized by the chemical industry in the United States (around $19 billion in 1991). The magnitude of their efforts can be appreciated when one realizes that since their introduction as 'cracking catalysts' in the early 1960's, they have saved the equivalent of 60 percent of the total oil production from Alaska's North Slope. Thus the performance of zeolite catalysts can have a profound effect on the U.S. economy. It is estimated that a 1 percent increase in yield of the gasoline fraction per barrel of oil would represent a savings of 22 million barrels of crude oil per year, representing a reduction of $400 million in the United States' balance of payments. Thus any activity that results in improvement in zeolite catalyst performance is of significant scientific and industrial interest. In addition, due to their 'stability,' uniformity, and, within limits, their 'engineerable' structures, zeolites are being tested as potential adsorbents to purify gases and liquids at the parts-per-billion levels needed in today's electronic, biomedical, and biotechnology industries and for the environment. Other exotic applications, such as host materials for quantum-confined semiconductor atomic arrays, are also being investigated. Because of the importance of this class of material, extensive efforts have been made to characterize their structures and to understand their nucleation and growth mechanisms, so as to be able to custom-make zeolites for a desired application. To date, both the nucleation mechanics and chemistry (such as what are the 'key' nutrients) are, as yet, still unknown for many, if not all, systems. The problem is compounded because there is usually a 'gel' phase present that is assumed to control the degree of supersaturation, and this gel undergoes a continuous 'polymerization' type reaction during nucleation and growth. Generally, for structure characterization and diffusion studies, which are useful in evaluating zeolites for improving yield in petroleum refining as well as for many of the proposed new applications (e.g., catalytic membranes, molecular electronics, chemical sensors) large zeolites (greater than 100 to 1000 times normal size) with minimum lattice defects are desired. Presently, the lack of understanding of zeolite nucleation and growth precludes the custom design of zeolites for these or other uses. It was hypothesized that the microgravity levels achieved in an orbiting spacecraft could help to isolate the possible effects of natural convection (which affects defect formation) and minimize sedimentation, which occurs since zeolites are twice as dense as the solution from which they are formed. This was expected to promote larger crystals by allowing growing crystals a longer residence time in a high-concentration nutrient field. Thus it was hypothesized that the microgravity environment of Earth orbit would allow the growth of large, more defect-free zeolite crystals in high yield.

A Sacco, Jr

High-energy, high-power, long-life battery

High-energy-density primary battery achieves energy densities of up to 130 watt hrs./lb. The electrochemical couple consists of a lithium anode, a copper-fluoride cathode, and uses methyl formate/lithium hexafluoroarsenate for the electrolyte. Once achieved, battery life is approximately 30 hours.

Abens, S. G.

Air Force standards for nickel hydrogen battery

The topics discussed are presented in viewgraph form and include Air Force nickel hydrogen standardization goals, philosophy, project outline, cell level standardization, battery level standardization, and schedule.

Hwang, Warren

Fullerenes, PAH, Carbon Nanostructures, and Soot in Low Pressure Diffusion Flames

The formation of fullerenes C 60 and C 7O is known to occur in premixed laminar benzene/oxygen/argon flames operated at reduced pressures. High resolution transmission electron microscopy (HRTEM) images of material collected from these flames has identified a variety of multishelled nanotubes and fullerene 'onions' as well as some trigonous structures. These fullerenes and nanostructures resemble the material that results from commercial fullerene production systems using graphite vaporization. As a result, combustion is an interesting method for fullerenes synthesis. If commercial scale operation is to be considered, the use of diffusion flames might be safer and less cumbersome than premixed flames. However, it is not known whether diffusion flames produce the types and yields of fullerenes obtained from premixed benzene/oxygen flames. Therefore, the formation of fullerenes and carbon nanostructures, as well as polycyclic aromatic hydrocarbons (PAH) and soot, in acetylene and benzene diffusion flames is being studied using high performance liquid chromatography (HPLC) and high resolution transmission electron microscopy (HRTEM).

William J Grieco

Technology Readiness Assessment for Stirling Power Convertor

Stirling-based power conversion system could represent a critical enabling technology for future NASA missions, offering significantly enhanced power efficiency over traditional thermoelectric systems. To ensure the successful infusion of this technology into deep space and planetary surface missions, a rigorous evaluation of its maturity and associated risks is essential. The objective of this Technology Readiness Assessment (TRA) is to determine the current technology readiness level (TRL) of the Stirling power convertor and identify key technical risks and challenges associated with its maturation and potential infusion into a targeted flight system. The evaluation process will rigorously follow the NASA TRA procedure: (1) determining the requirements that underpin the design, function, and performance; (2) finding and listing all new technology elements (NTEs) and critical technology elements (CTEs); (3) identifying the level of integration assumed for the assessment; and (4) assessing the TRL for each NTE and CTE. The overall subassembly TRL will then be determined via a roll-up using the “weakest link” criterion, culminating in a final (5) assessment of risks to further progression of maturity. This paper will present the results of a comprehensive technology readiness assessment (TRA) conducted on the Stirling-based dynamic power conversion subassembly, excluding the radioisotope heat source. The paper will also describe a detailed breakdown of the TRL roll-up and a matrix of identified risks and recommended mitigation paths, along with identified key technical risks and challenges to achieve the required long-duration performance. Key Words: Radioisotope Power Conversion, Technology Readiness Assessment

Radioisotope Power Conversion

The Radsetta Stone – Establishing a Common Environment Taxonomy Across Space Nuclear Technologies

Qualitative descriptions, such as “high temperature” or “long exposure” vary substantially according to the context and can obfuscate messaging. A quantitative taxonomy for describing space nuclear environments - encompassing fission, radioisotope, and natural - has been established to enable clear communication across technology applications. Zones have been defined to partition environments with an intent to achieve a useful level of granularity. These zones enable a more detailed assessment than the Technology Readiness Level and can also be used to identify gaps and overlaps spanning space nuclear technologies. This framework has been named the Radsetta Stone – a paronomasia of the Rosetta Stone. There are two directions in which the Radsetta Stone can be used. The user may be a technology developer or a technology customer. The developer would use the Radsetta Stone to communicate the current state of the technology they are developing. The maximum zone for each parameter would then be used to state the current limit of their technology. The customer could use the Radsetta Stone to communicate the environmental conditions of their system. Zones would be associated with different locations within the system. The Radsetta Stone is intended to enable clear communication regarding space nuclear technology. The following legend and tables show the levels of the Radsetta Stone. These levels show success criteria gates in a similar manner as Technology Readiness Levels.

taxonomy

A SIMULINK Environment for Flight Dynamics and Control Analysis - Application to the DHC-2 'Beaver', Part 1. Implementation of a Model Library in SIMULINK

The design of advanced Automatic Aircraft Control Systems (AACS's) can be improved upon considerably if the designer can access all models and tools required for control system design and analysis through a graphical user-interface, from within one software environment. This MSc-thesis presents the first step in the development of such an environment, which is currently being done at the Section for Stability and Control of Delft University of Technology, Faculty of Aerospace Engineering. The environment is implemented within the commercially available software package MATLAB/SIMULINK. The report consists of two parts. Part I gives a detailed description of the AACS design environment. The heart of this environment is formed by the SIMULINK implementation of a nonlinear aircraft model in block-diagram format. The model has been worked out for the old laboratory aircraft of the Faculty, the De Havilland DHC-2 'Beaver', but due to its modular structure, it can easily be adapted for other aircraft. Part I also describes MATLAB programs which can be applied for finding steady-state trimmed-flight conditions and for linearization of the aircraft model, and it shows how the built-in simulation routines of SIMULINK have been used for open-loop analysis of the aircraft dynamics. Apart from the implementation of the models and tools, a thorough treatment of the theoretical backgrounds is presented. Part II of this report presents a part of an autopilot design process for the 'Beaver' aircraft, which clearly demonstrates the power and flexibility of the AACS design environment from part I. Evaluations of all longitudinal and lateral control laws by means of nonlinear simulations are treated in detail. The AACS design environment from part I proved to be a very useful tool for designing the control laws of the 'Beaver' autopilot within a very tight time-schedule. The autopilot design process itself will be used as a guideline for future AACS research at the Faculty of Aerospace Engineering. Flight tests of the 'Beaver' autopilot, done after evaluating the control laws in the SIMULINK package, proved to be quite successful. In the future, the AACS design package will evolve into a standardized, integrated design environment which can be applied to virtually any type of aircraft. The AACS design cycle will be shortened further by developing tools for automatically porting control laws from the MATLAB/SIMULINK environment to a piloted real-time flight simulator and the Flight Control Computers of the aircraft.

Aircraft Modelling

Radiation-Resistant Ti/BN Coatings: Insights From 171 Days Exposure to Space Radiation and Atomic Oxygen in Low Orbit

Atmospheric Plasma Spray (APS) and Vacuum Plasma Spray (VPS) techniques were used to develop Ti/2 vol.% hBN coatings, for extreme space environments and tested aboard the International Space Station as part of the MISSE-17 (Materials International Space Station Experiments) program. The coatings were exposed to atomic oxygen, space radiation, and low-orbit thermal cycling. VPS coatings showed a 56% increase in microhardness, a 26% rise in elastic modulus, minimal porosity and crack density changes compared to APS coatings. The change in mechanical properties is attributed to the formation of TiO, TiO₂ and TiN from nitrogen retention, alongside radiation-induced dislocations, which enhanced surface hardening. The oxidation of titanium led to the formation of TiO and TiO₂, while boron nitride was retained and underwent transmutation in VPS coatings. XPS and EDS analyses confirmed the enhanced space-environment resistance of VPS coatings, making them ideal for long-term spacecraft protection in lunar and Martian conditions.

Abhijith Kunneparambil Sukumaran

Machine Learning for Predicting Team Functioning in HERA Missions

Team functioning is integral to success in future long term space exploration missions. Proactively detecting declines in team functioning can mitigate conflict and ensure mission success. This project developed a speech-based artificial intelligence (AI) system that unobtrusively predicts degradation in team functioning, including performance and cohesion, in the Human Exploration Research Analog (HERA) Campaigns 4 and 5. The AI system conducted automated analysis of the prosodic (tone of voice) and linguistic (language content) components of speech, modeling interpersonal dynamics at both the turn-taking and day-wide levels. We investigated team functioning via observing structured interactions (i.e., multi-mission space exploration vehicle-extra vehicular activity [MMSEV-EVA], team interaction battery [TIB]) and unstructured interactions before the MMSEV-EVA task. We developed machine learning models to predict team functioning (objective task accuracy, self reported team efficacy and self reported team cohesion) by analyzing OpenSmile acoustic features, linguistic descriptors extracted via the linguistic inquiry and word count (LIWC) dictionary, and semantic embeddings. In the TIB, static models using logistic regression and random forests were not able to predict task accuracy, but predicted team efficacy and cohesion during both the decision making and relational tasks to a moderate level (60-70%). Majority voting on the individual turns to predict day long team efficacy further increased accuracies (70-80%). Finally, long short-term memory (LSTM) models showed the best performance across all variables (80-91%), including task performance. In the MMSEV-EVA, static models achieved an accuracy of 60% with majority voting, which increased to 80% through the incorporation of mission day as a variable, accounting for the learning effect. A key finding across both tasks was the "team-dependent" nature of these interactions; models achieved much higher accuracy when trained on prior days of the same team's data rather than attempting to generalize across entirely different teams, with even 1-2 days of prior data per team achieving 5-15% improvement over team-independent models. In addition, the incorporation of pre-task data from the same team also improves model performance, e.g., incorporating data from the decision-making task of the TIB, which preceded the relational task, improved the prediction of team efficacy and cohesion during the latter. We compared model performance when trained on machine-generated data compared to data that had been further corrected by human annotators. Overall, models trained on human-corrected data exhibited a modest improvement in performance, particularly when acoustic features were used. We found no significant correlation between word error rate (WER) and model accuracy (r(55) = -0.08, p = 0.51), but model’s accuracy was significantly higher for medium/high quality transcription (0.74 (SD = 0.48)) compared to the low-quality group (0.64 (SD = 0.36)) (t(63)=2.82, p = 0.006). Based on these, several design recommendation emerge, that could inform Standards at NASA. Models predicting team functioning should incorporate at least one to two days of historical interaction data, include brief pre-task discussions, and explicitly model temporal learning effects, especially for longer operational tasks. Minimum quality standards for automated speech-processing pipelines are needed, given the performance gains observed with manually corrected acoustic data. Finally, systems should leverage both acoustic features and language embeddings in complementary ways, with modality choices and fusion strategies tailored to mission context, task demands, and data quality requirements.

Shrivatsa Mishra

Pressure Switch Is a Low Cost Battery Indicator

Conventional pressure switch, fabricated by printed-circuit manufacturing techniques, can indicate when charge on battery departs from preset level. Membrane on switch is exposed to internal pressure of battery, which varies according to stored charge. When pressure varies from preset level, switch can turn on a light-emitting diode or similar indicator to warn user that battery is low.

Abita, J. L.

NASA’s Electric Propulsion Development Activities for Space Nuclear Propulsion Applications

Given increased worldwide support for advanced nuclear technology for terrestrial applications, there is a renewed interest in the possibility of nuclear-reactor-powered spacecraft. NASA continues investing in the technology areas necessary to support NASA’s future scientific and exploration goals. One of those technologies areas is electric propulsion, a highly efficient means for in-space propulsion that increases fuel economy by ionizing and accelerating an onboard propellant using spacecraft electrical power. The current NASA portfolio of electric propulsion investments in support of space nuclear applications focuses on a range of future applications with total system power levels of 50 kilowatts to multimegawatt. These investments support a fast-paced incremental rate for technology development advancement to support these applications. Systems at the 50-kilowatt power level can be accomplished today with existing technology and systems at the multimegawatt level will require further technology developments over the coming decade. Propulsion systems based an array of multiple Hall thrusters have been identified the most likely technology option for the near-term applications and systems utilizing lithium-fueled magneto-plasma-dynamic thrusters have been identified as the most promising alternative technology option for the far-term applications at very high-power levels.

Electric Propulsion

NASA’s Electric Propulsion Development Activities for Space Nuclear Propulsion Applications

Given increased worldwide support for advanced nuclear technology for terrestrial applications, there is a renewed interest in the possibility of nuclear-reactor-powered spacecraft. NASA continues investing in the technology areas necessary to support NASA’s future scientific and exploration goals. One of those technologies areas is electric propulsion, a highly efficient means for in-space propulsion that increases fuel economy by ionizing and accelerating an onboard propellant using spacecraft electrical power. The current NASA portfolio of electric propulsion investments in support of space nuclear applications focuses on a range of future applications with total system power levels of 50 kilowatts to multimegawatt. These investments support a fast-paced incremental rate for technology development advancement to support these applications. Systems at the 50-kilowatt power level can be accomplished today with existing technology and systems at the multimegawatt level will require further technology developments over the coming decade. Propulsion systems based an array of multiple Hall thrusters have been identified the most likely technology option for the near-term applications and systems utilizing lithium-fueled magneto-plasma-dynamic thrusters have been identified as the most promising alternative technology option for the far-term applications at very high-power levels.

Electric propulsion