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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Stratospheric aircraft exhaust plume and wake chemistry studies

This report documents progress to date in an ongoing study to analyze and model emissions leaving a proposed High Speed Civil Transport (HSCT) from when the exhaust gases leave the engine until they are deposited at atmospheric scales in the stratosphere. Estimates are given for the emissions, summarizing relevant earlier work (CIAP) and reviewing current propulsion research efforts. The chemical evolution and the mixing and vortical motion of the exhaust are analyzed to track the exhaust and its speciation as the emissions are mixed to atmospheric scales. The species tracked include those that could be heterogeneously reactive on the surfaces of the condensed solid water (ice) particles and on exhaust soot particle surfaces. Dispersion and reaction of chemical constituents in the far wake are studied with a Lagrangian air parcel model, in conjunction with a radiation code to calculate the net heating/cooling. Laboratory measurements of heterogeneous chemistry of aqueous sulfuric acid and nitric acid hydrates are also described. Results include the solubility of HCl in sulfuric acid which is a key parameter for modeling stratospheric processing. We also report initial results for condensation of nitric acid trihydrate from gas phase H2O and HNO3.

Miake-Lye, R. C.↗

Propulsive lift noise

Propulsive life noise is the increase in noise that occurs when airframe surfaces are placed in the propulsive system's exhaust to increase their lift force. Increased local flow velocities and turbulence levels, due to the propulsive system exhaust gases passing along the airframe lifting surfaces, cause an increase in maximum lift coefficient. The airplane's flight speed required for takeoff and landing can then be significantly reduced, allowing operation from shorter runways than those of conventional commercial airports. Unfortunately, interaction of high velocity turbulent exhaust flow with the airframe's solid surfaces generates additional noise radiation. Aeroacoustic processes that cause propulsive lift noise also are present in airframe noise and propulsive system installation noise. Research studies of propulsive lift noise led to development of improved methods of predicting noise radiation from surfaces in turbulent flows. Noise reduction and prediction methods of aircraft noise are discussed.

Fink, Martin R.↗

Assessment of a flow-through balance for hypersonic wind tunnel models with scramjet exhaust flow simulation

The purpose of this investigation were twofold: first, to determine whether accurate force and moment data could be obtained during hypersonic wind tunnel tests of a model with a scramjet exhaust flow simulation that uses a representative nonwatercooled, flow-through balance; second, to analyze temperature time histories on various parts of the balance to address thermal effects on force and moment data. The tests were conducted in the NASA Langley Research Center 20-Inch Mach 6 Wind Tunnel at free-stream Reynolds numbers ranging from 0.5 to 7.4 x 10(exp 6)/ft and nominal angles of attack of -3.5 deg, 0 deg, and 5 deg. The simulant exhaust gases were cold air, hot air, and a mixture of 50 percent Argon and 50 percent Freon by volume, which reached stagnation temperatures within the balance of 111, 214, and 283 F, respectively. All force and moment values were unaffected by the balance thermal response from exhaust gas simulation and external aerodynamic heating except for axial-force measurements, which were significantly affected by balance heating. This investigation showed that for this model at the conditions tested, a nonwatercooled, flow-through balance is not suitable for axial-force measurements during scramjet exhaust flow simulation tests at hypersonic speeds. In general, heated exhaust gas may produce unacceptable force and moment uncertainties when used with thermally sensitive balances.

Huebner, Lawrence D.↗

Stratospheric aircraft exhaust plume and wake chemistry

Progress to date in an ongoing study to analyze and model emissions leaving a proposed High Speed Civil Transport (HSCT) from when the exhaust gases leave the engine until they are deposited at atmospheric scales in the stratosphere is documented. A kinetic condensation model was implemented to predict heterogeneous condensation in the plume regime behind an HSCT flying in the lower stratosphere. Simulations were performed to illustrate the parametric dependence of contrail droplet growth on the exhaust condensation nuclei number density and size distribution. Model results indicate that the condensation of water vapor is strongly dependent on the number density of activated CN. Incorporation of estimates for dilution factors into a Lagrangian box model of the far-wake regime with scale-dependent diffusion indicates negligible decrease in ozone and enhancement of water concentrations of 6-13 times background, which decrease rapidly over 1-3 days. Radiative calculations indicate a net differential cooling rate of the plume about 3K/day at the beginning of the wake regime, with a total subsidence ranging between 0.4 and 1 km. Results from the Lagrangian plume model were used to estimate the effect of repeated superposition of aircraft plumes on the concentrations of water and NO(y) along a flight corridor. Results of laboratory studies of heterogeneous chemistry are also described. Kinetics of HCl, N2O5 and ClONO2 uptake on liquid sulfuric acid were measured as a function of composition and temperature. Refined measurements of the thermodynamics of nitric acid hydrates indicate that metastable dihydrate may play a role in the nucleation of more stable trihydrates PSC's.

Miake-Lye, R. C.↗

Effects of Synthesis Gas Concentration, Composition, and Operational Time on Tubular Solid Oxide Fuel Cell Performance

There is tremendous potential to utilize the exhaust gases and heat already present within combustion chambers to generate electrical power via solid oxide fuel cells (SOFCs). Variations in system design have been investigated as well as thorough examinations into the impacts of environmental conditions and fuel composition/concentration on SOFC performance. In an attempt to isolate the impacts of carbon monoxide and hydrogen concentration ratios within the exhaust stream, this work utilizes multi-temperature performance analyses with simulated methane combustion exhaust as fuel combined with dilute hydrogen baseline tests. These comparisons reveal the impacts of the complex reaction pathways carbon monoxide participates in when used as an SOFC fuel. Despite these complexities, performance reductions as a result of the presence of carbon monoxide are low when compared to similarly dilute hydrogen as a fuel. This provides further motivation for the continued development of SOFC-CHP systems. Stability testing performed over 80 h reveals the need for careful control of the operating environment as well as signs of carbon deposition. As a result of gas flow disruption, impacts of anode oxidation that may normally not hinder power production become significant factors in addition to coarsening of the anode material. Thermal management and strategies to minimize these impacts are a topic of future research.

54 ENVIRONMENTAL SCIENCES↗

Effects of entrained water and strong turbulence on afterburning within solid rocket motor plumes

During the first few seconds of the space shuttle trajectory, the solid rocket boosters will be in the proximity of the launch pad. Because of the launch pad structures and the surface of the earth, the turbulent mixing experienced by the exhaust gases will be greatly increased over that for the free flight situation. In addition, a system will be present, designed to protect the lifting vehicle from launch structure vibrations, which will inject quantities of liquid water into the hot plume. The effects of these two phenomena on the temperatures, chemical composition, and flow field present in the afterburning solid rocket motor exhaust plumes of the space shuttle were studied. Results are included from both a computational model of the afterburning and supporting measurements from Titan 3 exhaust plumes taken at Kennedy Space Center with infrared scanned radiometers.

Gomberg, R. I.↗

Some Effects of Exposure to Exhaust-gas Streams on Emittance and Thermoelectric Power of Bare-wire Platinum Rhodium - Platinum Thermocouples

Thermocouples were exposed to exhaust gases from the combustion of propane, 72-octane gasoline, and JP-4 fuel. Exposure increased the emissivity of the thermocouple wire, which increased its radiation error. Two methods are presented for determining the emittance of the wires. The emissivity of a clean platinum rhodium-platinum thermocouple was approximately 0.2 in the temperature range investigated, while the emittance of an exposed thermocouple coated with exhaust residue was about 0.5. The exposure caused negligible change in the thermoelectric power of the thermocouples.

Glawe, George E↗

Ice Prevention on Aircraft by Means of Engine Exhaust Heat and a Technical Study of Heat Transmission from a Clark Y Airfoil

This investigation was conducted to study the practicability of employing heat as a means of preventing the formation of ice on airplane wings. The report relates essentially to technical problems regarding the extraction of heat from the exhaust gases and its proper distribution over the exposed surfaces. In this connection a separate study has been made to determine the variation of the coefficient of heat transmission along the chord of a Clark Y airfoil. Experiments on ice prevention both in the laboratory and in flight show conclusively that it is necessary to heat only the front portion of the wing surface to effect complete prevention. Experiments in flight show that a vapor-heating system which extracts heat from the exhaust and distributes it to the wings is an entirely practical and efficient method for preventing ice formation.

Theodorsen, Theodore↗

Interrelation of exhaust-gas constituents

This report presents the results of an investigation conducted to determine the interrelation of the constituents of the exhaust gases of internal-combustion engines and the effect of engine performance on these relations. Six single-cylinder, liquid-cooled tests engines and one 9-cylinder radial air-cooled engine were tested. Various types of combustion chambers were used and the engines were operated at compression ratios from 5.1 to 7.0 using spark ignition and from 13.5 to 15.6 using compression ignition. The investigation covered a range of engine speeds from 1,500 to 2,100 r.p.m. The fuels used were two grades of aviation gasoline, auto diesel fuel, and laboratory diesel fuel. Power, friction, and fuel-consumption data were obtained from the single-cylinder engines at the same time that the exhaust-gas samples were collected.

Gerrish, Harold C↗

DIGITAL APPLICATIONS USING REAL-TIME VEHICLE EXHAUST INFORMATION

Vehicle emission is a major source of air pollution that causes a significant number of deaths globally. It has a profound impact on energy and the environment as well. The existing vehicle emission monitoring system is unable to help mitigating the pollution properly and therefore, requires precise real-time pollution measurement. The purpose of this paper is to discuss novel applications using the real-time measurement of pollutants from a vehicle tailpipe where exhaust gases enter the environment. Today, it is possible to measure such emission due to the emergence of affordable digital technologies such as the Internet of Things (IoT), wireless connectivity, cloud platform, and artificial intelligence. This paper discusses how digital technologies can be used for real-time monitoring of NOx gas as a measure of vehicle emission and predictive analytics applications. A description of data collection and pre-processing methodologies, actual collected data, and an approach to identify patterns between inputs such as vehicle speed and altitude and output such as NOx emission are included. Applying a simple neural network has produced promising results and is a first step towards developing predictive applications.

Digital, Vehicle Exhaust, IoT, AI, 1.4.2, Predicti↗

Near-Zero Power MOF-Based Sensors for NO 2 Detection

Detection and capture of toxic nitrogen oxides (NO x ) is important for emissions control of exhaust gases and general public health. The ability to directly electrically detect trace (0.5–5 ppm) NO 2 by a metal–organic framework (MOF)-74-based sensor at relatively low temperatures (50 °C) is demonstrated via changes in electrical properties of M-MOF-74, M = Co, Mg, Ni. The magnitude of the change is ordered Ni > Co > Mg and explained by each variant's NO 2 adsorption capacity and specific chemical interaction. Ni-MOF-74 provides the highest sensitivity to NO 2 ; a 725× decrease in resistance at 5 ppm NO2 and detection limit <0.5 ppm, levels relevant for industry and public health. Furthermore, the Ni-MOF-74-based sensor is selective to NO 2 over N 2 , SO 2 , and air. Linking this fundamental research with future technologies, the high impedance of MOF-74 enables applications requiring a near-zero power sensor or dosimeter, with the active material drawing <15 pW for a macroscale device 35 mm 2 with 0.8 mg MOF-74. Finally, this represents a 10 4 –10 6 × decrease in power consumption compared to other MOF sensors and demonstrates the potential for MOFs as active components for long-lived, near-zero power chemical sensors in smart industrial systems and the internet of things.

47 OTHER INSTRUMENTATION↗

Low-frequency electrochemical pulsing to manage flooding and salt precipitation in zero-gap CO 2 -to-ethylene electrolyzers

The electrochemical reduction of carbon dioxide (CO 2 ) to ethylene presents a promising route for utilizing exhaust gases to produce value-added chemicals with broad manufacturing applications. While zero-gap electrolyzer architectures show great potential to enable commercial-scale CO 2 -to-ethylene conversion, their performance is often limited by failure within the first 100 hours. In this work, we demonstrate that a low-frequency electrochemical pulsing protocol effectively mitigates carbonate salt precipitation and flooding by managing water transport to and through the cathode gas diffusion electrode and associated flow fields. Operando neutron imaging further reveals the dynamics of water crossover and flooding, emphasizing the intricate interplay between electrochemical operation and ionic transport. By mitigating short-term flooding and salt precipitation failure modes, this study establishes a foundation for understanding long-term degradation mechanisms and advancing the practical viability of CO 2 electrolyzers for industrial-scale applications.

36 MATERIALS SCIENCE↗

Issues in Formation of Cryogenic Pellets for Fusion Applications

Cryogenic pellets are used for injection into fusion plasmas to add fuel to build up density and replace the ions lost from fusion reactions and imperfect confinement in the plasma. These pellets are formed at cryogenic temperatures with pure hydrogenic isotopes or mixtures of the isotopes. Technology to make these pellets and inject them into plasmas has been under development for many years, and various methods using freezing or desublimation have been shown to produce high-quality solid pellets suitable for injection. The throughput needed and possible impurity content from the necessary recirculation of fusion exhaust gases are two of the key issues to overcome for fusion pellet fueling systems in long-pulse burning plasmas. Here, we describe the technical challenges associated with these issues and the capability of pellet formation extruders to overcome them.Cryogenic pellets of deuterium, neon, and argon are also used in fusion tokamak devices for disruption mitigation in the form of large pellets that can be injected on demand to quickly dissipate the plasma thermal energy through radiation and add significant density in order to prevent runaway electron formation. Here, the issue is not throughput as with the fueling pellets but rather is the time it takes to form pellets of the size needed and the ability to dislodge them immediately on demand when needed to mitigate a disruption. The method used to make these pellets by desublimation is described, and examples related to how pellet size and input gas parameters affect the formation time are provided.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Environmental stability of additively manufactured siliconized silicon carbide for applications in hybrid energy systems

A key consideration for the successful operation of hybrid energy systems will be the environmental stability of materials used for their construction, particularly when experiencing service environments containing water vapor at high temperatures. Here, we report results from the characterization of siliconized silicon carbide (Si-SiC) prepared via binder jet additive manufacturing and reactive silicon melt infiltration after being exposed to environments representative of those in solid oxide fuel cell (SOFC) anodes, and to exhaust gases inside a microturbine operating on natural gas. In both cases, it was found that oxide scales formed on the surface and that these scales were dense, continuous, and well-bonded to the substrates, although there was evidence of transverse and longitudinal cracking most likely as a result of mismatches in the thermal expansion of the scale and the substrate. Measured values of the thickness of the oxide scale were compared to those predicted by parabolic oxidation kinetics of silicon, but the potential effects of silica volatilization induced by water vapor, and silica reduction when exposed to hydrogen are discussed. The overall results showed that the oxide scale is expected to be protective under the conditions of hybrid power generation systems.

36 MATERIALS SCIENCE↗

Understanding the Quadrupole Mass Filter and Testing a High-Resolution QMS RGA for ITER

A common type of residual gas analyzer is the quadrupole mass spectrometer. One of the main components within this instrument is a mass filter known as the quadrupole. It is responsible for the selective throughput of the ionized gas particles - by ascending mass number - prior to ion impacts on the analyzer (or detector) surface from which the ion current signal is generated for processing. However, the quadrupole is not fully described in relation to the electric field characteristics and the function as an ion mass separator. This paper describes the basic origins of the electrical design, the intricate assembly criteria, and performance of the quadrupole within the spectrometer. A specialized quadrupole mass spectrometer is part of a configuration for a diagnostic gas analyzer system planned for ITER, a fusion research machine. It has a verified capability, essential as a diagnostic criterion for this reactor project, to successfully deconvolute the mass signals of Helium-4 and deuterium (reactor fuel exhaust gases, separated by only 0.026 atomic mass units), down to a relative three-percent concentration of the former gas. The associated preliminary testing, performed at the Oak Ridge National Laboratory, is also addressed. Finally, one of the key parameters used to express gas concentration, the relative sensitivity factor, will be explained, including an evaluation of dependency on other variables.

Marcus, Chris [ORNL] (ORCID:0000000190139636)↗