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NASA NTRS1976

The making of the atmosphere

A model for the evolution of the earth's atmosphere is proposed in which the atmosphere and oceans are assumed to have accumulated as a result of volatile outgassing from the earth's interior. The bulk of the outgassed volatiles were originally trapped within the solid earth during the planetary accretion process, while other volatiles resulted from radiogenic decay within the solid earth. Atmospheric oxygen resulted from the photo-dissociation of water vapor during the earth's early history and from photosynthetic activity in more recent times. The origin and evolution of atmospheric ozone is closely related to the growth of oxygen. The rise of ozone and the evolution of life is discussed in terms of an evolving oxygen atmosphere.

Levine, J. S.↗

NASA NTRS1989

Thermal evolution of the earth - Effects of volatile exchange between atmosphere and interior

The thermal history of the earth is investigated using a parameterized model of mantle convection, that includes the effects of volatile exchange between the mantle and the surface reservoir and the softening of the mantle by the dissolved volatiles. The mantle degassing rate is taken to be directly proportional to the rate of seafloor spreading which depends on the mantle heat flow. It is shown that the dependence of the mantle viscosity on the volatile content has important effects on the thermal evolution of planetary interiors and the evolution of planetary atmospheres. Degassing is compensated by an increase in temperature, while regassing is compensated by a decrease in temperature. Reasonable degassing scenarios can account for an early rapid formation of the earth's atmosphere inferred from noble gas abundances.

Mcgovern, Patrick J.↗

NASA NTRS2014

Water Content of Earth's Continental Mantle Is Controlled by the Circulation of Fluids or Melts

A key mission of the ARES Directorate at JSC is to constrain models of the formation and geological history of terrestrial planets. Water is a crucial parameter to be measured with the aim to determine its amount and distribution in the interior of Earth, Mars, and the Moon. Most of that "water" is not liquid water per se, but rather hydrogen dissolved as a trace element in the minerals of the rocks at depth. Even so, the middle layer of differentiated planets, the mantle, occupies such a large volume and mass of each planet that when it is added at the planetary scale, oceans worth of water could be stored in its interior. The mantle is where magmas originate. Moreover, on Earth, the mantle is where the boundary between tectonic plates and the underlying asthenosphere is located. Even if mantle rocks in Earth typically contain less than 200 ppm H2O, such small quantities have tremendous influence on how easily they melt (i.e., the more water there is, the more magma is produced) and deform (the more water there is, the less viscous they are). These two properties alone emphasize that to understand the distribution of volcanism and the mechanism of plate tectonics, the water content of the mantle must be determined - Earth being a template to which all other terrestrial planets can be compared.

Peslier, Anne↗

DOE OSTI2020

Pressure-stabilized divalent ozonide CaO 3 and its impact on Earth's oxygen cycles

High pressure can drastically alter chemical bonding and produce exotic compounds that defy conventional wisdom. Especially significant are compounds pertaining to oxygen cycles inside Earth, which hold key to understanding major geological events that impact the environment essential to life on Earth. Here we report the discovery of pressure-stabilized divalent ozonide CaO3 crystal that exhibits intriguing bonding and oxidation states with profound geological implications. Our computational study identifies a crystalline phase of CaO 3 by reaction of CaO and O 2 at high pressure and high temperature conditions; ensuing experiments synthesize this rare compound under compression in a diamond anvil cell with laser heating. High-pressure x-ray diffraction data show that CaO 3 crystal forms at 35 GPa and persists down to 20 GPa on decompression. Analysis of charge states reveals a formal oxidation state of -2 for ozone anions in CaO 3 . These findings unravel the ozonide chemistry at high pressure and offer insights for elucidating prominent seismic anomalies and oxygen cycles in Earth’s interior. We further predict multiple reactions producing CaO 3 by geologically abundant mineral precursors at various depths in Earth’s mantle.

58 GEOSCIENCES↗

NASA NTRS1974

Contribution to the theory of tidal oscillations of an elastic earth. External tidal potential

The differential equations of the tidal oscillations of the earth were established under the assumption that the interior of the earth is laterally inhomogeneous. The theory was developed using vectorial and dyadic symbolism to shorten the exposition and to reduce the differential equations to a symmetric form convenient for programming and for numerical integration. The formation of tidal buldges on the surfaces of discontinuity and the changes in the internal density produce small periodic variations in the exterior geopotential which are reflected in the motion of artificial satellites. The analoques of Love elastic parameters in the expansion of exterior tidal potential reflect the asymmetric and inhomogeneous structure of the interior of the earth.

Musen, P.↗

NASA NTRS1984

Neutrino tomography - Tevatron mapping versus the neutrino sky

The feasibility of neutrino tomography of the earth's interior is discussed, taking the 80-GeV W-boson mass determined by Arnison (1983) and Banner (1983) into account. The opacity of earth zones is calculated on the basis of the preliminary reference earth model of Dziewonski and Anderson (1981), and the results are presented in tables and graphs. Proposed tomography schemes are evaluated in terms of the well-posedness of the inverse-Radon-transform problems involved, the neutrino generators and detectors required, and practical and economic factors. The ill-posed schemes are shown to be infeasible; the well-posed schemes (using Tevatrons or the neutrino sky as sources) are considered feasible but impractical.

Wilson, T. L.↗

NASA NTRS1993

Oxidation state of the Earth's upper mantle during the last 3800 million years: Implications for the origin of life

A popular, as well as scientifically rigorous, scenario for the origin of life on Earth involves the production of organic molecules by interaction of lightning (or other forms of energy) with a chemically reducing atmosphere in the early history of Earth. Experiments since the 1950's have convincingly demonstrated that the yield of organic molecules is high when the atmosphere contains molecular hydrogen, methane, ammonia, and water vapor. Additional work has also shown that such a highly reducing atmosphere might not, however, have been sufficiently long-lived in the presence of intense solar ultraviolet radiation for life to have formed from it. One way of maintaining such an atmosphere would be to have a continual replenishment of the reduced gases by prolonged volcanic outgassing from a reducing of Earth's interior. The length of time that this replenishment might need to continue is in part constrained by the flux of asteroids onto the Earth's surface containing sufficient energy to destroy most, if not all, life that had developed up to that point in time. If a reducing atmosphere is a key ingredient for the origin of life on Earth, the time of the last environmental sterilization due to large impacts would be an important constraint. In a deep marine setting (e.g., hydrothermal vent), the last global sterilization might have occurred at 4200-4000 Ma. On the Earth's surface, the last global sterilization event might have occurred at 4000-3700 Ma. If these are meaningful constraints, how likely is it that a reducing atmosphere could have survived on the Earth until about 3800 Ma ago? Due to the importance of replenishing this atmosphere with reducing components by volcanic outgassing from the mantle, geochemical information on the history of the mantle's oxidation state would be useful for addressing this question. Geochemical and experimental data discussed in this abstract suggest that extrusive mafic volcanics derived from the upper mantle have had oxidation states near the fayalite-magnetite quartz buffer throughout the last 3800 Ma. At magmatic temperatures, the gases released from volcanoes having this oxidation state would have been, as they are today, composed dominantly of carbon dioxide and water vapor, and would not contain the ingredients for maintaining a reducing atmosphere. Consequently, geochemical data do not favor the survival of a reducing atmosphere until about 3800 Ma. Alternative venues and pathways for the origin of life need to be investigated (e.g., hydrothermal vents along oceanic ridges).

Delano, J. W.↗

NASA NTRS1985

Chemical evolution of the Earth: Equilibrium or disequilibrium process?

To explain the apparent chemical incompatibility of the Earth's core and mantle or the disequilibrium process, various core forming mechanisms have been proposed, i.e., rapid disequilibrium sinking of molten iron, an oxidized core or protocore materials, and meteorite contamination of the upper mantle after separation from the core. Adopting concepts used in steady state thermodynamics, a method is devised for evaluating how elements should distribute stable in the Earth's interior for the present gradients of temperature, pressure, and gravitational acceleration. Thermochemical modeling gives useful insights into the nature of chemical evolution of the Earth without overly speculative assumptions. Further work must be done to reconcile siderophile elements, rare gases, and possible light elements in the outer core.

Sato, M.↗

NASA NTRS2018

Synchronous Separation, Seaming, Sealing and Sterilization (S4) using Brazing for Sample Containerization and Planetary Protection

The return of samples back to Earth in future missions would require protection of our planet from the risk of bringing uncontrolled biological materials back with the samples. This protection would require “breaking the chain of contact (BTC)”, where any returned material reaching Earth for further analysis would have to be sealed inside a container with extremely high confidence. Therefore, the acquired samples would need to be contained while destroying any potential biological materials that may contaminate the external surface of the container. A novel process that could be used to contain returning samples has been developed and demonstrated in a quarter scale size. The process consists of brazing using non-contact induction heating that synchronously separates, seams, seals and sterilizes (S4) the container. The use of brazing involves melting at temperatures higher than 500°C and this level of heating assures sterilization of the exposed areas since all carbon bonds (namely, organic materials) are broken at this temperature. The mechanism consists of a double wall container with inner and outer shells having Earth-clean interior surfaces. The process consists of two-steps, Step-1: the double wall container halves are fabricated and brazed (equivalent to production on Earth); and Step-2 is the S4 process and it is the equivalent to the execution on-orbit around Mars. In a potential future mission, the double wall container would be split into two halves and prepared on Earth. The potential on-orbit execution would consist of inserting the orbiting sample (OS) container into one of the halves and then mated to the other half and brazed. The latest results of this effort will be described and discussed in this manuscript.

Salazar, Eduardo↗

NASA NTRS1994

Analysis of selected materials flown on interior locations of the Long Duration Exposure Facility

This report documents the post-flight condition of selected hardware taken from interior locations on the Long Duration Exposure Facility (LDEF). This hardware was generally in excellent condition. Outgassing data is presented for heat shrink tubing and fiberglass composite shims. Variation in total mass loss (TML) values for heat shrink tubing were correlated with location. Nylon grommets were evaluated for mechanical integrity; slight embrittlement was observed for flight specimens. Multi-layer insulation blankets, wire bundles, and paints in non-exposed interior locations were all in visibly good condition. Silicon-containing contaminant films were observed on silver-coated hex nuts at the space- and Earth-end interior locations.

Smith, H. A.↗

NASA NTRS2022

Ongoing Progress Toward NASA's Surface Biology and Geology Mission

Pursuant to recommendations by the National Academies of Science, Engineering and Medicine's Earth Science Decadal Survey, the National Aeronautics and Space Administration (NASA) has announced the development of an Earth System Observatory (ESO), a series of missions designed to observe processes across the Earth's interior, surface and atmosphere. A key component of this system is the Surface Biology and Geology (SBG) investigation. SBG will measure the composition and properties of Earth's land, inland waters, and coastal oceans. The notional architecture consists of multiple spacecraft slated for launch in the 2027–2028 timeframe (Figure 1). Target science questions and geophysical variables span diverse disciplines including terrestrial and aquatic ecology, geology, vulcanology, hydrology and cryospheric sciences (Figure 2). Beyond simply measuring geophysical variables for each discipline, SBG will provide information about the links between the different domains, enabling a more comprehensive understanding of the Earth as a connected system. SBG measurements will also benefit a wide range of societal applications including agriculture, terrestrial and aquatic biodiversity, natural hazards, public health, and management of water and other natural resources. SBG will also coordinate measurements, data products, and analyses with other ESO elements to deliver an integrated Earth System perspective of Earth and its changing climate.

David R. Thompson↗

NASA NTRS2005

Proof-of-Concept Trajectory Designs for a Multi-Spacecraft, Low-Thrust Heliocentric Solar Weather Buoy Mission

A new solar weather mission has been proposed, involving a dozen or more small spacecraft spaced at regular, constant intervals in a mutual heliocentric circular orbit between the orbits of Earth and Venus. These solar weather buoys (SWBs) would carry instrumentation to detect and measure the material in solar flares, solar energetic particle events, and coronal mass ejections as they flowed past the buoys, serving both as science probes and as a radiation early warning system for the Earth and interplanetary travelers to Mars. The baseline concept involves placing a mothercraft carrying the SWBs into a staging orbit at the Sun-Earth L1 libration point. The mothercraft departs the L1 orbit at the proper time to execute a trailing-edge lunar flyby near New Moon, injecting it into a heliocentric orbit with its perihelion interior to Earth s orbit. An alternative approach would involve the use of a Double Lunar Swingby (DLS) orbit, rather than the L1 orbit, for staging prior to this flyby. After injection into heliocentric orbit, the mothercraft releases the SWBs-all equipped with low-thrust pulsed plasma thrusters (PPTs)-whereupon each SWB executes a multi-day low-thrust finite bum around perihelion, lowering aphelion such that each achieves an elliptical phasing orbit of different orbital period from its companions. The resulting differences in angular rates of motion cause the spacecraft to separate. While the lead SWB achieves the mission orbit following an insertion burn at its second perihelion passage, the remaining SWBs must complete several revolutions in their respective phasing orbits to establish them in the mission orbit with the desired longitudinal spacing. The complete configuration for a 14 SWB scenario using a single mothercraft is achieved in about 8 years, and the spacing remains stable for at least a further 6 years. Flight operations can be simplified, and mission risk reduced, by employing two mothercraft instead of one. In this scenario: the second mothercraft stays in a libration-point or DLS staging orbit until the first mothercraft has achieved nearly 180 separation from the Earth. The timing of the second mothercraft's subsequent lunar flyby is planned such that this spacecraft will be located 180 from the first mothercraft upon completion of its heliocentric circularization maneuvers. Both groups of satellites then only have to spread out over 180 to obtain full 360 coverage around the Sun.

Muller, Ronald↗

NASA NTRS2003

To Create Space on Earth: The Space Environment Simulation Laboratory and Project Apollo

Few undertakings in the history of humanity can compare to the great technological achievement known as Project Apollo. Among those who witnessed Armstrong#s flickering television image were thousands of people who had directly contributed to this historic moment. Amongst those in this vast anonymous cadre were the personnel of the Space Environment Simulation Laboratory (SESL) at the Manned Spacecraft Center (MSC) in Houston, Texas. SESL houses two large thermal-vacuum chambers with solar simulation capabilities. At a time when NASA engineers had a limited understanding of the effects of extremes of space on hardware and crews, SESL was designed to literally create the conditions of space on Earth. With interior dimensions of 90 feet in height and a 55-foot diameter, Chamber A dwarfed the Apollo command/service module (CSM) it was constructed to test. The chamber#s vacuum pumping capacity of 1 x 10(exp -6) torr can simulate an altitude greater than 130 miles above the Earth. A "lunar plane" capable of rotating a 150,000-pound test vehicle 180 deg replicates the revolution of a craft in space. To reproduce the temperature extremes of space, interior chamber walls cool to -280F as two banks of carbon arc modules simulate the unfiltered solar light/heat of the Sun. With capabilities similar to that of Chamber A, early Chamber B tests included the Gemini modular maneuvering unit, Apollo EVA mobility unit and the lunar module. Since Gemini astronaut Charles Bassett first ventured into the chamber in 1966, Chamber B has assisted astronauts in testing hardware and preparing them for work in the harsh extremes of space.

Walters, Lori C.↗

NASA NTRS1989

Venus and the Archean Earth: Thermal considerations

The Archean Era of the Earth is not a direct analog of the present tectonics of Venus. In this regard, it is useful to review the state of the Archean Earth. Most significantly, the temperature of the adiabatic interior of the Earth was 200 to 300 C hotter than the current temperature. Preservation biases limit what can be learned from the Archean record. Archean oceanic crust, most of the planetary surface at any one time, has been nearly all subducted. More speculatively, the core of the Earth has probably cooled more slowly than the mantle. Thus the temperature contrast above the core-mantle boundary and the vigor of mantle plumes has increased with time on the Earth. The most obvious difference between Venus and the present Earth is the high surface temperature and hence a low effective viscosity of the lithosphere. In addition, the temperature contrast between the adiabatic interior and the surface, which drives convection, is less on Venus than on the Earth. It appears that the hot lithosphere enhanced tectonics on the early Venus significantly enough that its interior cooled faster than the Earth's. The best evidence for a cool interior of Venus comes from long wavelength gravity anomalies. The low interior temperatures retard seafloor spreading on Venus. The high surface temperatures on Venus enhance crustal deformation. That is, the lower crust may become ductile enough to permit significant flow between the upper crust and the mantle. There is thus some analogy to modern and ancient areas of high heat flow on the Earth. Archean crustal blocks typically remained stable for long intervals and thus overall are not good analogies to the deformation style on Venus.

Sleep, N. H.↗

DOE OSTI2020

Mineralogy of the deep lower mantle in the presence of H 2 O

Understanding the mineralogy of the Earth's interior is a prerequisite for unravelling the evolution and dynamics of our planet. Here, we conducted high pressure-temperature experiments mimicking the conditions of the deep lower mantle (DLM, 1800–2890 km in depth) and observed surprising mineralogical transformations in the presence of water. Ferropericlase, (Mg, Fe)O, which is the most abundant oxide mineral in Earth, reacts with H 2 O to form a previously unknown (Mg, Fe)O 2 H x (x ≤ 1) phase. The (Mg, Fe)O 2 H x has a pyrite structure and it coexists with the dominant silicate phases, bridgmanite and post-perovskite. Depending on Mg content and geotherm temperatures, the transformation may occur at 1800 km for (Mg 0.6 Fe 0.4 )O or beyond 2300 km for (Mg 0.7 Fe 0.3 )O. The (Mg, Fe)O 2 H x is an oxygen excess phase that stores an excessive amount of oxygen beyond the charge balance of maximum cation valences (Mg 2+ , Fe 3+ and H + ). This important phase has a number of far-reaching implications including extreme redox inhomogeneity, deep-oxygen reservoirs in the DLM and an internal source for modulating oxygen in the atmosphere.

58 GEOSCIENCES↗

NASA NTRS1975

The exterior tidal potential acting on a satellite

The tidal potential is related to small periodic variations in the geopotential which are caused by the formation of the tidal bulge and by the redistribution of masses in the earth's interior under the influence of lunisolar tidal attraction. The tidal effects in the motion of a satellite can be interpreted as the result of tidal periodic oscillations. An investigation of the tidal disturbing potential is conducted and the differential equations for the variations of the elements are considered. It is suggested that a future planning should include the tidal observations on the earth surface.

Musen, P.↗

NASA NTRS1994

Rates of Earth degassing

The degassing of the Earth during accretion is constrained by Pu-U-I-Xe systematics. Degassing was much more efficient during the first 100-200 Ma than subsequently, and it was more complete for Xe than for the lighter gases. More than 90 percent of the degassed Xe escaped from the atmosphere during this period. The combination of fractional degassing of melts and rare gas escape from the atmosphere is able to explain the deficit of terrestrial Xe as a simple consequence of this early degassing history. By the time Xe was quantitatively retained in the atmosphere, the abundances of Kr and the lighter gases in the Earth's interior were similar to or higher than the present-day atmospheric abundances. Subsequent transfer of these lighter rare gases into the atmosphere requires a high rate of post-accretion degassing and melt production. Considerations of Pu-U-Xe systematics suggest that relatively rapid post-accretion degassing was continued to ca. 4.1-4.2 Ga. The present-day degassing history of the Earth is investigated through consideration of rare gas isotope abundances. Although the Earth is a highly degassed body, depleted in rare gases by many orders of magnitude relative to their solar abundances, it is at the present-day losing primordial rare gases which were trapped at the time of accretion.

Onions, R. K.↗

NASA NTRS1968

On the Equilibrium Figure of the Earth

If de Sitter's hydrostatic equations are developed independent of the external potential theory, the hydrostatic geopotential coefficient J(sub h) occurs explicitly on the right-hand side of those equations. J(sub h) here has to be treated as an unknown in the solution, it becomes rather difficult to solve the equations independently, regardless of which of the dynamical parameters associated with the earth is taken as the initial datum. Solution is possible, however, with the help of a boundary condition derived from the external potential theory which neither assumes nor discounts the presence of equilibrium conditions in the earth's interior. If a general solution i s constructed on this basis, the three particular solutions, usually quoted in literature, stem from it in the wake of the appropriate assumptions. Of course, the only meaningful solution--of these-- is that corresponding to the polar moment of inertia as the initial datum. It is essential that the solution be constructed in this way in order to demonstrate clearly the correct structure of the problem of hydrostatic equilibrium. The anomalous gravity field of the earth referred to the hydrostatic figure is compared with that referred to the international reference ellipsoid.

Khan, M. A.↗