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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Computing Q-D Relationships for Storage of Rocket Fuels

The Quantity Distance Measurement Tool is a GIS BASEP computer program that aids safety engineers by calculating quantity-distance (Q-D) relationships for vessels that contain explosive chemicals used in testing rocket engines. (Q-D relationships are standard relationships between specified quantities of specified explosive materials and minimum distances by which they must be separated from persons, objects, and other explosives to obtain specified types and degrees of protection.) The program uses customized geographic-information-system (GIS) software and calculates Q-D relationships in accordance with NASA's Safety Standard For Explosives, Propellants, and Pyrotechnics. Displays generated by the program enable the identification of hazards, showing the relationships of propellant-storage-vessel safety buffers to inhabited facilities and public roads. Current Q-D information is calculated and maintained in graphical form for all vessels that contain propellants or other chemicals, the explosiveness of which is expressed in TNT equivalents [amounts of trinitrotoluene (TNT) having equivalent explosive effects]. The program is useful in the acquisition, siting, construction, and/or modification of storage vessels and other facilities in the development of an improved test-facility safety program.

Jester, Keith↗
DOE OSTI2017

Tracking Radionuclide Fractionation in the First Atomic Explosion Using Stable Elements

Compositional analysis of postdetonation fallout is a tool for forensic identification of nuclear devices. However, the relationship between device composition and fallout composition is difficult to interpret because of the complex combination of physical mixing, nuclear reactions, and chemical fractionations that occur in the chaotic nuclear fireball. By using a combination of in situ microanalytical techniques (electron microprobe analysis and secondary ion mass spectrometry), we show that some heavy stable elements (Rb, Sr, Zr, Ba, Cs, Ba, La, Ce, Nd, Sm, Dy, Lu, U, Th) in glassy fallout from the first nuclear test, Trinity, are reliable chemical proxies for radionuclides generated during the explosion. Stable-element proxies show that radionuclides from the Trinity device were chemically, but not isotopically, fractionated by condensation. Moreover, stable-element proxies delineate chemical fractionation trends that can be used to connect present-day fallout composition to past fireball composition. Stable-element proxies therefore offer a novel approach for elucidating the phenomenology of the nuclear fireball as it relates to the formation of debris and the fixation of device materials within debris.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Seismic DAS Observations of a large underground chemical explosion in dry tuff

On 18 October 2023 a 16.3-ton TNT equivalent chemical explosion was detonated underground at the Nevada National Security Site, generating a seismic event (Meyers et al., 2024). The associated seismic wavefield was measured on a Distributed Acoustic Sensing (DAS) array with slant range distances from 27 m – 1123 m. The first arriving phase traveled at an apparent velocity of about 2640 m s -1 from 27 m to 420 m slant range and about 2470 m s -1 from 505 m to 1123 m slant range according to the first arrival moveouts on the DAS data. The first arrival from the explosion temporarily saturated the cable from a slant range of 27 m – 186 m and 0.009 s to 0.084 s post detonation. From 186 m slant range to 420 m slant range, peak strain rates of 5.6 x 10 6 nm m -1 s -1 were observed for the first arrival phase. For the first arrival from 505 m slant range to 1123 m slant range, peak strain rates reduced to 8.0 x 10 4 nm m -1 s -1 . A comparison of the scaled accelerations computed from DAS, the geophone pairs, and the measurements of co-located accelerometer pairs show common agreement at the scaled ranges of the single point sensors. This study adds to the body of work reporting near-source DAS observations of the seismic wavefields generated by underground chemical explosions. These results indicate that near-source DAS observations can refine interpretations of phase identification from single-point sensor observations. Phase identification could be one mechanism that contributes scatter to single point seismic measurements which would confound the performance of empirical relationships for small explosions. Removing that mechanism may therefore reduce interstation variability and increase empirical relationship performance for small explosions.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2025

Seismic DAS observations of a large underground chemical explosion in dry tuff

On 18 October 2023 a 16.3-ton TNT equivalent chemical explosion was detonated underground at the Nevada National Security Site, generating a seismic event with a magnitude of 1.7 (Meyers et al., 2024). The associated seismic wavefield was measured on a Distributed Acoustic Sensing (DAS) array with slant range distances from 27 m – 1123 m. The first arriving phase traveled at an apparent velocity of about 2640 m s -1 from 27 m to 420 m slant range and about 2470 m s -1 from 505 m to 1123 m slant range according to the first arrival moveouts on the DAS data. The first arrival from the explosion temporarily saturated the cable from a slant range of 27 m – 186 m and 0.009 s to 0.084 s post detonation. From 186 m slant range to 420 m slant range, peak strain rates of 5.6 x 10 6 nm m -1 s -1 were observed for the first arrival phase. For the first arrival from 505 m slant range to 1123 m slant range, peak strain rates reduced to 8.0 x 104 nm m -1 s -1 . A comparison of the scaled accelerations computed from DAS, the geophone pairs, and the measurements of co-located accelerometer pairs show common agreement at the scaled ranges of the single point sensors. This study adds to the body of work reporting near-source DAS observations of the seismic wavefields generated by underground chemical explosions. These results indicate that near-source DAS observations can refine interpretations of phase identification from single-point sensor observations. Phase identification could be one mechanism that contributes scatter to single point seismic measurements which would confound the performance of empirical relationships for small explosions. Removing that mechanism may therefore reduce interstation variability and increase empirical relationship performance for small explosions.

58 GEOSCIENCES↗
DOE OSTI2016

MULTICOLOR LIGHT CURVE SIMULATIONS OF POPULATION III CORE-COLLAPSE SUPERNOVAE: FROM SHOCK BREAKOUT TO {sup 56}CO DECAY

The properties of the first generation of stars and their supernova (SN) explosions remain unknown due to the lack of actual observations. Recently, many transient surveys have been conducted and the feasibility of detecting supernovae (SNe) of Pop III stars is growing. In this paper, we study the multicolor light curves for a number of metal-free core-collapse SN models (25–100 M{sub ⊙}) to determine the indicators for the detection and identification of first generation SNe. We use mixing-fallback supernova explosion models that explain the observed abundance patterns of metal-poor stars. Numerical calculations of the multicolor light curves are performed using the multigroup radiation hydrodynamic code stella. The calculated light curves of metal-free SNe are compared with non-zero-metallicity models and several observed SNe. We have found that the shock breakout characteristics, the evolution of the photosphere’s velocity, the luminosity, and the duration and color evolution of the plateau, that is, all of the SN phases from shock breakout to {sup 56}Co decay, are helpful for estimating the parameters of the SN progenitor: the mass, the radius, the explosion energy, and the metallicity. We conclude that the multicolor light curves could potentially be used to identify first-generation SNe in current (Subaru/HSC) and future transient surveys (LSST, James Webb Space Telescope). They are also suitable for identifying low-metallicity SNe in the nearby universe (PTF, Pan-STARRS, Gaia).

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1988

The Martian highland paterae: Evidence for explosive volcanism on Mars

The Martian surface exhibits numerous volcanic landforms displaying great diversity in size, age, and morphology. Most research regarding Martian volcanology has centered around effusive basaltic volcanism, including analyses of individual lava flows, extensive lava plains, and large shield volcanoes. These studies were hindered by a lack of definitive morphologic criteria for the remote identification of ash deposits. Knowledge of the abundances, ages, and geologic settings of explosive volcanic deposits on Mars is essential to a comprehensive understanding of the evolution of the Martian surface, with implications for the evolution of the lithosphere and atmosphere as well as the histories of specific volcanic centers and provinces.

Crown, David A.↗
NASA NTRS2020

Forecasting Rates of Volcanic Activity on Terrestrial Exoplanets

Similar to the planets and moons in our solar system, terrestrial exoplanets may be shaped by volcanism and tectonics. The magnitudes and rates of geological activity on terrestrial exoplanets will be intimately linked to their sizes and internal heating rates, and can either facilitate, or preclude, the existence of habitable environments. In order to place bounds on the potential for such activity, we estimate total internal heating rates for 52 exoplanets, with masses and radii up to ~ 8M(sub E) and 2R(sub E), respectively, assuming that internal heating is drawn from both radiogenic and tidal sources. We then compare these internal heating rates to those of the bodies in our solar system in an attempt to constrain the rates of volcanic activity on extrasolar worlds. We find that all of the exoplanets surveyed are likely to exhibit volcanic activity at their surfaces. We also find that at least 25% of the of the planets in our study may be extrasolar ocean worlds, the majority of which may contain internal oceans beneath layers of surface ice. These planets may be similar in structure to the icy moons of the giant planets and may have persistent cryovolcanic activity at their surfaces. Volcanic activity on exoplanets could be detected by next-generation space telescopes in transit spectra. In the case of planets with densities and/or effective temperatures that are consistent with H2O-rich compositions, spectral identification of excess water vapor and other molecules that are explosively vented into space during cryovolcanic eruptions could serve as a way to infer the presence of subsurface oceans, and therefore indirectly assess their habitability. Considering the implications for habitability, our results suggest that characterizing Earth-like exoplanets in terms of the potential for geological activity at their surfaces should be a priority in the coming years.

Lynnae C Quick↗
NASA NTRS2020

Forecasting Rates of Volcanic Activity on Terrestrial Exoplanets and Implications for Cryovolcanic Activity on Extrasolar Ocean Worlds

Like the planets and moons in our solar system, the surfaces of terrestrial exoplanets may be shaped by volcanic activity. The magnitudes and rates of volcanic activity on terrestrial exoplanets will be intimately linked to their sizes and internal heating rates and can either facilitate or preclude the existence of habitable environments. In order to place bounds on the potential for such activity, we estimate total internal heating rates for 53 exoplanets with masses and radii up to∼8M⊕and 2R⊕, respectively, assuming that internal heating is drawn from both radiogenic and tidal sources. We then compare these internal heating rates to those of the planets and moons in our solar system in an attempt to constrain the expected rates of volcanic activity on these extrasolar worlds. We find that all 53 of the exoplanets surveyed are likely to have volcanic activity at their surfaces, and that at least 26% of these planets may be extrasolar ocean worlds. The majority of these ocean worlds may be similar in structure to the icy moons of the giant planets, having internal oceans beneath layers of surface ice. If so, these planets may exhibit cryovolcanism (i.e., icy volcanism)at their surfaces. Recent studies have shown that extrasolar volcanism could be detected by high-resolution spectrographs on existing ground-based telescopes. In the case of planets with densities and/or effective temperatures that are consistent with H2O-rich compositions, spectral identification of excess water vapor and other molecules that are explosively vented into space during cryovolcanic eruptions could serve as a way to infer the presence of subsurface oceans, and therefore indirectly assess their habitability. Considering the implications for habitability, our results suggest that continued characterization of terrestrial exoplanets in terms of their potential for volcanic activity should be a priority in the coming years.

Lynnae C Quick↗
DOE OSTI2022

Investigating the electronic structure of high explosives with X-ray Raman spectroscopy

Abstract We investigate the sensitivity and potential of a synergistic experiment-theory X-ray Raman spectroscopy (XRS) methodology on revealing and following the static and dynamic electronic structure of high explosive molecular materials. We show that advanced ab-initio theoretical calculations accounting for the core-hole effect based on the Bethe-Salpeter Equation (BSE) approximation are critical for accurately predicting the shape and the energy position of the spectral features of C and N core-level spectra. Moreover, the incident X-ray dose typical XRS experiments require can induce, in certain unstable structures, a prominent radiation damage at room temperature. Upon developing a compatible cryostat module for enabling cryogenic temperatures ( $$\approx$$ ≈ 10 K) we suppress the radiation damage and enable the acquisition of reliable experimental spectra in excellent agreement with the theory. Overall, we demonstrate the high sensitivity of the recently available state-of-the-art X-ray Raman spectroscopy capabilities in characterizing the electronic structure of high explosives. At the same time, the high accuracy of the theoretical approach may enable reliable identification of intermediate structures upon rapid chemical decomposition during detonation. Considering the increasing availability of X-ray free-electron lasers, such a combined experiment-theory approach paves the way for time-resolved dynamic studies of high explosives under detonation conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Bubbles in US gasoline prices: Assessing the role of hurricanes and anti–price gouging laws

This paper examines the presence of bubbles — price changes that cannot be attributed to market fundamentals — in weekly US retail gasoline prices for ten US cities, and whether these bubbles are affected by hurricane events and anti–price gouging laws. Rolling-window, right-tailed unit root tests were used to identify and date bubbles. The analysis found 6 to 22 bubbles, lasting 4 weeks or longer, in city-level retail gasoline prices between 2000 and 2017. A linear regression model of the adjustment speed coefficients from the bubble identification step found that hurricane events increase the rate of price explosivity (or slow the rate of return to equilibrium) following a shock. Furthermore, the regression estimates also imply that state anti–price gouging laws can counteract these effects.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2012

THE HIGHLY ENERGETIC EXPANSION OF SN 2010bh ASSOCIATED WITH GRB 100316D

We present the spectroscopic and photometric evolution of the nearby (z = 0.059) spectroscopically confirmed Type Ic supernova, SN 2010bh, associated with the soft, long-duration gamma-ray burst (X-ray flash) GRB 100316D. Intensive follow-up observations of SN 2010bh were performed at the ESO Very Large Telescope (VLT) using the X-shooter and FORS2 instruments. Thanks to the detailed temporal coverage and the extended wavelength range (3000-24800 A), we obtained an unprecedentedly rich spectral sequence among the hypernovae, making SN 2010bh one of the best studied representatives of this SN class. We find that SN 2010bh has a more rapid rise to maximum brightness (8.0 {+-} 1.0 rest-frame days) and a fainter absolute peak luminosity (L{sub bol} Almost-Equal-To 3 Multiplication-Sign 10{sup 42} erg s{sup -1}) than previously observed SN events associated with GRBs. Our estimate of the ejected {sup 56}Ni mass is 0.12 {+-} 0.02 M{sub Sun }. From the broad spectral features, we measure expansion velocities up to 47,000 km s{sup -1}, higher than those of SNe 1998bw (GRB 980425) and 2006aj (GRB 060218). Helium absorption lines He I {lambda}5876 and He I 1.083 {mu}m, blueshifted by {approx}20,000-30,000 km s{sup -1} and {approx}28,000-38,000 km s{sup -1}, respectively, may be present in the optical spectra. However, the lack of coverage of the He I 2.058 {mu}m line prevents us from confirming such identifications. The nebular spectrum, taken at {approx}186 days after the explosion, shows a broad but faint [O I] emission at 6340 A. The light curve shape and photospheric expansion velocities of SN 2010bh suggest that we witnessed a highly energetic explosion with a small ejected mass (E{sub k} Almost-Equal-To 10{sup 52} erg and M{sub ej} Almost-Equal-To 3 M{sub Sun }). The observed properties of SN 2010bh further extend the heterogeneity of the class of GRB SNe.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

A THEORETICAL COLOR-VELOCITY CORRELATION FOR SUPERNOVAE ASSOCIATED WITH GAMMA-RAY BURSTS

We carry out the first multi-dimensional radiative transfer calculations to simultaneously compute synthetic spectra and light curves for models of supernovae driven by fast bipolar outflows. These allow us to make self-consistent predictions for the orientation dependence of both color evolution and spectral features. We compare models with different degrees of asphericity and metallicity and find significant observable consequences of both. In aspherical models, we find spectral and light curve features that vary systematically with observer orientation. In particular, we find that the early-phase light curves are brighter and bluer when viewed close to the polar axis but that the peak flux is highest for equatorial (off-axis) inclinations. Spectral line features also depend systematically on observer orientation, including the velocity of the Si II 6355 A line. Consequently, our models predict a correlation between line velocity and color that could assist the identification of supernovae associated with off-axis jet-driven explosions. The amplitude and range of this correlation depends on the degree of asphericity, the metallicity, and the epoch of observation but we find that it is always present and acts in the same direction.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Investigating the Effectiveness of P/S Amplitude Ratios for Local Distance Event Discrimination

The ability to discriminate between underground explosions and earthquakes is an important operation for global security and test-ban-treaty monitoring, and seismology plays a key role in this endeavor. The use of seismic P- to S-wave amplitude ratios has been demonstrated to be an effective discriminant at regional distances for a variety of emplacement conditions and test sites around the world. Increasing interest in detecting and discriminating smaller events, both for purposes of nuclear monitoring and seismic hazard estimation, requires the use of data with shorter event-to-station paths. At these local distances (≤ 200 km), the use of P/S ratios for event discrimination is poorly studied compared with regional distances (200-1500 km). The path averaging that allows for relatively simple corrections to P/S ratios to remove bias from along-path structural differences at regional distances may be insufficient to remove enough scatter from the ratios to allow for accurate event identification at local distances. We use data from a series of chemical explosions detonated as part of the Source Physics Experiment at the Nevada National Security Site in southern Nevada and surrounding seismicity to investigate the discrimination performance of P/S ratios at local distances. We find that discrimination at individual stations is highly variable, regardless of frequency. Network averaging of ratios improves discrimination performance above 6 Hz, as a result of the reduction of scatter among the earthquake ratios. Furthermore, azimuthal and distance–limited averaging suggests that explosion ratios are affected by a complicated source and path relationship that may lead to substantial variability in local P/S ratios at different locations.

58 GEOSCIENCES↗
NASA NTRS1992

Type IA Supernovae

Spectral calculations show that a model based on the thermonuclear explosion of a degenerate carbon/oxygen white dwarf provides excellent agreement with observations of Type Ia supernovae. Identification of suitable evolutionary progenitors remains a severe problem. General problems with estimation of supernova rates are outlined and the origin of Type Ia supernovae from double degenerate systems are discussed in the context of new rates of explosion per H band luminosity, the lack of observed candidates, and the likely presence of H in the vicinity of some SN Ia events. Re-examination of the problems of triggering Type Ia by accretion of hydrogen from a companion shows that there may be an avenue involving cataclysmic variables, especially if extreme hibernation occurs. Novae may channel accreting white dwarfs to a unique locus in accretion rate/mass space. Systems that undergo secular evolution to higher mass transfer rates could lead to just the conditions necessary for a Type Ia explosion. Tests involving fluorescence or absorption in a surrounding circumstellar medium and the detection of hydrogen stripped from a companion, which should appear at low velocity inside the white dwarf ejecta, are suggested. Possible observational confirmation of the former is described.

Wheeler, J. Craig↗
DOE OSTI2016

A mass graph-based approach for the identification of modified proteoforms using top-down tandem mass spectra

Motivation: Although proteomics has rapidly developed in the past decade, researchers are still in the early stage of exploring the world of complex proteoforms, which are protein products with various primary structure alterations resulting from gene mutations, alternative splicing, post-translational modifications, and other biological processes. Proteoform identification is essential to mapping proteoforms to their biological functions as well as discovering novel proteoforms and new protein functions. Top-down mass spectrometry is the method of choice for identifying complex proteoforms because it provides a “bird’s eye view” of intact proteoforms. The combinatorial explosion of various alterations on a protein may result in billions of possible proteoforms, making proteoform identification a challenging computational problem. Results: We propose a new data structure, called the mass graph, for efficient representation of proteoforms and design mass graph alignment algorithms. We developed TopMG, a mass graph-based software tool for proteoform identification by top-down mass spectrometry. Experiments on top-down mass spectrometry data sets showed that TopMG outperformed existing methods in identifying complex proteoforms.

Dynamic Programming↗
DOE OSTI2025

The DECam MAGIC Survey: Spectroscopic Follow-up of the Most Metal-poor Stars in the Distant Milky Way Halo *

In this work, we present high-resolution spectroscopic observations for six metal-poor stars with [Fe/H] < –3 (including one with [Fe/H] < –4), selected using narrowband Ca ii HK photometry from the DECam MAGIC Survey. The spectroscopic data confirm the accuracy of the photometric metallicities and allow for the determination of chemical abundances for 16 elements, from carbon to barium. The program stars have chemical abundances consistent with the [Fe/H] < –3 range. A kinematic/dynamical analysis suggests that all program stars belong to the distant Milky Way halo population (heliocentric distances 35 < d helio /kpc ≲ 55), including three with high-energy orbits that might have been associated with the Magellanic system and one, J0026−5445, having parameters consistent with being a member of the Sagittarius stream. The remaining two stars show kinematics consistent with the Gaia-Sausage/Enceladus dwarf galaxy merger. J0433−5548, with [Fe/H] = –4.12, is a carbon-enhanced ultra metal-poor star, with [C/Fe] = +1.73. This star is believed to be a bona fide second-generation star, and its chemical abundance pattern was compared with yields from metal-free supernova models. Results suggest that J0433−5548 could have been formed from a gas cloud enriched by a single supernova explosion from an ∼11 M ⊙ star in the early Universe. The successful identification of such objects demonstrates the reliability of photometric metallicity estimates, which can be used for target selection and statistical studies of faint targets in the Milky Way and its satellite population. These discoveries illustrate the power of measuring chemical abundances of metal-poor Milky Way halo stars to learn more about early galaxy formation and evolution.

CEMP stars↗
DOE OSTI2022

Raman signatures of detonation soot

Soot generated from the detonation of nine explosives was investigated with Raman microspectroscopy and high-resolution transmission electron microscopy (HRTEM). The first order bands, located at approximately 1,580 (G), 1,350 (D1), 1,620 cm –1 (D2), 1,500 (D3), and 1,200 (D4), are used to provide information on the carbon allotropes and defects. The intensity ratios and the full-width at half-maximum provide an indication of the disorder in the material. The Raman spectra of soot acquired from the detonation of nine explosives showed differences which can be used to identify the precursor explosive. Overall, most differences in the spectra were correlated with the presence of amorphous carbon in the soot. In additional to identification of distinct bands in the spectra via deconvolution, principal component analysis was also used to differentiate the different types of soot. HRTEM performed on soot samples with different explosive precursors identified several distinct allotropes of carbon such as nanodiamonds, carbon onions, graphite fibers, and amorphous carbon.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2011

THE PROGENITOR MASS OF SN 2011dh FROM STELLAR POPULATION ANALYSIS

Using Hubble Space Telescope photometry, we characterize the age of the stellar association in the vicinity of supernova (SN) 2011dh and use it to infer the zero-age main-sequence mass (M{sub ZAMS}) of the progenitor star. We find two distinct and significant star formation (SF) events with ages of <6 and 17{sup +3}{sub -4} Myr, and the corresponding M{sub ZAMS} are >29 and 13{sup +2}{sub -1} M{sub Sun }, respectively. These two bursts represent 18{sup +4}{sub -9}% (young) and 64{sup +10}{sub -14}% (old) of the total SF in the last 50 Myr. Adopting these fractions as probabilities suggests that the most probable M{sub ZAMS} is 13{sup +2}{sub -1} M{sub Sun }. These results are most sensitive to the luminosity function along the well-understood main sequence (MS) and are less sensitive to uncertain late-stage stellar evolution. Therefore, they stand even if the progenitor suffered disruptive post-MS evolution (e.g., eruptive mass loss or binary Roche-lobe overflow). Progenitor identification will help to further constrain the appropriate population. Even though pre-explosion images show a yellow supergiant (YSG) at the site of the SN, panchromatic SN light curves suggest a more compact star as the progenitor. In spite of this, our results suggest an association between the YSG and the SN. Not only was the star located at the SN site, but reinforcing an association, the star's bolometric luminosity is consistent with the final evolutionary stage of the 17 Myr old starburst. If the YSG disappears, then M{sub ZAMS} = 13{sup +2}{sub -1} M{sub Sun }, but if it persists, then our results allow the possibility that the progenitor was an unseen star of >29 M{sub Sun }.

79 ASTRONOMY AND ASTROPHYSICS↗