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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Revisiting the capacity-fading mechanism of P2-type sodium layered oxide cathode materials during high-voltage cycling

We report P2-type sodium layered oxide cathode (Na 2/3 Ni 1/3 Mn 2/3 O 2 , P2-NNMO) has attracted great attention as a promising cathode material for sodium ion batteries because of its high specific capacity. However, this material suffers from a rapid capacity fade during high-voltage cycling. Several mechanisms have been proposed to explain the capacity fade, including intragranular fracture caused by the P2-O2 phase transion, surface structural change, and irreversible lattice oxygen release. Here we systematically investigated the morphological, structural, and chemical changes of P2-NNMO during high-voltage cycling using a variety of characterization techniques. It was found that the lattice distortion and crystal-plane buckling induced by the P2-O2 phase transition slowed down the Na-ion transport in the bulk and hindered the extraction of the Na ions. The sluggish kinetics was the main reason in reducing the accessible capacity while other interfacial degradation mechanisms played minor roles. Our results not only enabled a more complete understanding of the capacity-fading mechanism of P2-NNMO but also revealed the underlying correlations between lattice doping and the moderately improved cycle performance.

25 ENERGY STORAGE↗
NASA NTRS1966

Signal fading characteristics, Echo II

Signal fading characteristics of Echo II SATELLITE - fade duration, and fade period probability distribution and density functions at various cross section levels

COMMUNICATION SYSTEM↗
NASA NTRS2013

Fading Losses on the LCRD Free-Space Optical Link Due to Channel Turbulence

The Laser Communications Relay Demonstration (LCRD) will implement an optical communications link between a pair of Earth terminals via an Earth-orbiting satellite relay. Clear air turbulence over the communication paths will cause random fluctuations, or fading, in the received signal irradiance. In this paper we characterize losses due to fading caused by clear air turbulence. We illustrate the performance of a representative relay link, utilizing a channel interleaver and error-correction-code to mitigate fading, and provide a method to quickly determine the link performance.

fading↗
NASA NTRS1995

Earth-Space Links and Fade-Duration Statistics

The available data on fade-duration statistics are reviewed, with emphasis on mobile and fixed satellite links. Fades in mobile links are due to roadside-tree shadowing, and fades in fixed links are due to rain attenuation.

fade-duration↗
DOE OSTI2023

Unraveling capacity fading in lithium-ion batteries using advanced cyclic tests: A real-world approach

Battery lifespan estimation is essential for effective battery management systems, aiding users and manufacturers in strategic planning. However, accurately estimating battery capacity is complex, owing to diverse capacity fading phenomena tied to factors such as temperature, charge-discharge rate, and rest period duration. In this work, we present an innovative approach that integrates real-world driving behaviors into cyclic testing. Unlike conventional methods that lack rest periods and involve fixed charge-discharge rates, our approach involves 1000 unique test cycles tailored to specific objectives and applications, capturing the nuanced effects of temperature, charge-discharge rate, and rest duration on capacity fading. This yields comprehensive insights into cell-level battery degradation, unveiling growth patterns of the solid electrolyte interface (SEI) layer and lithium plating, influenced by cyclic test parameters. Here, the results yield critical empirical relations for evaluating capacity fading under specific testing conditions.

25 ENERGY STORAGE↗
DOE OSTI2024

The Impact of Lithium Anode Interface on Capacity Fade in Polymer Electrolyte-Based Solid-State Batteries

This study investigates the Li stripping-plating morphology and failure mechanisms in full cells consisting of a solid polymer electrolyte (SPE) with two commercial Li anodes: Li chip and Li foil. The primary identified failure mechanism of the SPE cell is capacity fade, regardless of the Li manufacturer. While the cathode’s role in capacity fade is evident, the Li anode significantly influences cycling performance, with Li foil cells cycling 50% longer than Li chip cells, a statistical difference. Further, post-mortem scanning electron microscopy and X-ray photoelectron spectroscopy results attribute the Li chip’s faster capacity fade to a loss of contact and continuous growth of the solid electrolyte interphase (SEI). Conversely, Li foil maintains consistent contact with the solid polymer, displaying a thin and stable SEI. Additionally, failure mechanisms between a gel electrolyte in previous work and the dry SPE are compared.

25 ENERGY STORAGE↗
DOE OSTI2025

The Role of Catholyte Modulation in Suppressing the Initial Capacity Fade of Zinc Electrolytic Manganese Dioxide Coin Cells

Despite its potential for zinc–manganese oxide batteries, electrolytic manganese dioxide (EMD) can experience capacity fade due to a deficiency in the Mn 2+ supply at the cathode electrolyte interphase (CEI) from side reactions, even in the presence of an electrolyte additive. In this work, electrolyte loading modulation at the cathode electrolyte interface (CEI) was correlated with Zn∥EMD cell capacity retention and cycling performance, as a proposed measure to curb the initial capacity fade observed in EMD. Initial galvanostatic charge/discharge cycling, with varied electrolyte loading, revealed severe capacity fade (from ~188 to 10 mAh g –1 for the highest loading of 200 μL) within the first 15 cycles. Such a decrease in cell capacity is correlated with the formation of a Mn 4+ deposit on the current collector and consequently, the Mn 2+ depletion at CEI, as was supported by elemental and Raman analyses. Interestingly, confinement of the electrolyte to the CEI at a lower (≤15 μL) electrolyte loading mitigated Mn 4+ side-deposition, maintaining the cell capacity at >80% over the first 15 cycles. Interfacial Mn supply/depletion could be monitored via voltammetric analysis based on changes of the Zn 2+ insertionreduction peak. Additional galvanostatic experiments corroborated the voltammetric interpretation and the proposed degradation pathway in the studied cell conditions. The outcomes of this work provide practical insight into coin-cell design and configuration strategies for developing Zn∥EMD batteries.

25 ENERGY STORAGE↗
DOE OSTI2023

Understanding capacity fade in organic redox-flow batteries by combining spectroscopy with statistical inference techniques

Organic redox-active molecules are attractive as redox-flow battery (RFB) reactants because of their low anticipated costs and widely tunable properties. Unfortunately, many lab-scale flow cells experience rapid material degradation (from chemical and electrochemical decay mechanisms) and capacity fade during cycling (>0.1%/day) hindering their commercial deployment. In this work, we combine ultraviolet-visible spectrophotometry and statistical inference techniques to elucidate the Michael attack decay mechanism for 4,5-dihydroxy-1,3-benzenedisulfonic acid (BQDS), a once-promising positive electrolyte reactant for aqueous organic redox-flow batteries. We use Bayesian inference and multivariate curve resolution on the spectroscopic data to derive uncertainty-quantified reaction orders and rates for Michael attack, estimate the spectra of intermediate species and establish a quantitative connection between molecular decay and capacity fade. Our work illustrates the promise of using statistical inference to elucidate chemical and electrochemical mechanisms of capacity fade in organic redox-flow battery together with uncertainty quantification, in flow cell-based electrochemical systems.

25 ENERGY STORAGE↗
DOE OSTI2022

Investigation of SiO x anode fading mechanism with limited capacity cycling

Silicon suboxide (SiO x ) is one of the promising anode materials for the next-generation lithium-ion batteries. However, SiO x has a severe capacity fading problem during cycling. It is thus desired to investigate the detailed fading mechanisms of SiO x anode materials. In this study, limited capacity cycling was employed to examine the electrochemical behaviors of the SiO x anode, and the lithiation/delithiation cycling was limited within a range of 10% theoretical capacity. This strategy minimizes the volume variation of SiO x materials upon charging/discharging, which helps to reveal their decay factors other than volume fluctuation. It is demonstrated that the instability of the SiO x surface during cycling was likely a parallel factor of active material fading, which seems to cause unfavored electrode interface rearrangements with lowered electric conductivity.

electric vehicles↗
NASA NTRS1972

Simultaneous L-band and VHF ionospheric fading effects at the geomagnetic equator

Simultaneous observations of ionspheric fading of 1550 MHz and 136 MHz radio waves from the ATS-5 spacecraft were recorded on the geomagnetic equator at Ancon, Peru. The observations were made during a period around the 1971 spring equinox; they show fades as great as 27 db at 136 MHz, and 6 db at 1550 MHz. The general characteristics of the scintillation signatures at the two frequencies are discussed with emphasis on comparison of the two frequencies with respect to rates and depths of fades. Typical statistical distributions of signal levels are also presented from which time availabilities of the signals relative to the median levels can be derived.

Sessions, W. B.↗
NASA NTRS1973

Ionospheric fading effects on the equatorial zone

Microwave fading of space communication channels in the equatorial region is caused by the effects of the disturbed ionosphere. Three dimensional plots of percentage occurence of very high frequency scintillation effects shown as a function of time of day and week of the year prove that, most fading occurs at nighttime and around the weeks of the equinox. The magnitude of fading at the equator violates existing scattering theories and must be taken into account when designing a microwave communication link to space.

Golden, T. S.↗
NASA NTRS1974

Convolutional code performance in fading channels

The performance of convolutional codes in fading channels typical of the planetary entry channel is examined in detail. Short constraint length codes are considered in conjunction with binary phase-shift-keyed (BPSK) modulation and Viterbi maximum likelihood decoding while for longer constraint length codes we consider sequential decoding utilizing both the Fano and Zigangirov-Jelinek (ZJ) algorithms. For short constraint length codes we are primarily interested in the bit error probability performance parameterized by the fading channel parameters. For longer constraint length codes interest will center on the effect of the fading channel parameters on the computational requirements of both the Fano and ZJ algorithms. In either case the effects of simple block interleaving in combatting the memory of the channel is thoroughly explored. The approach is analytic where possible otherwise resort is made to digital computer simulation.

Modestino, J. W.↗
NASA NTRS1975

Performance of coded MFSK in a Rician fading channel

The performance of convolutional codes in conjunction with noncoherent multiple frequency shift-keyed (MFSK) modulation and Viterbi maximum likelihood decoding on a Rician fading channel is examined in detail. While the primary motivation underlying this work has been concerned with system performance on the planetary entry channel, it is expected that the results are of considerably wider interest. Particular attention is given to modeling the channel in terms of a few meaningful parameters which can be correlated closely with the results of theoretical propagation studies. Fairly general upper bounds on bit error probability performance in the presence of fading are derived and compared with simulation results using both unquantized and quantized receiver outputs. The effects of receiver quantization and channel memory are investigated and it is concluded that the coded noncoherent MFSK system offers an attractive alternative to coherent BPSK in providing reliable low data rate communications in fading channels typical of planetary entry missions.

Modestino, J. W.↗
NASA NTRS1976

Performance of convolutionally encoded noncoherent MFSK modem in fading channels

The performance of a convolutionally encoded noncoherent multiple-frequency shift-keyed (MFSK) modem utilizing Viterbi maximum-likelihood decoding and operating on a fading channel is described. Both the lognormal and classical Rician fading channels are considered for both slow and time-varying channel conditions. Primary interest is in the resulting bit error rate as a function of the ratio between the energy per transmitted information bit and noise spectral density, parameterized by both the fading channel and code parameters. Fairly general upper bounds on bit error probability are provided and compared with simulation results in the two extremes of zero and infinite channel memory. The efficacy of simple block interleaving in combatting channel memory effects are thoroughly explored. Both quantized and unquantized receiver outputs are considered.

Modestino, J. W.↗
NASA NTRS1985

Performance analysis of the ALOHA protocol with replication in a fading channel for the Mobile Satellite Experiment

The analysis of the ALOHA random access protocol for communications channels with fading is presented. The protocol is modified to send multiple contiguous copies of a message at each transmission attempt. Both pure and slotted ALOHA channels are considered. A general two state model is used for the channel error process to account for the channel fading memory. It is shown that greater throughput and smaller delay may be achieved using repetitions. The model is applied to the analysis of the delay-throughput performance in a fading mobile communications environment. Numerical results are given for NASA's Mobile Satellite Experiment.

Clare, L. P.↗
NASA NTRS1987

The performance of trellis coded multilevel DPSK on a fading mobile satellite channel

The performance of trellis coded multilevel differential phase-shift-keying (MDPSK) over Rician and Rayleigh fading channels is discussed. For operation at L-Band, this signalling technique leads to a more robust system than the coherent system with dual pilot tone calibration previously proposed for UHF. The results are obtained using a combination of analysis and simulation. The analysis shows that the design criterion for trellis codes to be operated on fading channels with interleaving/deinterleaving is no longer free Euclidean distance. The correct design criterion for optimizing bit error probability of trellis coded MDPSK over fading channels will be presented along with examples illustrating its application.

Simon, Marvin K.↗
NASA NTRS1986

Performance analysis of replication ALOHA for fading mobile communications channels

This paper describes an ALOHA random access protocol for fading communications channels. A two-state Markov model is used for the channel error process to account for the channel fading memory. The ALOHA protocol is modified to send multiple contiguous copies of a message at each transmission attempt. Both pure and slotted ALOHA channels are considered. The analysis is applicable to fading environments where the channel memory is short compared to the propagation delay. It is shown that smaller delay may be achieved using replications and, in noisy conditions, can also improve throughput.

Yan, Tsun-Yee↗
NASA NTRS1988

The design of trellis coded MPSK for fading channels: Performance criteria

It has been well established that the appropriate criterion for optimum trellis-coded modulation design on the additive white Gaussian noise channel is maximization of the free Euclidean distance. It is shown that when the trellis-coded modulation is used on a Rician fading channel with interleaving/deinterleaving, the design of the code of optimum performance is guided by other factors, in particular, the length of the shortest error-event path, and the product of branch distances (possibly normalized by the Euclidean distance of the path) along the path. Athough maximum free distance (dfree) is still an important consideration, it plays a less significant role the more severe the fading is on the channel. These considerations lead to the definition of a new distance measure of optimization of trellis codes transmitted over Rician fading channels. If no interleaving/deinterleaving is used, then once again the design of the trellis code is guided by maximizing dfree.

Divsalar, Dariush↗