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At least 73 records · Page 4

SULI Report - Development of a Molten Salt Circulation Loop for in-situ Spectroscopy

This project supports the development of real time optical monitoring capabilities for molten salt reactor (MSR) environments by designing, testing, and refining a molten salt circulation loop suitable for combined laser induced breakdown spectroscopy (LIBS) and ultraviolet visible (UV Vis) absorption measurements. Online spectroscopic monitoring is increasingly important for nuclear safeguards, corrosion tracking, and material accountancy, yet MSR process fluids present substantial challenges due to their chemical complexity and hazards such as high temperatures and radiation. To address these needs, this work focuses on Phase I, the development of a room temperature aqueous circulation loop that serves as a surrogate platform for evaluating flow behavior, optical access, and component performance prior to high temperature salt operation. Initial testing identified several practical issues—including leaks, obstructions, and two-phase flow through the absorption cell—that were systematically resolved through hardware replacement, flow path redesign, and venturi pressure optimization. Relocating the flow cell upstream of the primary venturi enabled periods of stable single-phase flow, demonstrating the feasibility of integrating optical diagnostics into a circulation system. The results of Phase I provide essential design insight for Phase II, which will incorporate furnace compatible materials and LiCl KCl eutectic salt. Completion of the molten salt system will deliver a reusable testbed for evaluating multimodal spectroscopic techniques, advancing nondestructive, real time monitoring tools for future MSR and nuclear fuel cycle applications.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗

Supports with integrated sensors for nuclear reactor steam generators, and associated systems and methods

Supports with integrated sensors for nuclear reactor steam generators, and associated systems and methods, are disclosed. A representative method for forming a nuclear-powered steam generator includes forming an instrumented support, the instrumented support including a carrier portion and a retainer portion, with at least one of the carrier portion or the retainer portion being integrally formed with a sensor via an additive manufacturing process. The method can further include coupling the sensor to a communication link, supporting a helical steam conduit on the instrumented support, and installing the helical steam conduit and the instrumented support in a nuclear reactor. The helical steam conduit is positioned along a primary flow path, which is in turn positioned to circulate a heated primary flow in thermal communication with the helical steam conduit.

Welter, Kent↗

Testing of Microchannels and Lab-Grown Stress Corrosion Cracks for Quantification of Aerosol Transmission

The formation of a stress corrosion crack (SCC) in the canister wall of a dry cask storage system (DCSS) has been identified as a potential issue for the long-term storage of spent nuclear fuel. The presence of an SCC in a storage system could represent a through-wall flow path from the canister interior to the environment. Modern, vertical DCSSs are of particular interest due to the commercial practice of using higher backfill pressures in the canister, up to approximately 800 kPa, compared to their horizontal counterparts. This pressure differential offers a relatively high driving potential for blowdown of any particulates that might be present in the canister. In this study, the rates of gas flow and aerosol transmission of a spent fuel surrogate through an engineered microchannel with dimensions representative of an SCC were evaluated experimentally using coupled mass flow and aerosol analyzers. The microchannel was formed by mating two gage blocks with a linearly tapering slot orifice nominally 13 μm (0.005 in.) tall on the upstream side and 25 μm (0.0010 in.) tall on the downstream side. The orifice is 12.7 mm (0.500 in.) wide by 8.86 mm (0.349 in.) long (flow length). Surrogate aerosols of cerium oxide, CeO 2 , were seeded and mixed with either helium or air inside a pressurized tank. The aerosol characteristics were measured immediately upstream and downstream of the simulated SCC at elevated and ambient pressures, respectively. These data sets are intended to add to previous testing that characterized SCCs under well-controlled boundary conditions through the inclusion of testing improvements that establish initial conditions in a more consistent way. While the engineered microchannel has dimensions similar to actual SCCs, it does not reproduce the tortuous path the aerosol laden flow would have to traverse for eventual transmission. SCCs can be rapidly grown in a laboratory setting given the right conditions, and initial characterization and clean-flow testing has begun on lab grown crack samples provided to Sandia National Laboratories (SNL). Many such samples are required to produce statistically relevant transmission results, and SNL is developing a procedure to produce samples in welded steel plates. These ongoing testing efforts are focused on understanding the evolution in both size and quantity of a hypothetical release of aerosolized spent fuel particles from failed fuel to the canister interior and ultimately through an SCC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Impacts of Mixed-Wettability on Brine Drainage and Supercritical CO 2 Storage Efficiency in a 2.5-D Heterogeneous Micromodel

Geological carbon storage (GCS) involves unstable drainage processes, the formation of patterns in a morphologically unstable interface between two fluids in a porous medium during drainage. The unstable drainage processes affect CO 2 storage efficiency and plume distribution and can be greatly complicated by the mixed-wet nature of rock surfaces common in hydrocarbon reservoirs where supercritical CO 2 (scCO 2 ) is used in enhanced oil recovery. Here, we performed scCO 2 injection (brine drainage) experiments at 8.5 MPa and 45°C in heterogeneous micromodels, two mixed-wet with varying water- and intermediate-wet patches, and one water-wet. The flow regime changes from capillary fingering through crossover to viscous fingering in the micromodels of the same pore geometry but different wetting surfaces at displacement rates with logCa (capillary number) increasing from –8.1 to –4.4. While the mixed-wet micromodel with uniformly distributed intermediate-wet patches yields ~0.15 scCO 2 saturation increase at both capillary fingering and crossover flow regimes (–8.1 ≤ logCa ≤ –6.1), the one heterogeneous wetting to scCO 2 results in ~0.09 saturation increase only at the crossover flow regime (–7.1 ≤ logCa ≤ –6.1). The interconnected flow paths in the former are quantified and compared to the channelized scCO 2 flow through intermediate-wet patches in the latter by topological analysis. At logCa > –6.1 (near well), the effects of wettability and pore geometry are suppressed by strong viscous force. Both scCO 2 saturation and distribution suggest the importance of wettability on CO 2 storage efficiency and plume shape in reservoirs and capillary leakage through caprock at GCS conditions.

58 GEOSCIENCES↗

Understanding Flow Characteristics in Metal Additive Manufacturing

In fluid flow, the frictional effects from interior surfaces of flow components create pressure loss across the surface. Understanding this inherent pressure loss due to friction and other phenomena is important when designing a flow system. For conventional manufacturing, friction loss has been empirically studied and is well known in the engineering community. However, newer manufacturing techniques, such as laser powder bed fusion (LPBF), an additive manufacturing technique, need to be understood. The inherent flow conditions resulting from the additive processes were studied. Test samples were printed with the flow path oriented in the vertical direction with different channel diameters to characterize the inherent fundamental flow properties of the process. Moody diagrams were replicated for a greater understanding of possibilities and shortfalls when implementing LPBF into design applications. Experimental flow testing revealed that greater effective sand grain roughness resulted from this process when compared to conventional machining methods. This roughness did not correlate well to the average roughness measured with a laser scanning microscope but was consistent with the average particle size of the powder metal feedstock.

42 ENGINEERING↗

Computational Fluid Dynamics Simulations to Assess Spatial Variability and Optimal Ventilation Scenarios for Biological Laboratory Exposures

A significant amount of uncertainty exists regarding potential human exposure to laboratory biomaterials and organisms in Biosafety Level 2 (BSL-2) research laboratories. Computational fluid dynamics (CFD) modeling is proposed as a way to better understand potential impacts of different combinations of biomaterials, laboratory manipulations, and exposure routes on risks to laboratory workers. Here, in this study, we use CFD models to simulate airborne concentrations of contaminants in an actual BSL-2 laboratory under different configurations. Results show that ventilation configuration, sampling location, and contaminant source location can significantly impact airborne concentrations and exposures. Depending on the source location and airflow patterns, the transient and time-integrated concentrations varied by several orders of magnitude. Contaminant plumes from sources located near a return vent (or exhaust like a fume hood or ventilated biosafety cabinet) are likely to be more contained than sources that are further from the exhaust. Having a direct flow between the source and the exhaust (through-flow condition) may reduce potential exposures to individuals outside the air flow path. Designing a BSL-2 room with ventilation and airflow patterns that maximize through-flow conditions to the return/exhaust vents and minimize dispersion and mixing throughout the room is, therefore, recommended. CFD simulations can also be used to assist in characterizing the impacts of supply and return vent locations, room layout, and source locations on spatial and temporal contaminant concentrations. In addition, proper placement of particle sensors can also be informed by CFD simulations to provide additional characterization and monitoring of potential exposures in BSL-2 facilities.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Influence of Agricultural Managed Aquifer Recharge (AgMAR) and Stratigraphic Heterogeneities on Nitrate Reduction in the Deep Subsurface

Agricultural managed aquifer recharge (AgMAR) is a strategy whereby surface water is used to intentionally flood croplands to recharge underlying aquifers. However, nitrate (NO 3 - ) contamination in agriculturally intensive regions poses a threat to groundwater resources under AgMAR. We use a reactive transport model to understand the effects of AgMAR management strategies (i.e., by varying the frequency, duration between flooding events, and amount of water) on NO 3 - leaching to groundwater under different stratigraphic configurations and antecedent moisture conditions. We examine the potential of denitrification and nitrogen retention in deep vadose zone sediments (~15 m) using variable AgMAR application rates on two-dimensional representations of differently textured soils, soils with discontinuous bands/channels, and with preferential flow paths characteristic of agricultural fields. Simulations indicate finer textured sediments, alone or embedded within/adjacent to high flow regions, are important reducing zones providing conditions needed for denitrification. Simulation results suggest that applying water all-at-once rather than in increments transports higher concentrations of NO 3 - deeper into the profile, which may exacerbate groundwater quality. This transport into deeper depths can be aggravated by wetter antecedent soil moisture conditions. However, applying water all-at-once also increases denitrification within the vadose zone by promoting anoxic conditions. We conclude that AgMAR can be designed to enhance denitrification in the subsurface and reduce NO 3 - leaching to groundwater, while specifically accounting for lithologic heterogeneity, antecedent soil moisture conditions, and depth to the water table. Our findings are potentially relevant to other systems that experience flooding inundation such as floodplains and dedicated recharge basins.

54 ENVIRONMENTAL SCIENCES↗

Laminar Flow Heat Transfer In Helical Oval-Twisted Tube for Heat Exchanger Applications

The heat transfer performance of a novel tube configuration that combines the swirling velocity induced by oval-twisting and secondary flow generated by a helical geometrical flow path is presented. The Nusselt number (Nu) and friction factor (f) are compared for the laminar flow regime (Re = 250- 2000) under isothermal wall conditions. Under the same flow and boundary conditions, the oval-twisted helical tube increased the Nu and slightly increased the f over the circular helical tube. The best performance with the highest Nuand lowest f occurs at the coil curvature ratio (d h /D) of 0.17. The quantified enhancement performance factor (h) shows a 46 - 56% increase for the oval-twisted helical tube over the circular helical tube with d h /D = 0.17. Correlations for the Nu and f are developed and agreed with the numerical results: ± 6% and ± 5% for the Nu and f, respectively.

42 ENGINEERING↗

Predictive Modeling of Local Film-Cooling Flow on a Turbine Rotor Blade

Abstract In the turbine section of a modern gas turbine engine, components exposed to the main gas path flow rely on cooling air to maintain hardware durability targets. Therefore, monitoring turbine cooling flow is essential to the diagnostic and prognostic efficacy of a condition-based operation and maintenance (CBOM) approach. This study supports CBOM goals by leveraging supervised machine learning to estimate relative changes to local film-cooling flowrate using surface temperature measured on the pressure side of a rotating turbine blade operating at engine-relevant aerothermal conditions. Throughout the lifetime of a film-cooled turbine component, characteristics of the film-cooling flow—such as film trajectory and cooling effectiveness—vary as degradation-driven geometry distortions occur, which ultimately affects the relationship between the model input and the model output—film-cooling flowrate predictions. The present study addresses this complication by testing a data-driven model on multiple turbine blades of the same nominal design, but with each blade exhibiting different localized film-cooling flow characteristics. By testing the model in this manner, strategies for mitigating the detrimental effects of film-cooling flow characteristic variations on model performance were investigated, and the corresponding flowrate prediction accuracy was quantified.

Engineering↗

Effects of structure and volcanic stratigraphy on groundwater and surface water flow: Hat Creek basin, California, USA

Abstract Hydrogeologic systems in the southern Cascade Range in California (USA) develop in volcanic rocks where morphology, stratigraphy, extensional structures, and attendant basin geometry play a central role in groundwater flow paths, groundwater/surface-water interactions, and spring discharge locations. High-volume springs (greater than 3 m 3 /s) flow from basin-filling (<800 ka) volcanic rocks in the Hat Creek and Fall River tributaries and contribute approximately half of the average annual flow of the Pit River, the largest tributary to Shasta Lake. A hydrogeologic conceptual framework is constructed for the Hat Creek basin combining new geologic mapping, water-well lithologic logs, a database of active faults, LiDAR mapping of faults and volcanic landforms, streamflow measurements and airborne thermal infrared remote sensing of stream temperature. These data are used to integrate the geologic structure and the volcanic and volcaniclastic stratigraphy to create a three-dimensional interpretation of the hydrogeology in the basin. Two large streamflow gains from focused groundwater discharge near Big Spring and north of Sugarloaf Peak result from geologic barriers that restrict lateral groundwater flow and force water into Hat Creek. The inferred groundwater-flow barriers divide the aquifer system into at least three leaky compartments. The two downstream compartments lose streamflow in the upstream reaches (immediately downstream of the groundwater-flow barriers) and gain in downstream reaches with the greatest inflows immediately upstream of the barriers.

Geology↗

Metal foam heat exchangers for air and gas cooling and heating applications

Improved heat exchangers according to several embodiments are provided. The heat exchangers provide improved heat transfer for air flow in wet and dry operating conditions, while minimizing pressure drop across the heat exchanger in some applications. According to one embodiment, an improved heat exchanger includes a plurality of metal foam fins between adjacent heat exchange conduits, the heat exchange conduits being arranged parallel to each other to define parallel flow paths between an inlet header and an outlet header. The metal foam fins occupy a cross-flow region between adjacent conduits, the fins having a fixed angular orientation or being rotatable in unison to vary the thermal capacitance of the heat exchanger.

Nawaz, Kashif↗

Results of Multiple Tracer Injections into Fractures in the EGS Collab Testbed-1

The EGS Collab project constructed an intermediate scale (~10-20 m) testbed at the 4850 level of the Stanford Underground Research Facility (SURF) in South Dakota for testing and validating fracture stimulation and flow/transport models. This testbed consists of eight ~200 ft (~60 m) HQ-diameter (9.6 cm) boreholes that are drilled into the crystalline rocks of the Poorman Formation from the West Access Drift tunnel. Of the eight boreholes, one borehole is used as an injection/stimulation well, while another sub-parallel borehole located about 10 m away from the injection well is used as a production well, and rest of the other boreholes are used as geophysical/fluid sampling monitoring wells. Hydraulic stimulation activities were conducted at three locations along the injection hole in an attempt to create direct fracture connections to the production hole. A flow system has been established between injection and production boreholes through a set of hydraulically stimulated fractures propagated from a notch located at 164 ft in the injection hole. Although we planned for a single production well, a set of natural fractures in the testbed is believed to have intersected the stimulated hydraulic fractures and provided additional flow paths for water to be transported to the drift through multiple monitoring boreholes and weep zones. As the flow tests continued after stimulation activities, single or a combination of two or three producers become dominant producers at different times, mostly as a response to intersection of hydraulic fracture and testbed wells, activation of natural fractures and making new leak points to the monitoring wells, resealing of leaky wells, and so on. Since late October 2018, multiple tracers were injected into the fracture system at the 164 ft location that involves both stimulated and natural fractures, and tracers were recovered from multiple locations in nearby wells and weep. The cumulative water recoveries over the time have ranged from 50 to 90%; however, the injected tracer recoveries from various production sources are much less (ranging from a few percentages to 38%). Changes in water/tracer recoveries, shifting of major producing wells from one well to the others, and other observations (e.g., microseismic, electric resistivity tomography, etc.) indicate a testbed that has undergone several changes since October 2018. In this paper, we present tracer recovery data accumulated during several tracer campaigns, provide conceptual testbed flow pathways, and provide observations that suggest a evolutionary nature of fracture volume and fracture geometry in the testbed.

15 GEOTHERMAL ENERGY↗

Wave function analysis with a maximum flow algorithm

An efficient algorithm for computing the maximum-flow path in a network is applied to the identification of the dominant configuration state functions (CSFs) in a graphically contracted function (GCF), configuration interaction, wave function. The flow network is a space of spin-adapted CSFs represented by a Shavitt graph, wherein the nodes correspond to orbital occupations and spin quantum numbers. The graph nodes are connected by arcs, and an arc density is defined as sums of the associated squared CSF coefficients. A max-min approach determines an upper bound to the maximum possible incoming flow for each graph node. A backtracking step generates a candidate walk and is followed by a limited search of alternative branching paths for the dominant CSF. The arc density contributions are removed from the graph, and the algorithm is reapplied to the updated graph. This list of generated walks can be partitioned in order to guarantee that the dominant CSFs have been identified. All of the steps in this algorithm are computationally efficient and do not depend on the potentially large dimension of the underlying linear CSF expansion space. An analysis of low-lying valence states of C-2 illustrates the method.

74 ATOMIC AND MOLECULAR PHYSICS↗

Shifting groundwater fluxes in bedrock fractures: Evidence from stream water radon and water isotopes

Geologic features (e.g., fractures and alluvial fans) can play an important role in the locations and volumes of groundwater discharge and degree of groundwater-surface water (GW-SW) interactions. However, the role of these features in controlling GW-SW dynamics and streamflow generation processes are not well constrained. GW-SW interactions and streamflow generation processes are further complicated by variability in precipitation inputs from summer and fall monsoon rains, as well as declines in snowpack and changing melt dynamics driven by warming temperatures. Using high spatial and temporal resolution radon and water stable isotope sampling and a 1D groundwater flux model, we evaluated how groundwater contributions and GW-SW interactions varied along a stream reach impacted by fractures (fractured-zone) and below the fractured hillslope (non-fractured zone) in Coal Creek, a Colorado River headwater stream affected by summer monsoons. During early summer, groundwater contributions from the fractured zone dominated, but declined throughout the summer. Groundwater contributions from the non-fractured zone were constant throughout the summer and became proportionally more important later in the summer. We hypothesize that groundwater in the non-fractured zone is dominantly sourced from a high-storage alluvial fan at the base of a tributary that is connected to Coal Creek throughout the summer and provides consistent groundwater influx. Water isotope data revealed that Coal Creek responds quickly to incoming precipitation early in the summer, and summer precipitation becomes more important for streamflow generation later in the summer. We quantified the change in catchment dynamic storage and found it negatively related to stream water isotope values, and positively related to modeled groundwater discharge and the ratio of fractured zone to non-fractured zone groundwater. Importantly, we interpret these relationships as declining hydrologic connectivity throughout the summer leading to late summer streamflow supported predominantly by shallow flow paths, with variable response to drying from geologic features based on their storage. As groundwater becomes more important for sustaining summer flows, quantifying local geologic controls on groundwater inputs and their response to variable moisture conditions may become critical for accurate predictions of streamflow.

54 ENVIRONMENTAL SCIENCES↗

RELAP-7 Application and Enhancement for FLEX Strategies and ATF Behavior under Extended Loss of AC Power Conditions

This report summarizes the results of a three-year research project sponsored by the U.S. Department of Energy (DOE) Nuclear Energy University Program (NEUP) to enhance and apply the RELAP-7 code by adding and improving several important components (e.g., a mechanistic Reactor Core Isolation Cooling (RCIC) system model) for thermal hydraulic studies of LWRs under ELAP conditions and evaluating the time available for transition to portable FLEX equipment. The project team included University of Massachusetts–Lowell, The Ohio State University, Texas A&M University, Idaho National Laboratory and Oak Ridge National Laboratory. In the Fukushima accident, it was found that the RCIC system played a crucial role in delaying core meltdown by almost three days in Fukushima Daiichi Unit 2, because of self-regulated operation of the steam driven RCIC turbine-pump injection system. Steam flow in the convergent-divergent nozzles of the RCIC Terry turbine is two-phase non-equilibrium transonic flow with homogenous nucleation condensation. To more accurately predict the dynamic process and behavior of the transonic compressible steam flow, a one-dimensional transient two-phase analytical model is presented. A simplified four-fluid model was employed in the present work with the consideration of four separate fluid fields: vapor, liquid film, entrained droplets and condensed droplets. The mass, momentum and energy interactions between the fluids were considered and modeled. An extended seven-equation non-equilibrium critical flow model was developed to obtain the critical pressure and velocities of each phase at the nozzle throat. To predict the wetness in the divergent section, a mechanistic nucleation condensation model was integrated in the nozzle analysis model, considering the generation and consequent growth of droplets. The governing differential equations on a staggered grid were discretized using the second-order Lax-Wendroff scheme with a flux limiter, and the Semi-Implicit Method for Pressure-Linked Equation (SIMPLE) algorithm was employed to solve the discrete linear system. To demonstrate the predictability and reliability of the physical models and the numerical method proposed in the present work, three representative nozzles were modeled and simulated. The results show good agreement with the available experimental data, even for condensation shock. Then, the 1D nozzle model was employed to obtain nozzle flow tables of the Terry turbine nozzle for different working pressures which can cover the operation pressure range of the RCIC system. A mechanistic RCIC turbine-pump system model was developed and implemented in the system code TRACE to simulate dynamic responses of the RCIC system under Beyond Design Basis Accident (BDBA) conditions. The turbine-pump governing equations are based on the control volume approach of the angular momentum balance. The physics based mechanistic RCIC model was developed using the TRACE control system components (i.e., signal variables, control blocks, and tables), and incorporated into a TRACE boiling water reactor (BWR) model. The TRACE model in this report has a detailed nodalization of the reactor pressure vessel (RPV), and all of the major flow paths and system components, including the safety relief valves (SRVs) and the containment suppression pool and drywell. Based on the nozzle flow tables generated from the 1D nozzle model developed, the turbine drive torque can be calculated from table lookup. Since the detailed specifications of the RCIC pump are unavailable, the homologous curves for a Bingham pump were used in the current pump component. A station black-out (SBO) accident test problem was selected to demonstrate the TRACE RCIC model. The short-term SBO simulations were performed for two cladding materials: Zircaloy and FeCrAl, to demonstrate the effect of the accident tolerant fuel cladding on fuel heat-up under BDBA accident conditions. The wetwell plays a vital safety role in SBO and other BWR accident scenarios in that it can reduce containment pressure and supply additional core make-up water. The suppression pool temperature distribution has a very large impact on both RPV and containment pressure. Thus, another novel contribution of the project comes mainly from an improved, systems-level wetwell model which can capture buoyancy-induced thermal stratification effects due to steam injection and condensation. A two-zone stratified wetwell model has been implemented in RELAP-7 and some results from that model are presented. This wetwell model is capable of simulating thermal stratification due to a low steam mass injection rate. With a low mass flow rate, the model assumes that all the steam condenses within the pipe and the resulting plume can be approximated with a purely buoyant, heat-source driven model. The wetwell model developed with these assumptions is adequate to simulate slow transients such as extended SBO transients.

42 ENGINEERING↗

Efficient Thermal Energy Storage with Radial Flow in Packed Beds

Thermal energy storage (TES) is a way to store excess heat in order to generate power later. These types of systems are valuable in the solar industry, where power production can still occur when sunlight is not available. This not only increases system flexibility, it drives down the cost of electricity. One option to store thermal energy is with a packed bed where the storage media resides in a cylindrical container. Flow from one end of the cylinder to the other deposits or recovers heat (axial flow). While a promising technology in terms of energy storage, it exhibits a high pressure drop that lowers overall system efficiency. This project seeks to flow the heat transfer fluid through the storage media in the radial direction. This system offers the potential to retain reasonable thermal performance while substantially lowering the pressure drop. The overall goal was to assess the performance of radial flow experimentally and numerically. Three main designs were considered in this work. The first system utilized a central pipe and four receiving pipes near the wall. The second system utilized a central pipe and an annulus with holes near the wall. The last approach considered segmenting the bed so only select zones would receive flow in the radial direction. In a high-aspect ratio system, the hole patterns in the piping are important for ensuring even flow into the bed, and a major design effort was testing holes patterns to promote even flow. The four pipe system was shown to be not feasible, as preferential flow paths occur that do not allow even and full heating of the packed bed. The annular system can lead to even flow, but the results show this is better accomplished through larger piping instead of considering variations in the hole pattern along the axial length of the pipe. Segmenting the bed can lead to similar exergetic performance when compared to axial or radial flow. However, the pressure drop in the segmented design is likely too high for practical implementation. A baseline commercial design showed exergetic efficiencies for axial, radial, and radial segments of 81.6%, 82.8%, and 80.2%, respectively. Pressure drop for the axial and radial results were 2.36 psi and 2.45 psi, respectively, with segments being nearly an order of magnitude higher. At these large scales, the aspect ratio of the system is important. From a baseline of 0.64, an aspect ratio of 0.32 for radial flow showed an exergetic efficiency of 86% but a pressure drop of 5.39 psi. All of these results provide new insights into packed bed thermal energy storage with radial flow. Competing effects must be considered when designing a radial system, and results show a radial design can show strong thermal results at the expense of system efficiencies from pressure drop. The COMSOL models used in this analysis are available to the public and other researchers. Public benefits include a potential increase in the efficiency of packed bed thermal energy storage. Higher efficiency in storage promotes green energy technologies while reducing costs.

14 SOLAR ENERGY↗

Influence of Agricultural Managed Aquifer Recharge (AgMAR) and Stratigraphic Heterogeneities on Nitrate Reduction in the Deep Subsurface

This data package contains input files for TOUGHREACT for a modeling study examining the effects of managed aquifer recharge on agricultural lands on nitrate cycling and transport in the Central Valley of CA near Modesto. The files contain all the geochemical species, reactions, and hydrological parameters for the model. The files are text files used for the TOUGH family of code created by LBNL. To use the files a license is required. https://tough.lbl.gov/licensing-download/toughreact-licensing-download/Accompanying Paper Abstract: Agricultural managed aquifer recharge (AgMAR) is a proposed management strategy whereby surface water flows are used to intentionally flood croplands with the purpose of recharging underlying aquifers. However, legacy nitrate (NO3-) contamination in agriculturally-intensive regions poses a threat to groundwater resources under AgMAR. To address these concerns, we use a reactive transport modeling framework to better understand the effects of AgMAR management strategies (i.e., by varying the frequency, duration between flooding events, and amount of water) on N leaching to groundwater under different stratigraphic configurations and antecedent moisture conditions. In particular, we examine the potential of denitrification and nitrogen retention in deep vadose zone sediments (~15 m) using variable AgMAR application rates on two-dimensional representations of differently textured soils, soils with discontinuous bands/channels, and soils with preferential flow paths characteristic of typical agricultural field sites. Our results indicate that finer textured sediments, such as silt loams, alone or embedded within high flow regions, are important reducing zones providing conditions needed for denitrification. Simulation results further suggest that applying water all-at-once rather than in increments for a fixed volume of recharge transports higher concentrations of NO3- deeper into the profile, which has the potential to exacerbate groundwater quality. This transport into deeper depths can be aggravated by wetter antecedent soil moisture conditions. However, applying water all-at-once also increases denitrification within the vadose zone by promoting anoxic conditions. We conclude that AgMAR management strategies can be designed to enhance denitrification in the subsurface and reduce N leaching to groundwater, while specifically accounting for lithologic heterogeneity, antecedent soil moisture conditions, and depth to the water table. Our findings are potentially relevant to other systems that experience flooding inundation such as riparian corridors, floodplains, wetlands, and other managed landscapes like dedicated recharge basins.

54 ENVIRONMENTAL SCIENCES↗

Semi-Annual Report for Horizontal Compact High Temperature Gas Reactor (HC-HTGR) Development during Performance Period October 2022-March 2023

Horizontal Compact High Temperature Gas Reactor (HC-HTGR) is being designed by a multi-disciplinary team of nuclear, mechanical, and structural engineers under the support of a DOE-NE Advanced Reactor Demonstration Program’s Advanced Reactor Concepts-20 (ARC-20) award. The objective of this ARC-20 project is to deliver a conceptual design for the proposed HC-HTGR in 3 years and support its commercialization as a safe, low-cost HTGR. Argonne National Laboratory (Argonne) is responsible for the design and analysis of the reactor cavity cooling system (RCCS) as a safety system for passive decay heat removal of the reactor concept. Additionally, Argonne is providing analysis of the primary heat transport system to ensure temperatures in the reactor systems, structures and components with significant safety margins during normal operation and design basis accident scenarios. This third semi-annual report summarized the progress made at Argonne on the two tasks during the first half of FY23. As a part of the RCCS design task, a design process for the water panel and the system configuration was performed to improve the thermal performance of the RCCS. The updated water panel design had achieved enhanced thermal performance with 0.96 MWth capability with major design updates made in structural interfaces with the RPV and initial configuration of the water tanks. The loop configuration of the RCCS has been proposed to have two independently working loops for system redundancy. A water panel material study was performed focusing on the use of carbon steel in water systems. Additional modeling strategies of primary system thermal fluids analyses were developed to meet modeling needs that are not well suited for the 1D-3D assembly level approach. The first of these is a reduced order assembly model, in which fuel centered unit cells are used to represent a fuel assembly. The 2D approach used in this model is much more computationally efficient, making this model useful for full core transient scenarios where fuel to coolant heat transfer is still the dominant flow path. The next model is the 3D core conduction model to be used to analyze decay heat removal in loss of primary system flow scenarios. Because these scenarios require a large domain to be modeled, a homogenized core model is being pursued to reduce the required computational costs. To accurately model decay heat scenarios it is necessary to couple a RCCS model to the 3D core conduction model. A simplified case is presented to demonstrate how the coupling methodology will be applied to the full core 3D conduction model.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗