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Global water cycle

This research is the MSFC component of a joint MSFC/Pennsylvania State University Eos Interdisciplinary Investigation on the global water cycle extension across the earth sciences. The primary long-term objective of this investigation is to determine the scope and interactions of the global water cycle with all components of the Earth system and to understand how it stimulates and regulates change on both global and regional scales. Significant accomplishments in the past year are presented and include the following: (1) water vapor variability; (2) multi-phase water analysis; (3) global modeling; and (4) optimal precipitation and stream flow analysis and hydrologic processes.

Robertson, Franklin↗

The Aqua-Aura Train

This talk will focus on the afternoon constellation of EOS platforms and the scientific benefits that arise from this formation. The afternoon EOS constellation or the "A-train" will provide unprecedented information on clouds and aerosols. At 1:30 PM crossing time EOS-Aqua begins the train with the MODIS, CERES and AIRS instruments making aerosol, cloud, radiation budget , temperature and water vapor measurements. AMSR-E will also make total column water measurements. Following Aqua by one minute, Cloudsat will make active radar precipitation measurements as and PICASSOCENA will make lidar measurements of clouds and aerosols. Fourteen minutes later, EOS-Aura will pass through the same space making upper troposphere water vapor and ice profiles as well as some key trace gases associated with convective processes (MLS and HIRDLS). Additional measurements of aerosols will be made by Aura's OMI instrument.

Schoeberl, Mark↗

Thermal Conductivity Studies of Sedimentary Materials from Central Australia and the Implications for Mars

In the search for life on Mars, investigating fluvial deposits will be a high priority for future landers. Although there is abundant evidence that fluvial processes worked with great intensity in the past (e.g., outflow channels, valley networks, and modified impact craters), aeolian processes dominate under the current environmental conditions. In fact there is evidence that extensive aeolian deposits may have filled in valley networks [1] and even shallow depressions where water may have ponded [2]. Thus, quite often there may be a disparity between the geology identified by orbital data and the geology accessible to a lander. Determining where fluvial deposits occur on the surface is important for addressing NASA's goal to "follow the water." In order to do that, however, existing remote sensing data must be evaluated and a set of diagnostic criteria for recognizing fluvial deposits must be established. To that end, we are conducting a first order analysis of the thermal characteristics of fluvial and aeolian materials collected from central Australia.

Craddock, Robert A.↗

Hints of Habitable Environments on Mars Challenge Our Studies of Mars-Analog Sites on Earth

Life as we know it requires water with a chemical activity (alpha) >or approx.0.6 and sources of nutrients and useful energy. Some biota can survive even if favorable conditions occur only intermittently, but the minimum required frequency of occurrences is poorly understood. Recent discoveries have vindicated the Mars exploration strategy to follow the water. Mars Global Surveyor s Thermal Emission Spectrometer (TES) found coarse-grained hematite at Meridiani Planum. Opportunity rover confirmed this and also found evidence of ancient sulfate-rich playa lakes and near-surface groundwater. Elsewhere, TES found evidence of evaporitic halides in topographic depressions. But alpha might not have approached 0.6 in these evaporitic sulfate- and halide-bearing waters. Mars Express (MEX) and Mars Reconnaissance Orbiter (MRO) found extensive sulfate evaporites in Meridiani and Valles Marineris. MEX found phyllosilicates at several sites, most notably Mawrth Valles and Nili Fossae. MRO's CRISM near-IR mapper extended the known diversity and geographic distribution of phyllosilicates to include numerous Noachian craters. Phyllosilicates typically occur at the base of exposed ancient rock sections or in sediments in early Hesperian craters. It is uncertain whether the phyllosilicates developed in surface or subsurface aqueous environments and how long aqueous conditions persisted. Spirit rover found remarkably pure ferric sulfate, indicating oxidation and transport of Fe and S, perhaps in fumaroles or hot springs. Spirit also found opaline silica, consistent with hydrothermal activity. CRISM mapped extensive silica deposits in the Valles Marineris region, consistent with aqueous weathering and deposition. CRISM also found ultramafic rocks and magnesite at Nili Fossae, consistent with serpentinization, a process that can sustain habitable environments on Earth. The report of atmospheric methane implies subsurface aqueous conditions. A working hypothesis is that aqueous environments persisted in the near-subsurface for hundreds of millions of years and might exist even today. Studies of Mars-analog environments must better understand subsurface nonphotosynthetic ecosystems and their biosignatures in mafic and ultramafic terranes. Studies must determine minimum needs for water activity and energy and also establish survival limits when conditions that support active metabolism and propagation become progressively less frequent over time.

desMarais, David J↗

Materials Combustion Testing and Combustion Product Sensor Evaluations in FY12

NASA Centers continue to collaborate to characterize the chemical species and smoke particles generated by the combustion of current space-rated non-metallic materials including fluoropolymers. This paper describes the results of tests conducted February through September 2012 to identify optimal chemical markers both for augmenting particle-based fire detection methods and for monitoring the post-fire cleanup phase in human spacecraft. These studies follow up on testing conducted in August 2010 and reported at ICES 2011. The tests were conducted at the NASA White Sands Test Facility in a custom glove box designed for burning fractional gram quantities of materials under varying heating profiles. The 623 L chamber was heavily instrumented to quantify organics (gas chromatography/mass spectrometry), inorganics by water extraction followed by ion chromatography, and select species by various individual commercially-available sensors. Evaluating new technologies for measuring carbon monoxide, hydrogen cyanide, hydrogen fluoride, hydrogen chloride and other species of interest was a key objective of the test. Some of these sensors were located inside the glovebox near the fire source to avoid losses through the sampling lines; the rest were located just outside the glovebox. Instruments for smoke particle characterization included a Tapered Element Oscillating Microbalance Personal Dust Monitor (TEOM PDM) and a TSI Dust Trak DRX to measure particle mass concentration, a TSI PTrak for number concentration and a thermal precipitator for collection of particles for microscopic analysis. Materials studied included Nomex®, M22759 wire insulation, granulated circuit board, polyvinyl chloride (PVC), Polytetrafluoroethylene (PTFE), Kapton®, and mixtures of PTFE and Kapton®. Furnace temperatures ranged from 340o to 640o C, focusing on the smoldering regime. Of particular interest in these tests was confirming burn repeatability and production of acid gases with different fuel mixture compositions, as well as the dependence of aerosol concentrations on temperature.

Smoke↗

Materials Combustion Testing and Combustion Product Sensor Evaluations in FY12

NASA Centers continue to collaborate to characterize the chemical species and smoke particles generated by the combustion of current space-rated non-metallic materials including fluoropolymers. This paper describes the results of tests conducted February through September 2012 to identify optimal chemical markers both for augmenting particle-based fire detection methods and for monitoring the post-fire cleanup phase in human spacecraft. These studies follow up on testing conducted in August 2010 and reported at ICES 2011. The tests were conducted at the NASA White Sands Test Facility in a custom glove box designed for burning fractional gram quantities of materials under varying heating profiles. The 623 L chamber was heavily instrumented to quantify organics (gas chromatography/mass spectrometry), inorganics by water extraction followed by ion chromatography, and select species by various individual commercially-available sensors. Evaluating new technologies for measuring carbon monoxide, hydrogen cyanide, hydrogen fluoride, hydrogen chloride and other species of interest was a key objective of the test. Some of these sensors were located inside the glovebox near the fire source to avoid losses through the sampling lines; the rest were located just outside the glovebox. Instruments for smoke particle characterization included a Tapered Element Oscillating Microbalance Personal Dust Monitor (TEOM PDM) and a TSI Dust Trak DRX to measure particle mass concentration, a TSI PTrak for number concentration and a thermal precipitator for collection of particles for microscopic analysis. Materials studied included Nomex(R), M22759 wire insulation, granulated circuit board, polyvinyl chloride (PVC), Polytetrafluoroethylene (PTFE), Kapton(R), and mixtures of PTFE and Kapton(R). Furnace temperatures ranged from 340 to 640 C, focusing on the smoldering regime. Of particular interest in these tests was confirming burn repeatability and production of acid gases with different fuel mixture compositions, as well as the dependence of aerosol concentrations on temperature.

Combustion↗

Possible Stick-Slip Mechanism for Whillans Ice Stream

Tidally-induced stick-slip motion in the mouth of Whillans Ice Stream provides a unique natural experiment in ice-stream response behavior and fiom which we might learn a great deal about subglacial till properties and sub-ice-stream conditions. At the IGS Symposium on Fast Glacier Flow (Yakutat, 2002), we reported our observations of stick- slip motion and demonstrated its synchronicity with tidal forcing. Recently, we have completed additional processing of our GPS data in differential mode. It reveals more details of the stick-slip events and illustrates that within 30 seconds, the temporal interval of our data, the ice stream accelerates to a speed corresponding to a completely lubricated bed. While details of individual events vary, there seems to be strong evidence of an elastic rebound on the time scale of one hour following most events. This suggests the event involves the release of stored elastic strain energy in the ice. The similar displacements of events suggest further that till or subglacial hydrologic properties limit the amount of elastic strain released in any single event. We follow a line of reasoning that dilatant strengthening limits the slip displacement and present model of the stick-slip process. To match the observed delay between the peak ocean tide and stick-slip events, our model includes a propagating pressure wave in the subglacial hydrologic system between the grounding line, where the rising tide first increases the subglacial water pressure and regions upstream where stored elastic strain increases the basal shear stress. This high-tide event is released when the increased water pressure reaches the region of increased shear stress. Dilatant strengthening stops the event by increasing pore volume and lowering the water pressure. Following this event, falling tide increases the normal forces, compresses the till and increases pore pressure again, leading to the second falling-tide event we observe every tidal cycle.

Bindschadler, Robert↗

Possible Stick-Slip Mechanism for Whillans Ice Stream

Tidally-induced stick-slip motion in the mouth of Whillans Ice Stream provides a unique natural experiment in ice-stream response behavior and from which we might learn a great deal about subglacial till properties and sub-ice-stream conditions. At the IGS Symposium on Fast Glacier Flow (Yakutat, 2002), we reported our observations of stick- slip motion and demonstrated its synchronicity with tidal forcing. Recently, we have completed additional processing of our GPS data in differential mode. It reveals more details of the stick-slip events and illustrates that within 30 seconds, the temporal interval of our data, the ice stream accelerates to a speed corresponding to a completely lubricated bed. While details of individual events vary, there seems to be strong evidence of an elastic rebound on the time scale of one hour following most events. This suggests the event involves the release of stored elastic strain energy in the ice. The similar displacements of events suggest further that till or subglacial hydrologic properties limit the amount of elastic strain released in any single event. We follow a line of reasoning that dilatant strengthening limits the slip displacement and present model of the stick-slip process. To match the observed delay between the peak ocean tide and stick-slip events, our model includes a propagating pressure wave in the subglacial hydrologic system between the grounding line, where the rising tide first increases the subglacial water pressure and regions upstream where stored elastic strain increases the basal shear stress. This high-tide event is released when the increased water pressure reaches the region of increased shear stress. Dilatant strengthening stops the event by increasing pore volume and lowering the water pressure. Following this event, falling tide increases the normal forces, compresses the till and increases pore pressure again, leading to the second falling-tide event we observe every tidal cycle.

Bindschadler, Robert↗

Per- and Polyfluoroalkyl Substances Confirmatory Sampling Report, South Repeater Building (SWMU 121), Kennedy Space Center, Florida

This Per- and Polyfluoroalkyl Substances (PFAS) Confirmatory Sampling (CS) Report was prepared by AECOM Technical Services, Inc. (AECOM) for the National Aeronautics and Space Administration (NASA) under Contract 80KSC019D0010, Task Order 80KSC021F0096. The purpose of this report is to document CS activities at the South Repeater Building, Solid Waste Management Unit (SWMU) 121, formerly known as the Area 3 Repeater Building (A3RB). A Phase I SWMU Assessment and Confirmatory Sampling Report (NASA 2019) and a Phase II and III SWMU Assessment and Confirmatory Sampling Report (NASA 2022b) were previously submitted detailing Center-Wide assessment activities performed at the John F. Kennedy Space Center (KSC) in Florida that identified 33 locations of concern and 19 areas of potential concern at KSC associated with the storage, use, or release of materials containing PFAS. A review of the analytical results from investigation derived waste samples collected in 2020 from the South Repeater Building area indicated concentrations of perfluorooctanesulfonic acid (PFOS) were above Florida Department of Environmental Protection (FDEP) provisional Groundwater Cleanup Target Levels of 70 nanograms per liter (ng/L) at a concentration of 1,750 ng/L. Following this review, the KSC Fire Chief was contacted; the Chief recalled fighting a brush fire in 1998 in the area, during which an unknown volume of aqueous film-forming foam was used to extinguish the fire. The Phase II and Phase III SWMU Assessment Report recommended this area proceed to CS. Historical results in this area are provided in Appendix A . PFAS CS activities were contracted at the South Repeater Building. Initial CS activities were conducted in accordance with the PFAS Assessment and Mitigation Work Plan (AECOM 2022), which was submitted to the NASA Remediation Project Management team and accepted by the team on November 1 and 8, 2021. The objectives of the PFAS CS were to: - - Confirm and begin to assess the extent of PFAS affected media in the South Repeater Building area. - - Identify locations for groundwater, soil, surface water, and soil core sampling. - - Qualitatively characterize the migration potential of released PFAS to environmental media (soil, groundwater, and surface water). The following activities were completed to meet the PFAS CS objectives: - - Installation of monitoring wells via direct push technology (DPT) and rotosonic techniques - - Groundwater, soil, and surface water sampling - - Collection of soil cores to evaluate site lithology - - Development of initial PFAS plume characterization

PFAS↗

Airborne and Ground-Based Measurements Using a High-Performance Raman Lidar

A high-performance Raman lidar operating in the UV portion of the spectrum has been used to acquire, for the first time using a single lidar, simultaneous airborne profiles of the water vapor mixing ratio, aerosol backscatter, aerosol extinction, aerosol depolarization and research mode measurements of cloud liquid water, cloud droplet radius, and number density. The Raman Airborne Spectroscopic Lidar (RASL) system was installed in a Beechcraft King Air B200 aircraft and was flown over the mid-Atlantic United States during July August 2007 at altitudes ranging between 5 and 8 km. During these flights, despite suboptimal laser performance and subaperture use of the telescope, all RASL measurement expectations were met, except that of aerosol extinction. Following the Water Vapor Validation Experiment Satellite/Sondes (WAVES_2007) field campaign in the summer of 2007, RASL was installed in a mobile trailer for groundbased use during the Measurements of Humidity and Validation Experiment (MOHAVE-II) field campaign held during October 2007 at the Jet Propulsion Laboratory s Table Mountain Facility in southern California. This ground-based configuration of the lidar hardware is called Atmospheric Lidar for Validation, Interagency Collaboration and Education (ALVICE). During theMOHAVE-II field campaign, during which only nighttime measurements were made, ALVICE demonstrated significant sensitivity to lower-stratospheric water vapor. Numerical simulation and comparisons with a cryogenic frost-point hygrometer are used to demonstrate that a system with the performance characteristics of RASL ALVICE should indeed be able to quantify water vapor well into the lower stratosphere with extended averaging from an elevated location like Table Mountain. The same design considerations that optimize Raman lidar for airborne use on a small research aircraft are, therefore, shown to yield significant dividends in the quantification of lower-stratospheric water vapor. The MOHAVE-II measurements, along with numerical simulation, were used to determine that the likely reason for the suboptimal airborne aerosol extinction performance during theWAVES_2007 campaign was amisaligned interference filter. With full laser power and a properly tuned interference filter,RASL is shown to be capable ofmeasuring themain water vapor and aerosol parameters with temporal resolutions of between 2 and 45 s and spatial resolutions ranging from 30 to 330 m from a flight altitude of 8 km with precision of generally less than 10%, providing performance that is competitive with some airborne Differential Absorption Lidar (DIAL) water vapor and High Spectral Resolution Lidar (HSRL) aerosol instruments. The use of diode-pumped laser technology would improve the performance of an airborne Raman lidar and permit additional instrumentation to be carried on board a small research aircraft. The combined airborne and ground-based measurements presented here demonstrate a level of versatility in Raman lidar that may be impossible to duplicate with any other single lidar technique.

Whiteman, David N.↗

Greenland Subglacial Drainage Evolution Regulated by Weakly Connected Regions of the Bed

Penetration of surface meltwater to the bed of the Greenland Ice Sheet each summer causes an initial increase in ice speed due to elevated basal water pressure, followed by slowdown in late summer that continues into fall and winter. While this seasonal pattern is commonly explained by an evolution of the subglacial drainage system from an inefficient distributed to efficient channelized configuration, mounting evidence indicates that subglacial channels are unable to explain important aspects of hydrodynamic coupling in late summer and fall. Here we use numerical models of subglacial drainage and ice flow to show that limited, gradual leakage of water and lowering of water pressure in weakly connected regions of the bed can explain the dominant features in late and post melt season ice dynamics. These results suggest that a third weakly connected drainage component should be included in the conceptual model of subglacial hydrology.

Greenland Ice Sheet↗

Water survey of Canada: Application for use of ERTS-A for retransmission of water resources data

The author has identified the following significant results. Water resources data were retransmitted from nine data collection platforms (DCP) located in remote regions of Canada. The DCPs located in the Arctic operated in temperatures lower than -40 C and the DCP antennas have survived wind speeds of greater than 80 kph and snow loads of a depth of one metre. Ice-out indicators were installed at a few DCP sites. The purpose of these indicators was to enable the detection of the movement of ice out of river channel during spring break-up. The suitability of satellite retransmission as a means of obtaining data from remote areas of Canada continues to be demonstrated. A modest expansion of the DCP network is planned.

Halliday, R. A.↗

Water survey of Canada: Application for use of ERTS-A for retransmission of water resources data

The author has identified the following significant results. Water resources data including water level, water velocity, precipitation, air temperature, ice condition, DCP battery voltage, and water stage recorder clock operation have been transmitted from remote areas in Canada using the ERTS Data Collection System. The Data Collection Platforms have met all requirements. The suitability of satellite retransmission as a means of obtaining data from remote areas has been demonstrated. The present network of 9 Data Collection Platforms will be expanded to 28 to develop a quasi-operational network.

Halliday, R. A.↗

Water survey of Canada: Application for use of ERTS-A for retransmission of water resources data

The author has identified the following significant results. Water resources data including water level, water velocity, precipitation, air temperature, ice-out indicator, data collection platform battery check and water stage recorder clock operation have been transmitted from remote areas in Canada using the ERTS Data Collection System. The system has met all requirements. The suitability of satellite retransmission has been demonstrated. The present network will be expanded to 28 in 1975.

Halliday, R. A.↗

Post-Landing Orion Crew Survival in Warm Ocean Areas: A Case Study in Iterative Environmental Design

The Orion crew module (CM) is being designed to perform survivable land and water landings. There are many issues associated with post-landing crew survival. In general, the most challenging of the realistic Orion landing scenarios from an environmental control standpoint is the off-nominal water landing. Available power and other consumables will be very limited after landing, and it may not be possible to provide full environmental control within the crew cabin for very long after splashdown. Given the bulk and thermal insulation characteristics of the crew-worn pressure suits, landing in a warm tropical ocean area would pose a risk to crew survival from elevated core body temperatures, if for some reason the crewmembers were not able to remove their suits and/or exit the vehicle. This paper summarizes the analyses performed and conclusions reached regarding post-landing crew survival following a water landing, from the standpoint of the crew s core body temperatures.

Rains, George E.↗

VLTI-GRAVITY Measurements of Cool Evolved Stars I. Variable Photosphere and Extended Atmosphere of the Mira Star R Peg

Context. Dynamic model atmospheres of Mira stars predict variabilities in the photospheric radius and in atmospheric molecular layers which are not yet strongly constrained by observations. Aim. Here we measure the variability of the oxygen-rich Mira star R Peg in near-continuum and molecular bands. Methods. We used near-infrared K-band spectro-interferometry with a spectral resolution of about 4000 obtained at four epochs between post-maximum and minimum visual phases employing the newly available GRAVITY beam combiner at the Very Large Telescope Interferometer (VLTI). Results. Our observations show a continuum radius that is anti-correlated with the visual lightcurve. Uniform disc (UD) angular diameters at a near-continuum wavelength of 2.24 m are steadily increasing with values of 8.7 0.1 mas, 9.4 0.1 mas, 9.8 0.1 mas, and 9.9 0.1 mas at visual phases of 0.15, 0.36, 0.45, 0.53, respectively. UD diameters at a bandpass around 2.05 m, dominated by water vapour, follow the near-continuum variability at larger UD diameters between 10.7 mas and 11.7 mas. UD diameters at the CO 2-0 bandhead, instead, are correlated with the visual lightcurve and anti-correlated with the near-continuum UD diameters, with values between 12.3 mas and 11.7 mas. Conclusions. The observed anti-correlation between continuum radius and visual lightcurve is consistent with an earlier study of the oxygen-rich Mira S Lac, and with recent 1D CODEX dynamic model atmosphere predictions. The amplitude of the variation is comparable to the earlier observations of S Lac, and smaller than predicted by CODEX models. The wavelength-dependent visibility variations at our epochs can be reproduced by a set of CODEX models at model phases between 0.3 and 0.6. The anti-correlation of water vapour and CO contributions at our epochs suggests that these molecules undergo different processes in the extended atmosphere along the stellar cycle. The newly available GRAVITY instrument is suited to conducting longer time series observations, which are needed to provide strong constraints on the model-predicted intra- and inter-cycle variability.

photospheric radius↗

Deconditioning-induced exercise responses as influenced by heat acclimation

A study to determine the effect of heat acclimation and physical training in temperate conditions on changes in exercise tolerance following water-immersion deconditioning is presented. Five young men were tested on a bicycle ergometer before and after heat acclimation and after water immersion. The subjects and the experimental procedure, heat acclimation and exercise training, water immersion, and exercise tolerance are discussed. Heat acclimation resulted in the usual decreases in exercise heart rate and rectal temperature and an increase in sweat rate. Water immersion resulted in substantial diuresis despite water consumed. The results show that heat acclimation provides an effective method of preventing the adverse effects of water-immersion deconditioning on exercise tolerance.

Shvartz, E.↗

Climatic consequences of very high carbon dioxide levels in the earth's early atmosphere

The possible consequences of very high carbon dioxide concentrations in the earth's early atmosphere have been investigated with a radiative-convective climate model. The early atmosphere would apparently have been stable against the onset of a runaway greenhouse (that is, the complete evaporation of the oceans) for carbon dioxide pressures up to at least 100 bars. A 10- to 20-bar carbon dioxide atmosphere, such as may have existed during the first several hundred million years of the earth's history, would have had a surface temperature of approximately 85 to 110 C. The early stratosphere should have been dry, thereby precluding the possibility of an oxygenic prebiotic atmosphere caused by photodissociation of water vapor followed by escape of hydrogen to space. Earth's present atmosphere also appears to be stable against a carbon dioxide-induced runaway greenhouse.

Kasting, James F.↗