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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Comparative life cycle assessment of woody biomass processing: air classification, drying, and size reduction powered by bioelectricity versus grid electricity

Sulfur accumulation during biofuel production is pollutive and toxic to conversion catalysts and causes the premature breakdown of processing equipment. Air classification is an effective preprocessing technology for ash and sulfur reduction from biomass feedstocks. Here, a life cycle assessment (LCA) sought to understand the environmental impact of implementing air classification as a sulfur-mitigation technique to improve feedstock quality for pine residues using a grid electricity scenario (GES) versus a bioelectricity scenario (BES). Global warming potential (GWP) for preprocessing was simulated using inventory databases embedded in SimaPro and the Argonne National Laboratory’s GREET model, specifically focusing on comparing the GWP of a GES versus a BES. Overall, the GES had a GWP impact over seven times that of the BES (136 versus 18 kg CO 2 equivalent per tonne of usable feedstock), with steam generation during rotary drying accounting for 57% of the GES’s GWP. Air classification represents 0.4% and 1.6% of the total GWP impact for the GES and BES, respectively. Therefore, air classification can facilitate a 30% reduction in feedstock sulfur content to improve feedstock quality for biofuel conversion and lessen corrosion of equipment while contributing minimal GWP impact during preprocessing.

Air classification↗

Impact of low-chemical storage pretreatment of loblolly pine bark on biochar from microwave pyrolysis

Forest product residues such as bark represent a low-cost, abundant feedstock for bioenergy, but their high ash and alkali and alkaline earth metal (AAEM) content limit thermochemical conversion efficiency. This study evaluates the use of low-severity chemical pretreatments during anaerobic storage to improve the performance of microwave pyrolysis for loblolly pine bark. Bark was treated with dilute sulfuric acid (0.1% and 1%, w/w) or sodium hydroxide (4%, w/w) and incubated anaerobically for one or two weeks to simulate in-pile biorefinery storage. The most effective treatment—1% H2SO4 for two weeks—reduced AAEM content by 35.7% and increased bio-oil yield by 11% compared to untreated controls, while also reducing pyrolysis gas production. In contrast, alkali treatment did not reduce AAEM levels and led to decreased bio-oil yields with increased gas formation. Although biochar yields were relatively stable across treatments, their physicochemical characteristics varied significantly. Acid-treated bark yielded biochars with higher carbon content, lower O/C and H/C ratios, greater surface area, and enhanced heating values. These improvements suggest that chemical pretreatment during storage can tailor biochar quality for specific end uses. Biochars produced under optimized conditions exhibited properties suitable for soil amendment, carbon sequestration, and solid fuel applications. This integrated approach—combining storage, mild chemical conditioning, and microwave pyrolysis—provides a viable pathway to enhance the value and sustainability of bark-derived bioenergy products.

09 - BIOMASS FUELS↗

Biomass Feedstock National User Facility--Improving Bale Deconstruction and Material Flow

The project aims to reduce feedstock variability using a quality-by-design approach beginning when the biomass is introduced to the process and will continue through the size reduction process, which will yield the results of fine generation reduction, contaminant removal, control of the physical and chemical critical material attributes in the process, and management of the flowability.

09 BIOMASS FUELS↗

Deconstruction of Woody Biomass via Protic and Aprotic Ionic Liquid Pretreatment for Ethanol Production

Ionic liquids (ILs) have emerged as important solvents for conversion of lignocellulosic feedstocks to fuels and chemicals due to their ability to enable efficient biomass deconstruction and fractionation. Woody biomass derived from forest and agricultural residues has the potential to be used for production of biofuels and its removal from forests can help mitigate disastrous wildfires in fire-prone states like California. This study evaluated woody biomass types (pine, almond, walnut, and fir) from California as potential biofuel feedstocks. The feedstocks were pretreated with the ILs cholinium lysinate ([Ch][Lys]) and ethanolamine acetate ([EOA][OAc]), followed by enzymatic hydrolysis and fermentation of lignocellulosic sugars to produce ethanol. Under optimal conditions, [EOA][OAc] pretreatment and enzymatic hydrolysis generated glucose and xylose yields in the range of 24-82 and 14-80%, respectively, while glucose and xylose yields for the [Ch][Lys] ranged between 28-83 and 23-80%, respectively. Maximum fermentable sugar was released from almond wood, and the lowest amount was from pine and fir. Further, blends of feedstocks were also explored, and a blend with a mass ratio of 2/2/1 (almond/walnut/pine) resulted in maximum glucose and xylose (>90%) yields using [Ch][Lys]. Fermentation of this hydrolysate using a C5-utilizing strain of Saccharomyces cerevisiae resulted in a maximum ethanol concentration of 17.9 g/L for mixture biomass hydrolysate, corresponding to 60.8% fermentation efficiency. This study represents the first demonstration of the use of these ILs for pretreatment of woody biomass blends that resulted in a high overall conversion efficiency for ethanol production.

09 BIOMASS FUELS↗

Soil microbiome feedbacks during disturbance-driven forest ecosystem conversion

Abstract Disturbances cause rapid changes to forests, with different disturbance types and severities creating unique ecosystem trajectories that can impact the underlying soil microbiome. Pile burning—the combustion of logging residue on the forest floor—is a common fuel reduction practice that can have impacts on forest soils analogous to those following high-severity wildfire. Further, pile burning following clear-cut harvesting can create persistent openings dominated by nonwoody plants surrounded by dense regenerating conifer forest. A paired 60-year chronosequence of burn scar openings and surrounding regenerating forest after clear-cut harvesting provides a unique opportunity to assess whether belowground microbial processes mirror aboveground vegetation during disturbance-induced ecosystem shifts. Soil ectomycorrhizal fungal diversity was reduced the first decade after pile burning, which could explain poor tree seedling establishment and subsequent persistence of herbaceous species within the openings. Fine-scale changes in the soil microbiome mirrored aboveground shifts in vegetation, with short-term changes to microbial carbon cycling functions resembling a postfire microbiome (e.g. enrichment of aromatic degradation genes) and respiration in burn scars decoupled from substrate quantity and quality. Broadly, however, soil microbiome composition and function within burn scar soils converged with that of the surrounding regenerating forest six decades after the disturbances, indicating potential microbial resilience that was disconnected from aboveground vegetation shifts. This work begins to unravel the belowground microbial processes that underlie disturbance-induced ecosystem changes, which are increasing in frequency tied to climate change.

Nelson, Amelia R.↗

Generating multiple benefits from forests by producing value-added products: Lessons from the Pacific Northwestern US

This paper asks what conditions are needed to counteract a declining forest industry. The mobilization of supply chains for new value-added forest products and services can be supported by programs designed to simultaneously achieve multiple goals related to health, climate, and rural economic development. But several challenges are identified that underscore the need to stack benefits and incentives to achieve muti-sectoral goals. Based on a case study in Washington state, we find opportunities and constraints for sourcing forest products are determined by the local and regional conditions such as availability of working forests and their residues, socioeconomic conditions, workforce availability, transportation options, and perceptions about social license of the new industry. Key recommendations are the need for (1) a consistent demand and resilient supply chain for the new product; (2) a stable, supportive policy and assessment framework; (3) timely, transparent, and trusted monitoring and reporting of benefits and costs; (4) fostering engagement and buy-in from stakeholders; (5) a context-specific evaluation of opportunities and constraints; and (6) agreement on the goals of sustainable forestry. A diversity of products and markets builds a more resilient forest-based economy by mitigating impacts of disruptions in any individual market, adding value to biomass, increasing employment, and reducing forest risks to fire, insects, and disease.

Bioenergy↗

Monitoring Regional Forest Disturbances across the US with near Real Time MODIS NDVI Products Resident to the ForWarn Forest Threat Early Warning System

Forest threats across the US have become increasingly evident in recent years. Sometimes these have resulted in regionally evident disturbance progressions (e.g., from drought, bark beetle outbreaks, and wildfires) that can occur across multiyear durations and have resulted in extensive forest overstory mortality. In addition to stand replacement disturbances, other forests are subject to ephemeral, sometimes yearly defoliation from various insects and varying types and intensities of ephemeral damage from storms. Sometimes, after prolonged severe disturbance, signs of recovery in terms of Normalized Difference Vegetation Index (NDVI) can occur. The growing prominence and threat of forest disturbances in part have led to the formation and implementation of the 2003 Healthy Forest Restoration Act which mandated that national forest threat early warning system be developed and deployed. In response, the US Forest Service collaborated with NASA, DOE Oakridge National Laboratory, and the USGS Eros Data Center to build and roll-out the near real time ForWarn early warning system for monitoring regionally evident forest disturbances. Given the diversity of disturbance types, severities, and durations, ForWarn employs multiple historical baselines that are used with current NDVI to derive a suite of six forest change products that are refreshed every 8 days. ForWarn employs daily quarter kilometer MODIS NDVI data from the Aqua and Terra satellites, including MOD13 data for deriving historical baseline NDVIs and eMODIS 7 NDVI for compiling current NDVI. In doing so, the Time Series Product Tool and the Phenological Parameters Estimation Tool are used to temporally de-noise, fuse, and aggregate current and historical MODIS NDVIs into 24 day composites refreshed every 8 days with 46 dates of products per year. The 24 day compositing interval enables disturbances to be detected, while minimizing the frequency of residual atmospheric contamination. Forest change products are computed versus the previous 1, previous 3, and all previous years in the MODIS record for a given 24 day interval. Other "weekly" forest change products include one computed using an adaptive length compositing method for quicker detection of disturbances, two others that adjust for seasonal fluctuations in normal vegetation phenology (e.g., early versus late springs). This overall approach enables forest disturbance dynamics from a variety of regionally evident biotic and abiotic forest disturbances to be viewed and assessed through the calendar year. The change products are also being utilized for forest change trend analysis and for developing regional forest overstory mortality products. ForWarn's forest change products are used to alert forest health specialists about new forest disturbances. Such alerts are also typically based on available Landsat, aerial, and ground data as well as communications with forest health specialists and previous experience. ForWarn products have been used to detect and track many types of regional disturbances to multiple forest types, including defoliation from caterpillars and severe storms, as well as mortality from both biotic and abiotic agents (e.g., bark beetles, drought, fire, anthropogenic clearing). ForWarn offers products that could be combined with other geospatial data on forest biomass to assess forest disturbance carbon impacts within the conterminous US.

Spruce, Joseph P.↗

Forward variable selection enables fast and accurate dynamic system identification with Karhunen-Loève decomposed Gaussian processes

A promising approach for scalable Gaussian processes (GPs) is the Karhunen-Loève (KL) decomposition, in which the GP kernel is represented by a set of basis functions which are the eigenfunctions of the kernel operator. Such decomposed kernels have the potential to be very fast, and do not depend on the selection of a reduced set of inducing points. However KL decompositions lead to high dimensionality, and variable selection thus becomes paramount. This paper reports a new method of forward variable selection, enabled by the ordered nature of the basis functions in the KL expansion of the Bayesian Smoothing Spline ANOVA kernel (BSS-ANOVA), coupled with fast Gibbs sampling in a fully Bayesian approach. It quickly and effectively limits the number of terms, yielding a method with competitive accuracies, training and inference times for tabular datasets of low feature set dimensionality. Theoretical computational complexities are O ( N P 2 ) in training and O ( P ) per point in inference, where N is the number of instances and P the number of expansion terms. The inference speed and accuracy makes the method especially useful for dynamic systems identification, by modeling the dynamics in the tangent space as a static problem, then integrating the learned dynamics using a high-order scheme. The methods are demonstrated on two dynamic datasets: a ‘Susceptible, Infected, Recovered’ (SIR) toy problem, along with the experimental ‘Cascaded Tanks’ benchmark dataset. Comparisons on the static prediction of time derivatives are made with a random forest (RF), a residual neural network (ResNet), and the Orthogonal Additive Kernel (OAK) inducing points scalable GP, while for the timeseries prediction comparisons are made with LSTM and GRU recurrent neural networks (RNNs) along with the SINDy package.

Hayes, Kyle↗

Machine learning reveals sequence-function relationships in family 7 glycoside hydrolases

Family 7 glycoside hydrolases (GH7) are among the principal enzymes for cellulose degradation in nature and industrially. These important enzymes are often bimodular, including a catalytic domain and carbohydrate binding module (CBM) attached via a flexible linker, and exhibit an active site that binds cello-oligomers of up to ten glucosyl moieties. GH7 cellulases consist of two major subtypes: cellobiohydrolases (CBH) and endoglucanases (EG). Despite the critical importance of GH7 enzymes, there remain gaps in our understanding of how GH7 sequence and structure relate to function. Here, we employed machine learning to gain data-driven insights into relationships between sequence, structure, and function across the GH7 family. Machine-learning models, trained only on the number of residues in the active-site loops as features, were able discriminate GH7 CBHs and EGs with up to 99% accuracy, demonstrating that the lengths of loops A4, B2, B3, and B4 strongly correlate with functional subtype across the GH7 family. Classification rules were derived such that specific residues at 42 different sequence positions each predicted the functional subtype with accuracies surpassing 87%. A random forest model trained on residues at 19 positions in the catalytic domain predicted the presence of a CBM with 89.5% accuracy. Our ML results recapitulate, as top-performing features, a substantial number of the sequence positions determined by previous experimental studies to play vital roles in GH7 activity. We surmise that the yet-to-be-explored sequence positions among the top-performing features also contribute to GH7 functional variation and may be exploited to understand and manipulate function.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Decision Support System

Forest-based value chains involve decisions that begin at the landscape level and extend through processing, product manufacturing, and end-use markets. However, these decisions are often made independently across sectors, with limited visibility into how upstream resource conditions, incentives, and land management choices influence downstream production systems. In forested regions of the United States, wildfire risk, fragmented ownership, and uncertain markets for low-value residues complicate efforts to align extraction, processing, and utilization decisions. Without tools that link these stages, stakeholders may overlook opportunities to improve resource utilization or inadvertently shift impacts elsewhere in the value chain. This repository introduces a decision support system (DSS) that applies a system-impact-analysis approach to forest biomass residues and co-products. The framework integrates forest inventory data, geospatial resource assessments, and economic modeling to evaluate how biomass extraction decisions influence downstream product pathways. By linking regional feedstock avail- ability with market incentives and processing options—such as fuels, wood products, or soil amendments like biochar—the tool allows decision-makers to compare value chain outcomes across multiple utilization strategies.

Davis, Maggie [Oak Ridge National Laboratory (ORNL↗

Contribution of National near Real Time MODIS Forest Maximum Percentage NDVI Change Products to the U.S. ForWarn System

This presentation reviews the development, integration, and testing of Near Real Time (NRT) MODIS forest % maximum NDVI change products resident to the USDA Forest Service (USFS) ForWarn System. ForWarn is an Early Warning System (EWS) tool for detection and tracking of regionally evident forest change, which includes the U.S. Forest Change Assessment Viewer (FCAV) (a publically available on-line geospatial data viewer for visualizing and assessing the context of this apparent forest change). NASA Stennis Space Center (SSC) is working collaboratively with the USFS, ORNL, and USGS to contribute MODIS forest change products to ForWarn. These change products compare current NDVI derived from expedited eMODIS data, to historical NDVI products derived from MODIS MOD13 data. A new suite of forest change products are computed every 8 days and posted to the ForWarn system; this includes three different forest change products computed using three different historical baselines: 1) previous year; 2) previous three years; and 3) all previous years in the MODIS record going back to 2000. The change product inputs are maximum value NDVI that are composited across a 24 day interval and refreshed every 8 days so that resulting images for the conterminous U.S. are predominantly cloud-free yet still retain temporally relevant fresh information on changes in forest canopy greenness. These forest change products are computed at the native nominal resolution of the input reflectance bands at 231.66 meters, which equates to approx 5.4 hectares or 13.3 acres per pixel. The Time Series Product Tool, a MATLAB-based software package developed at NASA SSC, is used to temporally process, fuse, reduce noise, interpolate data voids, and re-aggregate the historical NDVI into 24 day composites, and then custom MATLAB scripts are used to temporally process the eMODIS NDVIs so that they are in synch with the historical NDVI products. Prior to posting, an in-house snow mask classification product is computed for the current compositing period and integrated into the change images to account for snow related NDVI drops. The supplemental snow classification product was needed because other available QA cloud/snow mask typically underestimates snow cover. MODIS true and false color composites were also computed from eMODIS reflectance data and the true color RGBs are also posted on ForWarn?s FCAV; this data is used for assessing apparent occasional quality issues on the change products due to residual unmasked cloud cover. New forest change products are posted with typical latencies of 1-2 days after the last input eMODIS data collection date for a given 24 day compositing period.

Spruce, Joseph P.↗

Modeling Forest Biomass and Growth: Coupling Long-Term Inventory and Lidar Data

Combining spatially-explicit long-term forest inventory and remotely sensed information from Light Detection and Ranging (LiDAR) datasets through statistical models can be a powerful tool for predicting and mapping above-ground biomass (AGB) at a range of geographic scales. We present and examine a novel modeling approach to improve prediction of AGB and estimate AGB growth using LiDAR data. The proposed model accommodates temporal misalignment between field measurements and remotely sensed data-a problem pervasive in such settings-by including multiple time-indexed measurements at plot locations to estimate AGB growth. We pursue a Bayesian modeling framework that allows for appropriately complex parameter associations and uncertainty propagation through to prediction. Specifically, we identify a space-varying coefficients model to predict and map AGB and its associated growth simultaneously. The proposed model is assessed using LiDAR data acquired from NASA Goddard's LiDAR, Hyper-spectral & Thermal imager and field inventory data from the Penobscot Experimental Forest in Bradley, Maine. The proposed model outperformed the time-invariant counterpart models in predictive performance as indicated by a substantial reduction in root mean squared error. The proposed model adequately accounts for temporal misalignment through the estimation of forest AGB growth and accommodates residual spatial dependence. Results from this analysis suggest that future AGB models informed using remotely sensed data, such as LiDAR, may be improved by adapting traditional modeling frameworks to account for temporal misalignment and spatial dependence using random effects.

Babcock, Chad↗

Relationships among forest type, watershed characteristics, and watershed ET in rural basins of the Southeastern US

Evapotranspiration (ET) typically accounts for 60–70% of precipitation in rural basins of the Southeastern United States. Since 1930, substantial reforestation of former croplands has occurred in the Piedmont and Appalachian Highlands in this area, leading to an expected increase in ET and reduction in baseflow. This study examines relationships between basin vegetative cover, abiotic factors, and water-budget partitioning in 45 USGS-gaged rural basins in the Southeastern US. Data are for the 1982–2014 water years with watersheds having ≥40% forest cover, crystalline-rock aquifers, minimal basin water export, and no large reservoirs. Long-term annual ET is calculated using the water-budget equation (ET = P-Q), which ranges from 641 to 971 mm/yr. (median 824). Vegetative cover and other basin variables are regressed against ET to quantify the effects of vegetative and forest types. Budyko analysis is employed to compare the watersheds and to evaluate factors affecting residuals. Regression analysis indicates that ET behavior is best explained by abiotic factors (i.e., precipitation and temperature) but forest-cover type also has some effect. Evergreen forest cover is less common than deciduous or mixed forest but has a positive relationship with ET, while deciduous and total forest have negative relationships with ET. Comparison of water-balance and Budyko-estimated ET indicates that deciduous and total forest are associated with negative residuals while evergreen is not significant. Furthermore, these results show that: forest cover effects on basin ET are complicated; forest-cover type is important for water-yield management in this region, and abiotic basin characteristics exert stronger control than forest cover on ET.

60 APPLIED LIFE SCIENCES↗

Analysis of normalized difference and surface temperature observations over southeastern Australia

Relations between radiative surface temperature (TR) and visible and near-IR reflectances expressed as the normalized difference (ND) from a Landsat Thematic Mapper scene are analyzed to examine the heat balance of agriculture and native evergreen forests in southeastern Australia. Factors determining the residual scatter about, and slope of, the TR/ND relationships were analyzed using a coupled two-layer soil-vegetation model of the surface heat balance. Inverse linear relationships were observed between TR and ND for agriculture, but not for forests. This was due to a wide range of ND and TR values in agricultural regions caused by wide variations in fractional vegetation cover.

Smith, R. C. G.↗

Contributions of vegetation heterogeneity within tower footprint to CO 2 flux estimations through graph neural network modeling

Net ecosystem exchange of CO 2 (Fc) measured directly by eddy covariance towers is based on various assumptions, including large, flat and homogenous land cover type. In reality, often a tower site is not large enough for flux measurements, and landscapes consist of patches of different land cover types within the flux footprint. In addition, some portions of fluxes are contributed by different cover types when a footprint exceeds the size of the target ecosystem. The contributions of non-dominant patches to Fc are often ignored. Here, in this study, we propose a novel integrated modeling framework that combines random forest (RF) and XGBoost with a residual correction module based on a deep graph convolutional network (DeeperGCN) to simulate Fc for seven flux measurement sites in southwest Michigan. High-resolution remote sensing vegetation indices, soil properties, meteorological variables, and footprint-weighted spatial features were used as model inputs at three spatial resolutions (10 m, 20 m, 30 m), and their importance in predicting Fc with DeeperGCN was assessed. We found that residual correction using DeeperGCN significantly improved prediction accuracy, with the R 2 increasing from 0.9098 to 0.9479 for RF and from 0.9235 to 0.9433 for XGBoost. At site level, the maximum improvement in R 2 reached 0.1617. Paired t-tests confirmed that these improvements were statistically significant (p < 0.05). Among all predictors, leaf area index and incoming shortwave radiation emerged as the dominant drivers of spatial residual variation, followed by precipitation, relative humidity, and selected vegetation indices. The 20 m resolution yielded the best balance between model performance and computational efficiency. In conclusion, our modeling framework effectively captures both spatial heterogeneity and nonlinear interactions, offering a robust solution for spatially explicit flux modeling in structurally diverse ecosystems beyond the study sites.

footprint model↗

L-band radar backscatter modeling of forest stands

An L-band HH radar backscatter model of a coniferous forest stand is described and compared with SIR-B L-band image data of the Mount Shasta region of northern California. Being based upon an identification and implementation of the expected major components of forest backscattering, the model is simple in form and thus fast computationally, making possible extensive simulations of forest stands. A particularly important component in the model relates to representing the specular reflections expected from tree trunks to the ground and then back to the sensor. These are strong returns and are seen to be necessary to explain both the forest measurements made by the authors and the observations of others. Although the experimental data is limited in quantity and quality, agreement between available experimental and simulated values of forest backscatter is better than the residual uncertainty and relative calibration error of the experimental data, provided the model and experiment are matched initially at one set of parameter values.

Richards, John A.↗

Growing season boundary layer climate and surface exchanges in a subarctic lichen woodland

Between June and August 1990, observations were made at two surface micrometeorological towers near Schefferville Quebec (54 deg 52 min N, 66 deg 40.5 min W), one in a fen and one in the subarctic lichen woodland, and at four surface climatological stations. Data from these surface stations were supplemented by regular radiosonde launches. Supporting measurements of radiative components and soil temperatures allowed heat and moisture balances to be obtained at two sites. The overall surface meteorological experiment design and results of micrometeorological observations made on a 30-m tower in the lichen woodland are presented here. Seasonal variation in the heat and water vapor transport characteristics illustrate the marked effect of the late summer climatological shift in air mass type. During the first half of the summer, average valley sidewalls only 100 m high are sufficient to channel winds along the valley in the entire convective boundary layer. Channeling effects at the surface, known for some time at the long-term climate station in Schefferville, are observed both at ridge top and in the valley, possibly the response of the flow to the NW-SE orientation of valleys in the region. Diurnal surface temperature amplitude at ridge top (approximately equal to 10 C) was found to be half that observed in the valley. Relatively large differences in precipitation among these stations and the climatological station at Schefferville airport were observed and attributed to the local topography. Eddy correlation observations of the heat, moisture and momentum transports were obtained from a 30-m tower above a sparse (approximately equal to 616 stems/ha) black spruce lichen woodland. Properties of the turbulent surface boundary layer agree well with previous wind tunnel studies over idealized rough surfaces. Daytime Bowen ratios of 2.5-3 are larger than those reported in previous studies. Surface layer flux data quality was assessed by looking at the surface layer heat balance. Diurnal and seasonal scale heat budget imbalances were found. We suggest that unmeasured surface heat storage may be responsible for some of the observed imbalance. The presence of the unexplained residual in this and other studies of energy balance over forests casts a note of caution on the interpretation of energy balance components obtained using heat residual methods.

Fitzjarrald, David R.↗