Radiation Tolerance Studies of Commercial Strippable Coatings and Fixatives used for Decontamination - 18642
A number of commercially available products, designed for use as strippable coating and fixatives for decontamination purposes, were tested to determine their tolerability to high radiation fields and how they potentially degrade. Each product was cured and exposed to γ-radiation from a Co-60 source, up to a total dose of 500 kGy. Obvious physical colour changes and deformities were detected by visual inspection, and images captured by scanning electron microscope (SEM) showed major differences post-irradiation in some coatings. Other physical changes to the coatings were measured using Fourier-transform infrared spectroscopy (FT-IR), Raman spectroscopy, and energy-dispersive X-ray spectroscopy (EDS); both pre- and post-irradiation. FT-IR suggested that some chemical changes were taking place in the coatings, in particular the C-H bonds and the fingerprint region appeared to be drastically altered in some coatings. EDS data indicated an increase in surface oxygen content as a result of irradiation in the majority of the samples. Additionally, coating samples were subjected to analysis by gas chromatography mass spectrometry (GCMS) in order to determine the evolved gases. The GC-MS results show that short chain hydrocarbons are produced to some degree in all the coatings during irradiation. Finally, three of the best performing coatings were selected and were irradiated using an ion beam, mimicking Pu alpha particles (with energy of around 5.25 MeV). Using the Dalton Cumbrian Facility's 5 MV tandem accelerator, coating samples were irradiated by ∼5.25 MeV He{sup 2+} particles to total dose of approximately 500 kGy. Samples were analysed using SEM, FT-IR, Raman and EDS, as was done for the gamma irradiated samples, allowing a comparison to be made between α-particle and γ-ray damage. Results from the alpha and gamma irradiations showed many similarities for the comparable assessments. A number of spectral changes observed in the FT-IR analysis were consistent across both γ-ray and α-particle irradiated samples. While there were some differences, these may be attributed to the conditions under which the irradiations were carried out. The observed similarities may allow for the inference of alpha degradation by Co-60 gamma irradiation as a more easily accessible method for determining the extent of radiolytic damage. Furthermore, gamma irradiation allows for additional analysis that is currently otherwise not possible to achieve with ion-beam exposure. (authors)