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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

PEM Fuel Cell MODEL for Conceptual Design of Hydrogen eVTOL Aircraft

A model and software for design and analysis of a Proton Exchange Membrane fuel cell (PEMFC) system are developed for hydrogen eVTOL aircraft. Examples are provided of stacks designed for 80 kWe and 500 kWe net electrical power. Examples are provided of eVTOL designed for 250 and 400 lb payload. The trade-offs included stack characteristics, hydrogen storage characteristics, and aircraft payload and range. The objectives were to identify the key technology drivers of a hydrogen rotorcraft, establish technology targets for a viable aircraft, and recommend research to address the fundamental pre-competitive barriers. The current U.S. infrastructure on hydrogen informed the targets and recommendations. The key conclusion is that the advances made in cell electrochemical power density over the last decade might allow a PEMFC system to meet, or even beat, piston engine powered light-utility rotorcraft. The development must focus on the key drivers of a hydrogen eVTOL. The drivers are ultra-light stack cooling and short-term hydrogen storage. A stack system of net electrical power 100−150 kWe with specific power 1.1 kWe/kg including air, cooling, and electrical subsystems, and a tank storage of 15% weight fraction hydrogen are the minimum targets to meet the performance of a modern piston-engine rotorcraft, with a range of 180 nautical miles, payload of 400 lb, and gross weight of about 1400 lb. This is defined as the objective aircraft. If only one target is met, an aircraft of half the range could be produced, with a 30% greater gross take-off weight. This is defined as an intermediate aircraft. Because definitive conclusions are premature without weights and loads data on a flight-worthy stack system, it is recommended that a fuel cell powered hydrogen eVTOL demonstrator be built and flown. The existing hydrogen infrastructure for cars provide ample opportunity to create a pilot program. About 12 metric tons of retail hydrogen are available for cars every day in California, which is less than 0.05% of the yearly hydrogen production in the U.S.. A hypothetical fleet of 100 aircraft, operating 3 flights a day, would increase the demand by 2.25 tons per day and require 140 MWh of renewable electricity for green hydrogen.

PEM↗

Vibration Considerations for Cryogenic Tanks Using Glass Bubbles Insulation

The use of glass bubbles as an efficient and practical thermal insulation system has been previously demonstrated in cryogenic storage tanks. One such example is a spherical, vacuum-jacketed liquid hydrogen vessel of 218,000 liter capacity where the boiloff rate has been reduced by approximately 50 percent. Further applications may include non-stationary tanks such as mobile tankers and tanks with extreme duty cycles or exposed to significant vibration environments. Space rocket launch events and mobile tanker life cycles represent two harsh cases of mechanical vibration exposure. A number of bulk fill insulation materials including glass bubbles, perlite powders, and aerogel granules were tested for vibration effects and mechanical behavior using a custom design holding fixture subjected to random vibration on an Electrodynamic Shaker. The settling effects for mixtures of insulation materials were also investigated. The vibration test results and granular particle analysis are presented with considerations and implications for future cryogenic tank applications. A thermal performance update on field demonstration testing of a 218,000 L liquid hydrogen storage tank, retrofitted with glass bubbles, is presented. KEYWORDS: Glass bubble, perlite, aerogel, insulation, liquid hydrogen, storage tank, mobile tanker, vibration.

Werlink, Rudolph J.↗

Technology Development for Hydrogen Propellant Storage and Transfer at the Kennedy Space Center (KSC)

The National Aeronautics and Space Administration (NASA) is a major user of liquid hydrogen. In particular, NASA's John F. Kennedy (KSC) Space Center has operated facilities for handling and storing very large quantities of liquid hydrogen (LH2) since the early 1960s. Safe operations pose unique challenges and as a result NASA has invested in technology development to improve operational efficiency and safety. This paper reviews recent innovations including methods of leak and fire detection and aspects of large storage tank health and integrity. We also discuss the use of liquid hydrogen in space and issues we are addressing to ensure safe and efficient operations should hydrogen be used as a propellant derived from in-situ volatiles.

cryogenics↗

A simple approach to metal hydride alloy optimization

Hildebrand-Scott (1950) solubility parameters can be obtained for metals and alloys by calculating the cohesive energy density (CED), equal to the square of the solubility parameter, and a function of the heat of sublimation and the atomic volume. It is suggested that the solubility parameter permits estimation of the hydrogen storage capacity of an alloy and that alloys with a solubility parameter approximately equal to the parameter for hydrogen will have greater hydrogen storage capacity than other alloys. Equilibrium pressure - temperature relationships for some metal hydrides are presented in conjunction with the calculated solubility parameter and correlated with characteristics which would be useful in hydrogen-powered vehicles. Alloy properties which increase the amount of nonstoichiometric reversible hydrogen absorption are discussed.

Lawson, D. D.↗

Cryogenic Fluid Management Experiment (CFME) trunnion verification testing

The Cryogenic Fluid Management Experiment (CFME) was designed to characterize subcritical liquid hydrogen storage and expulsion in the low-g space environment. The CFME has now become the storage and supply tank for the Cryogenic Fluid Management Facility, which includes transfer line and receiver tanks, as well. The liquid hydrogen storage and supply vessel is supported within a vacuum jacket to two fiberglass/epoxy composite trunnions which were analyzed and designed. Analysis using the limited available data indicated the trunnion was the most fatigue critical component in the storage vessel. Before committing the complete storage tank assembly to environmental testing, an experimental assessment was performed to verify the capability of the trunnion design to withstand expected vibration and loading conditions. Three tasks were conducted to evaluate trunnion integrity. The first determined the fatigue properties of the trunnion composite laminate materials. Tests at both ambient and liquid hydrogen temperatures showed composite material fatigue properties far in excess of those expected. Next, an assessment of the adequacy of the trunnion designs was performed (based on the tested material properties).

Bailey, W. J.↗

Effects of high-pressure hydrogen on storage vessel materials

Tensile tests on welded plates of three grades of steel indicate an appreciable decrease of tensile strength and ductility of notched specimens and a decrease in ductility of unnotched samples. Surface cracking, evident in unnotched specimens, is conducive to breakdown in tensile strength and ductility.

Chandler, W. T.↗

Ongoing nickel-hydrogen energy storage device testing at George C. Marshall Space Flight Center

The primary objective of the testing is to characterize Ni-H2 cells for successful integration into the electrical power system (EPS) of the Hubble Space Telescope (HST). A broad spectrum of Ni-H2 design technology is encompassed by the testing configurations; tests include cells with dates of manufacture as early as 1976. The database includes cells of varied storage times, capacity, plate design, stack design, terminal configuration, pressure vessel thickness, separator material, potassium hydroxide (KOH) concentration, and thermal control. Currently, 196 Ni-H2 cells are being tested, grouped as follows: 12 RNH-35-3, 14 RNH-30-1, 22 HST cells (1 battery, flight spare lot), 132 HST cells (6 batteries, test modules 1 and 2, called TM1 and TM2), 12 HST cells (3 four-cell packs, TM1, TM2, flight spare module FSM), and 4 HST cells (engineering lot). In addition to the characterization and life testing, an extensive thermal vacuum and purge test was conducted in November 1989 and February 1990 using the HST FSM (3 batteries composed of 69 HST cells from the flight spare lot) to help verify thermal design. A report is presented of the progress, significant findings, and future objectives of the testing.

Lowery, John E.↗

Nickel-hydrogen capacity loss on storage

Nickel-hydrogen batteries are rapidly becoming accepted for use in low-earth-orbit and geosynchronous orbit applications. With their increased use it has become evident that the storage procedures commonly used for nickel-cadmium cells are not adequate for the nickel-hydrogen system. The capacity loss exhibited by nickel electrodes from various manufacturers when exposed to different storage conditions was determined. A comprehensive test matrix was developed to evaluate capacity loss in nickel electrodes from four different manufacturers. Two types of tests were run; individual electrode tests, which involved flooded capacity and impedance measurements before and after storage under varied conditions of temperature, hydrogen pressure, and electrolyte concentration; and cell tests which primarily evaluated the effects of state-of-charge on storage. The cell tests evaluated capacity loss on cells stored open circuit, shorted and trickle charged at C/100 following a full charge. The results indicate that capacity loss varies with the specific electrode manufacturing process, storage temperature and hydrogen pressure. In general, electrodes stored at low temperatures or low hydrogen pressures exhibited a smaller loss in capacity over the twenty-eight day storage period than those stored at high pressure and high temperature. The capacity loss appears to correlate with the level of cobalt in the nickel electrode, with the most significant loss of capacity occurring in electrodes with higher cobalt levels. Impedance measurements appear to correlate well with the capacity loss observed for a given type of electrode but do not correlate well with the capacity loss between electrodes fabricated by different manufacturers. There was a definite correlation between the electrode potential measured immediately following storage and the measured capacity loss.

Manzo, Michelle A.↗

Investigation of metal hydride materials as hydrogen reservoirs for metal-hydrogen batteries

The performance and suitability of various metal hydride materials were examined for use as possible hydrogen storage reservoirs for secondary metal-hydrogen batteries. Lanthanum pentanickel hydride appears as a probable candidate in terms of stable hydrogen supply under feasible thermal conditions. A kinetic model describing the decomposition rate data of the hydride has been developed.

ONISCHAK↗

Validation of a Two-Phase CFD Model for Predicting Tank Self-Pressurization in the Ground-Based K-Site Experiment

A two-phase CFD model for self-pressurization of a cryogenic storage tank partially filled with liquid hydrogen is presented using the Volume-Of-Fluid approach for representing the phase boundary and the associated interfacial heat, mass and momentum transfer between the liquid and the vapor regions. The CFD model is validated against self-pressurization experiment performed in the K-site flightweight hydrogen storage tank at NASA Glenn Research Center. Laminar and turbulent simulations together with conjugated heat transfer analysis are performed. Effects of turbulence, as well as tank wall conduction are presented and discussed. Predicted tank pressures and fluid temperatures are compared with the experimental data at two different heat loads for validating the CFD model.

phase change↗