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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Mid-Infrared Spectrum of the Zodiacal Emission: Detection of Crystalline Silicates in Interplanetary Dust

Within a few astronomical units of the Sun the solar system is filled with interplanetary dust, which is believed to be dust of cometary and asteroidal origin. Spectroscopic observations of the zodiacal emission with moderate resolution provide key information on the composition and size distribution of the dust in the interplanetary space. They can be compared directly to laboratory measurements of candidate materials, meteorites, and dust particles collected in the stratosphere. Recently mid-infrared spectroscopic observations of the zodiacal emission have been made by two instruments on board the Infrared Space Observatory; the camera (ISOCAM) and the spectrophotometer (ISOPHOT-S). A broad excess emission feature in the 9-11 micron range is reported in the ISOCAM spectrum, whereas the ISOPHOT-S spectra in 6-12 microns can be well fitted by a blackbody radiation without spectral features.

Ootsubo, T.↗

The far-infrared spectrum of S140 IR

The spectrum of S140 IR from 65 to 345 kaysers (155-29 microns) has been measured with 9.4-kayser resolution. The emission in this spectral range is consistent with a 9-arcsec-diameter blackbody radiating at a temperature of 70 K. Attempts at finding a self-consistent radiative-transfer model of the source suggest that the near- and far-infrared observations cannot result from a spherically symmetric nebula with a continuous density distribution and a central exciting source. A number of compact near-infrared sources may be embedded in the cloud.

Tokunaga, A. T.↗

The Infrared Spectrum of Matrix-Isolated Hexamethylenetetramine in Argon at 12 K

It is commonly accepted that constant exposure of comets and ice grains to ultraviolet (UV) radiation causes an organic crust to form on their surface, but the exact molecules that comprise the crust remains a mystery. Based on our lab simulations of interstellar and cometary ices (a paper to be submitted this spring) we believe that Hexamethylenetetramine (HMT) may be a major component of the organic crust on the surface of comets and ice grains. The enclosed paper presents the laboratory infrared spectra and UV photochemistry of HMT under conditions akin to that of the interstellar medium.

Bernstein, Max P.↗

A high-resolution atlas of the infrared spectrum of the sun and the earth atmosphere from space. A compilation of ATMOS spectra of the region from 650 to 4800 cm-1 (2.3 to 16 microns). Volume 2: Stratosphere and mesosphere, 650 to 3350 cm-1

During the period April 29 to May 2, 1985, the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment was operated for the first time, as part of the Spacelab-3 payload of the shuttle Challenger. The principal purpose of this experiment was to study the distributions of the atmosphere's minor and trace molecular constituents. The instrument, a modified Michelson interferometer covering the frequency range from 600 to 5000/cm-1 at a spectral resolution of 0.01/cm-1, recorded infrared absorption spectra of the sun and of the earth's atmosphere at times close to entry into and exit from occultation by the earth's limb. Spectra were obtained that are free from absorptions due to constituents of the atmosphere (i.e., they are pure solar spectra), as well as spectra of the atmosphere itself, covering line-of-sight tangent altitudes that span the range from the lower thermosphere to the bottom of the troposphere. This atlas presents a compilation of these spectra arranged in a hardcopy format suitable for quick-look reference purposes. Volume 2 covers the stratosphere and mesosphere (i.e., tangent altitudes from 20 to 80 km) for frequencies from 650 to 3350/cm-1.

Farmer, Crofton B.↗

The Infrared Spectrum of H 2 S from 1 to 5 µm

The absorption spectra of H 2 S from 2000 to 11 147 cm -1 have been obtained with spectral resolutions of 0.006, 0.012, and 0.021 cm -1 and optical paths of 1.5 m to 433 m using the Fourier transform spectrometer at Kitt Peak National Observatory/National Solar Observatory. The 20 new vibrational bands have been assigned for the first time and 8 others re-analyzed so that accurate energy levels, band origins, and rotational parameters could be determined for a total of 29 states. Experimental band centers have been modeled by vibrational calculations. Line intensity measurements and analysis are in progress. A prediction of the 4 µm bands of H 2 S is currently available.

absorption↗

ACCESS: A Visual to Near-infrared Spectrum of the Hot Jupiter WASP-43b with Evidence of H{sub 2}O, but No Evidence of Na or K

We present a new ground-based visual transmission spectrum of the hot Jupiter WASP-43b, obtained as part of the ACCESS Survey. The spectrum was derived from four transits observed between 2015 and 2018, with combined wavelength coverage between 5300 and 9000 Å and an average photometric precision of 708 ppm in 230 Å bins. We perform an atmospheric retrieval of our transmission spectrum combined with literature Hubble Space Telescope/WFC3 observations to search for the presence of clouds/hazes as well as Na, K, Hα, and H{sub 2}O planetary absorption and stellar spot contamination over a combined spectral range of 5318–16420 Å. We do not detect a statistically significant presence of Na i or K i alkali lines, or Hα in the atmosphere of WASP-43b. We find that the observed transmission spectrum can be best explained by a combination of heterogeneities on the photosphere of the host star and a clear planetary atmosphere with H{sub 2}O. This model yields a log evidence of 8.26 ± 0.42 higher than a flat (featureless) spectrum. In particular, the observations marginally favor the presence of large, low-contrast spots over the four ACCESS transit epochs with an average covering fraction f{sub het}=0.27{sub −0.16}{sup +0.42} and temperature contrast ΔT = 132 K ± 132 K. Within the planet’s atmosphere, we recover a log H{sub 2}O volume mixing ratio of −2.78{sub −1.47}{sup +1.38}, which is consistent with previous H{sub 2}O abundance determinations for this planet.

79 ASTRONOMY AND ASTROPHYSICS↗

The infrared spectrum of the Galactic center and the composition of interstellar dust

We have obtained 5-8 micrometers spectra of the Galactic center from the Kuiper Airborne Observatory at resolving powers of approximately 50, approximately 150, and approximately 300. These spectra show absorption features at 5.5, 5.8, 6.1, and 6.8 micrometers. Together with previously observed features in the 3 micrometers region, these features are compared with laboratory spectra of candidate materials. The 3.0 and 6.1 micrometers features are due to the OH stretching and bending variations of H2O and are well fitted by water of hydration in silicates (e.g., talc). The 3.0 micrometer band is equally well fitted by ice mixtures containing 30% H2O, but such mixtures do not provide a good fit to the observed 6.1 micrometer band. The 3.4 and 6.8 micrometers features are identified with the CH stretching and deformation modes in CH2 and CH3 groups in saturated aliphatic hydrocarbons. The 6.1 micrometer band shows a short wavelength shoulder centered on 5.8 micrometer, attributed to carbonyl (C double bond O) groups in this interstellar hydrocarbon dust component. Finally, the narrow 5.5 micrometer feature is also attributed to carbonyl groups, but in the form of metal carbonyls [e.g., Fe(CO)4]. We have derived column densities and abundances along the line of sight toward the Galactic center for the various identified dust components. This analysis shows that hydrocarbon grains contain only 0.08 of the elemental abundance of C and contribute only a relatively minor fraction (0.1) of the total dust volume. Most of the interstellar dust volume is made up of silicates (approximately 0.6). Small graphite grains, responsible for the 2200 angstroms bump, account for 0.07 of the total dust volume. The remaining one-quarter of the interstellar dust volume consists of a material(s) without strong IR absorption features. Likely candidates include large graphite grains, diamonds, or amorphous carbon grains, which all have weak or no IR active modes. Finally, various models for the origin of the hydrocarbon dust component of the interstellar dust are discussed. All of them face some problems in explaining the observations, in particular, the absence of the spectroscopic signature of hydrocrbon grains in sources associated with molecular clouds.

NASA Discipline Exobiology↗