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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Pu(IV) quantification via visible–near-infrared absorption spectroscopy: tackling interferences using D-optimal design and partial least squares

Here, this study presents a novel analytical approach for quantifying Pu(IV) in glove box environments using fiber-optic-based visible–near-infrared absorption spectroscopy in combination with partial least squares regression (PLSR) and design of experiments. The method addresses significant challenges posed by overlapping spectral features arising from Nd(III), which is a common fission product impurity, and the speciation variability of Pu(IV) nitrato complexes in HNO 3 concentrations ranging from 2.5 to 11 M. A curated training set consisting of data from 20 samples was developed via D-optimal design to enable robust PLSR model calibration for Pu(IV) using the near-infrared band near 1050 nm. The training set was acquired from samples in cuvettes with a 1-cm path length and was used to build the PLSR model. The robustness of the model was validated with data collected using a dip probe with a 1-cm path length and varying Pu(IV) concentrations. The strong performance of the model indicates good model transfer from cuvette to dip probe and highlights the potential for in situ measurements and online monitoring of reactions in a crystallization reactor vessel. The results demonstrate that this combined spectroscopic and chemometric approach can accurately and simultaneously quantify Pu(IV) and HNO 3 , thereby offering a promising tool for real-time monitoring in process environments.

Actinide↗
DOE OSTI2026

Quantifying Temperature Dependence of Pu(IV) Absorbance Spectra for Advanced Online Monitoring of Nuclear Processes

This article presents a systematic study of Pu(IV) absorbance spectral features as a function of temperature to develop an understanding of this parameter’s effect on chemometric models that can be used as online monitoring tools to support nuclear processing. The descriptive and predictive models that provide real-time feedback of these processes are usually constructed with data collected in conditions typical of a laboratory environment, which can differ drastically from a processing environment. To assess the impact of temperature on Pu(IV) absorbance spectra, 11 samples of Pu(IV) were synthesized with varying HNO 3 concentrations ranging from 0.6 to 9.5 M and heated between 15 and 45 °C. Ultraviolet (UV)–visible (vis)–near-infrared (NIR) absorption spectra collected at different HNO 3 concentrations and temperatures revealed that features associated with Pu(IV) are sensitive to temperature at all HNO 3 concentrations and that changes in features depend on HNO 3 concentration. The contributions of temperature and HNO 3 concentration to variation in Pu(IV) spectral features were evaluated using the principal component analysis of spectra that were baseline-corrected with an asymmetric least-squares method. Furthermore, predictive modeling for HNO 3 concentration with partial least-squares regression of UV–vis–NIR spectra highlighted the importance of accounting for temperature in the calibration set to optimize model performance. This methodology constitutes a new, systematic approach to account for the effect of temperature on the absorption spectra of metal ions and is useful for process monitoring applications in many industries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRSDate not supplied

The Stratospheric Aerosol and Gas Experiment IV

Atmospheric composition continues to be a key Earth science focus for international space agencies and research organizations. The target constituent varies depending upon the topic area of interest such as monitoring the ozone layer and the efficacy of the Montreal Protocol, assessing the influence of volcanic eruptions and large wildfires on the atmosphere, improving our knowledge of transport processes, or evaluating the impacts of greenhouse gases on climate. Additionally, there is a growing need for measurement continuity of many trace gases both from an inability to properly assess long-term trends without it as well as the reliance of reanalyses and chemistry climate models on observational input. To this end, proper continuity requires continuous and overlapping multi-instrument data records of which spaceborne measurements are a critical component. However, most current satellite systems are well beyond their expected lifetimes, and so we look toward the future to develop the Stratospheric Aerosol and Gas Experiment (SAGE) IV as a future mission concept. Enabled by the NASA Earth Science Technology Office’s (ESTO) Instrument Incubator Program, the SAGE IV Pathfinder project has developed and validated a prototype demonstration that paves the way for a future SAGE IV spaceflight mission. Utilizing solar occultation imaging, SAGE IV will be capable of measuring key species in the stratosphere and upper troposphere with the same quality as previous SAGE instruments but with greatly improved pointing knowledge and extensibility to new science targets. Furthermore, current technological advancements allow SAGE IV to fit within a CubeSat framework and make use of commercial hardware, significantly reducing the size and cost when compared with traditional missions and enabling sustainability of future measurements.

Robert Damadeo↗
NASA NTRSDate not supplied

The Stratospheric Aerosol and Gas Experiment (SAGE) IV

Atmospheric composition continues to be a key Earth science focus for international space agencies and research organizations. The target constituent varies depending upon the topic area of interest such as monitoring the ozone layer and the efficacy of the Montreal Protocol, assessing the influence of volcanic eruptions and large wildfires on the atmosphere, improving our knowledge of transport processes, or evaluating the impacts of greenhouse gases on climate. Additionally, there is a growing need for measurement continuity of many trace gases both from an inability to properly assess long-term trends without it as well as the reliance of reanalyses and chemistry climate models on observational input. To this end, proper continuity requires continuous and overlapping multi-instrument data records of which spaceborne measurements are a critical component. However, most current satellite systems are well beyond their expected lifetimes, and so we look toward the future to develop the Stratospheric Aerosol and Gas Experiment (SAGE) IV as a future mission concept. Enabled by the NASA Earth Science Technology Office’s (ESTO) Instrument Incubator Program, the SAGE IV Pathfinder project developed and validated a prototype demonstration that paves the way for a future SAGE IV spaceflight mission. Utilizing solar occultation imaging, SAGE IV will be capable of measuring key species in the stratosphere and upper troposphere with the same quality as previous SAGE instruments but with greatly improved pointing knowledge and extensibility to new science targets. The precision and stability of a well-designed occultation instrument can act as a calibration reference standard for other spaceborne instruments, ensuring proper continuity of the desired science targets. Furthermore, current technological advancements allow SAGE IV to fit within a CubeSat framework and make use of commercial hardware, significantly reducing the size and cost when compared with traditional missions and enabling sustainability of future measurements.

Robert Damadeo↗
DOE OSTI2025

Mk-IV Salt Crystallization Hot Finger Apparatus for Partitioning Used Electrorefiner Salt

Electrorefining is a controlled redox process used to regulate the behavior of ionic species. Through this process, metals can be deposited onto a cathode from an electrolyte solution in a controlled manner. The Mk-IV electrorefiner (Mk-IV ER) at Idaho National Laboratory is an engineering-scale, molten salt-based electrorefining cell that has been used for decades to recover metallic uranium from spent fuel. As a result, highly stable fission product chlorides have accumulated in the electrolyte. This accumulation results in changes to the salt’s properties, such as melting temperature, thermal conductivity, and density, as well as elevated product impurity and fissile materials criticality margin. These factors prompt the need for a salt regeneration process, such as melt-crystallization and species drawdown. This work focuses on providing a conceptual design to regenerate ER salt from used Mk-IV-ER salt in-situ, while minimizing salt waste volumes by concentrating the fission products in a final processed salt heal. We propose using a hot-finger crystallization apparatus design to fractionally crystallize salt in the Mk-IV-ER head space (or baffle space), allowing the collection of solid and liquid fractions. By using a cup-drain design, the used salt will be allowed to slowly solidify on the walls of a stainless-steel cup. The apparatus drain plug will then open to allow the liquid salt phase to drain to a lower cup, effectively separating the liquid phase from the solid phase. Under the hypothesis that the liquid phase salt concentrates the fission products, which is under examination in the accompanying work package, this separation allows the recovered solid salt to be reused while minimizing the high-level salt waste volume of used ER salt.

36 - MATERIALS SCIENCE↗
NASA NTRS2023

On More than Two Decades of Celestial Reference Frame VLBI Observations in the Deep South: IVS-CRDS (1995 - 2021)

The International VLBI Service for Geodesy & Astrometry (IVS) regularly provides high-quality data to produce Earth Orientation Parameters (EOP), and for the maintenance and realization of the International Terrestrial and Celestial Reference Frames, ITRF and ICRF. The first iteration of the celestial reference frame (CRF) at radio wavelengths, the ICRF1, was adopted by the International Astronomical Union (IAU) in 1997 to replace the FK5 optical frame. Soon after, the IVS began official operations and in 2009 there was a significant increase in data sufficient to warrant a second iteration of the CRF, ICRF2. The most recent ICRF3, was adopted by the IAU in 2018. However, due to the geographic distribution of observing stations being concentrated in the Northern hemisphere, CRFs are generally weaker in the South due to there being fewer Southern Hemisphere observations. To increase the Southern Hemisphere observations, and the density, precision of the sources, a series of deep South observing sessions was initiated in 1995. This initiative in 2004 became the IVS Celestial Reference Frame Deep South (IVS-CRDS) observing program. This paper covers the evolution of the CRDS observing program for the period 1995 to 2021, details the data products and results, and concludes with a summary of upcoming improvements to this ongoing project.

VLBI↗
DOE OSTI2026

Oxygen Effects and Selective Oxidation of Group IV Alloying Additions in Group V-Based Refractory Multi-principal Element Alloys

Refractory multi-principal element alloys (RMPEAs) hold significant potential for advancing ultra-high-temperature technologies due to their remarkable strength retention under these conditions. However, the beneficial effects of alloying on microstructural evolution and mechanical properties are often obscured by the presence of interstitial alloying elements. The intricate interactions between substitutional alloying elements of Groups IV, V, and VI and interstitial content, whether intentional or incidental, remain poorly understood. In this study, we investigate the impact of dissolved oxygen on the microstructural evolution and stability of RMPEAs primarily composed of Group V elements, Nb and V, along with Group IV elements Ti, Zr, and Hf. We show that the strong affinity of oxygen for Group IV elements Zr and Hf leads to the internal precipitation of oxides during heat treatment, which competes with the homogenization of the as-cast dendritic microstructure. Here, we demonstrate that careful control and design of oxygen content and Group IV alloying additions are essential to minimize micro-segregation and prevent the detrimental precipitation of internal oxides. To address these challenges, we propose employing non-equilibrium solidification calculations to predict and optimize as-cast solidification structures, thereby reducing the reliance on homogenization processes.

Alloy design↗
DOE OSTI2024

Kinetics and Mechanism of Ce(IV) Phase Transfer by the Neutral Extractants Tributyl Phosphate and N,N -Di(2-ethylhexyl)isobutyramide

Tributyl phosphate and N,N-di(2-ethylhexyl)isobutyramide (DEHiBA) are uranium-selective extractants that could be used to recover low-enriched uranium from commercial used nuclear fuel. The economic viability of liquid-liquid extraction processes for chemical separations depends on both thermodynamic and kinetic considerations. Here we used microfluidic droplet extraction to measure interfacial phase transfer rate constants for the extraction and stripping of Ce(IV), a non-radioactive actinide surrogate. The Damkohler numbers for each system were calculated and the phase transfer processes were determined to be diffusion-limited under all conditions, contrary to prior studies using constant interface stirred cells and single drop methods. A well-extracted 2:1 DEHiBA/Ce(IV) complex in the organic phase was determined from batch distribution studies, suggesting a different extraction mechanism for Ce(IV) compared with poorly extracted Pu(IV). Finally, phase disengagement rates were found to be rapid in both systems, in agreement with other studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Electrochemical Removal of Se(IV) from Wastewater Using RuO2‑Based Catalysts

The removal of selenite (SeO32-) from water is challenging due to the risk of secondary pollutants. To address this, we developed RuO2-based nanocatalysts on the titanium plate (RuO2/TP) for direct electrochemical reduction of Se(IV) to elemental selenium [Se(0)]. Optimizing Sn doping in RuO2 nanoparticles to induce charge redistribution enabled the Ru0.9Sn0.1Ox/TP catalyst to achieve ∼90% Se(IV) removal across concentrations of 0.1, 1, and 10 mM at -2 mA cm-2 over 8 h, outperforming undoped RuO2/TP. Furthermore, Ru0.9Sn0.1Ox/TP also maintained ∼90% removal efficiency in 1 mM of Se(IV) solutions containing competitive anions (0.5 M Cl-, 0.1 M SO42-, 0.01 M NO3-, and their mixtures), demonstrating suitability for complex wastewater treatment. Importantly, the catalysts were recyclable, with no observable contamination introduced into the solution. Density functional theory (DFT) calculations suggest that Sn doping effectively reduces the energy barrier for the reduction of Se(IV) to Se(0).

Hao, Shaoyun↗
NASA NTRS1979

Active cavity radiometer type IV

A new cavity pyrheliometer, the active cavity radiometer type IV (ACR IV), has been developed for the measurement of total solar optical irradiance. Analysis predicts its ability to measure at the solar constant level with 0.1% uncertainty in SI units. In comparison tests ACR IVs have consistently demonstrated 0.3% higher results than the World Radiometric Reference scale. A prototype has been tested, and a flight instrument has been developed and flown in a sounding rocket experiment to determine the solar constant. ACR IV instrumentation is being developed for flight experiments on the Spacelab I and Solar Maximum missions to monitor the total solar output of optical radiation as part of a long-term program to detect variations of climatological significance.

Willson, R. C.↗
NASA NTRS1979

C IV resonance line profiles in O stars

Graphs of normalized fluxes derived from objective-prism spectra (from the S-019 experiment on Skylab), and C IV profiles are presented. The C IV resonance profile, when studied with respect to bolometric magnitude and effective temperature, reveals mass loss conditions without requiring precise mass loss rates. There is a clear trend in the C IV feature toward more fully developed P Cygni profiles at higher luminosities, and a significant velocity shift in the C IV absorption down to bolometric magnitude approximately equal to -7.7.

Parsons, S. B.↗
NASA NTRS1983

Profiles and intensity ratios of the C IV lambda 1548, 1550 emission lines in planetary nebulae

The C IV resonance doublet at lambda 1548, 1550 is an important diagnostic tool in the study of planetary nebulae. The predicted theoretical intensity ratio of 2:1 is, however, rarely observed in the high dispersion IUE spectrograms. Values of 0.8-2.0 are observed for a sampling of 11 planetary nebulae of various excitation classes and for three proto-planetary nebulae. A diversity of line profiles is observed. In addition to the C IV doublet, weak subsidiary lines are seen. The spacing between these pseudo-lines happens to correspond to the separation of the C IV lines but are believed to be due to hot pixels and do not conform to the radial velocity displacement of the C IV lines.

Feibelman, W. A.↗
NASA NTRS1983

Dynamics of a surge observed in the C IV and H alpha lines

Time sequences of a surge have been obtained in Active Region 2701 during a coordinated SMY program, on October 2nd, 1980, while the MSDP spectrograph operated in H-alpha at the Meudon Solar Tower and the UVSP spectrometer on SMM observed in the 1548 A C IV resonance line. The cold (H-alpha) and hot (C IV) material follow the same channel, and the event lasts about 10 min in both lines. A good correlation is found between H-alpha and C IV velocities; radial velocities along the surge are in the range 40-60 km/s in both cases. The observations are consistent with the hypothesis that a pressure gradient drives the surge. The H-alpha data seem to indicate the presence of a shock wave in the chromosphere, while the C IV quantities (velocities, accelerations) vary on a very short time scale. Their maxima occur at some locations which could be interpreted as 'pinched' zones.

Schmieder, B.↗
NASA NTRS1984

Splitting of C IV lines in a QSO absorption-line system

The C IV doublet in the z = 1.795 absorption-line system in the QSO B2 1225 + 317 has been observed with the Multiple Mirror Telescope echelle spectrograph at a resolution of 10 km/s. The profile of C IV, previously known to contain at least three velocity components, is shown to consist of at least eleven. Individual components have Doppler width upper limits of 6.4-13.2 km/s. These low upper limits, plus a study of published profile shapes for several other species, suggest that the observed gas is not in an equilibrium state of collisional ionization, and that electron temperatures are 35,000 K or lower. The width of the aggregate profile (approximately 500 km/s) is larger by a factor of 5 than any C IV or Si IV profile observed through the halo of the Galaxy, while individual components are narrower than those in the Galaxy. Thus, intervening galaxies with halos similar to that of the Galaxy, even if occurring in groups, may not explain this QSO absorption-line system.

York, D. G.↗
NASA NTRS1984

Ultraviolet spectral morphology of the O stars - The remarkable luminosity dependence of the Si IV stellar wind effect

An extensive survey of ultraviolet O type spectra, by means of high-resolution data from the International Ultraviolet Explorer archives, shows a strong correlation between both the photospheric and stellar wind features, and the optical spectral types. In particular, the stellar wind effect in the Si IV resonance doublet displays a strong luminosity dependence which has not been completely described before: there is no effect anywhere on the main sequence, but it develops gradually through the intermediate luminosity classes into a full P Cygni profile in the supergiants. This behavior is in sharp contrast to that of the C IV and N V, which have strong P Cygni profiles throughout most of the O type domain, including the main sequence. The Si IV effect simultaneously provides a sensitive classification criterion and poses an outstanding problem for detailed astrophysical interpretation. In addition, a new emission feature at 1574 A, possibly due to N III or to N IV forbidden line, is reported.

Walborn, N. R.↗
NASA NTRS1990

Relations between the photospheric magnetic field and the emission from the outer atmospheres of cool stars. II - The C IV 1550 A doublet

Solar and stellar data are used to determine the relationship between C IV 1548 + 1551 A and magnetic flux densities. C IV SMM-UVSP spectroheliograms of solar quiet regions and plages are analyzed. Typical distribution functions of C IV flux densities over both quiet and active solar regions are presented. The C IV emission is shown to be dependent on magnetic flux density.

Schrijver, C. J.↗
NASA NTRS1991

C IV line profile correlations in NGC 4151

Novel correlations are presented between the peak emission of the two components of the strong UV resonance line C IV in the Seyfert 1 galaxy NGC 4151 and the total luminosity of the line. These correlations are distinctly different for the red and the blue peaks of the double-peaked C IV profile, implying that the physical parameters involved in their formation are quite different. The behavior of the red component appears more in accordance with the behavior of lines observed in other objects, while that of the blue peak appears more directly and strongly related to C IV luminosity and shows greater sensitivity to C IV flux changes. These findings imply the existence of specific, hitherto unknown, underlying physical processes.

Fahey, R. P.↗
NASA NTRS2003

Optimizing IV and V for Mature Organizations

NASA is intending for its future software development agencies to have at least a Level 3 rating in the Carnegie Mellon University Capability Maturity Model (CMM). The CMM has built-in Verification and Validation (V&V) processes that support higher software quality. Independent Verification and Validation (IV&V) of software developed by mature agencies can be therefore more effective than for software developed by less mature organizations. How is Independent V&V different with respect to the maturity of an organization? Knowing a priori the maturity of an organization's processes, how can IV&V planners better identify areas of need choose IV&V activities, etc? The objective of this research is to provide a complementary set of guidelines and criteria to assist the planning of IV&V activities on a project using a priori knowledge of the measurable levels of maturity of the organization developing the software.

Fuhman, Christopher↗