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At least 73 records · Page 4

Cambered Bipyridyl Ligand with Extended Aryl System Enables Electrochemical Reduction of Carbon Dioxide and Bicarbonate by Mn(bpy)(CO) 3 Br-type Catalyst Immobilized on Carbon Nanotubes

Heterogeneous materials containing molecular catalytic sites show promise for electrocatalytic reduction of CO 2 to energy-enriched carbon products. Interactions between the catalyst and the heterogeneous support increasingly are recognized as important in governing product selectivity and rate. Recent work on Mn(R-bpy)(CO) 3 Br type catalysts immobilized on multiwalled carbon nanotubes (MWCNT) demonstrated control of electrocatalytic behavior with steric modification of the molecular catalyst. Phenyl groups installed in the 4,4' positions of the bipyridine ligand (ph-bpy) maximized performance through π–π interactions with the MWCNT support. Herein we report the outcome of extending the ligand π system with Mn(nap-bpy)(CO) 3 Br (nap-bpy = 4,4'-di(naphthalen-1-yl)-2,2'-bipyridine) and Mn(pyr-bpy)(CO) 3 Br (pyr-bpy = 4,4'-di(pyren-1-yl)-2,2'-bipyridine) immobilized on MWCNT. We demonstrate exceptional electrocatalysis with Mn(nap-bpy)(CO) 3 Br/MWCNT (FE CO > 92%; J CO = 16.5 mA/cm 2 ) and find that this catalyst electrochemically reduces bicarbonate in the absence of deliberately added CO 2 at a remarkable overall selectivity of >80% for carbon products (FE HCOO – = 52% and FE CO = 29%). We show diminishing returns to simply adding aromatic character to the bipyridyl ligand with Mn(pyr-bpy)(CO) 3 Br/MWCNT and observe a unique cambering of the Mn(nap-bpy)(CO) 3 Br bipyridyl ligand that we believe enables selective catalysis. Mechanistic studies were carried out on Mn(nap-bpy)(CO) 3 Br/MWCNT using a novel thin-film infrared spectroelectrochemical (IR-SEC) technique. These experiments observe the immobilized Mn(nap-bpy)(CO) 3 Br undergo single electron reduction to a Mn-centered radical that binds CO 2 in a reduction-coupled process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Applying the Velocity Gradient Technique in NGC 1333: Comparison with Dust Polarization Observations

Magnetic fields (B-fields) are ubiquitous in the interstellar medium (ISM), and they play an essential role in the formation of molecular clouds and subsequent star formation. However, B-fields in interstellar environments remain challenging to measure, and their properties typically need to be inferred from dust polarization observations over multiple physical scales. In this work, we seek to use a recently proposed approach called the velocity gradient technique (VGT) to study B-fields in star-forming regions and compare the results with dust polarization observations in different wavelengths. The VGT is based on the anisotropic properties of eddies in magnetized turbulence to derive B-field properties in the ISM. We investigate that this technique is synergistic with dust polarimetry when applied to a turbulent diffused medium for the purpose of measuring its magnetization. Specifically, we use the VGT on molecular line data toward the NGC 1333 star-forming region ( 12 CO, 13 CO, C 18 O, and N 2 H + ), and we compare the derived B-field properties with those inferred from 214 and 850 μm dust polarization observations of the region using Stratospheric Observatory for Infrared Astronomy/High-Resolution Airborne Wide-band Camera Plus and James Clerk Maxwell Telescope/POL-2, respectively. We estimate both the inclination angle and the 3D Alfvénic Mach number M A from the molecular line gradients. Crucially, testing this technique on gravitationally bound, dynamic, and turbulent regions, and comparing the results with those obtained from polarization observations at different wavelengths, such as the plane-of-sky field orientation, is an important test on the applicability of the VGT in various density regimes of the ISM. We in general do not find a close correlation between the velocity gradient inferred orientations and the dust inferred magnetic field orientations.

79 ASTRONOMY AND ASTROPHYSICS↗

Synthesis, structure, and stability of a novel 2 H -azirine under pressure

We have synthesized 2,3-diphenyl-2H-azirine, a strained unsaturated heterocyclic compound, and examined its high-pressure behavior to above 10 GPa using diamond anvil cell techniques. Single crystal X-ray diffraction at ambient conditions reveals that the crystal structure is hexagonal and consists of interesting helices surrounding voids in the structure. A continuous shift of the Raman and infrared vibrational spectra with increasing pressure is observed, indicating that the molecular structure is preserved to at least 8 GPa at room temperature. High-pressure synchrotron powder X-ray diffraction shows that the hexagonal structure persists, with a smooth compression of the a and c parameters to 10 GPa. The structural stability under pressure is attributed to the reduction in void size within the helical framework despite the inherent strain and reactivity of the molecule. The channels in the structure could encapsulate small molecules for gas or energy storage applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hunting Dark Matter Lines in the Infrared Background with the James Webb Space Telescope

Dark matter particles with a mass around 1 eV can decay into near-infrared photons. Utilising available public blank sky observations from the NIRSpec IFU on the James Webb Space Telescope (JWST), we search for a narrow emission line due to decaying dark matter and derive leading constraints in the mass range 0.8-3 eV on the decay rate to photons, and more specifcally, on the axion-photon coupling for the case of axion-like particles. We exclude τ < 3.5 x 10 26 s at m DM ≃ 0.8 eV and, in the case of axions, g aγγ > 1.3 x 10 -11 GeV -1 for m a ≃ 2.2 eV. Our results do not rely on dedicated observations, rather we use blank sky observations intended for sky subtraction, and thus our reach may be automatically strengthened as JWST continues to observe.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Optical conductivity study of mixed-valent quasi-one-dimensional CeIr 3 ⁢B 2

Here, we present a combined theoretical and experimental study on the optical conductivity of CeIr 3 ⁢B 2 , where quasi-one-dimensional Ce chains form along the 𝑐 axis of the monoclinic crystal. Significant hybridization-induced features are observed along the Ce chains by broadband infrared spectroscopy, demonstrating mixed-valent behavior over a wide range of temperatures (6–300 K) and energies (up to 0.8 eV). The ferromagnetic transition at 41 K had no noticeable influence on the temperature evolution of the optical conductivity. A comparison with density functional theory plus dynamic mean-field theory calculations demonstrates the quasi-one-dimensional nature of CeIr 3 ⁢B 2 and the local character of the interactions responsible for the electronic renormalization. Furthermore, we demonstrate how the spectroscopic signatures of this mixed-valent compound are captured by theory, providing a clear distinction from the response expected in the integer-valent Kondo regime.

36 MATERIALS SCIENCE↗

NANT Site - ASSIST / Thermodynamic retrievals TROPoe / Derived Data

This dataset contains daily files with thermodynamic profiles retrieved with the optimal estimation physical retrieval TROPoe (Turner and Löhnert 2014; Turner and Blumberg 2019; Turner and Löhnert 2021). The profiles are retrieved every 10 minutes from instantaneous radiances observed with an Atmospheric Sounder Spectrometer by Infrared Spectral Technology (ASSIST, Rochette et al. 2009) operated by NOAA Physical Sciences Laboratory on Nantucket Island for WFIP3. The spectral bands used in the retrieval are in the wavenumber range from 612 - 905.4 cm-1 and are specified in Turner and Löhnert (2021). Additional input data in TROPoe are cloud base height from a collocated ceilometer operated by NOAA GML and temperature, water vapor mixing ratio, and pressure from a sensor attached to the ASSIST housing. In addition to these temporally resolved input data, TROPoe requires an a priori dataset (prior) that provides mean climatological estimates of thermodynamic profiles and specifies how temperature and humidity covary with height as an input (for details see, e.g., Djalalova et al. 2022). The prior is a key component of the retrieval and provides a constraint on the ill-posed inversion problem. A monthly prior was computed from operational radiosonde launches at Upton, NY.

17 WIND ENERGY↗

BLOC Site - ASSIST Thermodynamic retrievals TROPoe / Derived Data

This dataset contains daily files with thermodynamic profiles retrieved with the optimal estimation physical retrieval TROPoe (Turner and Löhnert 2014; Turner and Blumberg 2019; Turner and Löhnert 2021). The profiles are retrieved every 10 minutes from instantaneous radiances observed with an Atmospheric Sounder Spectrometer by Infrared Spectral Technology (ASSIST, Rochette et al. 2009) operated by NOAA Physical Sciences Laboratory on Block Island for WFIP3. The spectral bands used in the retrieval are in the wavenumber range from 612 - 905.4 cm-1 and are specified in Turner and Löhnert (2021). Radiances are noise-filtered but not averaged in time to minimize errors due to non-uniform clouds. Additional input data in TROPoe are cloud base height from a collocated ceilometer operated by NOAA GML and temperature, water vapor mixing ratio, and pressure from a sensor attached to the ASSIST housing. In addition to these temporally resolved input data, TROPoe requires an a priori dataset (prior) that provides mean climatological estimates of thermodynamic profiles and specifies how temperature and humidity covary with height as an input (for details see, e.g., Djalalova et al. 2022). The prior is a key component of the retrieval and provides a constraint on the ill-posed inversion problem. A monthly prior was computed from operational radiosonde launches at Upton, NY.

17 WIND ENERGY↗

BLOC Site - ASSIST Thermodynamic Retrievals TROPoe v0.18 / Derived Data

This dataset contains daily files with thermodynamic profiles retrieved with the optimal estimation physical retrieval TROPoe (Turner and Löhnert 2014; Turner and Blumberg 2019; Turner and Löhnert 2021). This is a post-processed dataset and recommended for use. The profiles are retrieved every 10 minutes from instantaneous radiances observed with an Atmospheric Sounder Spectrometer by Infrared Spectral Technology (ASSIST, Michaud-Belleau et al. 2025) operated by NOAA Physical Sciences Laboratory (PSL) on Block Island for WFIP3. The spectral bands used in the retrieval are in the wavenumber range from 612 - 905.4 cm-1 and are specified in Turner and Löhnert (2021). Additional input data in TROPoe are cloud base height from a collocated ceilometer operated by NOAA GML and temperature, water vapor mixing ratio, and pressure from a collocated surface tower operated by NOAA PSL. In addition to these temporally resolved input data, TROPoe requires an a priori dataset (prior) that provides mean climatological estimates of thermodynamic profiles and specifies how temperature and humidity covary with height as an input (for details see, e.g., Djalalova et al. 2022). The prior is a key component of the retrieval and provides a constraint on the ill-posed inversion problem. A monthly prior was computed from operational radiosonde launches at Upton, NY. The TROPoe docker container (version 0.18) is available from Docker Hub at https://hub.docker.com/r/davidturner53/tropoe/tags, and the source code code is available in the GitHub repository https://github.com/OAR-atmospheric-observations/TROPoe.

17 WIND ENERGY↗

NANT Site - ASSIST Thermodynamic Retrievals TROPoe v0.18 / Derived Data

This dataset contains daily files with thermodynamic profiles retrieved with the optimal estimation physical retrieval TROPoe (Turner and Löhnert 2014; Turner and Blumberg 2019; Turner and Löhnert 2021). This is a post-processed dataset and recommended for use. The profiles are retrieved every 10 minutes from instantaneous radiances observed with an Atmospheric Sounder Spectrometer by Infrared Spectral Technology (ASSIST, Michaud-Belleau et al. 2025) operated by NOAA Physical Sciences Laboratory (PSL) on Nantucket Island for WFIP3. The spectral bands used in the retrieval are in the wavenumber range from 612 - 905.4 cm-1 and are specified in Turner and Löhnert (2021). Additional input data in TROPoe are cloud base height from a collocated ceilometer operated by NOAA GML and temperature, water vapor mixing ratio, and pressure from a collocated surface tower operated by NOAA PSL. In addition to these temporally resolved input data, TROPoe requires an a priori dataset (prior) that provides mean climatological estimates of thermodynamic profiles and specifies how temperature and humidity covary with height as an input (for details see, e.g., Djalalova et al. 2022). The prior is a key component of the retrieval and provides a constraint on the ill-posed inversion problem. A monthly prior was computed from operational radiosonde launches at Upton, NY. The TROPoe docker container (version 0.18) is available from Docker Hub at https://hub.docker.com/r/davidturner53/tropoe/tags, and the source code code is available in the GitHub repository https://github.com/OAR-atmospheric-observations/TROPoe.

17 WIND ENERGY↗

Discovery of Powerful Multivelocity Ultrafast Outflows in the Starburst Merger Galaxy IRAS 05189–2524 with XRISM

We observed the X-ray-bright ultraluminous infrared galaxy IRAS 05189−2524 with XRISM during its performance verification phase. The unprecedented energy resolution of the onboard X-ray microcalorimeter revealed complex spectral features at ∼7–9 keV, which can be interpreted as blueshifted Fe XXV/XXVI absorption lines with various velocity dispersions, originating from ultrafast outflow (UFO) components with multiple bulk velocities of ∼0.076c, ∼0.101c, and ∼0.143c. In addition, a broad Fe–K emission line was detected around ∼7 keV, forming a P Cygni profile together with the absorption lines. The onboard X-ray CCD camera revealed a 0.4–12 keV broadband spectrum characterized by a neutrally absorbed power-law continuum with a photon index of ∼2.3 and intrinsic flare-like variability on timescales of ∼10 ks, both of which are likely associated with near-Eddington accretion. We also found potential variability of the UFO parameters on a timescale of ∼140 ks. Using these properties, we propose new constraints on the outflow structure and suggest the presence of multiple outflowing regions on scales of about tens to 100 Schwarzschild radii, located within roughly 2000 Schwarzschild radii. Since both the estimated momentum and energy outflow rates of the UFOs exceed those of galactic molecular outflows, our results indicate that powerful, multivelocity UFOs are already well developed during a short-lived evolutionary phase following a major galaxy merger, characterized by intense starburst activity and likely preceding the quasar phase. This system is expected to evolve into a quasar, sustaining strong UFO activity and suppressing star formation in the host galaxy.

Astronomy and AstroPhysics↗

Observations of Offshore Low‐Level Jets Off the U.S. East Coast Reveal Systematic Biases in ERA5 and HRRR

Low-level jets (LLJs)—wind speed maxima typically occurring a few hundred meters above the surface—are common off the U.S. East Coast and influence many atmospheric processes with societal importance, including cloud formation, aviation safety, and search-and-rescue. However, their vertical structure and frequency remain poorly quantified due to limited offshore observations. This study presents new scanning Doppler LiDAR and infrared spectroradiometer data from the 2024 summer deployment of an offshore barge during the Wind Forecast Improvement Project 3. These coupled wind and temperature profiles provide unprecedented resolution to assess LLJ behavior and model performance. LLJs occurred in over 21% of observed profiles, with a weak diurnal preference for nighttime and early morning hours and maximum winds typically near 300 m. Both ERA5 and High-Resolution Rapid Refresh analysis underestimate jet wind speeds and misrepresent the boundary layer thermal structure. These results highlight persistent model biases and the critical need for high-resolution offshore observations.

17 WIND ENERGY↗

Highly confined epsilon-near-zero and surface phonon polaritons in SrTiO 3 membranes

Recent theoretical studies have suggested that transition metal perovskite oxide membranes can enable surface phonon polaritons in the infrared range with low loss and much stronger subwavelength confinement than bulk crystals. Such modes, however, have not been experimentally observed so far. Here, using a combination of far-field Fourier-transform infrared (FTIR) spectroscopy and near-field synchrotron infrared nanospectroscopy (SINS) imaging, we study the phonon polaritons in a 100 nm thick freestanding crystalline membrane of SrTiO 3 transferred on metallic and dielectric substrates. We observe a symmetric-antisymmetric mode splitting giving rise to epsilon-near-zero and Berreman modes as well as highly confined (by a factor of 10) propagating phonon polaritons, both of which result from the deep-subwavelength thickness of the membranes. Theoretical modeling based on the analytical finite-dipole model and numerical finite-difference methods fully corroborate the experimental results. Our work reveals the potential of oxide membranes as a promising platform for infrared photonics and polaritonics.

36 MATERIALS SCIENCE↗

Improving Process Level Understanding of Boundary Layer Winds over the Northeast U.S. Shelf: The Third Wind Forecast Improvement Project (WFIP3)

The third Wind Forecast Improvement Project (WFIP3), a U.S. Department of Energy and National Oceanic and Atmospheric Administration sponsored investigation, sought to improve understanding of the physical phenomena in the atmosphere and ocean that dictate the structure and variability of wind and thermodynamic fields within the marine atmospheric boundary layer. WFIP3 focused on mesoscale and submesoscale flows -- including sea breezes, low-level jets, low-level clouds, and coastal storms -- and the ability of advanced numerical model parameterizations to represent them within fully coupled oceanic and atmospheric modeling systems and foundational weather forecast models. WFIP3 conducted a comprehensive 18-month observational study over the Northeast U.S. outer continental shelf, a high-use coastal zone, using a 3D multiscale sensor array to highly resolve the temporal, vertical, and horizontal structure of the coupled atmospheric and oceanic boundary layers. Multiple land-based study sites adjacent to the coastal ocean observed surface meteorology and vertical profiles of atmospheric properties via passive infrared and microwave radiometers, active lidars and radars, and radiosondes. At sea, an array of surface flux buoys and two vertical profiling lidar buoys observed both atmospheric and oceanic properties, augmented by land-based oceanographic radar systems and routine ship-based surveys. Intensive observations of the marine atmospheric boundary layer over the ocean was done from an air-sea interaction flux tower and extended deployments of a large autonomous barge platform. Numerous critical forecasting phenomena were observed that are being evaluated within regional coupled and uncoupled modeling systems, including the National Oceanic and Atmospheric Administration's foundational High-Resolution Rapid Refresh forecast model.

Kirincich, Anthony↗

Improving High Resolution Offshore Wind Resource Assessments and Forecasts using Observations in the MA/RI Lease Areas

The third Wind Forecast Improvement Project (WFIP3) sought to improve understanding of the physical phenomena in the atmosphere and ocean that dictate the structure and variability of wind and thermodynamic fields within the Marine Atmospheric Boundary Layer (MABL). WFIP3 conducted a comprehensive 18-month observational study over the Northeast U.S. outer continental shelf, a high use coastal zone, using a 3-D multiscale sensor array to highly resolve the temporal, vertical, and horizontal structure of the coupled atmospheric and oceanic boundary layers. Multiple land-based study sites adjacent to the coastal ocean observed surface meteorology and vertical profiles of atmospheric properties via passive infrared and microwave radiometers, active lidars and radars, and radiosondes. At sea, an array of surface flux buoys and two vertical profiling lidar buoys observed both atmospheric and oceanic properties, augmented by land-based oceanographic radar systems and routine ship-based surveys. Intensive observations of the MABL over the ocean was done from an air-sea interaction flux tower and extended deployments of a large barge platform. WFIP3 focused on mesoscale and sub-mesoscale flows -- including sea breezes, low-level jets, low-level clouds, and coastal storms -- and the ability of advanced numerical model parameterizations to represent them within fully coupled oceanic and atmospheric modeling systems and foundational weather forecast models. Numerous critical forecasting phenomena were observed, however the project was terminated prior to the completion of the field observational period and the analysis period.

54 ENVIRONMENTAL SCIENCES↗

Magnetic brightening and nanoscale imaging of spin-polarized helical edge modes in ZrTe 5

Efficient charge transport remains a fundamental challenge for nanoelectronic devices, as their performance is constrained by high dissipation and the impedance mismatch between high-frequency signal sources and nanoscale circuit interfaces. Although topologically protected helical edge modes offer a dissipationless and backscattering-resilient alternative, achieving nanoscale control over these modes requires direct visualization of their spatial electrodynamics, especially under high-frequency operation. Here, by utilizing cryogenic magneto-infrared scattering-type scanning near-field optical microscopy (cm-IR-sSNOM), we image spin-polarized helical edge channels in ZrTe 5 at the nanoscale, revealing magnetic-field-induced brightening as a high-frequency electrodynamic signature of robust topological edge modes. Operating at 1.8 K and under a magnetic field of up to 5 T, we observe the emergence of edge-state polarizability at infrared frequencies that is notably resilient to the magnetic gaps that typically quench d.c. and microwave edge transport. Our results reveal a topological ‘two-lane’ spatial reorganization in which an external magnetic field induces a spin-population imbalance between counterpropagating edge modes. Favoured helical branches are confined against physical boundaries to activate a net infrared near-field contrast. This electrodynamic response scales linearly with the number of atomic layers, which confirms that individual layers in ZrTe 5 preserve their discrete quantum spin Hall identities. These findings may be useful for developing topological spintronic devices, as the magnetic infrared tunability of helical edge channels provides a pathway for low-loss nanoscale interconnects and high-speed information processing.

36 MATERIALS SCIENCE↗

Enhanced biochemical sensing with high- Q transmission resonances in free-standing membrane metasurfaces

Optical metasurfaces provide solutions to label-free biochemical sensing by localizing light resonantly beyond the diffraction limit, thereby selectively enhancing light–matter interactions for improved analytical performance. However, high-Q resonances in metasurfaces are usually achieved in the reflection mode, which impedes metasurface integration into compact imaging systems. Here, we demonstrate a metasurface platform for advanced biochemical sensing based on the physics of the bound states in the continuum (BIC) and electromagnetically induced transparency (EIT) modes, which arise when two interfering resonances from a periodic pattern of tilted elliptic holes overlap both spectrally and spatially, creating a narrow transparency window in the mid-infrared spectrum. We experimentally measure these resonant peaks observed in transmission mode (Q ~ 734 at λ ~ 8.8 µm) in free-standing silicon membranes and confirm their tunability through geometric scaling. We also demonstrate the strong coupling of the BIC-EIT modes with a thinly coated PMMA film on the metasurface, characterized by a large Rabi splitting (32 cm -1 ) and biosensing of protein monolayers in transmission mode. Our new photonic platform can facilitate the integration of metasurface biochemical sensors into compact and monolithic optical systems while being compatible with scalable manufacturing, thereby clearing the way for on-site biochemical sensing in everyday applications.

Rosas, Samir [Univ. of Wisconsin, Madison, WI (Uni↗

Energy-energy correlators in 𝑒 + ⁢𝑒 − annihilation and deep inelastic scattering

We study energy-energy correlators (EECs) in 𝑒 + ⁢𝑒 − annihilation and deep inelastic lepton-hadron scattering (DIS), focusing on aspects of nonperturbative physics in these observables. We introduce the EEC jet functions and investigate the infrared behavior of both small-angle EECs and angle-integrated EECs by performing explicit one-loop calculations. The factorization and universality of the EECs in these processes are demonstrated. A matching scheme is proposed to smoothly connect kinematic regions where different scaling behaviors with jet energy are observed. In combination with the next-to-leading order correction, this matching provides a good description of the EEC data and pythia simulations in high-energy 𝑒 + ⁢𝑒 − annihilation. Predictions for DIS processes for future electron-ion collider kinematics are also presented.

Guo, Yuxun [Lawrence Berkeley National Laboratory ↗

Cold Gas and Star Formation in the Phoenix Cluster with JWST

We present integral field unit observations of the Phoenix Cluster with the JWST Mid-infrared Instrument’s Medium Resolution Spectrometer. We focus this study on the molecular gas, dust, and star formation in the brightest cluster galaxy (BCG). We use precise spectral modeling to produce maps of the silicate dust, molecular gas, and polycyclic aromatic hydrocarbons (PAHs) in the inner ∼50 kpc of the cluster. We measure the optical depth from silicates by comparing the observed H 2 line ratios to those predicted by excitation models. We provide updated measurements of the total molecular gas mass of $1.9^{+0.5}_{-0.04}$ x 10 10 M ⊙ , which agrees with CO-based estimates, providing an estimate of the CO-to-H 2 conversion factor of α CO = 0.8 ± 0.2 M ⊙ pc -2 (K km s -1 ) -1 ; an updated stellar mass of M * = 2.6 ± 0.5 × 10 10 M ⊙ ; and star formation rates (SFRs) averaged over 10 and 100 Myr of $\langle$SFR$\rangle$ 10 = 1340 ± 100 M ⊙ yr −1 and $\langle$SFR$\rangle$ 100 = 740 ± 80 M ⊙ yr −1 , respectively. The H 2 emission seems to be powered predominantly by shocks and star formation within the central ∼20 kpc, induced by stellar feedback and radio jets from the active galactic nucleus. Additionally, we find nearly an order-of-magnitude drop in the SFRs estimated by PAH fluxes in cool core BCGs compared to field galaxies, suggesting that hot particles from the intracluster medium are destroying PAH grains even in the central-most tens of kiloparsecs.

Active galaxies↗