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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

On the Stability of Jump-Linear Systems Driven by Finite-State Machines with Markovian Inputs

This paper presents two mean-square stability tests for a jump-linear system driven by a finite-state machine with a first-order Markovian input process. The first test is based on conventional Markov jump-linear theory and avoids the use of any higher-order statistics. The second test is developed directly using the higher-order statistics of the machine s output process. The two approaches are illustrated with a simple model for a recoverable computer control system.

Patilkulkarni, Sudarshan↗
NASA NTRS1988

Analytical study of the liquid phase transient behavior of a high temperature heat pipe

The transient operation of the liquid phase of a high temperature heat pipe is studied. The study was conducted in support of advanced heat pipe applications that require reliable transport of high temperature drops and significant distances under a broad spectrum of operating conditions. The heat pipe configuration studied consists of a sealed cylindrical enclosure containing a capillary wick structure and sodium working fluid. The wick is an annular flow channel configuration formed between the enclosure interior wall and a concentric cylindrical tube of fine pore screen. The study approach is analytical through the solution of the governing equations. The energy equation is solved over the pipe wall and liquid region using the finite difference Peaceman-Rachford alternating direction implicit numerical method. The continuity and momentum equations are solved over the liquid region by the integral method. The energy equation and liquid dynamics equation are tightly coupled due to the phase change process at the liquid-vapor interface. A kinetic theory model is used to define the phase change process in terms of the temperature jump between the liquid-vapor surface and the bulk vapor. Extensive auxiliary relations, including sodium properties as functions of temperature, are used to close the analytical system. The solution procedure is implemented in a FORTRAN algorithm with some optimization features to take advantage of the IBM System/370 Model 3090 vectorization facility. The code was intended for coupling to a vapor phase algorithm so that the entire heat pipe problem could be solved. As a test of code capabilities, the vapor phase was approximated in a simple manner.

Roche, Gregory Lawrence↗
DOE OSTI2024

NEXUS Qubit Analysis: Jump Rates and Efciencies

Correlated qubit errors are a hinderance to quantum computing, but when using quantum chips as a particle detector, they can be a sign of energy deposits. Using a four transmon qubit chip in the NEXUS fridge at Fermilab, we have taken data to better understand the impact ionizing radiation has on the correlated errors. To analyze this data, we need a jump detection code that is robustly tested with understood efficiencies. In this work, we describe the process of getting these efficiencies using a rolling $\chi^2$ jump detection code.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2006

Towards a Theory of Sampled-Data Piecewise-Deterministic Markov Processes

The analysis and design of practical control systems requires that stochastic models be employed. Analysis and design tools have been developed, for example, for Markovian jump linear continuous and discrete-time systems, piecewise-deterministic processes (PDP's), and general stochastic hybrid systems (GSHS's). These model classes have been used in many applications, including fault tolerant control and networked control systems. This paper presents initial results on the analysis of a sampled-data PDP representation of a nonlinear sampled-data system with a jump linear controller. In particular, it is shown that the state of the sampled-data PDP satisfies the strong Markov property. In addition, a relation between the invariant measures of a sampled-data system driven by a stochastic process and its associated discrete-time representation are presented. As an application, when the plant is linear with no external input, a sufficient testable condition for the convergence in distribution to the invariant delta Dirac measure is given.

Herencia-Zapana, Heber↗
DOE OSTI2016

Symmetry and diffusivity of the interstitial hydrogen shallow-donor center in In 2 O 3

Uniaxial stress experiments performed for the 3306 cm -1 vibrational line assigned to the interstitial-hydrogen, shallow-donor center in In 2 O 3 reveal its symmetry and transition- moment direction. The defect alignment that can be produced by a [001] stress applied at 165 K is due to a process that is also a hydrogen- diffusion jump, providing a microscopic determination of the diffusion constant for H in In 2 O 3 and its mechanism. Lastly, our experimental results strongly complement theoretical predictions for the structure and diffusion of the interstitial hydrogen donor center in In 2 O 3 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Unfolding bovine α-lactalbumin with T-jump: Characterizing disordered intermediates via time-resolved x-ray solution scattering and molecular dynamics simulations

The protein folding process often proceeds through partially folded transient states. Therefore, a structural understanding of these disordered states is crucial for developing mechanistic models of the folding process. Characterization of unfolded states remains challenging due to their disordered nature, and incorporating multiple methods is necessary. Combining the time-resolved x-ray solution scattering (TRXSS) signal with molecular dynamics (MD), we are able to characterize transient partially folded states of bovine α-lactalbumin, a model system widely used for investigation of molten globule states, during its unfolding triggered by a temperature jump. We track the unfolding process between 20 μs and 70 ms and demonstrate that it passes through three distinct kinetic states. The scattering signals associated with these transient species are then analyzed with TRXSS constrained MD simulations to produce protein structures that are compatible with the input signals. Without utilizing any experimentally extracted kinetic information, the constrained MD simulation successfully drove the protein to an intermediate molten globule state; signals for two later disordered states are refined to terminal unfolded states. From our examination of the structural characteristics of these disordered states, we discuss the implications disordered states have on the folding process, especially on the folding pathway. Finally, we discuss the potential applications and limitations of this method.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2012

Integration of the Total Lightning Jump Algorithm into Current Operational Warning Environment Conceptual Models

Key points that this analysis will begin to address are: 1)What physically is going on in the cloud when there is a jump in lightning? - Updraft variations, ice fluxes. 2)How do these processes fit in with severe storm conceptual models? 3)What would this information provide an end user (i.e., the forecaster)? - Relate LJA to radar observations, like changes in reflectivity, MESH, VIL, etc. based multi-Doppler derived physical relationships 4) How do we best transistionthis algorithm into the warning decision process. The known relationship between lightning updraft strength/volume and precipitation ice mass production can be extended to the concept of the lightning jump. Examination of the first lightning jump times from 329 storms in Schultz et al. shows an increase in the mean reflectivity profile and mixed phase echo volume during the 10 minutes prior to the lightning jump. Limited dual-Doppler results show that the largest lightning jumps are well correlated in time with increases in updraft strength/volume and precipitation ice mass production; however, the smaller magnitude lightning jumps appear to have more subtle relationships to updraft and ice mass characteristics.

Schultz, Christopher J.↗
DOE OSTI2017

Non-Darcy interfacial dynamics of air-water two-phase flow in rough fractures under drainage conditions

Two-phase flow interfacial dynamics in rough fractures is fundamental to understanding fluid transport in fractured media. The Haines jump of non-Darcy flow in porous media has been investigated at pore scales, but its fundamental processes in rough fractures remain unclear. In this study, the micron-scale Haines jump of the air-water interface in rough fractures was investigated under drainage conditions, with the air-water interface tracked using dyed water and an imaging system. The results indicate that the interfacial velocities represent significant Haines jumps when the meniscus passes from a narrow "throat" to a wide "body", with jump velocities as high as five times the bulk drainage velocity. Locally, each velocity jump corresponds to a fracture aperture variation; statistically, the velocity variations follow an exponential function of the aperture variations at a length scale of ~100 µm to ~100 mm. This spatial-scale-invariant correlation may indicate that the high-speed local velocities during the Haines jump would not average out spatially for a bulk system. The results may help in understanding the origin of interface instabilities and the resulting non-uniform phase distribution, as well as the micron-scale essence of the spatial and temporal instability of two-phase flow in fractured media at the macroscopic scale.

42 ENGINEERING↗
DOE OSTI2016

Diffusion of energetic electrons in turbulent plasmas of the solar wind

A method of calculation of the diffusion coefficients D(v) of particles in velocity space, based on the statistical analysis of the motion of a great number of test electrons, is proposed. In the case of Langmuir turbulence developing in plasmas with fluctuating density inhomogeneities such as the solar wind, simulations provide coefficients D(v) which mainly depend on the Langmuir wave spectra and agree well with the analytical predictions D{sub th}(v) of the quasilinear theory of weak turbulence. Nevertheless, some noticeable differences exist with this theory: in the range of phase velocity of the short waves where the main part of the wave energy is concentrated, D(v) is noticeably smaller than D{sub th}(v), due to the scattering, the reflection, and the focusing effects encountered by the Langmuir waves when they interact with the plasma density inhomogeneities. Moreover, the probability of large velocity jumps in the particles’ trajectories essentially exceeds the probability of a Gaussian distribution. These large jumps, which are connected with the waves’ transformation processes, modify the nature of the particle diffusion, which is no more classical. These higher order effects cause the discrepancies observed with the quasilinear theory, which does not take them into account in its perturbative approach. The solar wind plasmas, which present fluctuating density inhomogeneities of noticeable average levels, are a very good laboratory to study such diffusion processes, which can eventually influence significantly on the development of essential physical phenomena, as electromagnetic radio emissions by type III solar radio bursts, for example.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1986

Discrete-time Markovian-jump linear quadratic optimal control

This paper is concerned with the optimal control of discrete-time linear systems that possess randomly jumping parameters described by finite-state Markov processes. For problems having quadratic costs and perfect observations, the optimal control laws and expected costs-to-go can be precomputed from a set of coupled Riccati-like matrix difference equations. Necessary and sufficient conditions are derived for the existence of optimal constant control laws which stabilize the controlled system as the time horizon becomes infinite, with finite optimal expected cost.

Chizeck, H. J.↗
NASA NTRS1995

Stability mechanical considerations, and AC loss in HTSC monoliths, coils, and wires

For monolithic high-T(sub c) superconductors (HTSC's) calculations are presented of: (1) the initial flux jump field, H(sub fj), in melt-processed YBCO based on a field and temperature dependent J(sub c), and (2) the radial and circumferential stresses in solid and hollow cylinders containing trapped magnetic flux. For model multi filamentary (MF) HTSC/Ag strands calculations are presented of: (1) the limiting filament diameters for adiabatic and dynamic stability, and (2) the hysteretic and eddy current components of AC loss. Again for MF HTSC/Ag composite strands the need for filamentary subdivision and twisting is discussed.

Sumption, M. D.↗
NASA NTRS1988

Electron heating and the potential jump across fast mode shocks

Two different methods were applied to determine the cross-shock potential jump in the de Hoffmann-Teller reference frame, using a data set that represented 66 crossings of the terrestrial bow shock and 14 interplanetary shocks observed by various ISEE spacecraft, and one crossing each of the Jovian bow shock and the Uranian bow shock made by the Voyager spacecraft. Results for estimates of the electrostatic potential based on an estimate of the jump in electron enthalpy correlated well with estimates based on Liouville's theorem, although the Liouville-determined values were systematically the higher of the two, suggesting that significant irreversible processes contribute to the shape of the downstream distribution. The potential jump corresponds to approximately 12-15 percent of the incident ion ram kinetic energy, and was found not to be controlled by the Mach number, plasma beta, shock geometry, or electron to ion temperature ratios.

Schwartz, Steven J.↗
DOE OSTI2018

Nuclear Magnetic Resonance Study of Anion and Cation Reorientational Dynamics in (NH 4 ) 2 B 12 H 12

Here, diammonium dodecahydro-closo-dodecaborate (NH 4 ) 2 B 12 H 12 is the ionic compound combining NH 4 + cations and [B 12 H 12 ] 2– anions, both of which can exhibit high reorientational mobility. To study the dynamical properties of this material, we measured the proton NMR spectra and spin–lattice relaxation rates in (NH 4 ) 2 B 12 H 12 over the temperature range of 6–475 K. Two reorientational processes occurring at different frequency scales have been revealed. In the temperature range of 200–475 K, the proton spin–lattice relaxation data are governed by thermally activated reorientations of the icosahedral [B 12 H 12 ] 2– anions. This motional process is characterized by the activation energy of 486(8) meV, and the corresponding reorientational jump rate reaches ~10 8 s –1 near 410 K. Below 100 K, the relaxation data are governed by the extremely fast process of NH 4 + reorientations which are not “frozen out” at the NMR frequency scale down to 6 K. The experimental results in this range are described in terms of a gradual transition from the regime of low-temperature quantum dynamics (rotational tunneling of NH 4 groups) to the regime of classical jump reorientations of NH 4 groups with an activation energy of 26.5 meV. Our study offers physical insights into the rich dynamical behavior of (NH 4 ) 2 B 12 H 12 on an atomic level, providing a link between the microscopic and thermodynamic properties of this compound.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Stochastic Differential Games for Fully Coupled FBSDEs with Jumps

This paper is concerned with stochastic differential games (SDGs) defined through fully coupled forward-backward stochastic differential equations (FBSDEs) which are governed by Brownian motion and Poisson random measure. The upper and the lower value functions are defined by the doubly controlled fully coupled FBSDEs with jumps. Using a new transformation introduced in Buchdahn (Stocha Process Appl 121:2715–2750, 2011), we prove that the upper and the lower value functions are deterministic. Then, after establishing the dynamic programming principle for the upper and the lower value functions of this SDGs, we prove that the upper and the lower value functions are the viscosity solutions to the associated upper and the lower second order integral-partial differential equations of Isaacs’ type combined with an algebraic equation, respectively. Furthermore, for a special case (when σ and h do not depend on (y,z,k)), under the Isaacs’ condition, we get the existence of the value of the game.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Gyrotropic Hall effect in Berry-curved materials

We study the ac Hall response induced by passage of dc transport current in two- and three-dimensional metals with gyrotropic point groups—the gyrotropic Hall effect—and consider the phenomenon of current-induced optical activity in noncentrosymmetric metals as a physical application of our theory. While the effect is expected to be present in single crystals of any noncentrosymmetric metal, we expect it to be strongest in enantiomorphic Weyl semimetals. Using the semiclassical kinetic equation approach, we present several mechanisms underlying the gyrotropic Hall effect. Amongst them, the intrinsic mechanism is determined by the Berry curvature dipole, while extrinsic impurity-induced processes are related to skew scattering and side-jump phenomena. In general, the intrinsic and extrinsic contributions can be of similar magnitude. We discuss the gyrotropic Hall effect for all frequencies of practical interest, from the dc transport limit, to optical frequencies. We show that for frequencies that are small compared to relevant band splittings, the trace of the gyrotropic Hall tensor in three-dimensional materials is proportional to a topological, quantized Berry charge, and therefore is robust in gyrotropic Weyl systems. This implies that polycrystals of strongly gyrotropic Weyl semimetals will demonstrate strong current-induced optical activity, whereas the response vanishes for polycrystalline ordinary metals. Furthermore the current-induced optical activity can be considered a valuable tool in identifying the topological nature of a material.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Understanding the structure and mechanism of Na + diffusion in NASICON solid-state electrolytes and the effect of Sc- and Al/Y-substitution

NASICON (sodium superionic conductor) based ceramics are one of the most promising classes of solid-state electrolytes for all-solid-state batteries. However, the mechanism of sodium ion diffusion is not understood in great detail since there is still a discrepancy between reported average structure models, local structures, and the number and position of sodium sites. To close this gap, we investigate the underlying diffusion mechanism and structural changes governing the Na + transport in Na 3.4 Zr 2 Si 2.4 P 0.6 O 12 using quasielastic neutron scattering (QENS) and powder X-ray diffraction (XRD). In the temperature range from 298 K to 640 K, the correlations between structural changes of a monoclinic C2/c to rhombohedral R $\bar{3}$c phase transition and the result of ion diffusion are investigated. The analysis of the quasielastic neutron scattering data reveals two quasielastic components corresponding to the Chudley-Elliott jump-diffusion model. It clearly shows two different Na + diffusion processes, local and long-range, on two different time and length scales and allows calculations of their corresponding activation energies. Additionally, the effects of Sc 3+ and Al 3+ /Y 3+ aliovalent substitution of Zr 4+ ions on the crystal structure and Na + diffusion are also studied. We can distinguish a local, chain, and cross-chain diffusion mechanism based on correlated QENS and XRD comparison of relevant nearest crystallographic Na–Na distances. The results reveal that the Na + diffusion in these NASICONs is three-dimensional and can provide guidelines on how dopants and changes in the crystal structure can affect the Na + conductivity.

25 ENERGY STORAGE↗
NASA NTRS1991

An error bound for instantaneous coverage

An error bound is derived for a reliability model approximation method. The approximation method is appropriate for the semi-Markov models of reconfigurable systems that are designed to achieve extremely high reliability. The semi-Markov models of these system are complex, and a significant amount of their complexity arises from the detailed descriptions of the reconfiguration processes. The reliability model approximation method consists of replacing a detailed description of a reconfiguration process with the probabilities of the possible outcomes of the reconfiguration process. These probabilities are included in the model as instantaneous jumps from the fault-occurrence state. Since little time is spent in the reconfiguration states, instantaneous jumps are a close approximation to the original model. This approximation procedure is shown to produce an overestimation for the probability of system failure, and an error bound is derived for this overestimation.

White, Allan L.↗
DOE OSTI2015

Giant magnetocaloric effect and temperature induced magnetization jump in GdCrO{sub 3} single crystal

We report on a systematic study of the single-crystal GdCrO{sub 3}, which shows various novel magnetic features, such as temperature-induced magnetization reversal (TMR), temperature-induced magnetization jump (TMJ), spin reorientation, and giant magnetocaloric effect (MCE). In the field-cooled cooling process with modest magnetic field along the c axis, GdCrO{sub 3} first shows a TMR at T{sub comp}∼120−130 K and then an abrupt TMJ with a sign change of magnetization at T{sub jump}∼52−120 K, and finally a spin reorientation at T{sub SR}∼4−7 K. Interestingly, the remarkable TMJ behavior, which was not reported ever before, persists at higher fields up to 10 kOe even when TMR disappears. In addition, giant MCE with the maximum value of magnetic entropy change reaching ∼31.6 J/kg K for a field change of 44 kOe was also observed in GdCrO{sub 3} single crystal, suggesting it could be a potential material for low-T magnetic refrigeration. A possible mechanism for these peculiar magnetic behaviors is discussed based on the various competing magnetic interactions between the 3d electrons of Cr{sup 3+} ions and 4f electrons of Gd{sup 3+} ions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗