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At least 73 records · Page 4

Impact of Lithium‐Free Borate Additives on the Cycle Life and Calendar Aging of Silicon‐Based Lithium‐Ion Batteries

Silicon-anode lithium-ion batteries (LIBs) suffer from limited cycle life and poor calendar life, constraining their large-scale commercialization. Integrating additives into electrolytes is a simple and cost-effective strategy to improve these aspects. The effects of lithium-free boron-based additives on cycling and calendar performance of high-loading Si-anode LIBs remain largely unexplored. In this work, the influence of five Li-free borate additives, each with distinct molecular structures and elemental compositions, is systematically investigated. All additives enhance cycle life to varying extents. Notably, the addition of 1 v/v% tri(2,2,2-trifluoroethyl) borate to the baseline electrolyte nearly doubles the cycle life at 50% state of health. This enhancement is attributed to three key factors. Specifically, borate additives 1) improve electrochemical activity, 2) act as anion receptors that interact with [PF6]- anions and carbonate solvents to reduce electrolyte decomposition, and 3) promote the formation of a stable and polymeric solid electrolyte interphase layer. Furthermore, these additives exhibited negligible impact in mitigating leakage current during a 180 h voltage-hold calendar-aging test, indicating their limited effect in calendar life. These findings provide insight into the role of Li-free borate additives in improving cycle life while addressing the knowledge gap regarding their influence on calendar aging.

Li, Defu↗

Sensitivity of Age-of-Air Calculations to the Choice of Advection Scheme

The age of air has recently emerged as a diagnostic of atmospheric transport unaffected by chemical parameterizations, and the features in the age distributions computed in models have been interpreted in terms of the models' large-scale circulation field. This study shows, however, that in addition to the simulated large-scale circulation, three-dimensional age calculations can also be affected by the choice of advection scheme employed in solving the tracer continuity equation, Specifically, using the 3.0deg latitude X 3.6deg longitude and 40 vertical level version of the Geophysical Fluid Dynamics Laboratory SKYHI GCM and six online transport schemes ranging from Eulerian through semi-Lagrangian to fully Lagrangian, it will be demonstrated that the oldest ages are obtained using the nondiffusive centered-difference schemes while the youngest ages are computed with a semi-Lagrangian transport (SLT) scheme. The centered- difference schemes are capable of producing ages older than 10 years in the mesosphere, thus eliminating the "young bias" found in previous age-of-air calculations. At this stage, only limited intuitive explanations can be advanced for this sensitivity of age-of-air calculations to the choice of advection scheme, In particular, age distributions computed online with the National Center for Atmospheric Research Community Climate Model (MACCM3) using different varieties of the SLT scheme are substantially older than the SKYHI SLT distribution. The different varieties, including a noninterpolating-in-the-vertical version (which is essentially centered-difference in the vertical), also produce a narrower range of age distributions than the suite of advection schemes employed in the SKYHI model. While additional MACCM3 experiments with a wider range of schemes would be necessary to provide more definitive insights, the older and less variable MACCM3 age distributions can plausibly be interpreted as being due to the semi-implicit semi-Lagrangian dynamics employed in the MACCM3. This type of dynamical core (employed with a 60-min time step) is likely to reduce SLT's interpolation errors that are compounded by the short-term variability characteristic of the explicit centered-difference dynamics employed in the SKYHI model (time step of 3 min). In the extreme case of a very slowly varying circulation, the choice of advection scheme has no effect on two-dimensional (latitude-height) age-of-air calculations, owing to the smooth nature of the transport circulation in 2D models. These results suggest that nondiffusive schemes may be the preferred choice for multiyear simulations of tracers not overly sensitive to the requirement of monotonicity (this category includes many greenhouse gases). At the same time, age-of-air calculations offer a simple quantitative diagnostic of a scheme's long-term diffusive properties and may help in the evaluation of dynamical cores in multiyear integrations. On the other hand, the sensitivity of the computed ages to the model numerics calls for caution in using age of air as a diagnostic of a GCM's large-scale circulation field.

Eluszkiewicz, Janusz↗

Large Scale Granulator Development Designed to Process Reclaimed Feedstock for Sustainable Additive Manufacturing Applications

This CRADA between UT-Battelle, LLC (Contractor) and re:3D Inc. (Participant) aims to develop an affordable large-scale granulator system designed to process reclaimed plastic feedstock suitable for additive manufacturing applications. The 24-month project will focus on testing, prototyping, and optimizing a shredder/granulator system. This project also focuses on the processing steps (e.g. washing and sorting) that can convert waste plastics, like discarded water bottles, into flake/granules which can be 3D printed using re:3D’s Fused Granular Fabrication (FGF) 3D printers. If successful, this could enable more localized 3D printing using recycled plastics, reducing waste and feedstock costs.

Wang, Peter [Oak Ridge National Laboratory (ORNL),↗

Characteristics of Extreme Precipitation Events (EPE) in the Tropics and Association with Convective Aggregation

Extreme precipitation (EP) has become increasingly frequent and is causing more devastating impacts on society in recent years. EP is traditionally measured by the maximum or threshold-exceeding gridded precipitation of a given duration. We have developed an extreme precipitation event (EPE) algorithm that tracks entire precipitation life cycle across space and time, which enables us to characterize properties of the entire EPE, such as duration (from sub-daily to multi-day), areal coverage, and total rain volume of the event. These EPE characteristics are critical in understanding precipitation development and their interaction with large-scale meteorology, in addition, providing more comprehensive matrix for disaster management. This study examines the EPE characteristics from the tropics derived from high-resolution Integrated Multi-satellitE Retrievals fro GPM (IMERG) product. The difference between EPE characteristics between tropical land and ocean will be discussed. Large-scale meteorological control as well as convective aggregation will be studied on the impact of EPE characteristics in tropics.

Convective aggregation↗

Space station static and dynamic analyses using parallel methods

Algorithms for high-performance parallel computers are applied to perform static analyses of large-scale Space Station finite-element models (FEMs). Several parallel-vector algorithms under development at NASA Langley are assessed. Sparse matrix solvers were found to be more efficient than banded symmetric or iterative solvers for the static analysis of large-scale applications. In addition, new sparse and 'out-of-core' solvers were found superior to substructure (superelement) techniques which require significant additional cost and time to perform static condensation during global FEM matrix generation as well as the subsequent recovery and expansion. A method to extend the fast parallel static solution techniques to reduce the computation time for dynamic analysis is also described. The resulting static and dynamic algorithms offer design economy for preliminary multidisciplinary design optimization and FEM validation against test modes. The algorithms are being optimized for parallel computers to solve one-million degrees-of-freedom (DOF) FEMs. The high-performance computers at NASA afforded effective software development, testing, efficient and accurate solution with timely system response and graphical interpretation of results rarely found in industry. Based on the author's experience, similar cooperation between industry and government should be encouraged for similar large-scale projects in the future.

Gupta, V.↗

A Model of the Chicxulub Impact Basin Based on Evaluation of Geophysical Data, Well Logs, and Drill Core Samples

Abundant evidence now shows that the buried Chicxulub structure in northern Yucatan, Mexico, is indeed the intensely sought-after source of the ejecta found world-wide at the Cretaceous-Tertiary (K/T) boundary. In addition to large-scale concentric patterns in gravity and magnetic data over the structure, recent analyses of drill-core samples reveal a lithological assemblage similar to that observed at other terrestrial craters. This assemblage comprises suevite breccias, ejecta deposit breccias (Bunte Breccia equivalents), fine-grained impact melt rocks, and melt-matrix breccias. All these impact-produced lithologies contain diagnostic evidence of shock metamorphism, including planar deformation features in quartz, feldspar, and zircons; diaplectic glasses of quartz and feldspar; and fused mineral melts and whole-rock melts. In addition, elevated concentrations of Ir, Re, and Os, in meteoritic relative proportions, have been detected in some melt-rock samples from the center of the structure. Isotopic analyses, magnetization of melt-rock samples, and local stratigraphic constraints identify this crater as the source of K/T boundary deposits.

Sharpton, Virgil L.↗

Additional Large-Drop Ice Accretion Test Results for a Large Scale Swept Wing Section from January 2022

In-flight icing is an important consideration that affects aircraft design, performance, certification and safety. Newer regulations combined with increasing demand to reduce fuel burn, emissions and noise are driving a need for improvements in icing simulation capability. To that end, this paper presents the results of additional ice accretion testing conducted in the NASA Icing Research Tunnel in January 2022 with a large swept wing section typical of a modern commercial transport. The model was based upon a section of the Common Research Model wing at the 64% semispan station with a streamwise chord length of 136 in. The test conditions were developed with an icing scaling analysis to generate similar conditions for a small median volumetric diameter (MVD) = 25 μm cloud and a large MVD = 110 μm cloud. A series of tests were conducted over a range of total temperature from -23.8 ˚C to -1.4 ˚C with all other conditions held constant. Another series of tests explored cloud MVD variations from 50 μm to 230 μm while holding constant certain scaling parameters. The variation in ice mass and scanned ice volume across repeat conditions was approximately 50% lower than the uncertainty in the cloud MVD and liquid water content. The measured ice mass and volume calculated from the 3D scans were used to compute the mass to volume ratio that is sometimes referred to as ice density or void fraction. When the ice volume based on the ice shape maximum combined cross section was used to determine this ratio, the resulting values were in the range of 240 to 455 kg/m 3 . This is consistent with analogous values previously reported in the literature. The ice shape mass and volume increased with MVD from 50 to 230 μm at fixed values of the scaling parameters. The ice mass to volume ratio was approximately constant for all of the cases which showed that the accreted mass and volume increased at approximately the same rate. These results demonstrate the significance of cloud MVD on ice shape mass and volume.

Ice accretion, Large drops, Wind tunnel↗

Additional Large-Drop Ice Accretion Test Results for a Large Scale Swept Wing Section from January 2022

In-flight icing is an important consideration that affects aircraft design, performance, certification and safety. Newer regulations combined with increasing demand to reduce fuel burn, emissions and noise are driving a need for improvements in icing simulation capability. To that end, this paper presents the results of additional ice accretion testing conducted in the NASA Icing Research Tunnel in January 2022 with a large swept wing section typical of a modern commercial transport. The model was based upon a section of the Common Research Model wing at the 64% semispan station with a streamwise chord length of 136 in. The test conditions were developed with an icing scaling analysis to generate similar conditions for a small median volumetric diameter (MVD) = 25 μm cloud and a large MVD = 110 μm cloud. A series of tests were conducted over a range of total temperature from -23.8 ˚C to -1.4 ˚C with all other conditions held constant. Another series of tests explored cloud MVD variations from 50 μm to 230 μm while holding constant certain scaling parameters. The variation in ice mass and scanned ice volume across repeat conditions was approximately 50% lower than the uncertainty in the cloud MVD and liquid water content. The measured ice mass and volume calculated from the 3D scans were used to compute the mass to volume ratio that is sometimes referred to as ice density or void fraction. When the ice volume based on the ice shape maximum combined cross section was used to determine this ratio, the resulting values were in the range of 240 to 455 kg/m3. This is consistent with analogous values previously reported in the literature. The ice shape mass and volume increased with MVD from 50 to 230 μm at fixed values of the scaling parameters. The ice mass to volume ratio was approximately constant for all of the cases which showed that the accreted mass and volume increased at approximately the same rate. These results demonstrate the significance of cloud MVD on ice shape mass and volume.

Ice accretion↗

Low Temperature CO2 Capture from an NGCC Flue Gas Using a Magnetically Stabilized, Inductively Heated Fluidized Bed Reactor

The lab sorbent testing finalized the sorbent composition and operating conditions for the integrated unit. The bench unit design included COMSOL simulation to finalize the coil design and select initial operating conditions of the power supply system. Fluidized bed testing with the induction heating verified that a heating efficiency of up to 90% can be achieved. The integrated bench unit operations provided valuable data confirming the feasibility of using induction heating for the desorption of CO2. Major challenge observed was the limited working capacity of the sorbent, requiring additional development in future projects. In addition, a large-scale reactor demonstration is required to mitigate the risk of uniform temperature distribution and heating efficiency over a large cross-sectional area when using induction heating.

Tong, Andrew↗

Morphological changes in the NGC 6251 jet

The giant radio galaxy NGC 6251 is a particularly good object for observational tests of relativistic jet models. Due to its high declination and approximately 0.5 Jy radio nucleus, high-quality Very Long Baseline Interferometry (VLBI) images of the central regions of the source can be made with northern hemisphere arrays. In addition, the large-scale radio morphology strongly suggests that the radio axis lies close to the plane of the sky, so Doppler boosting should be less extreme than in the core-dominated superluminal sources. Earlier 18 cm VLBI observations of NGC 6251 revealed an unexpectedly large jet/counterjet brightness ratio and small transverse motion of a feature in the parsec-scale jet. These early results are difficult to reconcile with the simplest symmetric relativistic jet models. In this paper we present a third-epoch 18 cm VLBI image of the parsec-scale radio jet in NGC 6251, and compare jet morphology over a 5 year time span. The jet shows a minor brightness peak at nearly the same distance from the core as the '25 mas knot' seen in the first- and second-epoch VLBI images. This feature is much less pronounced in the third epoch, and a relatively bright, new knot has appeared approximately 12 mas from the core. If this new component had a constant brightness during the 5 years separating the first and third observing epochs, then it must have moved away from the core with an apparent speed of at least 1.2c (compared with an upper limit of 0.23c for motion of the 25 mas knot). However, we cannot yet rule out a local brightening of the inner jet in favor of a new moving component. We determine a lower limit for the jet/couterjet brightness ratio of 100:1 within 6 mas of the core. We also present a new Very Large Array (VLA) image of the kpc-scale jet with 3 sec resolution, made from data obtained during the VLBI observations. The rate of decrease in jet surface brightness from parsec to kiloparsec scales is similar to jets in known superluminal radio sources.

Jones, Dayton L.↗

Condition Monitoring of Large-Scale Facilities

This document provides a summary of the research conducted for the NASA Ames Research Center under grant NAG2-1182 (Condition-Based Monitoring of Large-Scale Facilities). The information includes copies of view graphs presented at NASA Ames in the final Workshop (held during December of 1998), as well as a copy of a technical report provided to the COTR (Dr. Anne Patterson-Hine) subsequent to the workshop. The material describes the experimental design, collection of data, and analysis results associated with monitoring the health of large-scale facilities. In addition to this material, a copy of the Pennsylvania State University Applied Research Laboratory data fusion visual programming tool kit was also provided to NASA Ames researchers.

Hall, David L.↗

Summer Synoptic-Scale Waves over Tropical West Africa Observed by TRMM

A 5-year daily rainfall dataset (3B42) from TRMM (Tropical Rainfall Measuring Mission) is used to investigate the activity and properties of westward-propagating synoptic-scale waves over tropical West Africa. Evident wave signals appearing in wavenumber-frequency space show their modulations on the surface rainfall pattern during the boreal summer. Interannual variability exists in both their intensity and spectral properties, i. e., dominant frequency and wavenumber ranges. These variabilities can be partly ascribed to year-to-year variations of their embedded large-scale environment, especially the status of mid-tropospheric African easterly jet (AEJ). Generally, a stronger (weaker) AEJ indicates more (less) instability energy yielding a stronger (weaker) wave activity season. Seasonal mean rainfall has shown an impact on these waves in some years. However, the impact is not as clear and consistent as AEJ, implying the complexity of their relationship with large-scale environment. To fully understand interannual variability of synoptic-scale waves over tropical West Africa, including the variability in their preferred frequencies and wavenumbers, it is therefore necessary to examine possible intra-seasonal variations existing in both wave activity and large-scale fields, in addition to their structure, propagation, and associated convection.

Starr, David O.↗

Cloud Resolving Modeling

One of the most promising methods to test the representation of cloud processes used in climate models is to use observations together with cloud-resolving models (CRMs). CRMs use more sophisticated and realistic representations of cloud microphysical processes, and they can reasonably well resolve the time evolution, structure, and life cycles of clouds and cloud systems (with sizes ranging from about 2-200 km). CRMs also allow for explicit interaction between clouds, outgoing longwave (cooling) and incoming solar (heating) radiation, and ocean and land surface processes. Observations are required to initialize CRMs and to validate their results. This paper provides a brief discussion and review of the main characteristics of CRMs as well as some of their major applications. These include the use of CRMs to improve our understanding of: (1) convective organization, (2) cloud temperature and water vapor budgets, and convective momentum transport, (3) diurnal variation of precipitation processes, (4) radiative-convective quasi-equilibrium states, (5) cloud-chemistry interaction, (6) aerosol-precipitation interaction, and (7) improving moist processes in large-scale models. In addition, current and future developments and applications of CRMs will be presented.

Tao, Wei-Kuo↗

Guidelines for CubeSat's Thermal Design

Thermal and Fluids Analysis Workshop 2015, Silver Spring, MD. NCTS 19104-15. What does it take to thermally designlow cost, low mass cubesats? What are the differences in the approach when you compare with large scale missions?What additional risk is acceptable? What is the approach to hardware? How is the testing campaign run? These aresome of the questions that will be addressed in this course, which is designed to equip the attendees to support thedevelopment of cubesats at their organization.

0000↗

A CloudSat-CALIPSO View of Cloud and Precipitation Properties Across Cold Fronts over the Global Oceans

The distribution of cloud and precipitation properties across oceanic extratropical cyclone cold fronts is examined using four years of combined CloudSat radar and CALIPSO lidar retrievals. The global annual mean cloud and precipitation distributions show that low-level clouds are ubiquitous in the post frontal zone while higher-level cloud frequency and precipitation peak in the warm sector along the surface front. Increases in temperature and moisture within the cold front region are associated with larger high-level but lower mid-/low level cloud frequencies and precipitation decreases in the cold sector. This behavior seems to be related to a shift from stratiform to convective clouds and precipitation. Stronger ascent in the warm conveyor belt tends to enhance cloudiness and precipitation across the cold front. A strong temperature contrast between the warm and cold sectors also encourages greater post-cold-frontal cloud occurrence. While the seasonal contrasts in environmental temperature, moisture, and ascent strength are enough to explain most of the variations in cloud and precipitation across cold fronts in both hemispheres, they do not fully explain the differences between Northern and Southern Hemisphere cold fronts. These differences are better explained when the impact of the contrast in temperature across the cold front is also considered. In addition, these large-scale parameters do not explain the relatively large frequency in springtime post frontal precipitation.

Marine meteorology↗

Morphological Changes in the NGC 6251 Jet

The giant radio galaxy NGC 6251 is a particularly good object for observational tests of relativistic jet models. Due to its high declination and similar 0.5 Jy radio nucleus, high quality VLBI images of the central regions of the source can be made with northern hemisphere arrays. In addition, the large-scale radio morphology strongly suggests that the radio axis lies close to the plane of the sky, so Doppler boosting should be less extreme than in the core-dominated superluminal sources. Earlier 18-cm VLBI observations of NGC 6251 revealed an unexpectedly large jet/counterjet brightness ratio and small transverse motion of a feature in the parsec-scale jet. These early results are difficult to reconcile with the simplest symmetric relativistic jet models.

Wehrle, A. E.↗

TOPEX/POSEIDON Mission Early Results

The joint U.S./France TOPEX/Poseidon satellite was launched on August 10, 1992. Orbiting at an altitude of 1336 km with an inclination of 66 degrees, the satellite has been measuring the global sea surface height using a radar altimeter system along the same tracks on Earth every 10 days since late September, 1992. The major goal of the mission is to make precise measurements of the height of the sea surface for the study of the dynamics of large-scale ocean circulation. Additionally, the data will be used for studying ocean tides and marine geophysics. The radar altimeter also measures wave height and wind speed. The mission is being conducted to optimize the sea surface height measurements for a minimum of three years. The primary objective of the first six months of the mission was to calibrate and validate the mission's measurements...

Christensen, Edward J.↗

Detection of scintillation light in noble gases with wavelength-shifting optical fibers

Wavelength-shifting (WLS) techniques enable particle detectors based on noble gases, whose scintillation light is predominantly emitted in the vacuum-ultraviolet. We investigate WLS fibers coated with tetraphenyl butadiene (TPB) for scintillation light detection in gaseous xenon and argon at pressures up to 8.5 bar, motivated by future high-pressure xenon time-projection chambers of the NEXT program. Two detector configurations are studied: an elongated high-pressure vessel with four PTFE panels equipped with WLS fibers read by temperature-stabilized SiPMs, and a compact box-shaped detector operated at 1 bar Xe with WLS fibers read out by PMTs. Both operate with continuous gas purification. The detector response is characterized using cosmic muons and alpha particles from a $^{241}$Am source. With the SiPM setup, we measure a light collection efficiency (LCE) of ${1.18 \pm 0.01~\mathrm{(sta.)}~^{+0.07}_{-0.09}~\mathrm{(sys.)}~\%}$ for xenon and ${1.07 \pm 0.01~\mathrm{(sta.)}~^{+0.06}_{-0.08}~\mathrm{(sys.)}~\%}$ for argon. With PMT readout, we measure a LCE of ${0.45 \pm 0.01~\mathrm{(sta.)} \pm 0.05~\mathrm{(sys.)}~\%}$ in xenon, in agreement with the SiPM result once photon detection efficiency is accounted for. Average scintillation waveforms in xenon and argon are studied to assess the time structure of the emitted light. Cosmic-muon measurements yield a mean energy required to produce a scintillation photon $45\pm7~\mathrm{(sta.)}~^{+4}_{-5}~\mathrm{(sys.)}~\mathrm{eV}$ at 1.5 bar, in agreement with the literature. The results demonstrate that TPB-coated WLS fiber systems can reliably detect scintillation light in high-pressure gaseous noble detectors, with a LCE representing an upper limit for realistic large-scale TPCs, where additional photon losses from materials and fiber attenuation are expected.

Soleti, S. R. [Donostia Intl. Phys. Ctr., San Seba↗