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In this paper, we discuss the development of very sensitive long wavelength infrared (LWIR) GaAs/AlxGa1-xAs quantum well infrared photodetectors (QWIPs), fabrication of random reflectors for efficient light coupling, and the demonstration of first hand-held long-wavelength 256x256 QWIP focal plane array camera. Excellent imagery, with a noise equivalent differential temperature of 25 mK has been achieved.
In this paper, we discuss the development of very sensitive long wavelength infrared (LWIR) GaAs/Al(x)Ga(l-x)As quantum well infrared photodetectors (QWIPs), fabrication of random reflectors for efficient light coupling, and the demonstration of the first hand-held long-wavelength 256 x 256 QWIP focal plane array camera. Excellent imagery, with a noise equivalent differential temperature (NE Delta T) of 25 mK has been achieved.
NASA plans for space-based studies of the portion of the electromagnetic spectrum spanning about 30 through 1000 microns are reviewed. The scientific goals of such investigations are examined, and the relevant missions are discussed, including the Space Infrared Telescope Facility (SIRTF), the Submillimeter Wave Astronomy Satellite (SWAS), the Submillimeter Imager and Line Survey (SMILS), the Large Deployable Reflector (LDR), and the lunar submillimeter interferometer. Performance comparisons for these long wavelength missions are presented.
One of the simplest device realizations of the classic particle-in-the-box problem of basic quantum mechanics is the Quantum Well Infrared Photodetector (QWIP). In this paper we discuss the optimization of the detector design, material growth and processing that has culminated in realization of 15 micron cutoff 128x128 QWIP focal plane array camera, hand-held and palmsize 256x256 long-wavelength QWIP cameras and 648x480 long-wavelength cameras, holding forth great promise for myriad applications in 6-25 micron wavelength range in science, medicine, defense and industry.
Two modules of gallium-doped germanium (Ge:Ga) infrared detectors with integrated multiplexing readouts and supporting drive electronics were designed and tested. This development investigated the feasibility of producing two-dimensional Ge:Ga arrays by stacking linear modules in a housing capable of providing uniaxial stress for enhanced long-wavelength response. Each module includes 8 detectors (1x1x2 mm) mounted to a sapphire board. The element spacing is 12 microns. The back faces of the detector elements are beveled with an 18 deg angle, which was proved to significantly enhance optical absorption. Each module includes a different silicon metal-oxide semiconductor field effect transistor (MOSFET) readout. The first circuit was built from discrete MOSFET components; the second incorporated devices taken from low-temperature integrated circuit multiplexers. The latter circuit exhibited much lower stray capacitance and improved stability. Using these switched-FET circuits, it was demonstrated that burst readout, with multiplexer active only during the readout period, could successfully be implemented at approximately 3.5 K.
In this paper we discuss the optimization of the detector design, material growth and processing that has culminated in realization of 15 micron cutoff 128 x 128 QWIP focal plane array camera, hand-held and palmize 256 x 256 long-wavelength QWIP cameras and 648 x 480 long-wavelength cameras, holding forth great promise for myriad applications in 6-25 micron wavelength range in science, medicine, defense and industry.
We discuss a universal nonequilibrium enhancement of long-wavelength Goldstone bosons induced by quenches to the broken phase in Model G—the dynamical universality class of an 𝑂(4) antiferromagnet and the chiral phase transition in QCD. Scaling arguments for the coarsening dynamics describing the formation of the chiral condensate predict a parametric enhancement in the infrared spectra of Goldstone bosons, a prediction confirmed by stochastic simulations of the transition. The details of the enhancement are determined by the nonlinear dynamics of a superfluid effective theory, which is a limit of Model G reflecting the broken 𝑂(4) symmetry. Our results translate to a parametric enhancement of low-momentum pions in heavy-ion collisions at the LHC, which are underpredicted in current hydrodynamic models without critical dynamics.
IRAS flux densities are presented for all galaxies in the Center for Astrophysics magnitude-limited sample (mB not greater than 14.5) detected in the IRAS Faint Source Survey (FSS), a total of 1544 galaxies. The detection rate in the FSS is slightly larger than in the PSC for the long-wavelength 60- and 100-micron bands, but improves by a factor of about 3 or more for the short wavelength 12- and 25-micron bands. This optically selected sample consists of galaxies which are, on average, much less IR-active than galaxies in IR-selected samples. It possesses accurate and complete redshift, morphological, and magnitude information, along with observations at other wavelengths.
Measurements at a wavelength of 1.25 mm have been obtained for 17 IRAS galaxies selected on the basis of high far-infrared luminosity. These measurements are used to estimate the lower and upper limits to the mass of cold dust in infrared galaxies. As a lower limit on dust mass, all of the galaxies can be successfully modeled without invoking any dust colder than the dust responsible for the 60 and 100 micron emission that was detected by IRAS. As an upper limit, it is possible that the dust mass in a number of the galaxies may actually be dominated by cold dust. This large difference between the lower and upper limits is due primarily to uncertainty in the long-wavelength absorption efficiency of the astrophysical dust grains.
While experimentally there is great regularity below 1 deg K in the behavior of a particular thermal property for all amorphous dielectrics it is not understood why these properties should differ from those of crystalline dielectrics, since it would seem that at low temperatures long-wavelength elastic waves, similar in both cases, would determine the thermal properties. A model involving systems having very few levels is used in the present study, although the relation between the model's systems and the nature of the glassy state is not known. It is shown, among other effects, that: specific heat measurements above 0.1 K indicate a distribution of local modes independent of energy; ultrasonic velocity measurements give information about phonon-local mode coupling parameters; and thermal expansion and far infrared experiments indicate a phonon-assisted tunneling model.
Astronomical constraints on disks around young stellar objects are reviewed in this abstract. Since disks around the youngest stars cannot generally be resolved spatially, most results are based on analyses of the infrared and radio emission from circumstellar dust and gas. At least half of all young stars seem to have substantial circumstellar disks at an age of approximately 10(exp 6) yr. The young objects without disks tend to be binary stellar systems, though not exclusively, and some close binaries may have outer disks that are not tidally disrupted. Probably most, if not all, stars formed originally with circumstellar disks, but evolutionary timescales may differ dramatically. All the results, disk disappearance, disk mass around young stars, and long-wavelength dust opacities, are subject to the additional uncertainty of the effects of infalling dusty envelopes, which produce the disks in the first place.
A general process for creating complete, continuous, and absolutely calibrated 1-35 micron stellar spectra is described. The method is demonstrated by constructing an absolutely calibrated 1-35 micron spectrum of Alpha Tau and the method is independently validated using new observations. The absolute calibration of the IRAS low resolution spectrometer (LRS) data base is investigated by comparing the observed spectrum of Alpha Tau with that assumed in the original LRS calibration scheme. An analysis of asteroidal LRS spectra results in an independent assessment of the calibration problems with the LRS and provides a natural complement to the effort based on Alpha Tau. A direct comparison of LRS stellar spectra with independently calibrated long-wavelength airborne and ground-based spectra is made.
Infrared photometry from 1 to 20 microns and spectroscopy at about 2 microns are presented for Nova Cygni 1975 for the period from 2 days before to 1 yr after maximum light. The data can be explained by a simple model in which the expanding gas expelled during the explosion is always a plasma at approximately 10,000 K. Initially the gas is optically thick; this phase clearly defines the time of onset of the nova. Later, as the gas continues to expand, it becomes optically thin. The temporal dependence of the observed flux suggests that in this phase the expanding cloud is in the form of a shell. After about 300 days, long-wavelength emission which may be attributable to thermal reradiation from dust is observed.
The ability to capture and utilize light in the near-ultraviolet (NUV), visible and near-infrared (NIR-I and NIR-II) spectral regions (i.e., 320–400, 400–700, 700–1000, 1000–1700 nm) is essential for any solar-energy conversion scheme. Nature employs chlorophylls and bacteriochlorophylls in light-harvesting architectures to absorb light in the blue and red/NIR regions. Accessory pigments (carotenoids, bilins) augment absorption of the (bacterio)chlorophylls in the green region. The harvested energy is funneled to a reaction center protein, where charge separation occurs. Subsequent migration of the electron and the hole stabilizes and stores the energy from light via redox chemistry. The long-term objective of the Bocian/Holten&Kirmaier/Lindsey research program under this DOE grant has been to develop tetrapyrrole-based molecular architectures that absorb sunlight, funnel energy and separate charge with high efficiency. Integral to the program has been iterative cycles of design, synthesis and characterization that provided deep insights into the relationships between chemical composition, electronic structure, and key static and dynamic properties (vibrational, redox, photophysical, energy/charge transfer) of tetrapyrrolic systems. Such architectures included monomers, dyads, larger arrays, and complexes with accessory components. The objective was to develop molecular designs and guiding principles to enhance current and future energy-conversion schemes. Molecular arrays targeted to address one or more fundamental questions concerning light harvesting and energy/charge transfer were constructed from analogues of the naturally occurring hemes, chlorophylls and bacteriochlorophylls. Diverse, tunable synthetic building blocks were prepared that spanned the three respective tetrapyrrole families, which are the porphyrins, chlorins and bacteriochlorins. Thus, the research focused on porphyrins as well as synthetic surrogates for chlorophylls (chlorins, 13 1 -oxophorbines and chlorin-imides) and bacteriochlorophylls (bacteriochlorins, bacterio-13 1 -oxophorbines and bacteriochlorin-imides), generically termed hydroporphyrins. Although the three tetrapyrrole classes (porphyrins, chlorins and bacteriochlorins) absorb light strongly in the violet-blue spectral region, the long-wavelength absorption band typically lies in the green-orange, red, and NIR regions, respectively, with increasing intensity. Understanding the spectra, electronic structure, and energy/charge-transfer properties of such tetrapyrrolic macrocycles is of central importance for the rational design of molecular architectures for solar-energy conversion. Our integrated program of molecular design and synthesis coupled with a variety of spectroscopic, electrochemical, and computational studies have probed from first principles how structural and electronic properties of tetrapyrrolic macrocycles dictate spectral properties as well as the rates of ground-state hole/electron transfer and excited-state energy flow in multicomponent architectures. Individual molecules and multicomponent architectures were designed to test ideas of fundamental importance, often requiring the development of new synthetic methodology. The members of the collaborative team had almost daily discussions by phone and/or e-mail concerning design of molecules, flow of compounds between the labs, planning of physical characterization studies, discussing results and analysis and integrating into design of next generation architectures, and the preparation of manuscripts. Furthermore, students and postdocs in the different labs routinely communicated with one another to facilitate the advancement of the research activities. In short, a highly integrated and collaborative research program was well established among the groups. The research effort involved molecular design and synthesis of synthetic molecular architectures by the Lindsey group integrated with physicochemical and photophysical characterization by the Bocian group and the Holten&Kirmaier group (Figure 2). The Bocian group carried out electrochemical, electron paramagnetic resonance (EPR), resonance Raman (RR), and Fourier-transform infrared (FT-IR) studies, as well as density functional theory (DFT) calculations and the time-dependent extension (TDDFT) to gain insight into excited-state properties. The Holten&Kirmaier group carried out static and time-resolved absorption and fluorescence spectroscopy studies and simulated absorption spectra using molecular orbital (MO) energies from DFT as input to the four-orbital model to complement the TDDFT calculations. The combined measurements provided understanding of the vibrational/electronic properties of the individual molecules and the changes that occur upon incorporation into multicomponent architectures. This information underpinned elucidating the mechanisms and timescales of ground-state hole/electron transfer and excited-state energy and charge transfer.
The sub-Terahertz and Terahertz bands play a critical role in next-generation wireless communication and sensing technologies, thanks to the large amount of available bandwidth in this spectral regime. While long-wavelength (microwave to mm-Wave) and short-wavelength (near-infrared to ultraviolet) devices are well-established and studied, the sub-THz to THz regime remains relatively underexplored and underutilized. Traditional approaches used in the aforementioned spectral regions are more difficult to replicate in the THz band, leading to the need for the development of novel devices and structures that can manipulate THz radiation effectively. Herein a novel organic, solid-state electrochemical device is presented, capable of achieving modulation depths of over 90% from ≈500 nm of a conducting polymer that switches conductivity over a large dynamic range upon application of an electronically controllable external bias. The stability of such devices under long-term, repeated voltage switching, as well as continuous biasing at a single voltage, is also explored. Switching stabilities and long-term bias stabilities are achieved over two days for both use cases. Additionally, both depletion mode (always “ON”) and accumulation mode (always “OFF”) operation are demonstrated. These results suggest applications of organic electrochemical THz modulators in large area and flexible implementations.
The detection of mid-infrared (MIR) light is technologically important for applications such as night vision, imaging, sensing, and thermal metrology. Traditional MIR photodetectors either require cryogenic cooling or have sophisticated device structures involving complex nanofabrication. Here, we conceive spectrally tunable MIR detection by using two-dimensional metal halide perovskites (2D-MHPs) as the critical building block. Leveraging the ultralow cross-plane thermal conductivity and strong temperature-dependent excitonic resonances of 2D-MHPs, we demonstrate ambient-temperature, all-optical detection of MIR light with sensitivity down to 1 nanowatt per square micrometer, using plastic substrates. Through the adoption of membrane-based structures and a photonic enhancement strategy unique to our all-optical detection modality, we further improved the sensitivity to sub–10 picowatt-per-square-micrometer levels. The detection covers the mid-wave infrared regime from 2 to 4.5 micrometers and extends to the long-wave infrared wavelength at 10.6 micrometers, with wavelength-independent sensitivity response. Our work opens a pathway to alternative types of solution-processable, long-wavelength thermal detectors for molecular sensing, environmental monitoring, and thermal imaging.
The morphology of Titan's infrared spectral features reveals a pattern of differences with respect to Saturn's bands. Titan's bands exhibit a progressive washing out with increasing wavelength relative to the corresponding bands in Saturn's spectrum. Unidentified absorption features of apparently gaseous origin appear in the long-wavelength wing of Titan's 1-micron CH4 band complex with considerably greater strength. Greater absorption is also observed in the 1.1 micron region. Not all of the phenomena can be explained by enhanced CH4 absorption, so Titan's spectrum implies the existence of another spectroscopically active gas. Several candidates for this gas are briefly considered.
Infrared observations from 30 to 37 microns of IRC+10216 extend the wavelength coverage of the 30-micron feature found in four carbon stars and two planetary nebulae by Forrest, Houck, and McCarthy (1981). The present data confirm the existence of this newly observed feature and determine its shape beyond 30 microns. The determination of the long-wavelength end of the spectral excess depends critically on the assumed underlying continuum. A combined spectrum of the excess is presented and shows the feature to extend to at least 37 microns.