SEARCH · Search NASA

Results for “MEO”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 73 records · Page 4

All sources NASA NTRS DOE OSTI

NASA NTRS2017

Comparing Eyewitness-Derived Trajectories of Bright Meteors to Instrumentally-Observed Data

The NASA Meteoroid Environment Office (MEO) is often called upon to analyze meteors of public interest observed over the United States. Data from meteor networks are often utilized to accomplish this, as are recordings from the general public. When these methods fail, eyewitness reports are the only resource which can be leveraged. The MEO developed a tool to crudely calculate the trajectories of bright meteors from the eyewitness reports submitted to the American Meteor Society. The tool was tested on eyewitness data for 33 cases and compared to observed data from the NASA All Sky Fireball Network. The tool performed better for cases with more than 75 eyewitness reports than those with fewer than 75, by almost a factor of two across all metrics except for the end height. For these cases, the eyewitness-derived trajectory was about 50 km from the observed trajectory, the radiant was within 15deg, and the speed was within 20% of that observed on average. A description of the tool, example case studies, and general trends are described.

D E Moser↗

NASA NTRS2019

Meteoroid Engineering Model (MEM) 3: NASA’s Newest Meteoroid Model

Meteoroid impacts threaten spacecraft and astronauts at all locations within the Solar System. At certain altitudes in low-Earth orbit, orbital debris dominates the risk, but meteoroids are more significant within 250 km of the Earth’s surface and above 4000 km [1]. In interplanetary space, orbital debris is nonexistent and meteoroids constitute the entire population of potentially dangerous impactors. The NASA Meteoroid Environment Office (MEO) produces the Meteoroid Engineering Model (MEM) to support meteoroid impact risk assessments [2]; MEM is a stand-alone piece of software that describes the flux, speed, directionality, and bulk density of meteoroids striking a spacecraft on a user-supplied trajectory. The MEO released version 3 of MEM in 2019 [3]. This proceeding describes the orbital populations that form the core of MEM, highlights key differences between MEM 3 and its predecessors, discusses the implications of these changes for spacecraft, summarizes our validation against meteor and in-situ data, and delineates the model’s limitations.

Moorhead, Althea V.↗

DOE OSTI2025

A new synthetic method of [Ru(2,2′:6′,2″-terpyridine)(2,2′-bipyridine)Cl] + complexes using cis -[Ru(2,2′:6′,2″-terpyridine)(NCCH 3 ) 2 Cl] + as an intermediate and comparison to a method using [Ru(benzene)(2,2′-bipyridine)Cl] + intermediates

A new method of synthesizing [Ru(terpy)(bpy)Cl] + (terpy = 2,2′:6′,2″-terpyridine, bpy = 2,2′-bipyridine) complexes using the starting material cis-[Ru(terpy)(NCCH 3 ) 2 Cl](PF 6 ) is reported. The yields of four derivatives ([Ru(terpy)(NN)Cl](PF 6 ): NN = bpy, 1; 4,4′-(MeO) 2 bpy, 2; 4,4′-(CF 3 ) 2 bpy, 3; 2,2′-biquinoline, 4) with this method range from 58 to 94 % and are similar to or greater than a known reaction in which the starting material is [Ru(benzene)(NN)Cl](PF 6 ). However, the use of cis-[Ru(terpy)(NCCH 3 ) 2 Cl](PF 6 ) results in lower levels of homoleptic Ru byproducts in the synthesis of 1 as compared to the use of [Ru(benzene)(bpy)Cl](PF 6 ) as determined by 1 H NMR spectroscopy. In addition, a high-purity and gram-scale synthesis of cis-[Ru(terpy)(NCCH 3 ) 2 Cl](PF 6 ) that does not use column chromatography is reported, in contrast to the original synthesis disclosed in the literature.

Bipyridine↗

DOE OSTI2025

Synthesis and structural characterization of 2,2′:6′,2″-terpyridine zinc formate: Hydroboration and hydrosilylation of CO 2 and carbonyl compounds

The zinc formate compound (terpy)Zn(O 2 CH) 2 is obtained via the reaction of Zn(O 2 CH) 2 with 2,2′:6′,2″-terpyridine (terpy) and has been structurally characterized by X-ray diffraction as possessing formate ligands that coordinate via a κ 1 -monodentate coordination mode, which is in accord with IR spectroscopic studies. In terms of reactivity, (terpy)Zn(O 2 CH) 2 participates in catalytic transformations involving CO 2 and carbonyl compounds via hydrosilylation and hydroboration reactions. For example, (terpy)Zn(O 2 CH) 2 achieves hydroboration of Me 2 CO and Ph 2 CO by HBpin to afford R 2 C(H)OBpin, and triple insertion of Ph 2 CO, PhC(O)Me, Me 2 CO and PhCHO into the Si–H bonds of PhSiH 3 to afford PhSi[OCH(R)R’] 3 . In addition, CO 2 also undergoes hydroboration and hydrosilylation by HBpin and (MeO) 3 SiH in the presence of (terpy)Zn(O 2 CH) 2 to afford HCO 2 Bpin and HCO 2 Si(OMe) 3 , respectively.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Anion-Activated Bases and Nucleophiles Characterized by Photoelectron Spectroscopy

In this study, negative ion photoelectron spectra at 20 K along with ab initio (CCSD(T)) and M06-2X density function theory calculations are reported for a series of six basic and nucleophilic pyridine derivatives with an anionic substituent (i.e., 3- and 4-PyrBX 3 –, where X = F, 4-t-BuC 6 H 4 , 4- MeOC 6 H 4 , and 3,5-(MeO) 2 C 6 H 3 ). Vertical detachment energies spanning from 4.50 – 5.85 eV are observed and well reproduced by M06-2X/aug-cc-pVTZ and CCSD(T)/maug-cc-pVTZ computations. Surprisingly, the VDEs are found to correlate with the S N 2 reactivity of the PPh 4 + salts of the anions with 1-iodooctane. Spin densities of the neutral structures formed from the anionic species are also reported and indicate where the excess electron density in the anions resides and likely cation-interaction sites in their corresponding salts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Tuning Excited-State Charge Transfer Character in Cofacial Core-Substituted Perylenediimide Dimers

Understanding the interplay between excimer formation and symmetry-breaking charge separation is important for optimizing charge separation in organic photovoltaic materials. To explore this connection, we synthesized four 1,6,7,12-tetrakis( p -X-phenoxy)perylene-(3,4:9,10)-bisdicarboximide cofacially stacked dimers, where X = MeO, tert -butyl, Br, and CF 3 . Steady-state spectroscopy reveals H-type aggregation and excimer formation in all four dimers, while transient absorption spectroscopy shows relatively small changes in their excited-state absorptions. However, time-resolved fluorescence (TRF) spectroscopy shows that relaxation occurs from an initial Frenkel exciton-dominated excimer state to one in which charge transfer (CT) character contributes. Relaxation to the lower-lying state with CT character is attributed to a combination of structural and charge distribution changes elicited by varying the substituents. Finally, this study illustrates how subtle changes in charge distribution and structure can combine to influence the excited state dynamics that influence charge separation in molecular dimers.

fluorescence↗

DOE OSTI2022

Catalytic reduction of carbon dioxide by a zinc hydride compound, [Tptm]ZnH, and conversion to the methanol level

The zinc hydride compound, [Tptm]ZnH, may achieve the reduction of CO 2 by (RO) 3 SiH (R = Me, Et) to the methanol oxidation level, (MeO) x Si(OR) 4–x , via the formate species, HCO 2 Si(OR) 3 . Furthermore, because insertion of CO 2 into the Zn–H bond is more facile than insertion of HCO 2 Si(OR) 3 , conversion of HCO 2 Si(OR) 3 to the methanol level only occurs to a significant extent in the absence of CO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Stabilized hole-selective layer for high-performance inverted p-i-n perovskite solar cells

P-i-n geometry perovskite solar cells (PSCs) offer simplified fabrication, greater amenability to charge extraction layers, and low-temperature processing over n-i-p counterparts. Self-assembled monolayers (SAMs) can enhance the performance of p-i-n PSCs but ultrathin SAMs can be thermally unstable. Here we report a thermally robust hole-selective layer comprised of nickel oxide (NiO x ) nanoparticle film with a surface-anchored (4-(3,11-dimethoxy-7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid (MeO-4PADBC) SAM that can improve and stabilize the NiO x /perovskite interface. The energetic alignment and favorable contact and binding between NiO x /MeO-4PADBC and perovskite reduced the voltage deficit of PSCs with various perovskite compositions and led to strong interface toughening effects under thermal stress. The resulting 1.53–electron-volt devices achieved 25.6% certified power conversion efficiency and maintained >90% of their initial efficiency after continuously operating at 65 degrees Celsius for 1200 hours under 1-sun illumination.

14 SOLAR ENERGY↗

NASA NTRS1993

Trends in mobile satellite communication

Ever since the U.S. Federal Communication Commission opened the discussion on spectrum usage for personal handheld communication, the community of satellite manufacturers has been searching for an economically viable and technically feasible satellite mobile communication system. Hughes Aircraft Company and others have joined in providing proposals for such systems, ranging from low to medium to geosynchronous orbits. These proposals make it clear that the trend in mobile satellite communication is toward more sophisticated satellites with a large number of spot beams and onboard processing, providing worldwide interconnectivity. Recent Hughes studies indicate that from a cost standpoint the geosynchronous satellite (GEOS) is most economical, followed by the medium earth orbit satellite (MEOS) and then by the low earth orbit satellite (LEOS). From a system performance standpoint, this evaluation may be in reverse order, depending on how the public will react to speech delay and collision. This paper discusses the trends and various mobile satellite constellations in satellite communication under investigation. It considers the effect of orbital altitude and modulation/multiple access on the link and spacecraft design.

Johannsen, Klaus G.↗

NASA NTRS1993

INMARSAT's personal communicator system

Inmarsat has been providing near global mobile satellite communications since 1982 and Inmarsat terminals are currently being used in more than 130 countries. The terminals have been reduced in size and cost over the years and new technology has enabled the recent introduction of briefcase sized personal telephony terminals (Inmarsat-M). This trend continues and we are likely to see Inmarsat handheld terminals by the end of the decade. These terminals are called Inmarsat-P and this paper focuses on the various elements required to support a high quality service to handheld terminals. The main system elements are: the handheld terminals; the space segment with the associated orbits; and the gateways to terrestrial networks. It is both likely and desirable that personal handheld satellite communications will be offered by more than one system provider and this competition will ensure strong emphasis on service quality and cost of ownership. The handheld terminals also have to be attractive to a large number of potential users, and this means that the terminals must be small enough to fit in a pocket. Battery lifetime is another important consideration, and this coupled with radiation safety requirements limits the maximum radiated EIRP. The terminal G/T is mainly constrained by the gain of the omnidirectional antenna and the noise figure of the RF front end (including input losses). Inmarsat has examined, with the support of industry, a number of Geosynchronous (GSO), Medium Earth Orbit (MEO) and Low Earth Orbit (LEO) satellite options for the provision of a handheld mobile satellite service. This paper describes the key satellite and orbit parameters and tradeoffs which affect the overall quality of service and the space segment costing. The paper also stresses not only the importance of using and sharing the available mobile frequency band allocations efficiently, but also the key considerations affecting the choice of feeder link bands. The design of the gateways and the terrestrial network is critical to the overall viability of the service, and this paper also examines the key technical parameters associated with the Land Earth Stations (LES), which act as gateways into the Public Switched Telephone Network (PSTN). These not only include the design tradeoffs associated with the LES, but also the different terrestrial network interface options. The paper concludes with a brief description of the satellite propagation conditions associated with the use of handheld terminals. It describes how the handheld results in a number of propagation impairments which are not common to the previous measurements associated with vehicle mounted antennas. These measurements indicate that there is a complex tradeoff between link margin and the elevation angle to the satellite which has a significant impact on the space segment requirements and costing.

Hart, Nick↗

NASA NTRS1993

Global coverage Mobile Satellite Systems: System availability versus channel propagation impairments

Mobile Satellite Systems (MSS) in Highly Elliptical (HEO) and circular Earth orbits at Medium (MEO) and Low (LEO) altitudes have been intensively studied in the last few years as an effective means of providing global communication services. Such global coverage MSS networks are also expected to mitigate typical channel impairments usually encountered in geostationary Land Mobile Satellite (LMS) systems. In the design stages of these satellite networks, information regarding the mobile propagation channel is needed to assess the overall link availability versus elevation angle and environmental scenarios. For multisatellite LMS configurations, the mobile user on the Earth surface sees, at any given time, more than one satellite of the constellation. In our paper, it is shown that, under certain working assumptions regarding the statistics of the propagation channel, an improvement of the link availability may be achieved through the use of a multisatellite constellation. The analyses have been carried out using the European Space Agency (ESA) LMS propagation data base which presently covers a wide range of elevation angles and environmental scenarios.

Sforza, M.↗

NASA NTRS1993

Study on networking issues of medium earth orbit satellite communications systems

Two networking issues of communications systems with medium earth orbit (MEO) satellites, namely network architectures and location determination and registration methods for hand-held terminals, are investigated in this paper. For network architecture, five candidate architectures are considered and evaluated in terms of signaling traffic. For location determination and registration, two methods are discussed and evaluated.

Araki, Noriyuki↗

NASA NTRS1993

The possibilities for mobile and fixed services up to the 20/30 GHz frequency bands

Satellite Communications and broadcasting is presently in a period of considerable change. In the fixed service there is strong competition from terrestrial fiber optic systems which have virtually arrested the growth of the traditional satellite market for long distance high capacity communications. The satellite has however made considerable progress in areas where it has unique advantages; for example, in point to multipoint (broadcasting), multipoint to point (data collection) and generally in small terminal system applications where flexibility of deployment coupled with ease of installation are of importance. In the mobile service, in addition to the already established geostationary systems, there are numerous proposals for HEO, MEO and LEO systems. There are also several new frequency allocations as a result of the WARC 92 to be taken into account. At one extreme there are researchers working on Ka band 20/30 GHz mobile systems and there are other groups who foresee no future above the L-band frequency allocations. Amongst all these inputs it is difficult to see the direction in which development activities both for satellites and for earth segment should be focused. However, as an aid to understanding, this paper seeks to find some underlying relationships and to clarify some of the variables.

Hughes, Clifford D.↗

NASA NTRS1995

An update on SCARLET hardware development and flight programs

Solar Concentrator Array with Refractive Linear Element Technology (SCARLET) is one of the first practical photovoltaic concentrator array technologies that offers a number of benefits for space applications (i.e. high array efficiency, protection from space radiation effects, a relatively light weight system, minimized plasma interactions, etc.) The line-focus concentrator concept, however, also offers two very important advantages: (1) low-cost mass production potential of the lens material; and (2) relaxation of precise array tracking requirements to only a single axis. These benefits offer unique capabilities to both commercial and government spacecraft users, specifically those interested in high radiation missions, such as MEO orbits, and electric-powered propulsion LEO-to-GEO orbit raising applications. SCARLET is an aggressive hardware development and flight validation program sponsored by the Ballistic Missile Defense Organization (BMDO) and NASA Lewis Research Center. Its intent is to bring technology to the level of performance and validation necessary for use by various government and commercial programs. The first phase of the SCARLET program culminated with the design, development and fabrication of a small concentrator array for flight on the METEOR satellite. This hardware will be the first in-space demonstration of concentrator technology at the 'array level' and will provide valuable in-orbit performance measurements. The METEOR satellite is currently planned for a September/October 1995 launch. The next phase of the program is the development of large array for use by one of the NASA New Millenium Program missions. This hardware will incorporate a number of the significant improvements over the basic METEOR design. This presentation will address the basic SCARLET technology, examine its benefits to users, and describe the expected improvements for future missions.

Jones, P. Alan↗

NASA NTRS1995

Hand-held terminal antennas for personal satellite communications

This paper deals with two hand-held antenna types operating with geostationary and medium earth orbit (GEO and MEO) satellite systems. They could be applied to the low earth orbit (LEO) and highly elliptical orbit (HEO) systems respectively doing the appropriate frequency scale designs. The first one is a lambda/2 (1/2 turn) quadrifilar helix (quasi-hemispherical coverage), and the second one is a self-diplexed antenna made of a circular patch and a short-circuited ring patch in stacked configuration (zenithal coverage).

Caballero, J. E.↗

NASA NTRS1995

The Ellipso (TM) mobile satellite system

The Ellipso(trademark) Mobile Satellite System is conceived to extend telecommunication services throughout the world to users that are not well, or not at all served by existing mobile or fixed telephone systems. Unlike cellular telephones, Ellipso(trademark) offers fully nationwide service to every served country, thereby providing service to users located anywhere within the national boundaries, no matter how isolated or remote. With Ellipso(trademark), a user in the middle of a wilderness area will have the same mobile telecommunications service as a user in a major metropolitan area. Ellipso(trademark) uses medium earth orbiting (MEO) satellites and an efficient system design to reach its subscribers directly and at a price that is competitive with terrestrial telephone services. The subscriber only requires a clear view of a serving satellite to achieve a connection and to connect to anyone else served by the national telecommunications system. Subscribers within view of two or more satellites will benefit from Ellipso's(trademark) unique satellite diversity processing, using all available satellites simultaneously to optimize circuit quality.

Castiel, David↗

NASA NTRS1995

Non-GEO mobile satellite systems: A risk assessment

Since 1991, The MITRE Corporation has performed several independent evaluations of proposed mobile satellite service (MSS) systems that would operate from low Earth orbit (LEO) or medium Earth orbit (MEO), also known as intermediate circular orbit (ICO). This paper introduces a top level Risk Taxonomy tailored to summarize the technical and programmatic risks that MITRE has identified. In general, as risks are identified and addressed, a system's technical characteristics, cost and schedule are affected. This paper traces changes in three key parameters - satellite launch mass, system cost, and system schedule - for each of the five original non-GEO MSS systems for which license applications were made to the U.S. Federal Communications Commission (FCC) from November 1990 until June 1991. Finally, specific risk areas are identified using the Risk Taxonomy as a framework for discussion.

Gaffney, Leah M.↗

NASA NTRS1996

Space-Based Information Infrastructure Architecture for Broadband Services

This study addressed four tasks: (1) identify satellite-addressable information infrastructure markets; (2) perform network analysis for space-based information infrastructure; (3) develop conceptual architectures; and (4) economic assessment of architectures. The report concludes that satellites will have a major role in the national and global information infrastructure, requiring seamless integration between terrestrial and satellite networks. The proposed LEO, MEO, and GEO satellite systems have satellite characteristics that vary widely. They include delay, delay variations, poorer link quality and beam/satellite handover. The barriers against seamless interoperability between satellite and terrestrial networks are discussed. These barriers are the lack of compatible parameters, standards and protocols, which are presently being evaluated and reduced.

Price, Kent M.↗