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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Toxic Hazards Research Unit annual technical report, 1972

The activities of the Toxic Hazards Research Unit (THRU) for the period of June 1971 through May 1972 are reviewed in this report. Acute inhalation toxicity experiments were conducted on hydrogen chloride (HCl) gas and aerosol, ethyl bromide (C2H5Br), hydrogen bromide (HBr), hydrogen sulfide (H2S), ammonia (NH3), chlorine (CL2), and silane (SiH4). Subacute toxicity studies were conducted on chlorine pentafluoride (ClF5), dichloromethane (CH2Cl2) and coal tar volatiles. Further toxicity studies of subacute and chronic responses to inhaled monomethylhydrazine (MMH) are also described.

Macewen, J. D.↗

Thermal control and structures approach for fluorinated propulsion.

FLOX and fluorine oxidizers require cryogenic storage at 86 K (-305 F) aboard a spacecraft, whereas their respective fuels MMH and hydrazine require room temperature storage. Propulsion configuration trade-off studies have been made for two potential classes of missions, an outer planet orbiter utilizing RTG's and an inner planet orbiter utilizing solar panels. The preliminary designs incorporate the fuel tank within the thermally controlled electronics compartment and expose the cryogenic tank to space. The cryogenic tank is isolated with foam, shadow shields and a titanium truss support. Its vernier temperature control is accomplished with electrical heaters.

Stimpson, L. D.↗

Development of the propulsion subsystem for the Viking 75 Orbiter

The development of the Viking 75 Orbiter propulsion subsystem has been completed and qualification is under way. This development required an extension of the Mariner Mars 1971 propulsion subsystem technology to meet the Viking 75 requirements of three times the burn time and five times the number of burns. Modifications have been incorporated into the rocket engine to increase the cooling margin for the 2700-second Mars orbit insertion burn. This capability has been demonstrated in both engine firings and subsystem tests. A new surface tension device has been developed to position the propellants (N2O4 and MMH) over the tank outlets during zero-g flight. Extensive scale model testing has been conducted to prove this propellant management concept. This subsystem will provide midcourse corrections, an orbit insertion burn and 20 orbit trims for the Viking 75 Spacecraft. The Viking Project is managed by the Langley Research Center, National Aeronautics and Space Administration.

Vote, F. C.↗

A feasibility study of developing toroidal tanks for a spinning spacecraft

The use of toroidal tanks in an advanced Pioneer, spin-stabilized Jupiter orbiter was investigated. Fluid behavior in spinning toroids was evaluated and the need for a propellant acquisition system was established. A common surface tension acquisition system design was selected from four candidates for gas-free liquid feed to a single outlet in both MMH and N2O4 tanks. Fabrication of toroidal tanks using either titanium or aluminum alloys is feasible. Integration of two toroidal tanks with surface tension systems in place of four spherical tanks provides spacecraft weight, packaging, structural mounting, thermal control and stability advantages.

Anderson, J. E.↗

Potential seal candidates for high-energy propellants

Five potential seal candidates (linear Tefzel, linear Halar, crosslinked Halar, Viton ECD-006, and phosphazine fluoroelastomer) were evaluated for the orbital maneuvering system of the space shuttle. Since this system employs nitrogen tetroxide (N2O4) and monomethyl hydrazine (MMH) as hypergolic propellants, the seal candidates were selected on the basis of projected chemical resistance as well as rheological behavior. Chemical resistance to these high-energy fuels was determined via conventional isothermal and thermal cycling immersion tests. Rheological measurements, however, were performed on O-rings molded from the subject seal candidates. Properties determined, such as cyclic work and hysteresis, stress relaxation, and indicated modulus, therefore, relate to the O-ring seals themselves.

Merz, P. L.↗

Low-G fluid transfer technology study

Technology gaps and system characteristics critical to cryogenic and noncryogenic in-orbit fluid transfer were identified. Four different supply systems were conceptually designed as space shuttle payloads. These were; (1) space tug supply - LH2, LO2, N2H4, He - linear acceleration for liquid acquisition with supply module and tug separated from shuttle, (2) tug supply using orbiter drag, (3) orbiter supply - N2O4,MMH,He, H2,O2 - surface tension screens, (4) multiple receivers supply 0 solar electric propulsion stage, Hg, diaphragm - HEAO B, HEe, paddle fluid rotation-satellite control section, N2H4, screens. It was found that screens had the best overall potential for low weight and simplicity, however, thermal problems with cryogenics still need final resolution.

Stark, J. A.↗

Evaluation of the SSRCT engine with a hydrazine as a fuel, phase 1

The performance parameters for the space shuttle reaction control thruster (SSRCT) when the fuel is changed from monomethylhydrazine to hydrazine were predicted. Potential problems are higher chamber wall temperature during steady state operation and explosive events during pulse mode operation. Solutions to the problems are suggested. To conduct the analysis, a more realistic film cooling model was devised which considers that hydrazine based fuels are reactive when used as a film coolant on the walls of the combustion chamber. Hydrazine based fuels can decompose exothermally as a monopropellant and also enter into bipropellant reactions with any excess oxidizer in the combustion chamber. It is concluded that the conversion of the thruster from MMH to hydrazine fuel is feasible but that a number of changes would be required to achieve the same safety margins as the monomethylhydrazine-fueled thruster.

Minton, S. J.↗

Solar rocket system concept analysis

The use of solar energy to heat propellant for application to Earth orbital/planetary propulsion systems is of interest because of its performance capabilities. The achievable specific impulse values are approximately double those delivered by a chemical rocket system, and the thrust is at least an order of magnitude greater than that produced by a mercury bombardment ion propulsion thruster. The primary advantage the solar heater thruster has over a mercury ion bombardment system is that its significantly higher thrust permits a marked reduction in mission trip time. The development of the space transportation system, offers the opportunity to utilize the full performance potential of the solar rocket. The requirements for transfer from low Earth orbit (LEO) to geosynchronous equatorial orbit (GEO) was examined as the return trip, GEO to LEO, both with and without payload. Payload weights considered ranged from 2000 to 100,000 pounds. The performance of the solar rocket was compared with that provided by LO2-LH2, N2O4-MMH, and mercury ion bombardment systems.

Boddy, J. A.↗

Handbook on Hypergolic Propellant Discharges and Disposal

The efficiency of all treatment methods formerly or currently used in treating chemical wastes is assessed with emphasis on the disposal of hypergolic propellants. Maximum focus is on the space shuttle propellants MMH and N2O4. Except for hydrogen peroxide oxidizers, all the propellants are nitrogen based and can be potentially reduced to valuable plant nutrients. In theory, all the propellants can be reduced to carbon, hydrogen, nitrogen, and oxygen, except of fuming nitric acid which contains a small amount of fluorine. Appendices cover: (1) a general design criteria for disposal ponds; (2) thermal aspects of reaction in dilute solution; (3) gas bubble growth, detachment, and rise (4) absorption scrubber fundamentals and descriptions; (5) separation of a propellant vapor from a helium stream by permeation; and (6) atmospheric emission limits.

Bowman, T. E.↗

Monomethylhydrazine versus hydrazine fuels - Test results using a 100 pound thrust bipropellant rocket engine

A test program was performed to evaluate hydrazine (N2H4) as a fuel for a 445 Newton (100 lbf) thrust bipropellant rocket engine. Results of testing with an identical thruster utilizing monomethylhydrazine (MMH) are included for comparison. Engine performance with hydrazine fuel was essentially identical to that experienced with monomethylhydrazine although higher combustor wall temperatures (approximately 400 F) were obtained with hydrazine. Results are presented which indicate that hydrazine as a fuel is compatible with Marquardt bipropellant rocket engines which use monomethylhydrazine as a baseline fuel.

Smith, J. A.↗

Rain estimation from satellites: An examination of the Griffith-Woodley technique

The Griffith-Woodley Technique (GWT) is an approach to estimating precipitation using infrared observations of clouds from geosynchronous satellites. It is examined in three ways: an analysis of the terms in the GWT equations; a case study of infrared imagery portraying convective development over Florida; and the comparison of a simplified equation set and resultant rain map to results using the GWT. The objective is to determine the dominant factors in the calculation of GWT rain estimates. Analysis of a single day's convection over Florida produced a number of significant insights into various terms in the GWT rainfall equations. Due to the definition of clouds by a threshold isotherm the majority of clouds on this day did not go through an idealized life cycle before losing their identity through merger, splitting, etc. As a result, 85% of the clouds had a defined life of 0.5 or 1 h. For these clouds the terms in the GWT which are dependent on cloud life history become essentially constant. The empirically derived ratio of radar echo area to cloud area is given a singular value (0.02) for 43% of the sample, while the rainrate term is 20.7 mmh-1 for 61% of the sample. For 55% of the sampled clouds the temperature weighting term is identically 1.0. Cloud area itself is highly correlated (r=0.88) with GWT computed rain volume. An important, discriminating parameter in the GWT is the temperature defining the coldest 10% cloud area. The analysis further shows that the two dominant parameters in rainfall estimation are the existence of cold cloud and the duration of cloud over a point.

Negri, A. J.↗

An engineering evaluation of the Space Shuttle OMS engine after 5 orbital flights

Design features, performances on the first five flights, and condition of the Shuttle OMS engines are summarized. The engines were designed to provide a vacuum-fed 6000 lb of thrust and a 310 sec specific impulse, fueled by a combination of N2O4 and monomethylhydrazine (MMH) at a mixture ratio of 1.65. The design lifetime is 1000 starts and 15 hr of cumulative firing duration. The engine assembly is throat gimballed and features yaw actuators. No degradation of the hot components was observed during the first five flights, and the injector pattern maintained a uniform, enduring level of performance. An increase in the take-off loads have led to enhancing the wall thickness in the nozzle in affected areas. The engine is concluded to be performing to design specifications and is considered an operational system.

David, D.↗

Rain estimation from satellites - An examination of the Griffith-Woodley Technique

The Griffith-Woodley Technique (GWT) is an approach to estimating precipitation using infrared observations of clouds from geosynchronous satellites. It is examined in three ways: an analysis of the terms in the GWT equations; a case study of infrared imagery portraying convective development over Florida; and the comparison of a simplified equation set and resultant rain map to results using the GWT. The objective is to determine the dominant factors in the calculation of GWT rain estimates. Analysis of a single day's convection over Florida produced a number of significant insights into various terms in the GWT rainfall equations. Due to the definition of clouds by a threshold isotherm the majority of clouds on this day did not go through an idealized life cycle before losing their identity through merger, splitting, etc. As a result, 85 percent of the clouds had a defined life of 0.5 or 1 h. For these clouds, the terms in the GWT which are dependent on cloud life history become essentially constant. The empirically derived ratio of radar echo area to cloud area is given a singular value (0.02) for 43 percent of the sample, while the rainrate term is 20.7 mmh-1 for 61 percent of the sample. For 55 percent of the sampled clouds, the temperature weighting term is identically 1.0. Cloud area itself is highly correlated (r = 0.88) with GWT computed rain volume. An important, discriminating parameter in the GWT is the temperature defining the coldest 10 percent cloud area. The analysis further shows that the two dominant parameters in rainfall estimation are the existence of cold cloud and the duration of cloud over a point. Previously announced in STAR as N84-13735

Negri, A. J.↗

Orbital Maneuvering system design evolution

Preliminary design considerations and changes made in the baseline space shuttle orbital maneuvering system (OMS) to reduce cost and weight are detailed. The definition of initial subsystem requirements, trade studies, and design approaches are considered. Design features of the engine, its injector, combustion chamber, nozzle extension and bipropellant valve are illustrated and discussed. The current OMS consists of two identical pods that use nitrogen tetroxide (NTO) and monomethylhydrazine (MMH) propellants to provide 1000 ft/sec of delta velocity for a payload of 65,000 pounds. Major systems are pressurant gas storage and control, propellant storage supply and quantity measurement, and the rocket engine, which includes a bipropellant valve, an injector/thrust chamber, and a nozzle. The subsystem provides orbit insertion, circularization, and on orbit and deorbit capability for the shuttle orbiter.

Gibson, C.↗

Space Shuttle RCS Oxidizer Leak Repair for STS-26

Following propellant loading of the Space Shuttle's reaction control system (RCS) for mission STS 26, an oxidizer leak was detected in the left orbital maneuvering system (OMS) pod, where the RCS is located. Subsequent investigation determined that the leak was isolated at a mechanical Dynatube fitting near the RCS nitrogen tetroxide tank. An intense effort was initiated to design, fabricate, and qualify a sealing device to stop the oxidizer leak externally so that the Space Shuttle launch could proceed. It was discovered that sealing devices called clamshells were widely used throughout the petrochemical and power generation industries to stop leaks developed in large diameter pipes which carry steam or other hazardous fluids. These clamshells are available in different diameters and strengths and are placed around the pipe at the location of the leak. A sealing compound is then injected under high pressure into the clamshell to stop the leak. This technology was scaled down and applied to the problem of stopping the leak on the Orbiter, which was on a half-inch diameter line in a nearly inaccessible location. Many obstacles had to be overcome such as determining that the sealing material would be compatible with the nitrogen tetroxide and ensuring that the clamshell would actually fit around the Dynatube fitting without interfering with other lines which were in close proximity. The effort at the NASA Johnson Space Center included materials compatibility testing of several sealants, design of a clamshell to fit in the confined compartment, and manufacture and qualification of the flight hardware. A clamshell was successfully placed around the Dynatube fitting on the Orbiter and the oxidizer leak was terminated. Then it was decided to apply this technology further and design clamshells for other mechanical fittings onboard the Orbiter and develop sealing compounds which will be compatible with fuels such as monomethyl hydrazine (MMH). The potential exists for using this type of sealing device in numerous other applications throughout the aerospace industry.

Delventhal, R. A.↗

Launch vehicle performance using metallized propellants

Metallized propellant propulsion systems are considered as replacements for the solid rocket boosters and liquid sustainer stages on the current launch vehicles: both the Space Transportation System (STS) and the Titan 4. Liquid rocket boosters for the STS were analyzed as replacements for current solid rocket boosters. These boosters can provide a liquid propulsion system within the volume constraints of a solid rocket booster. A replacement for the Space Shuttle Main Engines using metallized O2/H2/Al was studied. The liquid stages of the Titan 4 were also investigated; the Aerozine-50 (A-50) fuel was replaced with metallized storable A-50/Al. A metallized propellant is similar to a traditional liquid propellant. However, it has metal particles, such as aluminum, that are suspended in a gelled fuel, such as hydrogen, RP-1, A-50 or monomethyl hydrazine (MMH). The fuels then undergo combustion with liquid oxygen or nitrogen tetroxide (NTO). These propellants provide options for increasing the performance of existing launch vehicle chemical propulsion systems by increasing fuel density or specific impulse or both. These increases in density and specific impulse can significantly reduce the propulsion system liftoff weight and allow a liquid rocket booster to fit into the same volume as an existing solid rocket booster. Also, because gelled fuels are akin to liquid propellants, metallized systems can provide enhanced controllability over solid propulsion systems. Gelling of the propellant also reduces the sensitivity to impacts and consequently reduces the propellant explosion hazard.

Palaszewski, Bryan A.↗

Launch vehicle performance using metallized propellants

Metallized propellant propulsion systems are considered as replacements for the solid rocket boosters and liquid sustainer stages on the current launch vehicles: both the Space Transportation System (STS) and the Titan 4. Liquid rocket boosters for the STS were analyzed as replacements for current solid rocket boosters. These boosters can provide a liquid propulsion system within the volume constraints of a solid rocket booster. A replacement for the Space Shuttle Main Engines using metallized 02/H2/A1 was studied. The liquid stages of the Titan 4 were also investigated; the Aerozine-50 (A-50) fuel was replaced with metallized storable A-50/A1. A metallized propellant is similar to a traditional liquid propellant. However, it has metal particles, such as aluminum, that are suspended in a gelled fuel, such as hydrogen, RP-1, A-50 or monomethyl hydrazine (MMH). The fuels then undergo combustion with liquid oxygen or nitrogen tetroxide (NTO). These propellants provide options for increasing the performance of existing launch vehicle chemical propulsion systems by increasing fuel density or specific impulse or both. These increases in density and specific impulse can significantly reduce the propulsion system liftoff weight and allow a liquid rocket booster to fit into the same volume as an existing solid rocket booster. Also, because gelled fuels are akin to liquid propellants, metallized systems can provide enhanced controllability over solid propulsion systems. Gelling of the propellant also reduces the sensitivity to impacts and consequently reduces the propellant explosion hazard.

Palaszewski, Bryan↗