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Long-range interatomic forces from thermal energy spectra, elastic scattering cross sections for atomic beams and limiting curve of dissociation
Ionization potential, dissociation energy and electron affinity for molecular oxygen
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Auroral particles induced molecular oxygen dissociation in polar upper atmosphere, relating increased ozone concentration to atmospheric IR hydroxyl emission
Molecular oxygen dissociative excitation in vacuum UV by electron impact, discussing resonance triplet atomic emission cross section
The molecular photoionization, dissociative photoionization and double photoionization cross sections for CO2 were measured from their onsets down to 90 A by using various combinations of mass spectrometers (a coincidence time-of-flight mass spectrometer and a magnetic mass spectrometer) and light sources (synchrotron radiation, and glow and spark discharge). It is concluded that the one broad peak and the three shoulders in the total adsorption cross section curve between 640 and 90 A are caused completely by dissociative ionization processes. Several peaks observed in the cross section curve for the total fragmentation CO(+)3, O(+) and C(+) are compared with those in the photoelectron spectrum reported for CO2.
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In this work we present a molecular level study of N2+N collisions, focusing on excitation of internal energy modes and non-equilibrium dissociation. The computation technique used here is the direct molecular simulation (DMS) method and the molecular interactions have been modeled using an ab−initio potential energy surface (PES) developed at NASA's Ames Research Center. We carried out vibrational excitation calculations between 5000K and 30000K and found that the characteristic vibrational excitation time for the N + N2 process was an order of magnitude lower than that predicted by the Millikan and White correlation. It is observed that during vibrational excitation the high energy tail of the vibrational energy distribution gets over populated first and the lower energy levels get populated as the system evolves. It is found that the non-equilibrium dissociation rate coefficients for the N + N2 process are larger than those for the N2 + N2 process. This is attributed to the non-equilibrium vibrational energy distributions for the N + N2 process being less depleted than that for the N2 +N2 process. For an isothermal simulation we find that the probability of dissociation goes as 1/T(sub tr) for molecules with internal energy (epsilon(sub int)) less than approximately 9.9eV, while for molecules with epsilon (sub int) greater than 9.9eV the dissociation probability was weakly dependent on translational temperature of the system. We compared non-equilibrium dissociation rate coefficients and characteristic vibrational excitation times obtained by using the ab-initio PES developed at NASA's Ames Research Center to those obtained by using an ab-initio PES developed at the University of Minnesota. Good agreement was found between the macroscopic properties and molecular level description of the system obtained by using the two PESs.
The present paper examines the role of an electrostatic field generated by the outermost monolayer of metal ions prior to gas adsorption in aiding the dissociation of homonuclear diatomic gas molecules. The interaction of five homonuclear diatomic gases, Cl 2 , F 2 , H 2 , N 2 and O 2 , with several pure metals are examined using Coulomb’s law to calculate the attractive and repulsive forces between the electrons or ions in the gas molecule and the free surface metallic electrons or ions assuming a Bohr model. These calculations demonstrate that the total energy of the electrostatic fields from the metals can exceed the molecular binding energies of Cl 2 , F 2 , and O 2 at some distance from the metallic surface thereby suggesting that these gases interact primarily with the metallic surface in their atomic states after molecular bond dissociation prior to reaction. In contrast, H 2 and N 2 gases do not dissociate prior to reaching the metal surface due to the fact that the effective charge of the gas ions is less than the total electron charge at the outermost electronic shell. The present results correlate linearly with the electrochemical series standard reduction potential as well as with the Pauling electronegativity for several metals.
Dissociation and reassociation reactions of hemocyanin mixtures analyzed by electron microscopy, noting original molecular structures
Thermal control and vacuum sealing achieved while contamination avoided. Simple, relatively inexpensive molecular-hydrogen dissociator for atomic-hydrogen masers used on Earth or in vacuum of space. No air cooling required, and absence of elastomeric O-ring seals prevents contamination. In-vacuum dissociator for atomic hydrogen masers, hydrogen gas in glass dissociator dissociated by radio-frequency signal transmitted from surrounding 3-turn coil. Heat in glass conducted away by contacting metal surfaces.
Neutral sodium emissions encircling Jupiter exhibit an intricate and variable structure that is well matched by a simple loss process from Io's atmosphere. These observations imply that fast neutral sodium is created locally in the Io plasma torus, both near Io and as much as 8 hours downstream. Sodium-bearing molecules may be present in Io's upper atmosphere, where thay are ionized by the plasma torus and swept downstream. The molecular ions dissociate and dissociatively recombine on a short time scale, releasing neutral fragments into escape trajectories from Jupiter. This theory explains a diverse set of sodium observations, and it implies that molecular reactions (particularly electron impact ionization and dissociation) are important at the top of Io's atmosphere.
Recent progress in the detection of H2 in the interstellar medium is reviewed. The hydrogen molecule is discussed in terms of properties, and collisional excitation and dissociation rates. Molecular hydrogen formation and cooling and heating by H2 are also discussed. Ultraviolet studies provided information for the study of the formation-destruction equilibrium of H2, the kinetic temperature of the cloud, the hydrogen particle density, and the ultraviolet radiation field. Infrared observations in Orion and the planetary nebula NGC 7027 reveal two detections of vibrationally excited H2. In addition, thermal and nonthermal excitation mechanisms are discussed. Finally, it is noted that increased ultraviolet sensitivity is necessary for thorough H2 studies.
The interaction of space shuttle orbiter Thermal Protection System (TPS) metals with the chemical environment to which it is exposed during reentry is considered with emphasis on the effects of dissociated oxygen. Experimental results comparing the interactions of atomic (dissociated) and molecular oxygen with five candidate shuttle TPS metals, Ni-20Cr-2ThO2, Ni-20Cr-3.5Al-2ThO2, Ni-16Cr-15Fe-2Mn-.5Si-.3La-2ThO2, Haynes Alloy Number 188, and Ti-6Al-4V at their maximum planned use temperature are presented. As measured by metal recession, weight change, rate of oxide scale formation, and scale spalling, the first four metals show enhanced degradation in a dissociated oxygen environment. The enhanced degradation appears to result from differing rates of alloy constituent reactions in the two environments. The dissociated oxygen environmental tests are found to better assess the usefulness of shuttle skin materials for the planned mission than do conventional molecular (either flowing or static) oxidation experiments.-
Dislocation rate magnitudes and relative collision frequencies influencing relaxation profiles in diatomic gases
A free radical propulsion concept utilizing the recombination energy of dissociated low molecular weight gases to produce thrust was examined. The concept offered promise of a propulsion system operating at a theoretical impulse, with hydrogen, as high as 2200 seconds at high thrust to power ratio, thus filling the gas existing between chemical and electrostatic propulsion capabilities. Microwave energy used to dissociate a continuously flowing gas was transferred to the propellant via three body recombination for conversion to propellant kinetic energy. Power absorption by the microwave plasma discharge was in excess of 90 percent over a broad range of pressures. Gas temperatures inferred from gas dynamic equations showed much higher temperatures from microwave heating than from electrothermal heating. Spectroscopic analysis appeared to corroborate the inferred temperatures of one of the gases tested.
Dissociation cross section of hydrogen molecule exchange excited by electron impact from ground to triplet state, using one-center wave functions
Previous experimental studies have hypothesized that the onset of Solar Array Arc (SAA) initiation in low-density space plasmas is caused by a desorbed gas molecular ionization mechanism. Indeed past investigations performed at the NASA Glenn Plasma Interaction Facility tend to not only support the desorbed gas molecular ionization mechanism, but have gone as far as identifying the crucial molecular species that must be present for molecular ion dominated process to occur. When electrical breakdown occurs at a triple junction site on a solar array panel, a quasi-neutral plasma cloud is ejected. Assuming the main component of the expelled plasma cloud by weight is due to water vapor, the fastest process available is due to HO molecules and OH(+) ions, or more succinctly, dissociative molecular-ion dominated recombination processes: H2O(+) + e(-) yields H* + OH*. Recently published spectroscopic observations of solar array arc spectra in ground tests have revealed the well-known molecular OH band (302 to 309nm), as well as the molecular SiH band (387nm peak), and the molecular CH band (432nm peak). Note that the OH band is observed in emission arcs where water vapor is present. Strong atomic lines were also observed for H(sub beta) at 486nm and H(sub alpha) at 656.3nm in prior ground testing. Independent supporting evidence of desorbed gas molecular ionization mechanisms also come from measurements of arc current pulse widths at different capacitances. We will revisit an earlier first order approximation demonstrating the dependence of arc current pulse widths on the square root of the capacitance. The simple arc current pulse width model will be then be used to estimate the temperature of the arc plasma (currently believed to be somewhere in the range of 3 to 5 eV). The current paper then seeks to extend the outlined work by including numerous vacuum chamber measurements obtained with a quadrupole mass spectrometer. A small solar array was mounted inside the vacuum chamber. A plasma source, also mounted inside the vacuum chamber, is used to simulate a low-density plasma environment. The solar array is then biased to a high negative potential and allowed to arc while a mass spectrometer is used to record the partial pressure of H2O and to track other significant changes in mass (1 to 150) AMU.